Li,Pb and Tl abundances in the K-alkaline rocks from the Middle Latina Valley volcanoes (southern Latium,Italy) and their petrological significance     

G. Calderoni  V. Ferrini  U. Masi 《Bulletin of Volcanology》1984,47(3):413-419

Li, Pb and Tl contents of 15 primitive lava samples from the Middle Latina Valley volcanoes (southern Latium, Italy) are higher in the high-K than in the K-Series rocks, the enrichment factors roughly following the increase of the ionic size of the elements.The abundances in both series are higher than those of typical alkali basalts from oceanic environments, but similar to those of granitoid rocks. Such anomalous features may be explained as due to either crustal contamination of the parental magmas or derivation of these latter from a lithophile-enriched mantle region due to metasomatism by a lower crust-derived fluid. In both hypotheses, however, a larger involvement of crustal materials is suggested for the HKS rocks.Comparison of Li, Pb and Tl abundances in the primitive rocks of the Middle Latina Valley and Roccamonfina volcanoes shows that, unlike the KS rocks from the two districts show comparable levels and probably originated under similar conditions, the HKS rocks from the Middle Latina Valley are enriched in Li, Pb and Tl relative to their analogues from Roccamonfina. This suggests either a higher involvement of crustal materials in their genesis, or an evolution at shallower depth in the crust.  相似文献   

Nitrogen distribution as a function of radiocarbon age in Paleosol humic acids     

G. Calderoni  M. Schnitzer 《Organic Geochemistry》1984,5(4):203-209

Humic acids were extracted from six Paleosols (buried soils), ranging in radiocarbon ages from about 6000 to 29,000 yr. The N distribution (total N, amino acid-N, amino sugar-N, ammonia-N and “unknown” N) in each Paleosol humic acid was determined. After 6 M HCl hydrolysis, amino acid-N and ammonia-N decreased with increasing age but relative concentrations of “unknown” N increased. Aspartic acid, valine and serine were the most stable amino acids. Concentrations of amino sugars were very small, with concentrations of galactosamine exceeding those of glucosamine. The data showed that with increasing age, identifiable N components were converted to complex polymeric compounds whose identities still remain unknown. The different N-forms in HA's of geological times are valuable geochemical markers which provide useful information on the history of these soils.  相似文献   

Effects of age on the chemical structure of paleosol humic acids and fulvic acids     

Gilberto Calderoni  Morris Schnitzer 《Geochimica et cosmochimica acta》1984,48(10):2045-2051

Humic acids and fulvic acids were extracted from six paleosols in Southern Italy. Humic acids (HAs) constituted between 96.5 and 99.2% of the total extracts; the remaining materials consisted of fulvic acids (FAs). Radiocarbon ages of the HAs ranged from about 6,000 to close to 29,000 years B.P., δ¹³C values averaged $\text{?25.6 ± 0.3‰}$ The HAs were characterized by chemical (elemental and functional group analyses) and spectroscopic (IR, ESR, ¹³CNMR, E₄/E₆ ratios) methods. FAs were characterized by chemical methods, E₄/E₆ ratios and IR spectra.The chemical and spectroscopic analyses showed practically no differences in the chemical structure and composition of the six HAs and FAs, so that age appeared to have little effect on these parameters. The paleosols were found to be closed systems with low polysaccharide and protein contents, thus providing unfavorable substrates for microbial activity. The preservation of the humic materials in the paleosols may have been due to low biological activity and/or to retention by amorphous minerals. The HAs did not appear to be affected by temperatures higher than 170–200°C over the 23,000 year period which we observed.  相似文献   

Using Ontologies for Integrated Geographic Information Systems   总被引：13，自引：0，他引：13  

Frederico T. Fonseca  Max J. Egenhofer  Peggy Agouris  & Gilberto Câmara 《Transactions in GIS》2002,6(3):231-257

Today, there is a huge amount of data gathered about the Earth, not only from new spatial information systems, but also from new and more sophisticated data collection technologies. This scenario leads to a number of interesting research challenges, such as how to integrate geographic information of different kinds. The basic motivation of this paper is to introduce a GIS architecture that can enable geographic information integration in a seamless and flexible way based on its semantic value and regardless of its representation. The proposed solution is an ontology-driven geographic information system that acts as a system integrator. In this system, an ontology is a component, such as the database, cooperating to fulfill the system's objectives. By browsing through ontologies the users can be provided with information about the embedded knowledge of the system. Special emphasis is given to the case of remote sensing systems and geographic information systems. The levels of ontologies can be used to guide processes for the extraction of more general or more detailed information. The use of multiple ontologies allows the extraction of information in different stages of classification. The semantic integration of aerial images and GIS is a crucial step towards better geospatial modeling.  相似文献   

On the response of flexible risers to loads imposed by hydraulic collars     

José R.M. de Sousa  Carlos Magluta  Ney Roitman  Gilberto B. Ellwanger  Edison C.P. Lima  Arnaldo Papaleo 《Applied Ocean Research》2009,31(3):157-170

Even though hydraulic collars are largely used to install flexible risers, neither the loads imposed by this equipment nor the response of the risers to these loads have been previously studied. Hence, this paper presents a three-dimensional nonlinear finite element (FE) model to predict the response of flexible risers to loads imposed by hydraulic collars and also provides a set of equations to predict these loads. The FE model relies on an analogy between helical tendons and orthotropic shells to simulate the inner carcass and the pressure armour of flexible risers. Shell elements are used to represent the polymeric layers and three-dimensional beam elements simulate the wires of the tensile armours. Material, geometric and contact nonlinearities are addressed. Contact interactions between the layers of the riser are handled by surface to surface contact elements with a contact detection algorithm based on the pinball technique and contact forces evaluated with the augmented Lagrangian method. A 9.5″ flexible riser is analyzed and the numerical results are compared to those from the experimental tests. The agreement between all results indicates that the proposed FE model is an efficient approach to predict the response of flexible risers to loads imposed by hydraulic collars and, moreover, may be used to analyze the response of such structures to other types of loads.  相似文献   

Thermal expansion and phase transitions in åkermanite and gehlenite     

Marco Merlini  Mauro Gemmi  Gilberto Artioli 《Physics and Chemistry of Minerals》2005,32(3):189-196

Thermal expansion has been measured by laboratory and synchrotron X-ray powder diffraction for end-member åkermanite (ak, Ca₂MgSi₂O₇) and gehlenite (ge, Ca₂Al₂SiO₇) in the range 20–1,500 K. In ak in the range 340–390 K, there is a negative linear thermal expansion in [001] direction. This is related to the phase transition from an incommensurate modulated structure (IC) to a normal one (N). The volumetric mean thermal expansion coefficients for ak and ge, obtained with a linear fit of the experimental data in the temperature range 298–1,400 K, are respectively 32.1×10^–6 and 28.3×10^–6 K^–1 . The variation of the c/a ratio with temperature, due to different thermal expansion along the crystallographic axes, can be related to the different behaviour of the tetrahedral layers in the N and IC phases. Analysis of the variation of the superstructure peaks intensity across the phase transition confirms the tricritical behaviour of the IC/N transition in ak.  相似文献   

Probabilistic inversion of Rayleigh-wave dispersion data: an application to Mt. Etna, Italy     

Léna Cauchie  Gilberto Saccorotti 《Journal of Seismology》2013,17(2):335-346

We present a methodology for determining the elastic properties of the shallow crust from inversion of surface wave dispersion characteristics through a fully nonlinear procedure. Using volcanic tremor data recorded by a small-aperture seismic array on Mount Etna, we measured the surface waves dispersion curves with the multiple signal classification technique. The large number of measurements allows the determination of an a priori probability density function without the need of making any assumption about the uncertainties on the observations. Using this information, we successively conducted the inversion of phase velocities using a probabilistic approach. Using a wave-number integration method, we calculated the predicted dispersion function for thousands of 1-D models through a systematic grid search investigation of shear-wave velocities in individual layers. We joined this set of theoretical dispersion curves to the experimental probability density function (PDF), thus obtaining the desired structural model in terms of an a posteriori PDF of model parameters. This process allowed the representation of the objective function, showing the non-uniqueness of the solutions and providing a quantitative view of the uncertainties associated with the estimation of each parameter. We then compared the solution with the surface wave group velocities derived from diffuse noise Green’s functions calculated at pairs of widely spaced (~5–10 km) stations. In their gross features, results from the two different approaches are comparable, and are in turn consistent with the models presented in several earlier studies.  相似文献   

Horizontal rotation signals detected by “G-Pisa” ring laser for the M w = 9.0, March 2011, Japan earthquake     

Jacopo Belfi  Nicolò Beverini  Giorgio Carelli  Angela Di Virgilio  Enrico Maccioni  Gilberto Saccorotti  Fabio Stefani  Alexander Velikoseltsev 《Journal of Seismology》2012,16(4):767-776

We report the observation of the ground rotation induced by the M _w = 9.0, 11th of March 2011, Japan earthquake. The rotation measurements have been conducted with a ring laser gyroscope operating in a vertical plane, thus detecting rotations around the horizontal axis. Comparison of ground rotations with vertical accelerations from a co-located force balance accelerometer shows excellent ring laser coupling at periods longer than 100?s. Under the plane wave assumption, we derive a theoretical relationship between horizontal rotation and vertical acceleration for Rayleigh waves. Due to the oblique mounting of the gyroscope with respect to the wave direction of arrival, apparent velocities derived from the acceleration/rotation rate ratio are expected to be always larger than or equal to the true wave propagation velocity. This hypothesis is confirmed through comparison with fundamental mode, Rayleigh-wave phase velocities predicted for a standard Earth model.  相似文献   

Experimental simulation of base‐isolated buildings pounding against moat wall and effects on superstructure response     

Armin Masroor  Gilberto Mosqueda 《地震工程与结构动力学》2012,41(14):2093-2109

Base‐isolated buildings are typically important facilities expected to remain functional after a major earthquake. However, their behavior under extreme ground shaking is not well understood. A series of earthquake simulator experiments were performed to assess performance limit states of seismically isolated buildings under strong ground motions, including pounding against a moat wall. The test setup consists of a quarter scale three‐story frame isolated at the base with friction pendulum bearings and a moat wall model. An effort was made to properly scale the strength and the stiffness of the frame relative to the bearings properties from a professionally designed isolated three‐story steel intermediate moment‐resisting frame so that realistic yielding mechanisms can be observed. The moat wall was modeled as either a rigid triangle steel stopper or a concrete wall of various thicknesses with soil backfill. The moat wall gap was set to various displacement increments to examine the sensitivity of this parameter and also to assess the effects of impact on the superstructure at different velocities. The test results indicate that the contact forces are largely dependent on the gap distance, impact velocity and wall flexibility and, in extreme cases, pounding can induce yielding in the superstructure. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

A baseline study of perfluorochemicals in Franciscana dolphin and Subantarctic fur seal from coastal waters of Southern Brazil     

Leonel J  Kannan K  Tao L  Fillmann G  Montone RC 《Marine pollution bulletin》2008,56(4):778-781

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