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11.
The paper discusses the newly produced temperature and precipitation series from instrumental observations in the Western Mediterranean (WM) area, dating back to 1654. The two series had a continuous swing and unstable coupling passing from correlation to anti-correlation. Only after 1950 are they permanently anti-correlated with increasing temperature and decreasing precipitation. It is not clear how long this coupling will persist. The analysis of the correlation between the Northern Hemisphere (NH) and the WM temperature anomalies and their trends shows a certain variability from 1850 to 1950; later a strong coupling between NH and WM. Results suggest that the WM climate is approaching a turning point that might locally oppose the adverse effects of Global Warming.  相似文献   
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The European Quaker project has been a powerful opportunity to accelerate the development of the ability to carry out earthquake simulations at reduced scale in the centrifuge in LCPC—France. This paper summarizes the main original technologies of this simulator. The quality of the checked performances is demonstrated in terms of ability to perform since earthquakes as well as to simulate scaled records of real earthquakes. The consistancy of the results is presented in the time and in the frequency domains.  相似文献   
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Over this one-year study, the variations of inorganic As species were examined monthly along the salinity gradient of the Penzé estuary (NW France) in relation with different biogeochemical parameters. In most cases, dissolved As exhibited a non-conservative behaviour which resulted from the competition between two major processes. In the upstream section of the estuary, a strong input of both total inorganic As and As(III) occurred. Then, the removal of the same species, under precipitation of iron oxides/oxyhydroxides, was observed in the low-salinity range (S < 10). Using our experimental data, the fluxes of the various As species were estimated for the first time in estuarine waters. Inputs from the river were mainly constituted of particulate As (∼70%). Conversely, dissolved species were predominant in the net fluxes (∼65%) and As(III) accounted for ∼15% of the dissolved net flux.  相似文献   
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An interaction of dissolved natural organic matter (DNOM) with copper ions in the water column of the stratified Krka River estuary (Croatia) was studied. The experimental methodology was based on the differential pulse anodic stripping voltammetric (DPASV) determination of labile copper species by titrating the sample using increments of copper additions uniformly distributed on the logarithmic scale. A classical at-equilibrium approach (determination of copper complexing capacity, CuCC) and a kinetic approach (tracing of equilibrium reconstitution) of copper complexation were considered and compared. A model of discrete distribution of organic ligands forming inert copper complexes was applied. For both approaches, a home-written fitting program was used for the determination of apparent stability constants (Kiequ), total ligands concentration (LiT) and association/dissociation rate constants (ki1,ki- 1).A non-conservative behaviour of dissolved organic matter (DOC) and total copper concentration in a water column was registered. An enhanced biological activity at the freshwater–seawater interface (FSI) triggered an increase of total copper concentration and total ligand concentration in this water layer. The copper complexation in fresh water of Krka River was characterised by one type of binding ligands, while in most of the estuarine and marine samples two classes of ligands were identified. The distribution of apparent stability constants (log K1equ: 11.2–13.0, log K2equ:8.8–10.0) showed increasing trend towards higher salinities, indicating stronger copper complexation by autochthonous seawater organic matter.Copper complexation parameters (ligand concentrations and apparent stability constants) obtained by at-equilibrium model are in very good accordance with those of kinetic model. Calculated association rate constants (k11:6.1–20 × 103 (M s)− 1, k21: 1.3–6.3 × 103 (M s)− 1) indicate that copper complexation by DNOM takes place relatively slowly. The time needed to achieve a new pseudo-equilibrium induced by an increase of copper concentration (which is common for Krka River estuary during summer period due to the nautical traffic), is estimated to be from 2 to 4 h.It is found that in such oligotrophic environment (dissolved organic carbon content under 83 µMC, i.e. 1 mgCL− 1) an increase of the total copper concentration above 12 nM could enhance a free copper concentration exceeding the level considered as potentially toxic for microorganisms (10 pM).  相似文献   
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Research conducted in the Yamé Valley (Dogon Country, Mali) provides valuable information about the river systems and their Holocene evolution in Sudano-Sahelian West Africa. Past research in the region has relied primarily on marine and lacustrine records. The new results confirm correlation between palaeoclimatic fluctuations recorded in both the river system and in tropical African lakes. They offer a new continental milestone for understanding of the environmental repercussions of Holocene monsoon oscillations. These studies demonstrate the value of river systems as a palaeoenvironmental record and the role of palaeoclimatic and anthropogenic factors in the Holocene dynamics of Sudano-Sahelian hydrosystems.  相似文献   
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Soil profiles developed on serpentinites from several localities in the Czech Republic were investigated by a combination of geochemical and mineralogical methods (selective extractions, XRD, SEM/EDS) to determine the partitioning and mobility of chromium (Cr) and nickel (Ni). Whereas Cr is released from pyroxenes, amphiboles and Cr-spinels present in the bedrock, Ni is primarily mobilized from olivines and small Fe-Ni sulphide inclusions. The results of extraction methods indicated significant differences in the availability and mobility of Cr and Ni in soils. Chromium is almost not phytoavailable, as indicated by the DTPA extractions. The selective extractions showed that Cr is tightly bound to well-crystallised Fe-oxides and primary rock-derived phases. In contrast, Ni is substantially more mobile in soil, being mainly controlled by Mn-oxides and amorphous/less crystallised Fe-oxides. The DTPA extraction indicated that up to 10% of total Ni might be phytoavailable.  相似文献   
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Over the past few years, there has been a steady increase in the interest in dry‐stone walling not only to preserve existing constructions but also to build new ones. Yet, dry masonry's expansion is slowed down by the lack of scientific knowledge to assess its reliability. This study aims at contributing to the construction of this scientific frame using a simplified model based on yield design and homogenization, which can be directly exploited for engineering purposes. A new analytical expression of the ultimate load is thus established. Then, the validity of the method is assessed by comparisons with limit equilibrium analysis, distinct element method, and field trials. Finally, possible improvements of the model are discussed. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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The oxygen isotopic composition of gem corundum was measured from 22 deposits and occurrences in Madagascar to provide a gemstone geological identification and characterization. Primary corundum deposits in Madagascar are hosted in magmatic (syenite and alkali basalt) and metamorphic rocks (gneiss, cordieritite, mafic and ultramafic rocks, marble, and calc-silicate rocks). In both domains the circulation of fluids, especially along shear zones for metamorphic deposits, provoked in situ transformation of the corundum host rocks with the formation of metasomatites such as phlogopite, sakenite, and corundumite. Secondary deposits (placers) are the most important economically and are contained in detrital basins and karsts. The oxygen isotopic ratios (18O/16O) of ruby and sapphire from primary deposits are a good indicator of their geological origin and reveal a wide range of δ18O (Vienna Standard Mean Ocean Water) between 1.3 and 15.6‰. Metamorphic rubies are defined by two groups of δ18O values in the range of 1.7 to 2.9‰ (cordieritite) and 3.8 to 6.1‰ (amphibolite). “Magmatic” rubies from pyroxenitic xenoliths contained in the alkali basalt of Soamiakatra have δ18O values ranging between 1.3 and 4.7‰. Sapphires are classified into two main groups with δ18O in the range of 4.7 to 9.0‰ (pyroxenite and feldspathic gneiss) and 10.7 to 15.6‰ (skarn in marble from Andranondambo). The δ18O values for gem corundum from secondary deposits have a wide spread between −0.3 and 16.5‰. The ruby and sapphire found in placers linked to alkali basalt environments in the northern and central regions of Madagascar have consistent δ18O values between 3.5 and 6.9‰. Ruby from the placers of Vatomandry and Andilamena has δ18O values of 5.9‰, and between 0.5 and 4.0‰, respectively. The placers of the Ilakaka area are characterized by a huge variety of colored sapphires and rubies, with δ18O values between −0.3 and 16.5‰, and their origin is debated. A comparison with oxygen isotope data obtained on gem corundum from Eastern Africa, India, and Sri Lanka is presented. Giant placer deposits from Sri Lanka, Madagascar, and Tanzania have a large variety of colored sapphires and rubies with a large variation in δ18O due to mingling of corundum of different origin: mafic and ultramafic rocks for ruby, desilicated pegmatites for blue sapphire, syenite for yellow, green, and blue sapphire, and skarn in marbles for blue sapphire.  相似文献   
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