Experimental determination of the chromium-aluminum mixing parameter in garnet     

Glen S. Mattioli  Finley C. Bishop 《Geochimica et cosmochimica acta》1984,48(6):1367-1371

The equilibrium Grossular + Quartz = Anorthite + 2 Wollastonite was used to obtain the mixing properties of Cr and Al in grossular-uvarovite solid solutions by determining displacement of the univariant boundary curve for measured values of $\text{x}{}_{\mathrm{gross}}{}^{\mathrm{gt}}$. Experiments were performed in a piston cylinder apparatus with initial garnet compositions Gr₁₀₀, Gr₈₀Uv₅₀, Gr₅₀Uv₅₀, and Gr₂₀Uv₈₀. Reversals were obtained in the temperature range 1040°C–1320°C and corrected pressure range 10–17 kbar. Results indicate that grossular-uvarovite solutions can be modeled as nearly ideal two-site solid solutions. W_G^Cr,Al of +200 to + 1000 cal/mole is consistent with our experimental results.  相似文献   

Lead in corals: reconstruction of historical industrial fluxes to the surface ocean     

Glen T. Shen  Edward A. Boyle 《Earth and Planetary Science Letters》1987,82(3-4)

Twentieth century environmental lead chronologies for the western North Atlantic, Pacific, and Indian Oceans have been reconstructed from annually-banded scleractinian corals. Measurements of lattice-bound Pb in sequential coral bands reveal temporal changes in surface water Pb concentrations and Pb isotopic distributions. Perturbations are observable in all specimens studied, attesting to global augmentation of environmental Pb by industrialization.In the western North Atlantic, Pb perturbations have occurred in direct response to the American industrial revolution and the subsequent introduction and phasing-out of alkyl Pb additives in gasoline. Surface ocean conditions near Bermuda may be reliably reconstructed from the coral data via a lead distribution coefficient of 2.3 for the species,Diploria strigosa. Based on²¹⁰Pb measurements, a similar distribution coefficient may be characteristic of corals in general. Surface Pb concentrations in the pre-industrial Sargasso Sea were about 15–20 pM. Concentrations rose to near 90 pM by 1923 as a result of metals manufacture and fossil fuel combustion. Beginning in the late 1940's, increased utilization of leaded gasoline eventually led to a peak concentration of 240 pM in 1971, representing an approximate 15-fold increase over background. Surface ocean concentrations are presently declining rapidly (128 pM in 1984) as a result of curtailed alkyl Pb usage. Lead isotopic shifts parallel the concentration record indicating that characteristic industrial and alkyl Pb source signatures have not changed appreciably in time. Industrial releases recorded in the Florida Keys reflect a weaker source and evidence of recirculated Pb (5–6 years old) from the North Atlantic subtropical gyre. An inferred background concentration of 38 pM suggests influence of shelf and/or resuspended inputs of Pb to these coastal waters.In remote areas of the South Pacific and Indian Oceans, industrial signals are fainter and the corals studied much younger than their Atlantic counterparts. Contemporary Pb concentrations implied by coral measurements (assumingK_D = 2.3) are 40–50 pM for surface waters near Tutuila and Galapagos in the South Pacific, and 25–29 pM near Mauritius in the Indian Ocean. A single coral band from Fiji (1920 ± 5yr) implies a pre-industrial surface water concentration of 16–19 pM Pb for the South Pacific. In view of reported surface water measurements and the North Atlantic coral data, the Pacific coral extrapolations may be slightly high. This could be a result of small variations inK_D among different coral genera, or incorporation of diagenetic Pb by corals sampled in coastal environments.  相似文献   

Conditioning Geologic Models to Local Continuity Azimuth in Spectral Simulation     

Tingting Yao  Craig Calvert  Tom Jones  Lincoln Foreman  Glen Bishop 《Mathematical Geology》2007,39(3):349-354

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Transitional palaeomagnetic field at the terminius of the Mammoth Reverse Subchron (3.05 Ma)     

Joseph C. Liddicoat  Jonathan M. Glen  Robert S. Coe 《Surveys in Geophysics》1996,17(2):183-188

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Sediment toxicity in the Hudson-Raritan estuary: Distribution and correlations with chemical contamination     

Douglas A. Wolfe  Edward R. Long  Glen B. Thursby 《Estuaries and Coasts》1996,19(4):901-912

The Hudson-Raritan Estuary is one of several United States coastal areas where chemical data have suggested a potential for contaminant-related biological effects, and multiyear intensive bioeffects surveys have been conducted by the National Oceanic and Atmospheric Administration. The severity and spatial patterns in sediment toxicity were determined in an estuary-wide survey during spring 1991 using amphipods, bivalve larvae, and luminescent bacteria as test organisms. Spatial patterns in toxicity corresponded to the distributions of a number of toxic chemicals in the sediments. Areas that exhibited the greatest sediment toxicity included the upper East River, Arthur Kill, Newark Bay, and Sandy Hook Bay. The lower Hudson River adjacent to Manhattan Island, upper New York Harbor, lower New York Harbor off Staten Island, and parts of western Raritan Bay generally showed lower toxicity. Supporting chemical analyses of the sediments, including acid-volatile sulfide and simultaneously-extracted metals, suggested that metals were generally not the cause of the observed toxicity, with the possible exception of mercury. Among all contaminants analyzed, toxicity was most strongly associated with polynuclear aromatic hydrocarbons, which were substantially more concentrated in toxic samples than in nontoxic samples, and which frequently exceeded sediment quality criteria.  相似文献   

Steady state hodographs in a baroclinic boundary layer     

MacKay  Kenneth P. 《Boundary-Layer Meteorology》1971,2(2):161-168

If the steady-state geostrophic wind vector varies exponentially with height in the planetary boundary layer, calculated hodographs of the 24-hour mean wind resemble the classic Ekman spiral distorted by thermal effects. For such an assumed distribution, Lettau's (1967) conclusion that the effects of thermal influence on the steady-state boundary-layer winds can be linearly superimposed on the effects of internal friction is justified.The minimum value of the cross-isobar angle of the surface wind for a given magnitude of the thermal wind vector occurs when that vector points about 345° to the right of the surface geostrophic wind vector and the maximum value occurs when it points at an azimuth of about 120° relative to the surface geostrophic wind vector. The range of values of the cross-isobar angle is almost directly proportional to the magnitude of the thermal wind vector.Hodographs resulting from the assumed variation of the geostrophic wind have approximately the same shape as 24-hour mean hodographs at two locations over the Great Plains.This work is part of a thesis submitted to the University of Wisconsin in partial fulfillment of the requirements for the Ph.D. Degree, written under the supervision of Professor H. Lettau, Department of Meteorology.  相似文献   

Linking Ecotourism and Biodiversity Conservation: A Case Study of Doi Inthanon National Park, Thailand     

Glen T. Hvenegaard  & Philip Dearden 《Singapore journal of tropical geography》1998,19(2):193-211

Ecotourism, or tourism that promotes conservation, does not occur in isolation, but as part of an interdependent system. Based on a case study at Doi Inthanon National Park, Thailand, this study outlines a conceptual framework for such a system, placing biodiversity conservation in the context of other major tourism components, including tourists, ecotourism infrastructure, protected areas and local people. In an interactive way, each component affects the conservation of biodiversity. Based on a tourist survey and participant observation, we examine the interrelationships among the key tourism components and potential changes over time. Several environmental, social, economic and educational effects illustrate the complex nature of the ecotourism-conservation relationship. Recommendations to increase conservation benefits from ecotourism are provided.  相似文献   

Climatic control on river discharge simulations,Zackenberg River drainage basin,northeast Greenland     

Sebastian H. Mernild  Bent Hasholt  Glen E. Liston 《水文研究》2008,22(12):1932-1948

A spatially distributed, physically based, hydrologic modeling system (MIKE SHE) was applied to quantify intra‐ and inter‐annual discharge from the snow and glacierized Zackenberg River drainage basin (512 km²; 20% glacier cover) in northeast Greenland. Evolution of snow accumulation, distribution by wind‐blown snow, blowing‐snow sublimation, and snow and ice surface melt were simulated by a spatially distributed, physically based, snow‐evolution modelling system (SnowModel) and used as input to MIKE SHE. Discharge simulations were performed for three periods 1997–2001 (calibration period), 2001–2005 (validation period), and 2071–2100 (scenario period). The combination of SnowModel and MIKE SHE shows promising results; the timing and magnitude of simulated discharge were generally in accordance with observations (R² = 0·58); however, discrepancies between simulated and observed discharge hydrographs do occur (maximum daily difference up to 44·6 m³ s^?1 and up to 9% difference between observed and simulated cumulative discharge). The model does not perform well when a sudden outburst of glacial dammed water occurs, like the 2005 extreme flood event. The modelling study showed that soil processes related to yearly change in active layer depth and glacial processes (such as changes in yearly glacier area, seasonal changes in the internal glacier drainage system, and the sudden release of glacial bulk water storage) need to be determined, for example, from field studies and incorporated in the models before basin runoff can be quantified more precisely. The SnowModel and MIKE SHE model only include first‐order effects of climate change. For the period 2071–2100, future IPCC A2 and B2 climate scenarios based on the HIRHAM regional climate model and HadCM3 atmosphere–ocean general circulation model simulations indicated a mean annual Zackenberg runoff about 1·5 orders of magnitude greater (around 650 mmWE year^?1) than from today 1997–2005 (around 430 mmWE year^?1), mainly based on changes in negative glacier net mass balance. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Transient climate changes in a perturbed parameter ensemble of emissions-driven earth system model simulations     

James M. Murphy  Ben B. B. Booth  Chris A. Boulton  Robin T. Clark  Glen R. Harris  Jason A. Lowe  David M. H. Sexton 《Climate Dynamics》2014,43(9-10):2855-2885

We describe results from a 57-member ensemble of transient climate change simulations, featuring simultaneous perturbations to 54 parameters in the atmosphere, ocean, sulphur cycle and terrestrial ecosystem components of an earth system model (ESM). These emissions-driven simulations are compared against the CMIP3 multi-model ensemble of physical climate system models, used extensively to inform previous assessments of regional climate change, and also against emissions-driven simulations from ESMs contributed to the CMIP5 archive. Members of our earth system perturbed parameter ensemble (ESPPE) are competitive with CMIP3 and CMIP5 models in their simulations of historical climate. In particular, they perform reasonably well in comparison with HadGEM2-ES, a more sophisticated and expensive earth system model contributed to CMIP5. The ESPPE therefore provides a computationally cost-effective tool to explore interactions between earth system processes. In response to a non-intervention emissions scenario, the ESPPE simulates distributions of future regional temperature change characterised by wide ranges, and warm shifts, compared to those of CMIP3 models. These differences partly reflect the uncertain influence of global carbon cycle feedbacks in the ESPPE. In addition, the regional effects of interactions between different earth system feedbacks, particularly involving physical and ecosystem processes, shift and widen the ESPPE spread in normalised patterns of surface temperature and precipitation change in many regions. Significant differences from CMIP3 also arise from the use of parametric perturbations (rather than a multimodel ensemble) to represent model uncertainties, and this is also the case when ESPPE results are compared against parallel emissions-driven simulations from CMIP5 ESMs. When driven by an aggressive mitigation scenario, the ESPPE and HadGEM2-ES reveal significant but uncertain impacts in limiting temperature increases during the second half of the twenty-first century. Emissions-driven simulations create scope for development of errors in properties that were previously prescribed in coupled ocean–atmosphere models, such as historical CO₂ concentrations and vegetation distributions. In this context, historical intra-ensemble variations in the airborne fraction of CO₂ emissions, and in summer soil moisture in northern hemisphere continental regions, are shown to be potentially useful constraints, subject to uncertainties in the relevant observations. Our results suggest that future climate-related risks can be assessed more comprehensively by updating projection methodologies to support formal combination of emissions-driven perturbed parameter and multi-model earth system model simulations with suitable observational constraints. This would provide scenarios underpinned by a more complete representation of the chain of uncertainties from anthropogenic emissions to future climate outcomes.  相似文献   

A 2000-yr reconstruction of air temperature in the Great Basin of the United States with specific reference to the Medieval Climatic Anomaly   总被引：1，自引：0，他引：1  

Scott A. Reinemann  David F. Porinchu  Glen M. MacDonald  Bryan G. Mark  James Q. DeGrand 《Quaternary Research》2014

A sediment core representing the past two millennia was recovered from Stella Lake in the Snake Range of the central Great Basin in Nevada. The core was analyzed for sub-fossil chironomids and sediment organic content. A quantitative reconstruction of mean July air temperature (MJAT) was developed using a regional training set and a chironomid-based WA-PLS inference model (r²_jack = 0.55, RMSEP = 0.9°C). The chironomid-based MJAT reconstruction suggests that the interval between AD 900 and AD 1300, corresponding to the Medieval Climate Anomaly (MCA), was characterized by MJAT elevated 1.0°C above the subsequent Little Ice Age (LIA), but likely not as warm as recent conditions. Comparison of the Stella Lake temperature reconstruction to previously published paleoclimate records from this region indicates that the temperature fluctuations inferred to have occurred at Stella Lake between AD 900 and AD 1300 correspond to regional records documenting hydroclimate variability during the MCA interval. The Stella Lake record provides evidence that elevated summer temperature contributed to the increased aridity that characterized the western United States during the MCA.  相似文献