Biomarkers in croakers Micropogonias furnieri (Teleostei: Sciaenidae) from polluted and non-polluted areas from the Patos Lagoon estuary (Southern Brazil): evidences of genotoxic and immunological effects     

Amado LL  da Rosa CE  Leite AM  Moraes L  Pires WV  Pinho GL  Martins CM  Robaldo RB  Nery LE  Monserrat JM  Bianchini A  Martinez PE  Geracitano LA 《Marine pollution bulletin》2006,52(2):199-206

Biomarkers of exposure and effect of pollutants were analyzed in croakers Micropogonias furnieri (Teleostei: Sciaenidae) captured in winter and summer in a polluted and in a non-polluted site at the Patos Lagoon estuary (Southern Brazil). Catalase and glutathione S-transferase activities (exposure biomarkers) and lipid peroxidation (effect biomarker) were analyzed in liver samples. Other two effect biomarkers were also studied: blood cells DNA damage (through comet assay and micronucleus test) and respiratory burst measurements. In a broad view, results point to an important seasonal variation of the biochemical biomarkers analyzed. However, data obtained clearly indicate that croakers collected in winter at the polluted site were subjected to a level of clastogenic agents sufficient to generate irreversible genetic damages (mutations) and impair the fish immune system.  相似文献   

Metabolites in bile of fish from São Sebastião Channel, São Paulo, Brazil as biomarkers of exposure to petrogenic polycyclic aromatic compounds     

da Silva DA  Buzitis J  Krahn MM  Bícego MC  Pires-Vanin AM 《Marine pollution bulletin》2006,52(2):175-183

This study reports the analysis of polycyclic aromatic compound (PAC) metabolites, as biomarkers of exposure to PACs in marine environment. PAC metabolites were measured in bile samples from 14 species of demersal fish caught in the São Sebastião Channel (SSC), SE Brazilian coastline. Naphthalene (NPH) equivalents, phenanthrene (PHN) equivalents, and benzo[a]pyrene (BaP) equivalents were quantified using a reverse-phase high-performance liquid chromatography coupled with fluorescence detection method. For all samples, the means (±standard deviation, n = 37) of concentrations obtained for NPH, PHN, and BaP equivalents were, respectively, 290,000 ± 200,000 ng/g, 18,000 ± 14,000 ng/g, and 970 ± 1900 ng/g. These results indicate recent exposure of these fish to PACs in their environment. In addition, two species (Cyclichthys spinosus and Prionotus nudigula) of fish were analyzed in order to investigate local sources of PAC contamination in the SSC and the influence of the petroleum terminal in fish caught in remote areas. The results showed that these fish species potentially migrate along the channel, especially P. nudigula. Correlations among groups of PAC metabolites indicate the same petrogenic source for NPH and PHN equivalents and a combustion source (e.g., automobile, ships) for BaP equivalents. The ratio BaP/PHN equivalents (0.05 ± 0.07, n = 37) confirms the predominance of petrogenic PACs for contamination by these chemicals in this region.  相似文献   

Gaussian Processes for history-matching: application to an unconventional gas reservoir     

Hamidreza Hamdi  Ivo Couckuyt  Mario Costa Sousa  Tom Dhaene 《Computational Geosciences》2017,21(2):267-287

The process of reservoir history-matching is a costly task. Many available history-matching algorithms either fail to perform such a task or they require a large number of simulation runs. To overcome such struggles, we apply the Gaussian Process (GP) modeling technique to approximate the costly objective functions and to expedite finding the global optima. A GP model is a proxy, which is employed to model the input-output relationships by assuming a multi-Gaussian distribution on the output values. An infill criterion is used in conjunction with a GP model to help sequentially add the samples with potentially lower outputs. The IC fault model is used to compare the efficiency of GP-based optimization method with other typical optimization methods for minimizing the objective function. In this paper, we present the applicability of using a GP modeling approach for reservoir history-matching problems, which is exemplified by numerical analysis of production data from a horizontal multi-stage fractured tight gas condensate well. The results for the case that is studied here show a quick convergence to the lowest objective values in less than 100 simulations for this 20-dimensional problem. This amounts to an almost 10 times faster performance compared to the Differential Evolution (DE) algorithm that is also known to be a powerful optimization technique. The sensitivities are conducted to explain the performance of the GP-based optimization technique with various correlation functions.  相似文献   

Numerical modelling assessment of climate-change impacts and mitigation measures on the Querença-Silves coastal aquifer (Algarve,Portugal)     

Rui Hugman  Tibor Stigter  Luis Costa  José Paulo Monteiro 《Hydrogeology Journal》2017,25(7):2105-2121

Predicted changes in climate will lead to seawater intrusion in the Querença-Silves (QS) coastal aquifer (south Portugal) during the coming century if the current water-resource-management strategy is maintained. As for much of the Mediterranean, average rainfall is predicted to decrease along with increasing seasonal and inter-annual variability and there is a need to understand how these changes will affect the sustainable use of groundwater resources. A density-coupled flow and transport model of the QS was used to simulate an ensemble of climate, water-use and adaptation scenarios from 2010 to 2099 taking into account intra- and inter-annual variability in recharge and groundwater use. By considering several climate models, bias correction and recharge calculation methods, a degree of uncertainty was included. Changes in rainfall regimes will have an immediate effect on groundwater discharge; however, the effect on saltwater intrusion is attenuated by the freshwater–saltwater interfaces’ comparatively slow rate of movement. Comparing the effects of adaptation measures demonstrates that the extent of intrusion in the QS is controlled by the long-term water budget, as the effectiveness of both demand and supply oriented measures is proportional to the change in water budget, and that to maintain the current position, average groundwater discharge should be in the order of 50 × 10⁶ m³ yr^?1.  相似文献   

Relationship between geoacoustic properties and chemical content of submarine polymetallic crusts from offshore Brazil     

Arthur Ayres Neto  Vanessa Alves da Costa  Clara Pinto Ferreira Maia Porto  Thais Cristina Vargas Garrido  Jean-Pierre Hermand 《Marine Georesources & Geotechnology》2020,38(4):437-449

Abstract

Marine mining is the ocean’s new exploration frontier, and polymetallic crusts (PMCs) and ferromanganese nodules are considered a strategic resource for the future. Acoustic geophysical methods are a valuable tool for oceanic research and have been employed for several decades in the exploration of marine resources and environmental evaluations. The main objective of this work was to investigate the correlation between the chemical composition of PMCs from three different areas along the Brazilian continental margin and their physico-acoustic attributes (P-wave velocity, density and acoustic impedance). The results show that the geoacoustic properties of PMCs are correlated to their chemical composition. Measurements showed positive and negative trends between acoustic impedance and studied elements (Fe, Mn, Co, Cu, Zn, W and Ni) according to the direction of measurement, indicting high anisotropy levels. Our study sheds initial light on the correlation between acoustic properties and metal content of PMCs. The study facilitates assessments of the acoustic responses of PMCs allowing more efficient prospection and exploitation compared to ship-board geophysical techniques that are too qualitative to identify PMCs. The results can contribute to determining the best procedures and techniques for more efficient future exploration of this resource.  相似文献   

Analyzing the spatial interactions between rainfall levels and flooding prediction in São Paulo     

Wagner da Silva Billa  Leonardo Bacelar Lima Santos  Rogério Galante Negri 《Transactions in GIS》2023,27(8):2159-2174

Rainfall is one of the primary triggers for many geological and hydrological natural disasters. While the geological events are related to mass movements in land collapse due to waterlogging, the hydrological ones are usually assigned to runoff or flooding. Studies in the literature propose predicting mass movement events as a function of accumulated rainfall levels recorded at distinct periods. According to these approaches, a two-dimensional rainfall levels feature space is segmented into the occurrence and non-occurrence decision regions by an empirical critical curve (CC). Although this scheme may easily be extended to other purposes and applications, studies in the literature need to discuss its use for flooding prediction. In light of this motivation, the present study is unfolded in (1) verifying that defining CCs in the rainfall levels feature space is a practical approach for flooding prediction and (2) analyzing how geospatial components interact with rainfall levels and flooding prediction. A database containing the rainfall levels recorded for flooding and non-flooding events in São Paulo city, Brazil, regarding the period 2015–2016, was considered in this study. The results indicate good accuracy for flooding prediction using only partial rain, which can be improved by adding physical characteristics of the flooding locations, demonstrating a direct correlation with spatial interactions, and rainfall levels.  相似文献   

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS     

Jacob Mulder  Graham Hagen-Peter  Teresa Ubide  Rasmus Andreasen  Ellen Kooijman  Melanie Kielman-Schmitt  Yue-Xing Feng  Bence Paul  Andreas Karlsson  Christian Tegner  Charles Lesher  Fidel Costa 《Geostandards and Geoanalytical Research》2023,47(2):311-336

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.  相似文献   

Vertical deformation partitioning across a collapsing large and hot orogen     

F. A. Temporim  Ricardo Ivan Ferreirae da Trindade  Marcos Egydio-Silva  Tiago Valim Angelo  Eric Tohver  Caroline Cibele Soares  Lucas Pequeno Gouvêa  Julio Cesar Mendes  Silvia Regina Medeiros  Antônio Carlos Pedrosa-Soares  Gabriel Gomes Silva 《地学学报》2023,35(1):23-31

Featuring 3 000-km-long large and hot orogen, the Mantiqueira Province provides a rare opportunity to study the process of gravitational collapse at mid to deep crustal levels. Distinct but contemporary (~500 Ma) post-collisional intrusions show structures and anisotropy of magnetic susceptibility (AMS) fabrics related to their emplacements, recording different flow patterns. In southern deep-seated intrusions, ellipsoidal-shaped roots with gabbroic-to-hybrid cores surrounded by granitic rocks show concentric patterns of AMS fabrics that cut across the NE-trending regional foliation. In contrast, northern intrusions, exposed as the upper sections of batholith-size bodies of coarse-grained granite emplaced at the shallow to mid-crust, show general NS-trending magnetic fabrics roughly parallel to strike of the orogen and the regional foliation of host rocks. These contrasting magnetic patterns from shallow to deeper crust suggest vertical magma migration from the overthickened orogenic core to be emplaced across its thinner stretched flanks during the gravitational collapse of the orogenic edifice.  相似文献   

Paleoenvironmental dynamics in central-eastern Brazil during the last 23 000 years: tropical peatland record in the Cerrado biome     

Camila Rodrigues Costa  Cynthia Fernandes Pinto da Luz  Ingrid Horák-Terra  Plínio Barbosa de Camargo  Uidemar Morais Barral  Carlos Victor Mendonça-Filho  Thamyres Sabrina Gonçalves  Alexandre Christófaro Silva 《第四纪科学杂志》2023,38(1):61-75

The Cerrado biome is the second largest in Brazil, but the evolution of the Cerrado during the late Quaternary is not yet fully known. This study identifies paleoenvironmental changes during the last 23 000 years, based on a tropical mountain peatland record, in the Serra do Espinhaço Meridional in central-eastern Brazil. A multi-proxy approach was used that involved palynological analysis, stable isotopes (δ¹³C, δ¹⁵N), geochemistry, radiocarbon dating and multivariate statistics derived from a peatland core from Rio Preto (Minas Gerais state). The study reveals a very humid and cold climate during the late Pleistocene, with an increase in temperature and decrease in humidity at the Pleistocene–Holocene transition. During this period there was strong instability in the landscape (episodes of erosion). At the beginning of the Holocene there was a reduction in humidity with greater landscape stability. The current sub-humid climatic conditions seem to have been established in the mid-/late Holocene, with periods of landscape instability. Our findings agree with other Cerrado records that contradict previously established hypotheses, such as the Amazonian Refuge and the Pleistocene Arc.  相似文献   

Hydrogeological origin of the CO2-rich mineral water of Vilajuïga in the Eastern Pyrenees (NE Catalonia,Spain)     

Mas-Pla  Josep  Brusi  David  Roqué  Carles  Soler  David  Menció  Anna  Costa  Josep M  Zamorano  Manuel  Meredith  Warren 《Hydrogeology Journal》2023,31(3):661-684

The mineral water of Vilajuïga village in Alt Empordà (NE Catalonia, Spain) owes its uniqueness to an emanation of geogenic CO₂ that modifies groundwater hydrochemistry to produce a differentiated HCO₃–Na- and CO₂-rich groundwater among the usual Ca–HCO₃ type found in this region. A hydrogeological conceptual model attributes its occurrence to the intersection of two faults: La Valleta and Garriguella-Roses. The former provides a thrust of metamorphic over igneous rocks, formed during the Paleozoic, over a layer of ampelitic shale that, from a hydrogeological perspective, acts as a confining layer. The Garriguella-Roses normal fault, which originated during the Neogene, permits the degassing of geogenic CO₂ that is attributed to volcanic activity occurring in the Neogene. Groundwater mixing from the metamorphic and igneous rock units plus the local occurrence of CO₂ creates a HCO₃–Na water that still holds free-CO₂ in solution. Interaction with the gas phase is restricted at the intersection of the two faults. Radiocarbon dating, after correcting for geogenic dead carbon, estimates an age of 8,000 years BP. The low tritium content (0.7 TU) indicates that Vilajuïga water is a mix of “older” groundwater recharged in the metamorphic rocks of the Albera range and “younger” groundwater from the igneous rocks of the Rodes range, over a recharge area of 45 km² and a maximum elevation of 600 m. Given its origin as rare groundwater in the southern slope of the Eastern Pyrenees, purposeful monitoring is necessary to evaluate the groundwater vulnerability and anticipate impacts from nearby wells and climate-change effects.

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