Biosorption of cadmium(II), lead(II) and cobalt(II) from aqueous solution by biochar from cones of larch (<Emphasis Type="Italic">Larix decidua</Emphasis> Mill. <Emphasis Type="Italic">subsp. decidua</Emphasis>) and spruce (<Emphasis Type="Italic">Picea abies</Emphasis> L. H. Karst)     

Bogdan Saletnik  Grzegorz Zaguła  Dorota Grabek-Lejko  Idalia Kasprzyk  Marcin Bajcar  Maria Czernicka  Czesław Puchalski 《Environmental Earth Sciences》2017,76(16):574

Because of their physicochemical properties, biochars can be used as sorption materials for removal of toxic substances. The purpose of the present study was to determine whether biochar obtained from cones of larch (Larix decidua Mill. subsp. decidua) and spruce (Picea abies L. H. Karst) could be used as a sorbent for Cd²⁺, Pb²⁺ and Co²⁺ in aqueous solutions. So far, this feedstock had not been tested in this respect. The material was subjected to pyrolysis at 500 and 600 °C for the duration of 5, 10 and 15 min. The obtained pyrolysates were found to differ in terms of pH and the contents of the essential macroelements. The different values of these parameters were determined for varying temperature, duration of the pyrolysis process and type of feedstock. Sorption capacities of the biochars for removal of Cd²⁺, Pb²⁺ and Co²⁺ were examined using simulated contamination of aqueous solutions with salts of these metals. The findings showed the highest, nearly complete, removal for Pb²⁺ were maximum 99.7%, and almost three times lower value for Cd²⁺ and Co²⁺ (respectively, 35.7 and 24.8%). It was demonstrated that pyrolysis of conifer cones produced optimum sorption capacities when the process was conducted at a temperature of 500 °C for the duration of 5 min. It was shown that products of spruce cone pyrolysis were characterized by better sorption capacity in comparison with products of larch cone pyrolysis. The properties of conifer cone biochar create the possibility of using it as an adsorbent in water and wastewater treatment as well as in production of filters and activated carbon.  相似文献   

Mining Induced Seismic Event on an Inactive Fault     

Grzegorz Lizurek  Łukasz Rudziński  Beata Plesiewicz 《Acta Geophysica》2015,63(1):176-200

On 19 March 2013, a tremor shook the surface of Polkowice town where the Rudna Mine is located. This event, of ML = 4.2, was the third most powerful seismic event recorded in the Legnica G?ogów Copper District (LGCD). Inhabitants of the area reported that the felt tremor was bigger and lasted longer than any other ones felt in the last couple of years. Analysis of spectral parameters of the records from in-mine seismic system and surface LUMINEOS network along with broadband station KSP record were carried out. The location of the event was close to the Rudna G?ówna Fault zone; the nodal planes orientations determined with two different approaches were almost parallel to the strike of the fault. The mechanism solutions were also obtained as Full Moment Tensor from P-wave amplitude pulses of underground records and waveform inversion of surface network seismograms. The results from the seismic analysis along with macroseismic survey and observed effects from the destroyed part of the mining panel indicate that the mechanism of the event was complex rupture initiated as thrust faulting on an inactive tectonic normal fault zone. The results confirm that the fault zones are the areas of higher risk, even in case of carefully taken mining operations.  相似文献   

OSL‐based chronostratigraphy of river terraces in mountainous areas,Dunajec basin,West Carpathians: a revision of the climatostratigraphical approach          下载免费PDF全文

Janusz Olszak  Grzegorz Adamiec 《Boreas: An International Journal of Quaternary Research》2016,45(3):483-493

The technique of optically stimulated luminescence (OSL) dating applied to fluvial sediments provided a geochronological framework of river terrace formation in the middle part of the Dunajec River basin – a reference area for studies of evolution of river valleys in the northern part of the Carpathians (West Carpathians). Fluvial sediments at 18–90 m above valley bottoms were dated in the valleys of the Dunajec River and one of its tributaries. The resulting ages range from 158.9±8.3 to 12.2±1.3 ka. This indicates that some of the terrace sediments were deposited much later than previously assumed on the grounds of a combined morphostratigraphical and climatostratigraphical approach. The OSL‐based chronostratigraphy of terrace formation consists of seven separate phases of fluvial aggradation, separated by periods of incision and lateral erosion. Some of the ages determined correspond to warm stages of the Pleistocene – Marine Isotope Stage 3 (MIS 3) and MIS 5 – demonstrating that some terraces were formed during interstadial or interglacial periods. The results provide a key for evaluating rates of neotectonic uplift, allowing us to decipher the response of a fluvial system to climate change within the context of the glacial–interglacial scheme.  相似文献   

Heterochromatin and NOR location in northern pike (Esox lucius)   总被引：2，自引：0，他引：2  

Malgorzata Jankun  Pawel Woznicki  Grzegorz Dajnowicz  Krystyna Demska-Zakes  Marek J. Luczynski  Miroslaw Luczynski 《Aquatic Sciences - Research Across Boundaries》1998,60(1):17-21

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Infragravity waves at a dissipative coast; evidence upon multi-resolution analysis     

Grzegorz Różyński 《Coastal Engineering》2007

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Comparative study of radiation-induced damage in magnesium aluminate spinel by means of IL,CL and RBS/C techniques     

Iwona Jozwik  Jacek Jagielski  Grzegorz Gawlik  Przemyslaw Jozwik  Renata Ratajczak  Gerard Panczer  Nathalie Moncoffre  Anna Wajler  Agata Sidorowicz  Lionel Thomé 《Physics and Chemistry of Minerals》2016,43(6):439-445

A comparative study of damage accumulation in magnesium aluminate spinel (MgAl₂O₄) has been conducted using ionoluminescence (IL), cathodoluminescence (CL) and Rutherford Backscattering Spectrometry/channeling (RBS/C) techniques. MgAl₂O₄ single crystal and polycrystalline samples were irradiated with 320 keV Ar⁺ ions at fluencies ranging from 1 × 10¹² to 2 × 10¹⁶ cm^?2 in order to create various levels of radiation damage. RBS/C measurements provided quantitative data about damage concentration in the samples. These values were then compared to the luminescence measurements. The results obtained by IL and RBS/C methods demonstrate a two-step character of damage buildup process. The CL data analysis points to the three-step damage accumulation mechanism involving the first defect transformation at fluencies of about 10¹³ cm^?2 and second at about 10¹⁵ cm^?2. The rate of changes resulting from the formation of nonluminescent recombination centers is clearly nonlinear and cannot be described in terms of continuous accumulation of point defects. Both, IL and CL techniques, appear as new, complementary tools bringing new possibilities in the damage accumulation studies in single- and polycrystalline materials.  相似文献   

The first record of Cuon alpinus (Pallas, 1811) from Poland and the possible impact of other large canids on the evolution of the species     

Adrian Marciszak  Aleksandra Kropczyk  Grzegorz Lipecki 《第四纪科学杂志》2021,36(6):1101-1121

The presence of Cuon alpinus in Poland is documented here for the first time. Between 650 and 450 ka, Lycaon lycaonoides dominated the open lands, while Cuon alpinus priscus tended to prefer forests, mountains and highlands. Canis mosbachensis coexisted in all these environments. Between 480 and 430 ka, there was a drastic reduction in the number and range of L. lycaonoides. The balance between canids was disturbed and a critical point in the lycaon–wolf relationship was passed. Probably between 450 and 400 ka, the lycaon was too rare to be a real competitor and a limiting factor for the wolf. It was also at this time that the lycaon disappeared completely. With disappearance of the lycaon from Eurasia, there was a slow increase in the body size of the wolf. Between 400 and 300 ka, the dhole and the wolf were still close in body size, but the wolf was slowly increasing in size. Between 300 and 250 ka, the wolf became the dominant dog species and took a niche occupied until then by the lycaon. Because of competition, C. alpinus decreased in body size and adapted to hunting and living in forest, mountain and highland environments.  相似文献   

Thermal‐infrared remote sensing of surface water–groundwater exchanges in a restored anastomosing channel (Upper Rhine River,France)          下载免费PDF全文

David Eschbach  Guillaume Piasny  Laurent Schmitt  Laurent Pfister  Pierre Grussenmeyer  Mathieu Koehl  Grzegorz Skupinski  Abdelaziz Serradj 《水文研究》2017,31(5):1113-1124

Ecohydrological processes are a key element to consider in functional river restorations. In the framework of a LIFE+ European restoration program, we have investigated the potential for airborne thermal‐infrared remote sensing to map surface water–groundwater exchanges and to identify their driving factors. We focused our attention on anastomosing channels on an artificial island of the Upper Rhine River (Rohrschollen), where a new channel was excavated from the floodplain to reconnect an older channel in its upstream part. These hydraulic engineering works led to an increased inflow from the Rhine Canal. Here, we propose an original data treatment chain to (a) georeference the thermal‐infrared images in geographic information system based on visible images, (b) detect and correct data errors, and (c) identify and locate thermal anomalies attributed to groundwater inputs and hyporheic upwellings. Our results, which have been compared to morpho‐sedimentary data, show that groundwater upwelling in the new channel is controlled by riffle–pool sequences and bars. This channel is characterized by large bedload transport and morphodynamic activity, forming riffles and bars. In the old channel, where riffle–pool sequences no longer exist, due to impacts of engineering works and insufficient morphodynamic effects of the restoration, thermal anomalies appeared to be less pronounced. Groundwater inputs seem to be controlled by former gravel bars outcropping on the banks, as well as by local thinning of the low‐permeability clogging layer on the channel bed.  相似文献   

A continuous multi-millennial record of surficial bivalve mollusk shells from the São Paulo Bight,Brazilian shelf     

Troy A. Dexter  Darrell S. Kaufman  Richard A. Krause Jr.  Susan L. Barbour Wood  Marcello G. Simões  John Warren Huntley  Yurena Yanes  Christopher S. Romanek  Michał Kowalewski 《Quaternary Research》2014

To evaluate the potential of using surficial shell accumulations for paleoenvironmental studies, an extensive time series of individually dated specimens of the marine infaunal bivalve mollusk Semele casali was assembled using amino acid racemization (AAR) ratios (n = 270) calibrated against radiocarbon ages (n = 32). The shells were collected from surface sediments at multiple sites across a sediment-starved shelf in the shallow sub-tropical São Paulo Bight (São Paulo State, Brazil). The resulting ¹⁴C-calibrated AAR time series, one of the largest AAR datasets compiled to date, ranges from modern to 10,307 cal yr BP, is right skewed, and represents a remarkably complete time series: the completeness of the Holocene record is 66% at 250-yr binning resolution and 81% at 500-yr binning resolution. Extensive time-averaging is observed for all sites across the sampled bathymetric range indicating long water depth-invariant survival of carbonate shells at the sediment surface with low net sedimentation rates. Benthic organisms collected from active depositional surfaces can provide multi-millennial time series of biomineral records and serve as a source of geochemical proxy data for reconstructing environmental and climatic trends throughout the Holocene at centennial resolution. Surface sediments can contain time-rich shell accumulations that record the entire Holocene, not just the present.  相似文献   

Pleurozium schreberi as bioindicator of mercury pollution in heavily industrialized region     

Aleksandra Samecka-Cymerman  Grzegorz Kosior  Krzysztof Kolon  Bronisław Wojtuń  Krzysztof Zawadzki  Andrzej Rudecki  Alexander J. Kempers 《Journal of Atmospheric Chemistry》2013,70(2):105-114

This research is continuation of the investigation of metal accumulation in native and transplanted moss Pleurozium schreberi in the most industrialized and affected region in Poland (Upper Silesia). We tested the hypotheses that in Upper Silesia transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent; a 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. An assay was carried out with native mosses at 27 polluted sites and mosses from an uncontaminated control site transplanted to the same 27 polluted sites. P. schreberi collected from the same sites as classified for more and less polluted basing on Pb and Zn concentrations show quite different pattern of pollution with mercury; The accumulation of Hg by the transplants increased much faster in the first 45 days of the experiment (accumulation factor 1.5–6.7; mean 3.4?±?0.5) in comparison with the second period from day 45 to 90 (accumulation factor 1.0–1.6; mean 1.2?±?0.1). The 90 days exposure of transplanted P. schreberi was long enough for evaluation of Hg pollution of the environment. Transplants of P. schreberi may be used in a 90 days bioindication experiment in case native specimens are absent.  相似文献