Chloride transfer in cement‐based materials. Part 1. Theoretical basis and modelling     

K. Bourbatache  O. Millet  A. Aït‐Mokhtar  O. Amiri 《国际地质力学数值与分析法杂志》2013,37(11):1614-1627

In this first part of the work, we develop macroscopic models for migration and diffusion–migration of ionic species in saturated porous media, based on periodic homogenization. The prior application is chloride transport in cementitious materials. The dimensional analysis of Nernst–Planck equation lets appear to dimensionless numbers characterizing the ionic transfer in the porous medium. Using experimental data obtained from electrodiffusion tests on cement‐based materials (Part II), these dimensionless numbers are linked to the perturbation parameter ?. For a strong imposed electrical field, the asymptotic expansion of Nernst–Planck equation leads to a macroscopic model where the migration is predominant. For a weak imposed electrical field or in natural diffusion, we obtain a macroscopic model coupling diffusion and migration at the same order. In both models, the expression of the homogenized diffusion tensor is identical and only involves the geometric properties of the material microstructure. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Phase equilibria constraints on melting of stromatic migmatites from Ronda (S. Spain): insights on the formation of peritectic garnet     

O. Bartoli  L. Tajčmanová  B. Cesare  A. Acosta‐Vigil 《Journal of Metamorphic Geology》2013,31(7):775-789

Stromatic metatexites occurring structurally below the contact with the Ronda peridotite (Ojén nappe, Betic Cordillera, S Spain) are characterized by the mineral assemblage Qtz+Pl+Kfs+Bt+Sil+Grt+Ap+Gr+Ilm. Garnet occurs in low modal amount (2–5 vol.%). Very rare muscovite is present as armoured inclusions, indicating prograde exhaustion. Microstructural evidence of melting in the migmatites includes pseudomorphs after melt films and nanogranite and glassy inclusions hosted in garnet cores. The latter microstructure demonstrates that garnet crystallized in the presence of melt. Re‐melted nanogranites and preserved glassy inclusions show leucogranitic compositions. Phase equilibria modelling of the stromatic migmatite in the MnO–Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂–O₂–C (MnNCaKFMASHOC) system with graphite‐saturated fluid shows P–T conditions of equilibration of 4.5–5 kbar, 660–700 °C. These results are consistent with the complete experimental re‐melting of nanogranites at 700 °C and indicate that nanogranites represent the anatectic melt generated immediately after entering supersolidus conditions. The P–T estimate for garnet and melt development does not, however, overlap with the low‐temperature tip of the pure melt field in the phase diagram calculated for the composition of preserved glassy inclusions in garnet in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O (NCKFMASH) system. A comparison of measured melt compositions formed immediately beyond the solidus with results of phase equilibria modelling points to the systematic underestimation of FeO, MgO and CaO in the calculated melt. These discrepancies are present also when calculated melts are compared with low‐T natural and experimental melts from the literature. Under such conditions, the available melt model does not perform well. Given the presence of melt inclusions in garnet cores and the P–T estimates for their formation, we argue that small amounts (<5 vol.%) of peritectic garnet may grow at low temperatures (≤700 °C), as a result of continuous melting reactions consuming biotite.  相似文献   

Failure and size effect for notched and unnotched concrete beams     

D. Grégoire  L.B.  Rojas‐Solano  G. Pijaudier‐Cabot 《国际地质力学数值与分析法杂志》2013,37(10):1434-1452

Modelling failure in geomaterials, concrete or other quasi‐brittle materials and proper accounting for size effect, geometry and boundary effects are still pending issues. Regularised failure models are capable of describing size effect on specimens with a specific geometry, but extrapolations to other geometries are rare, mostly because experimental data presenting size effect for different geometries and for the same material are lacking. Three‐point bending fracture tests of geometrically similar notched and unnotched specimens are presented. The experimental results are compared with numerical simulations performed with an integral‐type non‐local model. Comparisons illustrate the shortcomings of this classical formulation, which fails to describe size effect over the investigated range of geometries and sizes. Finally, experimental results are also compared with the universal size effect law. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Hydrous olivine alteration on Mars and Earth     

Zoltn Vci  Carl B. Agee  Christopher D. K. Herd  Erin Walton  Oliver Tschauner  Karen Ziegler  Vitali B. Prakapenka  Eran Greenberg  Sylvia Monique‐Thomas 《Meteoritics & planetary science》2020,55(5):1011-1030

Hydrous alteration of olivine macrocrysts in a Martian olivine phyric basalt, NWA 10416, and a terrestrial basalt from southern Colorado are examined using SEM, EPMA, TEM, and µXRD techniques. The olivines in the meteorite contain linear nanotubes of hydrous material, amorphous areas, and fluid dissolution textures quite distinct from alteration identified in other Martian meteorites. Instead, they bear resemblance to terrestrial deuteric alteration features. The presence of the hydrous alteration phase Mg‐laihunite within the olivines has been confirmed by µXRD analysis. The cores of the olivines in both Martian and terrestrial samples are overgrown by unaltered rims whose compositions match those of a separate population of groundmass olivines, suggesting that the core olivines are xenocrysts whose alteration preceded crystallization of the groundmass. The terrestrial sample is linked to deep crustal metasomatism and the “ignimbrite flare‐up” of the Oligocene epoch. The comparison of the two samples suggests the existence of an analogous relatively water‐rich magmatic reservoir on Mars.  相似文献   

Combining IR and X‐ray microtomography data sets: Application to Itokawa particles and to Paris meteorite     

Zelia Dionnet  Rosario Brunetto  Alice Alon‐Toppani  Stefano Rubino  Donia Baklouti  Ferenc Borondics  Anne‐Ccile Buellet  Zahia Djouadi  Andrew King  Tomoki Nakamura  Alessandra Rotundi  Christophe Sandt  David Troadec  Akira Tsuchiyama 《Meteoritics & planetary science》2020,55(7):1645-1664

In the near future, a new generation of sample return missions (Hayabusa2, OSIRIS‐REx, MMX, etc.) will collect samples from small solar system bodies. To maximize the scientific outcome of laboratory studies and minimize the loss of precious extraterrestrial samples, an analytical sequence from less destructive to more destructive techniques needs to be established. In this work, we present a combined X‐ray and IR microtomography applied to five Itokawa particles and one fragment of the primitive carbonaceous chondrite Paris. We show that this analytical approach is able to provide a 3‐D physical and chemical characterization of individual extraterrestrial particles, using the measurement of their 3‐D structure and porosity, and the detection of mineral and organic phases, and their spatial co‐localization in 3‐D. We propose these techniques as an efficient first step in a multitechnique analytical sequence on microscopic samples collected by space missions.  相似文献   

Mesozoic exhumation history of the Grenvillian Oaxacan Complex,southern Mexico     

Fanis Abdullin  Luigi Solari  Jesús Sol  Carlos Ortega‐Obregn 《地学学报》2021,33(1):86-94

We present the first fission‐track results from the Grenvillian Oaxacan Complex, southern Mexico. Time–temperature modelling of the data indicates that two significant Mesozoic cooling episodes are recorded in the Oaxacan Complex and these are interpreted as resulting from exhumation. The older cooling event took place from the Late Triassic to Middle Jurassic and is possible linked to the break‐up of Pangea (including the initial opening of the Gulf of Mexico during the Jurassic). The younger exhumation period in the Early Cretaceous is contemporaneous with the final stages of rifting of the Gulf of Mexico. Key stratigraphic records also provide independent evidence for these exhumation episodes. In our view, both Mesozoic rapid exhumation events were controlled by the activity of the Caltepec Fault Zone and the Oaxaca Fault. Our data suggest that both these large fault systems have remained active since, at least, the Late Triassic.  相似文献   

Alternating augite‐plagioclase wedges in basement dolerites of Lockne impact structure,Sweden: A new shock wave‐induced deformation feature          下载免费PDF全文

A. Agarwal  B. Reznik  L. M. Alva‐Valdivia  D. C. Srivastava 《Meteoritics & planetary science》2017,52(3):458-470

This paper reports peculiar alternating augite‐plagioclase wedges in basement dolerites of Lockne impact structure, Sweden. The combined microscopic and spectroscopic studies of the micro/nanoscale wedges reveal that these are deformation‐induced features. First, samples showing wedges, 12 out of 18 studied, are distributed in the impact structure within a radius of up to 10 km from the crater center. Second, the margins between the augite and labradorite wedges are sharp and the {110} prismatic cleavage of augite develops into fractures and thereafter into wedges. The fractures are filled with molten labradorite pushed from the neighboring bulk labradorite grain. Third, compared to the bulk labradorite, the dislocation density and the residual strain in the labradorite wedges are significantly higher. A possible mechanism of genesis of the wedges is proposed. The mechanism explains that passing of the shock waves in the basement dolerite induced (i) formation of microfractures in augite and labradorite; (ii) development of the augite prismatic cleavages into the wedges, which overprint the microfracture in the labradorite wedges; and (iii) thereafter, infilling of microfractures in the augite wedges by labradorite.  相似文献   

Increasing water losses from snow captured in the canopy of boreal forests: A case study using a 30 year data set          下载免费PDF全文

Nataliia Kozii  Hjalmar Laudon  Mikaell Ottosson‐Löfvenius  Niles J. Hasselquist 《水文研究》2017,31(20):3558-3567

Water losses from snow intercepted by forest canopy can significantly influence the hydrological cycle in seasonally snow‐covered regions, yet how snow interception losses (SIL) are influenced by a changing climate are poorly understood. In this study, we used a unique 30 year record (1986–2015) of snow accumulation and snow water equivalent measurements in a mature mixed coniferous (Picea abies and Pinus sylvestris ) forest stand and an adjacent open area to assess how changes in weather conditions influence SIL. Given little change in canopy cover during this study, the 20% increase in SIL was likely the result of changes in winter weather conditions. However, there was no significant change in average wintertime precipitation and temperature during the study period. Instead, mean monthly temperature values increased during the early winter months (i.e., November and December), whereas there was a significant decrease in precipitation in March. We also assessed how daily variation in meteorological variables influenced SIL and found that about 50% of the variation in SIL was correlated to the amount of precipitation that occurred when temperatures were lower than ?3 °C and to the proportion of days with mean daily temperatures higher than +0.4 °C. Taken together, this study highlights the importance of understanding the appropriate time scale and thresholds in which weather conditions influence SIL in order to better predict how projected climate change will influence snow accumulation and hydrology in boreal forests in the future.  相似文献   

The petrology,geochemistry, and age of lunar regolith breccias Miller Range 090036 and 090070: Insights into the crustal history of the Moon          下载免费PDF全文

A. Calzada‐Diaz  K. H. Joy  I. A. Crawford  S. Strekopytov 《Meteoritics & planetary science》2017,52(1):3-23

Meteorites ejected from the surface of the Moon as a result of impact events are an important source of lunar material in addition to Apollo and Luna samples. Here, we report bulk element composition, mineral chemistry, age, and petrography of Miller Range (MIL) 090036 and 090070 lunar meteorites. MIL 090036 and 090070 are both anorthositic regolith breccias consisting of mineral fragments and lithic clasts in a glassy matrix. They are not paired and represent sampling of two distinct regions of the lunar crust that have protoliths similar to ferroan anorthosites. ⁴⁰Ar‐³⁹Ar chronology performed on two subsplits of MIL 090070,33 (a pale clast impact melt and a dark glassy melt component) shows that the sample underwent two main degassing events, one at ~3.88 Ga and another at ~3.65 Ga. The cosmic ray exposure data obtained from MIL 090070 are consistent with a short (~8–9 Ma) exposure close to the lunar surface. Bulk‐rock FeO, TiO₂, and Th concentrations in both samples were compared with 2‐degree Lunar Prospector Gamma Ray Spectrometer (LP‐GRS) data sets to determine areas of the lunar surface where the regolith matches the abundances observed on the sample. We find that MIL 090036 bulk rock is compositionally most similar to regolith surrounding the Procellarum KREEP Terrane, whereas MIL 090070 best matches regolith in the feldspathic highlands terrane on the lunar farside. Our results suggest that some areas of the lunar farside crust are composed of ferroan anorthosite, and that the samples shed light on the evolution and impact bombardment history of the ancient lunar highlands.  相似文献   

Lithological control of land subsidence induced by groundwater withdrawal in new urban AREAS (Granada Basin,SE Spain). Multiband DInSAR monitoring          下载免费PDF全文

Davide Notti  Rosa María Mateos  Oriol Monserrat  Nùria Devanthéry  Tomás Peinado  Francisco Javier Roldán  Francisca Fernández‐Chacón  Jorge Pedro Galve  Francisco Lamas  Jose Miguel Azañón 《水文研究》2016,30(13):2317-2331

Ground subsidence in the southeastern border of the Granada Basin (SE Spain) has been studied using remote sensing techniques. Over the last decades, the region has experienced a huge urban expansion, which has caused a substantial increase in water supply requirements. Water needs are exclusively met by groundwater by means of numerous pumping wells, which exploit a confined detrital aquifer of alluvial fan deposits with a heterogeneous facies distribution. A general piezometric level decline (up to 50 m) has been recorded in the aquifer during the past 30 years that has induced the generation of a subsiding area with oval shape oriented WNW‐ESE just where the new urban areas and pumping wells are located. Subsidence has been monitored by exploiting synthetic aperture radar (SAR) images from ENVISAT (2003–2009) and Cosmo‐SkyMed (2011–2014). A new approach, which combines A‐DInSAR and small‐area persistent scatterer interferometry (PSI) analysis, has been applied obtaining a good accuracy regarding temporal and spatial dimension of the subsidence. ENVISAT data (2003–2009) reveal subsidence rates up to 10–15 mm/year, and Cosmo‐SkyMed (2011–2014) values slightly lower; up to 10 mm/year. Temporal variations in the subsidence velocity are in accordance with the rainfall pattern and piezometric fluctuations in the aquifer. The sector with highest rates of subsidence does not correspond to the area with more intense groundwater exploitation but to the area with greater presence of clays in the confining layer of the aquifer. There is a clear lithological control in the spatial distribution of the ground subsidence. This work integrates detailed geological and hydrogeological data with differential SAR interferometry monitoring with the aim to better understand subsidence processes in detrital aquifers with small‐scale heterogeneity. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献