Nuclear and incommensurate magnetic structure of NaFeGe2O6 between 5?K and 298?K and new data on multiferroic NaFeSi2O6     

G��nther J. Redhammer  Anatoliy Senyshyn  Martin Meven  Georg Roth  Sebastian Prinz  Astrid Pachler  Gerold Tippelt  Clemens Pietzonka  Werner Treutmann  Markus Hoelzel  Bj?rn Pedersen  Georg Amthauer 《Physics and Chemistry of Minerals》2011,38(2):139-157

The compound NaFeGe₂O₆ was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe₂O₆ is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO₄ tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe₂O₆ transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO₆ octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe₂O₆ with NaFeSi₂O₆ is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.  相似文献   

Eoalpine tectonics of the Eastern Alps: implications from the evolution of monometamorphic Austroalpine units (Schneeberg and Radenthein Complex)     

Kurt Krenn  Walter Kurz  Harald Fritz  Georg Hoinkes 《Swiss Journal of Geoscience》2011,104(3):471-491

Monometamorphic metasediments of Paleozoic or Mesozoic age constituting Schneeberg and Radenthein Complex experienced coherent deformation and metamorphism during Late Cretaceous times. Both complexes are part of the Eoalpine high-pressure wedge that formed an intracontinental suture and occur between the polymetamorphosed Ötztal–Bundschuh nappe system on top and the Texel–Millstatt Complex below. During Eoalpine orogeny Schneeberg and Radenthein Complexes were south-dipping and they experienced a common tectonometamorphic history from ca. 115 Ma onwards until unroofing of the Tauern Window in Miocene times. This evolution is subdivided into four distinct tectonometamorphic phases. Deformation stage D1 is characterized by WNW-directed shearing at high temperature conditions (550–600°C) and related to the initial exhumation of the high-pressure wedge. D2 and D3 are largely coaxial and evolved during high- to medium-temperature conditions (ca. 450 to ≥550°C). These stages are related to advanced exhumation and associated with large-scale folding of the high-pressure wedge including the Ötztal-Bundschuh nappe system above and the Texel–Millstatt Complex below. For the area west of the Tauern Window, F2/F3 fold interference results in the formation of large-scale sheath-folds in the frontal part of the nappe stack (formerly called “Schlingentektonik” by previous authors). Earlier thrusts were reactivated during Late Cretaceous normal faulting at the base of the Ötztal–Bundschuh nappe system and its cover. Deformation stage D4 is of Oligo-Miocene age and accounted for tilting of individual basement blocks along large-scale strike-slip shear zones. This tilting phase resulted from indentation of the Southern Alps accompanied by the formation of the Tauern Window.  相似文献   

TiO2 exsolution from garnet by open-system precipitation: evidence from crystallographic and shape preferred orientation of rutile inclusions     

Alexander Proyer  Gerlinde Habler  Rainer Abart  Richard Wirth  Kurt Krenn  Georg Hoinkes 《Contributions to Mineralogy and Petrology》2013,166(1):211-234

We investigated rutile needles with a clear shape preferred orientation in garnet from (ultra) high-pressure metapelites from the Kimi Complex of the Greek Rhodope by electron microprobe, electron backscatter diffraction and TEM techniques. A definite though complex crystallographic orientation relationship between the garnet host and rutile was identified in that Rt[001] is either parallel to Grt<111> or describes cones with opening angle 27.6° around Grt<111>. Each Rt[001] small circle representing a cone on the pole figure displays six maxima in the density plots. This evidence together with microchemical observations in TEM, when compared to various possible mechanisms of formation, corroborates a precipitate origin. A review of exchange vectors for Ti substitution in garnet indicates that rutile formation from garnet cannot occur in a closed system. It requires that components are exchanged between the garnet interior and the rock matrix by solid-state diffusion, a process we refer to as “open-system precipitation” (OSP). The kinetically most feasible reaction of this type will dominate the overall process. The perhaps most efficient reaction involves internal oxidation of Fe²⁺ to Fe³⁺ and transfer from the dodecahedral to the octahedral site just vacated by $ {\text{Ti}}^{ 4+ }: 6\,{\text{M}}^{ 2+ }_{ 3} {\text{TiAl}}\left[ {{\text{AlSi}}_{ 2} } \right]{\text{O}}_{ 1 2} + 6\,{\text{M}}^{ 2+ }_{ 2, 5} {\text{TiAlSi}}_{ 3} {\text{O}}_{ 1 2} = 10\,{\text{M}}^{ 2+ }_{ 3.0} {\text{Al}}_{ 1. 8} {\text{Fe}}_{0. 2} {\text{Si}}_{ 3} {\text{O}}_{ 1 2} + {\text{M}}^{2+} + 2 {\text{e}}^{-} + 1 2\,{\text{TiO}}_{ 2} . $ OSP is likely to occur at conditions where the transition of natural systems to open-system behaviour becomes apparent, as in the granulite and high-temperature eclogite facies.  相似文献   

Identification of maars and similar volcanic landforms in the West Eifel Volcanic Field through image processing of DTM data: efficiency of different methods depending on preservation state     

Nadine Seib  Jonas Kley  Georg Büchel 《International Journal of Earth Sciences》2013,102(3):875-901

The West Eifel Volcanic Field comprises 98 maars, tuff rings, and scoria rings of volcanoes younger than 700 ka. Digital Terrain Models (DTMs) allow to automatically measure morphologic parameters of volcanic edifices such as slope angles, diameters, elevations, floor, and slope surface areas. Based on their morphological characteristics, we subdivided the West Eifel volcanoes into five morphometric groups which reflect different stages of erosion. Group I, II, and IV comprise clear ring-shaped structures. The difference between these groups is that a tephra ring is well preserved in Group I, partially preserved in Group II and absent in Group IV. The original shapes of Group III maars have been lost more substantially than in Groups I, II, or IV, but they nevertheless retain a negative shape (a depression) and have characteristic channel systems, which can be used as search criteria. Maar-diatremes of Group V are eroded down to their feeder pipes and form hills. In order to locate potential volcanic depressions that are likely to be maar volcanoes, we defined common search criteria such as circular negative landforms or particular drainage system patterns for all groups except the least well-preserved Group V. These criteria were taken as the basis for further processing of the DTM data. The first processing step consisted of constructing a residual relief calculated as the difference between a filtered (smoothed) topographic surface and the original DTM data. This identifies local topographic features. We propose a method for regulating the degree of smoothing which is based on filtering of local maxima according to their distance from a surface constructed from local minima. The previously defined search criteria for Groups I to IV such as specific ranges of curvature, slope, circularity, density of the drainage network were then applied to the residual relief in order to extract maar shapes. Not all criteria work equally well for all morphological groups. Combinations of multiple search criteria therefore yield the best results and efficiently identify most known maars. They also separate some probable new, hitherto unrecognized maars from a large number of other local depressions. We also compared the erosional state of maars to their absolute ages. Published estimates of erosion rates for maars in the French Massif Central suggest a general trend of erosion rates decreasing with time elapsed since eruption. However, this cannot explain the strongly varying ages for maars of the same morphometric group (i.e., similar preservation state) in the West Eifel Volcanic Field. The spatial distribution of the morphometric groups shows some regularity. For example, strongly eroded maars are concentrated in the Gerolstein area (where maar density is highest), whereas most well-preserved maars are located east of the Eifel North–South Depression (ENSD). Most maars affected by fluvial erosion lie near the Kyll and Kleine Kyll streams. These observations suggest differential recent uplift of the West Eifel Volcanic Field, with stronger uplift occurring west of the ENSD.  相似文献   

Modeling the water exchanges between the Venice Lagoon and the Adriatic Sea     

Debora Bellafiore  Georg Umgiesser  Andrea Cucco 《Ocean Dynamics》2008,58(5-6):397-413

A hydrodynamic model of the Venice Lagoon and the Adriatic Sea has been developed in order to study the exchanges at the inlets of the Venice Lagoon, a complex morphological area connecting the sea and the lagoon. The model solves the shallow water equations on a spatial domain discretized by a staggered finite element grid. The grid represents the Adriatic Sea and the Venice Lagoon with different spatial resolutions varying from 30 m for the smallest channels of the lagoon to 30  km for the inner areas of the central Adriatic Sea. Data from more than ten tide gauges displaced in the Adriatic Sea have been used in the calibration of the simulated water levels. After the calibration, the tidal wave propagation in the North Adriatic and in the Venice Lagoon is well reproduced by the model. To validate the model results, empirical flux data measured by acoustic Doppler current profiler probes installed inside the inlets of Lido and Malamocco have been used and the exchanges through the three inlets of the Venice Lagoon have been analyzed. The comparison between modeled and measured fluxes at the inlets outlines the efficiency of the model to reproduce both tide- and wind-induced water exchanges between the sea and the lagoon. Even in complex areas, where highly varying resolution is needed, the model is suitable for the simulation of the dominating physical processes.  相似文献   

Multistage Variscan magmatism in the central Tauern Window (Austria) unveiled by U/Pb SHRIMP zircon data   总被引：2，自引：0，他引：2  

Roland Eichhorn  Georg Loth  Rudolf Höll  Fritz Finger  Andreas Schermaier  Allen Kennedy 《Contributions to Mineralogy and Petrology》2000,139(4):418-435

U/Pb SHRIMP ages of nine Variscan leucocratic orthogneisses from the central Tauern Window (Austria) reveal three distinct pulses of magmatism in Early Carboniferous (Visean), Late Carboniferous (Stephanian) and Early Permian, each involving granitoid intrusions and a contemporaneous opening of volcano-sedimentary basins. A similar relationship has been reported for the Carboniferous parts of the basement of the Alps further to the west, e.g. the “External massifs” in Switzerland. After the intrusion of subduction-related, volcanic-arc granitoids (374?±?10?Ma; Zwölferkogel gneiss), collisional intrusive-granitic, anatectic and extrusive-rhyolitic/dacitic rocks were produced over a short interval at ca. 340?Ma (Augengneiss of Felbertauern: 340?±?4?Ma, Hochweißenfeld gneiss: 342?± 5?Ma, Falkenbachlappen gneiss: 343?±?6?Ma). This Early Carboniferous magmatism, which produced relatively small volumes of melt, can be attributed to the amalgamation of the Gondwana-derived “Tauern Window” terrane with Laurussia–Avalonia. Probably due to the oblique nature of the collision, transtensional phenomena (i.e. volcano-sedimentary troughs and high-level intrusives) and transpressional regimes (i.e. regional metamorphism and stacked nappes with anatexis next to thrust planes) evolved contemporaneously. The magmas are mainly of the high-K I-type and may have been generated during a short phase of decompressional melting of lithospheric mantle and lower crustal sources. In the Late Carboniferous, a second pulse of magmatism occurred, producing batholiths of calc-alkaline I-type granitoids (e.g. Venediger tonalite: 296?±?4?Ma) and minor coeval bodies of felsic and intermediate volcanics (Heuschartenkopf gneiss: 299?±?4?Ma, Peitingalm gneiss: 300?±?5?Ma). Prior to this magmatism, several kilometres of upper crust must have been eroded, because volcano-sedimentary sequences hosting the Heu- schartenkopf and Peitingalm gneisses rest unconformably on 340-Ma-old granitoids. The youngest (Permian) period of magma generation contains the intrusion of the S-type Granatspitz Central Gneiss at 271?±?4?Ma and the extrusion of the rhyolitic Schönbachwald gneiss protolith at 279?±?9?Ma. These magmatic rocks may have been associated with local extension along continental wrench zones through the Variscan orogenic crust or with a Permian rifting event. The Permian and the above-mentioned Late Carboniferous volcano-sedimentary sequences were probably deposited in intra-continental graben structures, which survived post-Variscan uplift and Alpine compressional tectonics.  相似文献   

Glacial isostatic adjustment in Fennoscandia for a laterally heterogeneous earth   总被引：2，自引：0，他引：2  

Georg Kaufmann  Patrick Wu  Guoying Li 《Geophysical Journal International》2000,143(1):262-273

Glaciation and deglaciation in Fennoscandia during the last glacial cycles has significantly perturbed the Earth's equilibrium figure. Changes in the Earth's solid and geoidal surfaces due to external and internal mass redistributions are recorded in sequences of ancient coastlines, now either submerged or uplifted, and are still visible in observations of present‐day motions of the surface and glacially induced anomalies in the Earth's gravitational field. These observations become increasingly sophisticated with the availability of GPS measurements and new satellite gravity missions.
Observational evidence of the mass changes is widely used to constrain the radial viscosity structure of the Earth's mantle. However, lateral changes in earth model properties are usually not taken into account, as most global models of glacial isostatic adjustment assume radial symmetry for the earth model. This simplifying assumption contrasts with seismological evidence of significant lateral variations in the Earth's crust and upper mantle throughout the Fennoscandian region.
We compare predictions of glacial isostatic adjustment based on an ice model over the Fennoscandian region for the last glacial cycle for both radially symmetric and fully 3‐D earth models. Our results clearly reveal the importance of lateral variations in lithospheric thickness and asthenospheric viscosity for glacially induced model predictions. Relative sea‐level predictions can differ by up to 10–20 m, uplift rate predictions by 1–3 mm yr⁻¹ and free‐air gravity anomaly predictions by 2–4 mGal when a realistic 3‐D earth structure as proposed by seismic modelling is taken into account.  相似文献   

The constancy of galactic cosmic rays as recorded by cosmogenic nuclides in iron meteorites     

Thomas Smith  David L. Cook  Silke Merchel  Stefan Pavetich  Georg Rugel  Andreas Scharf  Ingo Leya 《Meteoritics & planetary science》2019,54(12):2951-2976

We measured the He, Ne, and Ar isotopic concentrations and the ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From ⁴¹Ca and ³⁶Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The ³⁶Cl‐³⁶Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The ³⁶Cl‐³⁶Ar CRE ages are on average 40% lower than the ⁴¹K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the ⁴¹K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined ⁴¹K‐K CRE age system the most likely explanation. Finally, we present new ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.  相似文献   

Experimental impact cratering: A summary of the major results of the MEMIN research unit     

Thomas Kenkmann  Alex Deutsch  Klaus Thoma  Matthias Ebert  Michael H. Poelchau  Elmar Buhl  Eva-Regine Carl  Andreas N. Danilewsky  Georg Dresen  Anja Dufresne  Nathanaël Durr  Lars Ehm  Christian Grosse  Max Gulde  Nicole Güldemeister  Christopher Hamann  Lutz Hecht  Stefan Hiermaier  Tobias Hoerth  Astrid Kowitz  Falko Langenhorst  Bernd Lexow  Hanns-Peter Liermann  Robert Luther  Ulrich Mansfeld  Dorothee Moser  Manuel Raith  Wolf Uwe Reimold  Martin Sauer  Frank Schäfer  Ralf Thomas Schmitt  Frank Sommer  Jakob Wilk  Rebecca Winkler  Kai Wünnemann 《Meteoritics & planetary science》2018,53(8):1543-1568

This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.  相似文献   

On the occurrence and origin of anthropogenic radionuclides found in a fragment of the Chelyabinsk (LL5) meteorite          下载免费PDF全文

Rebecca Querfeld  Mohammad R. Tanha  Lars Heyer  Franz Renz  Georg Guggenberger  Franz Brandstätter  Ludovic Ferrière  Christian Koeberl  Georg Steinhauser 《Meteoritics & planetary science》2017,52(6):1244-1250

A piece of the 2013 Chelyabinsk meteorite was investigated for its content of anthropogenic radionuclides. In addition to traces of cesium‐137 that had been previously reported for this particular fragment, we found an unusually high amount of strontium‐90, which indicates that the source of this contamination was the Kyshtym accident (1957). A high Sr‐90/Cs‐137 activity ratio is characteristic for Kyshtym‐derived contaminations. Based on the cesium‐137 content in the soil from the finding site, it is estimated that the fragment was contaminated with soil particles in the milligram range upon impact. Investigation of the soil revealed very unusual ferromagnetic characteristics and an iron‐rich chemical composition. Mössbauer spectroscopy indicated the presence of steel components in this soil, suggesting that the investigated meteorite fragment was found in an industrial dumping site rather than natural soil.  相似文献