Determining hydrologic pathways of streamflow using geochemical tracers in a claypan watershed     

Fengjing Liu  Robert N. Lerch  John Yang  Greg Peters 《水文研究》2020,34(11):2494-2509

Despite the low permeability of claypan soils, groundwater has been heavily contaminated by nitrate in agricultural watersheds dominated by claypan soils. However, it is unclear how nitrate concentrations in groundwater affect stream water quality. In this study, streamflow pathways were investigated using natural geochemical tracers in the 73-km² Goodwater Creek Experimental Watershed in northeastern Missouri. Samples were collected from 2011 to 2017 from stream water (weekly-biweekly), precipitation (event-based), groundwater in 25 wells with screened depths varying from 2 to 16 m (bimonthly–seasonal) and interflow above the claypan in 7 shallow piezometers (weekly–monthly). The results of endmember mixing analysis using major ions indicate that streamflow was dominated by near-surface runoff (59 ± 20%), followed by interflow (25 ± 16%) and groundwater (16 ± 13%). Analysis of endmember distances using the mixing space defined by stream water chemistry suggests that groundwater contributions to streamflow came primarily from the intermediate to deep glacial till aquifer near and below 8 m. Near-surface runoff was persistent and dominant even after isolated precipitation events during a prolonged dry period. It is hypothesised that the alluvial aquifer near stream banks acts as a mixing zone to receive and store various source waters, resulting in persistent delivery of runoff to the stream. Groundwater, even though its contribution was limited, plays a significant role in regulating streamflow NO₃⁻ concentrations. This study significantly improves our understanding of claypan hydrology and will lead to the development of models and decision support tools for implementation of management practices that improve groundwater and stream water quality in restrictive layer watersheds.  相似文献   

Experimental phase and melting relations of metapelite in the upper mantle: implications for the petrogenesis of intraplate magmas     

Carl Spandler  Greg Yaxley  David H. Green  Dean Scott 《Contributions to Mineralogy and Petrology》2010,160(4):569-589

We performed a series of piston-cylinder experiments on a synthetic pelite starting material over a pressure and temperature range of 3.0–5.0 GPa and 1,100–1,600°C, respectively, to examine the melting behaviour and phase relations of sedimentary rocks at upper mantle conditions. The anhydrous pelite solidus is between 1,150 and 1,200°C at 3.0 GPa and close to 1,250°C at 5.0 GPa, whereas the liquidus is likely to be at 1,600°C or higher at all investigated pressures, giving a large melting interval of over 400°C. The subsolidus paragenesis consists of quartz/coesite, feldspar, garnet, kyanite, rutile, ±clinopyroxene ±apatite. Feldspar, rutile and apatite are rapidly melted out above the solidus, whereas garnet and kyanite are stable to high melt fractions (>70%). Clinopyroxene stability increases with increasing pressure, and quartz/coesite is the sole liquidus phase at all pressures. Feldspars are relatively Na-rich [K/(K + Na) = 0.4–0.5] at 3.0 GPa, but are nearly pure K-feldspar at 5.0 GPa. Clinopyroxenes are jadeite and Ca-eskolaite rich, with jadeite contents increasing with pressure. All supersolidus experiments produced alkaline dacitic melts with relatively constant SiO₂ and Al₂O₃ contents. At 3.0 GPa, initial melting is controlled almost exclusively by feldspar and quartz, giving melts with K₂O/Na₂O ~1. At 4.0 and 5.0 GPa, low-fraction melting is controlled by jadeite-rich clinopyroxene and K-rich feldspar, which leads to compatible behaviour of Na and melts with K₂O/Na₂O ≫ 1. Our results indicate that sedimentary protoliths entrained in upwelling heterogeneous mantle domains may undergo melting at greater depths than mafic lithologies to produce ultrapotassic dacitic melts. Such melts are expected to react with and metasomatise the surrounding peridotite, which may subsequently undergo melting at shallower levels to produce compositionally distinct magma types. This scenario may account for many of the distinctive geochemical characteristics of EM-type ocean island magma suites. Moreover, unmelted or partially melted sedimentary rocks in the mantle may contribute to some seismic discontinuities that have been observed beneath intraplate and island-arc volcanic regions.  相似文献   

Hydrologic Sensitivity of Global Rivers to Climate Change   总被引：12，自引：1，他引：12  

Bart Nijssen  Greg M. O'Donnell  Alan F. Hamlet  Dennis P. Lettenmaier 《Climatic change》2001,50(1-2):143-175

Climate predictions from four state-of-the-art general circulation models (GCMs) were used to assess the hydrologic sensitivity to climate change of nine large, continental river basins (Amazon, Amur, Mackenzie, Mekong, Mississippi, Severnaya Dvina, Xi, Yellow, Yenisei). The four climate models (HCCPR-CM2, HCCPR-CM3, MPI-ECHAM4, and DOE-PCM3) all predicted transient climate response to changing greenhouse gas concentrations, and incorporated modern land surface parameterizations. Model-predicted monthly average precipitation and temperature changes were downscaled to the river basin level using model increments (transient minus control) to adjust for GCM bias. The variable infiltration capacity (VIC) macroscale hydrological model (MHM) was used to calculate the corresponding changes in hydrologic fluxes (especially streamflow and evapotranspiration) and moisture storages. Hydrologic model simulations were performed for decades centered on 2025 and 2045. In addition, a sensitivity study was performed in which temperature and precipitation were increased independently by 2 °C and 10%, respectively, during each of four seasons. All GCMs predict a warming for all nine basins, with the greatest warming predicted to occur during the winter months in the highest latitudes. Precipitation generally increases, but the monthly precipitation signal varies more between the models than does temperature. The largest changes in the hydrological cycle are predicted for the snow-dominated basins of mid to higher latitudes. This results in part from the greater amount of warming predicted for these regions, but more importantly, because of the important role of snow in the water balance. Because the snow pack integrates the effects of climate change over a period of months, the largest changes occur in early to mid spring when snow melt occurs. The climate change responses are somewhat different for the coldest snow dominated basins than for those with more transitional snow regimes. In the coldest basins, the response to warming is an increase of the spring streamflow peak, whereas for the transitional basins spring runoff decreases. Instead, the transitional basins have large increases in winter streamflows. The hydrological response of most tropical and mid-latitude basins to the warmer and somewhat wetter conditions predicted by the GCMs is a reduction in annual streamflow, although again, considerable disagreement exists among the different GCMs. In contrast, for the high-latitude basins increases in annual flow volume are predicted in most cases.  相似文献   

    

Lance M. Leslie  Greg J. Holland  Peter J. Webster 《Meteorology and Atmospheric Physics》1995,56(1-2):1

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Noble-gas-rich separates from the Allende meteorite     

Ulrich Ott  Ruth Mack 《Geochimica et cosmochimica acta》1981,45(10):1751-1788

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Hydrogeology of the Sierra Nevada Foothill Lineament Near Oakhurst, California     

Seymour Mack  Kenneth D. Schmidt 《Ground water》1981,19(2):149-155

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Sulfur geochemistry of hydrothermal waters in Yellowstone National Park,Wyoming, USA. III. An anion-exchange resin technique for sampling and preservation of sulfoxyanions in natural waters     

Greg?K?Druschel  Martin?AA?SchoonenEmail author  D?Kirk?Nordstrom  James?W?Ball  Yong?Xu  Corey?A?Cohn 《Geochemical transactions》2003,4(1):12

A sampling protocol for the retention, extraction, and analysis of sulfoxyanions in hydrothermal waters has been developed in the laboratory and tested at Yellowstone National Park and Green Lake, NY. Initial laboratory testing of the anion-exchange resin Bio-Rad™ AG1-X8 indicated that the resin was well suited for the sampling, preservation, and extraction of sulfate and thiosulfate. Synthetic solutions containing sulfate and thiosulfate were passed through AG1-X8 resin columns and eluted with 1 and 3 M KCl, respectively. Recovery ranged from 89 to 100%. Comparison of results for water samples collected from five pools in Yellowstone National Park between on-site IC analysis (U.S. Geological Survey mobile lab) and IC analysis of resin-stored sample at SUNY-Stony Brook indicates 96 to 100% agreement for three pools (Cinder, Cistern, and an unnamed pool near Cistern) and 76 and 63% agreement for two pools (Sulfur Dust and Frying Pan). Attempts to extract polythionates from the AG1-X8 resin were made using HCl solutions, but were unsuccessful. Bio-Rad™ AG2-X8, an anion-exchange resin with weaker binding sites than the AG1-X8 resin, is better suited for polythionate extraction. Sulfate and thiosulfate extraction with this resin has been accomplished with KCl solutions of 0.1 and 0.5 M, respectively. Trithionate and tetrathionate can be extracted with 4 M KCl. Higher polythionates can be extracted with 9 M hydrochloric acid. Polythionate concentrations can then be determined directly using ion chromatographic methods, and laboratory results indicate recovery of up to 90% for synthetic polythionate solutions using AG2-X8 resin columns.  相似文献   

Late Pleistocene (Last Interglacial) terrace deposits, Bahia Coyote, Baja California Sur, México     

Teresa DeDiego- Forbis  Robert Douglas  Donn Gorsline  Enrique Nava-Sanchez  Larry Mack  Jay Banner 《Quaternary International》2004,120(1):29

Late Pleistocene age terrace deposits are exposed in the narrow cliffed coastal plain of Bahia Coyote, Baja California Sur, resting unconformably on the lagoonal-shallow water volcaniclastics of the early Miocene Cerro Colorado Member of the El Cien Formation. The terrace is dissected by widely spaced arroyos and partically covered by alluvial fans in the inner and central areas. The marine deposits vary in thickness from 0.5 to 10 m and were laid down in pre-existing erosional channels and depressions in the Pleistocene landscape. The sequence begins with a cobble conglomerate with oyster shells, overlain by poorly bedded molluscan-rich bioclastic sands and coral rubble, beds of massive Porites in growth position and coral-rhodolith sands and marls. Beach sands and gravels and coastal dunes cap the sequence.Samples of Porites panamensis selected for U/Th dating are well-preserved aragonite (>95%). Preliminary results yield U/Th ages of 109–209 ka but the corals have initial δ ²³⁴U values in excess of modern seawater values. This indicates open-system behavior and uncertainty associated with the ages. A corrected age for the top of the massive Porites unit suggests that the corals grew during the last interglacial, marine isotope stage (MIS) 5e sea level high stand.Assuming global sea level during MIS 5e was ca. 4–5 m above present-day sea level (McCulloch and Esat, 2000) and the growth position of the corals was 1–5 m below sea level, the terraces have been uplifted between 12 and 25 m (12–15 cm/kyr). This is consistent with other terrace-based uplift rates for the central Baja California peninsula, north of the La Paz fault.  相似文献   

Inhabiting the Imaginary: Factory Women at Home on Batam Island, Indonesia     

Jennifer Mack 《Singapore journal of tropical geography》2004,25(2):156-179

Batam Island, Indonesia, located a short ferry ride away from Singapore, is a place where tourism and industry have been developed simultaneously and a border area where “developed” and “developing” nations meet. Government officials, investing international corporations and the “factory women” who work in the island's industrial estates arrive in Batam ‐ native to none of them ‐ with their own preconceptions and goals. When challenges not foreseen through master planning arise, the authorities cling ever more tightly to their physical and structural development model: the nearby city‐state of Singapore. Conversely, the factory workers who travel intranationally to work in this export processing zone (EPZ) find their objectives contested in the face of the Master Plan, corporate agendas and ethnic fusions characterising this transnational capitalist space. Entering into the homes of three groups of women migrants living and working in Batam, the relationship between the private realm that they inhabit and the social contexts in which they participate publicly is investigated. Some of the choices that women make at and about home are identified, and their ability to “micro‐resist” these external structures is explored. At home, the dynamic relationship between the Batam development project and the women's own hopes and visions of the place ‐ sometimes parallel and sometimes incongruous ‐ are revealed. As they experience life on Batam, their “social imaginaries” of it are shaped into various new realities, and their homes, removed from the confines of the factory floor, thus become spaces of release from these tensions.  相似文献   

Bar-top hollows: A new element in the architecture of sandy braided rivers     

Jim Best  John Woodward  Phil Ashworth  Greg Sambrook Smith  Chris Simpson 《Sedimentary Geology》2006,190(1-4):241-255

Discrete hollows in the bar tops of the South Saskatchewan River are described that form a newly-recognized morphological element of sandy braided rivers. These bar-top hollows, which are up to 1.7 m deep and may extend for 10–30 m down and across flow, have a circular to ovoid planform and are shown, through use of ground penetrating radar, to be filled by a series of distinct, often angle-of-repose, foresets. The hollows form by both erosion and bar-top deposition and may be generated by bar-tail accretion, cross-bar channel cutoff and subsequent fill or lateral accretion at the bar-head. Bar-top hollows occur in the upper part of the bar depositional sequence and may thus prove useful indicators for braid bar reconstruction in ancient sediments, and should not be confused with channel scour.  相似文献