Kinetics of peptide hydrolysis and amino acid decomposition at high temperature     

Qian Y  Engel MH  Macko SA  Carpenter S  Deming JW 《Geochimica et cosmochimica acta》1993,57(14):3281-3293

Dipeptide hydrolysis and amino acid decomposition appear to follow a first-order rate law. The hydrolysis rate increases exponentially with increasing temperature in aqueous solution at both 265 atm and water steam pressures over the temperature range of 100 to 220 degrees C. Dipeptide hydrolysis has a lower apparent activation energy at 265 atm (44.1 KJ/mol) than at water steam pressure (98.9 KJ/mol). At lower temperatures (<200-220 degrees C), the rate of peptide bond hydrolysis is faster at 265 atm than at water steam pressure. At higher temperatures (>200-220 degrees C), however, peptide bond hydrolysis is slower at 265 atm than at water steam pressure. In aqueous solution, amino acid decomposition rates also increase exponentially with increasing temperature. Amino acid decomposition rates are much higher at 265 atm than at water steam pressure over the entire temperature range investigated.  相似文献   

辽宁避暑旅游气候适宜度评价     

侯亚红  息涛  明惠青  赵淼  关健华 《气象科技》2021,49(6):960-967

利用辽宁省59个国家气象站2008—2017年6—8月逐时地面观测资料，综合考虑夏季气候舒适度和高影响天气对避暑旅游的不利影响，确定辽宁避暑旅游气候适宜度评价方法，分析了辽宁避暑旅游适宜度时空分布，为公众及旅游相关部门了解当地避暑旅游气候资源提供参考。研究表明：①辽宁避暑旅游适宜度由西北到东南逐渐增强， 59个地市（县）中，很适宜避暑的有14个，适宜避暑的有22个，较适宜避暑的有16个。②夏季辽宁大部避暑旅游气候舒适度较好，辽东和辽南气候舒适度优于辽宁中部和西部。辽宁东部的本溪和沿海的丹东、大连、葫芦岛和锦州南部气候舒适度等级最高，避暑气候条件更好。③辽宁夏季暴雨高风险区在东南部的宽甸、丹东和凤城一带。高温高风险区在朝阳大部和锦州西部。大风高风险区在铁岭北部、彰武、锦州、营口和长海。雷暴高风险区在铁岭、抚顺东部、朝阳西部和庄河一带。④6月、8月是辽宁适合避暑旅游的月份，尤其是 6月，避暑旅游适宜度最高，适宜面积最大。8月份次之， 7月避暑旅游适宜度较差。  相似文献   

敦煌北部岩浆-变质杂岩构造环境初步探讨:对中亚造山带南缘扩展方式的启示     

石梦岩  程南南  侯泉林  吴春明  闫全人  张国成  张谦  王浩 《岩石学报》2021,37(12):3673-3686

中亚造山带南缘如何向南扩展，对深入理解增生型造山作用和大陆地壳生长机制以及中亚构造域与特提斯构造域的衔接具有重要科学意义。作为中亚造山带南缘的关键构造单元，敦煌构造带大地构造属性长期备受关注且颇有争议。传统观点认为敦煌构造带是古亚洲洋南侧的前寒武纪稳定大陆地块，以刚性块体的形式参与了中亚造山带南缘的最终拼贴过程。然而，近年来研究认为敦煌构造带卷入了古亚洲洋南部的俯冲增生造山过程，属于中亚造山带南缘的增生系统。显然，这一争议限制了对中亚造山带南缘向南扩展方式及增生造山过程的理解。敦煌北部三危山地区出露一套古生代岩浆-变质杂岩，是解开这一争论的关键。本文综合前人研究基础及新的资料，归纳了这套岩浆-变质杂岩的野外岩石-构造组合、地球化学和年代学等方面特征：该岩浆-变质杂岩整体显示"二元结构"特征，即较老的增生杂岩为基底，弧岩浆岩侵入或不整合覆盖其上；其中岩浆岩属于中钾-高钾钙碱性系列中酸性岩浆岩，富集大离子亲石元素（LILE）和轻稀土元素（LREE），亏损高场强元素（HFSE），与典型的弧岩浆岩类似，并且微量元素组成特征反映中酸性岩浆的源区与俯冲沉积物部分熔融有关；岩浆作用大致归为510Ma、460~410Ma和370~360Ma三期。岩浆岩中结晶锆石不一致的ε_Hf（t）值（既有正值，又有负值）以及继承锆石的存在表明，岩浆源区既有古老地壳物质的加入，也有新生地壳物质的形成。以上这些特征与发育在增生杂岩之上的增生弧十分类似，因此本文提出敦煌北部岩浆-变质杂岩的属性为古生代增生弧，并且该增生弧与其南部的红柳峡俯冲增生杂岩共同勾勒出敦煌构造带自北向南增生弧-增生杂岩的基本构造格架，即敦煌构造带的大地构造属性实为造山带而非稳定地块。结合区域地质背景及敦煌地区与北山地区古生代至早中生代构造-热事件的对应关系，认为敦煌造山带属于中亚造山带中段南缘的增生系统，中亚造山带中段以增生弧-增生杂岩的形式向南扩展至敦煌地区。  相似文献   

《北京旅游图集》设计与编制研究   总被引：2，自引：0，他引：2  

钱金凯 《测绘学报》1992,21(4):299-306

  相似文献   

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China   总被引：3，自引：0，他引：3  

Qian Zhang    Xiaoqing Zhu    Yuliang He  Junjie Jiang  Dapeng Wang 《Resource Geology》2006,56(3):337-346

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.  相似文献   

Threshold velocity for wind erosion: the effects of porous fences   总被引：3，自引：0，他引：3  

Zhibao Dong  Guangqiang Qian  Wanyin Luo  Hongtao Wang 《Environmental Geology》2006,51(3):471-475

Porous fence is a kind of artificial windbreak that has many practical applications. The threshold wind velocities at different distances downwind from porous fences were measured and the corresponding characteristics of particle movement observed to assess their shelter effect. It is found that the fence’s porosity is the key factor that determines the resulting shelter effect. The area near a fence can be typically classified into five regions, each with a different mode of particle movement. Dense fences, and especially solid fences, favor the accumulation of sand upwind of the fences. Fences with porosities of 0.3–0.4 produce the maximum threshold wind velocity; those with porosities of 0.3–0.6 (depending on the fence height) provide the maximum effective shelter distance. It is confirmed that the fence porosities of 0.3–0.4 that have been proposed for practical application in previous research are the most effective for abating wind erosion.  相似文献   

Water–rock interaction during the process of steam stimulation exploitation of viscous crude oil in Liaohe Shuguang Oil Field, Liaoning, China     

Qian Hui  Yang Zhenghua  Li Yunfeng  Xu Wancai  Sun Yaqiao 《Environmental Geology》2006,50(2):229-236

In the process of steam stimulation exploitation of viscous crude oil, the injected water, at high temperature and under high pressure, reacts intensively with the host rock. This kind of water–rock interaction in Liaohe Shuguang Oil Field was studied on the basis of analysis of water composition changes, laboratory experiments, mineral saturation indices analysis, and mass balance calculation. Compared with the injected water, the changes of the composition of discharged water are mainly the distinct decrease of pH, Na⁺, SiO₂ and Cl⁻, as well as the increase of K⁺, Ca²⁺, Mg²⁺, SO ₄ ²⁻ and HCO ₃ ⁻ . Laboratory experiments under field conditions showed: the dissolution sequence of minerals quantitatively is quartz>potassium feldspar>albite, and the main change of clay minerals is the conversion of kaolinite to analcime. Mass balance calculation indicated during the process of steam stimulation, large quantities of analcime are precipitated with the dissolution of large amounts of quartz, kaolinite, potassium feldspar, and CO₂. These results correlated very well with the experimental results. The calculated results of Liaohe Shuguang Oil Field showed that during the steam stimulation for viscous crude oil, the amounts of minerals dissolved (precipitated) are huge. To control the clogging of pore spaces of oil reservoirs, increased study of water–rock interaction is needed.  相似文献   

基于Poisson过程分析的景区旅游承载力管理对策研究     

侯志强 《福建地理》2006,21(2):86-88

旅游承载力是研究旅游地可持续发展的关键因素,但目前该理论的研究处于难以运用到实践的困境,核心问题就是缺乏可操作性。通过引入Poisson过程分析旅游者在景区的时空活动规律,可为景区管理提供有力的证据和科学的参考,便于景区根据旅游承载力管理景区的各项工作。  相似文献   

REE characteristics of the Fanshan alunite deposit in Zhejiang Province, China     

何玉良  张乾  邵树勋  朱笑青  祝朝辉  王大鹏 《中国地球化学学报》2006,25(4):366-373

1 Introduction Alunite [KAl3(SO4)2(OH)6] is a very important non-ferrous metal resource, so many countries throughout the world have made great investments in research on the mechanism of its formation, its geological characteristics and applications. O…  相似文献   

GIS中直线元内插点精度及对误差带的影响   总被引：1，自引：0，他引：1  

魏峰远  邰茜 《测绘学院学报》2005,22(3):232-234

基于误差传播定律，考虑参数r误差影响，推导了线元内插点的精度计算公式，讨论内插点精度对线元误差带的影响，并对影响的结果进行了分析，得到了一些有益的结论。  相似文献