First investigations on the quaternary system Na2O-K2O-CaO-SiO2: synthesis and crystal structure of the mixed alkali calcium silicate K1.08Na0.92Ca6Si4O15     

Kahlenberg  Volker  Mayerl  Michael Jean-Philippe  Schmidmair  Daniela  Krüger  Hannes  Tribus  Martina 《Mineralogy and Petrology》2018,112(2):219-228

Mineralogy and Petrology - In the course of an exploratory study on the quaternary system Na2O-K2O-CaO-SiO2 single crystals of the first anhydrous sodium potassium calcium silicate have been...  相似文献   

Quantifying Metabolically Driven pH and Oxygen Fluctuations in US Nearshore Habitats at Diel to Interannual Time Scales     

Hannes Baumann  Erik M. Smith 《Estuaries and Coasts》2018,41(4):1102-1117

We compiled and examined 15 years (2002–2016) of high-frequency monitoring data from the National Estuarine Research Reserve System (NERRS) to characterize diel to interannual variability of pH and dissolved oxygen (DO, % saturation) across 16 diverse, shallow-water habitats along the US Atlantic, Gulf of Mexico, Caribbean, and Pacific coasts. We asked whether these systems exhibit a common pH/DO relationship, whether there were detectable interannual trends in temperature, pH, and DO within and across systems, and how pH/DO dynamics would relate to measured levels of nutrients and chlorophyll. Our analyses confirmed that large, metabolically driven, and thus concurrent fluctuations of pH and DO are a unifying feature of nearshore habitats. Moreover, we derived well-constrained relationships that predict (i) monthly mean pH or (ii) mean diel pH fluctuations across systems based on habitat mean salinity and (i) mean DO or (ii) mean diel DO fluctuations. This suggests that common metabolic principles drive diel to seasonal pH/DO variations within as well as across a diversity of estuarine environments. Yearly pH and DO anomalies did not show monotonous trends over the study period and differed considerably between sites and regions. However, weekly anomalies of means, diel minima, and diel ranges of pH and DO changed significantly over time and were strongly correlated to temperature anomalies. These general patterns lend strong empirical support to the notion that coastal acidification—in addition to being driven by eutrophication and atmospheric CO₂ increases—is exacerbated simply by warming, likely via increasing community respiration. Nutrient and chlorophyll dynamics were inversely related in these shallow, well-mixed systems, but higher nutrient levels were still associated with lower pH and lower DO levels in most, but not all, systems. Our analyses emphasize the particular dynamics of nearshore habitats and the critical importance of NERRS and its system-wide monitoring program.  相似文献   

Novel applications of fluid inclusions and isotope geochemistry in unravelling the genesis of fossil travertine systems   总被引：1，自引：0，他引：1       下载免费PDF全文

Hamdy El Desouky  Jeroen Soete  Hannes Claes  Mehmet Özkul  Frank Vanhaecke  Rudy Swennen 《Sedimentology》2015,62(1):27-56

The Denizli Basin is a fault‐bounded Neogene–Quaternary depression located in the Western Anatolian Extensional Province, Western Turkey. The basin is a unique geological site with abundant active and fossil (Quaternary) travertine and tufa deposits. Fluid inclusion microthermometry and isotopic analysis were applied to study the genesis of the Ball?k fossil travertine deposits, located in the south‐eastern part of the basin. Microthermometry on fluid inclusions indicates that the main travertine precipitating and cementing fluids are characterized by low salinity (<0·7 wt% NaCl equivalent) and variable temperatures that cluster at <50°C and ca 100°C. Fluids of meteoric origin have been heated by migration to the deeper subsurface, possibly in a local high geothermal gradient setting. A later uncommon cementation phase is related to a fluid with a significantly higher salinity (25·5 to 26·0 wt% bulk). The fluid obtained its salinity by interaction with Late Triassic evaporite layers. Strontium isotopes indicate that the parent carbonate source rock of the different travertine precipitates is very likely to be the Triassic limestone of the Lycian Nappes. Carbon isotopes suggest that the parent CO₂ gas originated from thermal decarbonation of the Lycian limestones with minor contributions of magmatic degassing and organic soil CO₂. Oxygen isotopes confirm the meteoric origin of the fluids and indicate disequilibrium precipitation because of evaporation and degassing. Results were integrated within the available geological data of the Denizli Basin in a generalized travertine precipitation model, which enhanced the understanding of fossil travertine systems. The study highlights the novel application of fluid inclusion research in unravelling the genesis of continental carbonates and provides several recommendations for hydrocarbon exploration in travertine‐bearing sedimentary basins. The findings suggest that travertine bodies and their parent carbonate source rocks have the potential to constitute interesting subsurface hydrocarbon reservoirs.  相似文献   

Single-crystal structure and Raman spectroscopy of synthetic titanite analog CaAlSiO<Subscript>4</Subscript>F     

Hannes Krüger  Daniel M. Többens  Peter Tropper  Udo Haefeker  Volker Kahlenberg  Martin R. Fuchs  Vincent Olieric  Ulrike Troitzsch 《Mineralogy and Petrology》2015,109(5):631-641

Synthetic CaAlSiO₄F, the Al-F analog of titanite, has been investigated using single-crystal synchrotron diffraction experiments at Beamline X06DA (Swiss Light Source, Paul Scherrer Institute, Villigen, Switzerland) and Raman spectroscopy. The presented structural model with 40 parameters was refined against 506 unique reflections to a final R _{o b s} of 0.026 (space group A2/a, a = 6.9120(11), b = 8.5010(10), c = 6.435(2) Å, β = 114.670(11)°, and Z = 4) and exhibits less distorted coordination polyhedra than earlier models from powder data. Vibrational spectra were calculated in harmonic approximation at the Γ point from fully relaxed energy optimisations of the crystal structure, using 3D-periodic density functional theory with Gaussian basis sets and the software CRYSTAL06. The lattice parameters of the fully relaxed structure were in good agreement with the experimental values, with the calculated values 0.8 ± 0.4 % too large; the monoclinic angle was calculated 0.4° too large. The agreement of the calculated Raman frequencies with the observed ones was very good, with standard deviation ±3 cm^?1 and maximum deviations of ±7 cm^?1. Furthermore, a detailed discussion of the atomic displacements associated with each Raman mode is given.  相似文献   

Stellar intensity interferometry: Prospects for sub-milliarcsecond optical imaging     

Dainis Dravins  Stephan LeBohec  Hannes Jensen  Paul D. Nuñez 《New Astronomy Reviews》2012,56(5):143-167

Using kilometric arrays of air Cherenkov telescopes at short wavelengths, intensity interferometry may increase the spatial resolution achieved in optical astronomy by an order of magnitude, enabling images of rapidly rotating hot stars with structures in their circumstellar disks and winds, or mapping out patterns of nonradial pulsations across stellar surfaces. Intensity interferometry (once pioneered by Hanbury Brown and Twiss) connects telescopes only electronically, and is practically insensitive to atmospheric turbulence and optical imperfections, permitting observations over long baselines and through large airmasses, also at short optical wavelengths. The required large telescopes (～10 m) with very fast detectors (～ns) are becoming available as the arrays primarily erected to measure Cherenkov light emitted in air by particle cascades initiated by energetic gamma rays. Planned facilities (e.g., CTA, Cherenkov Telescope Array) envision many tens of telescopes distributed over a few square km. Digital signal handling enables very many baselines (from tens of meters to over a kilometer) to be simultaneously synthesized between many pairs of telescopes, while stars may be tracked across the sky with electronic time delays, in effect synthesizing an optical interferometer in software. Simulated observations indicate limiting magnitudes around m_V = 8, reaching angular resolutions ～30 μarcsec in the violet. The signal-to-noise ratio favors high-temperature sources and emission-line structures, and is independent of the optical passband, be it a single spectral line or the broad spectral continuum. Intensity interferometry directly provides the modulus (but not phase) of any spatial frequency component of the source image; for this reason a full image reconstruction requires phase retrieval techniques. This is feasible if sufficient coverage of the interferometric (u, v)-plane is available, as was verified through numerical simulations. Laboratory and field experiments are in progress; test telescopes have been erected, intensity interferometry has been achieved in the laboratory, and first full-scale tests of connecting large Cherenkov telescopes have been carried out. This paper reviews this interferometric method in view of the new possibilities offered by arrays of air Cherenkov telescopes, and outlines observational programs that should become realistic already in the rather near future.  相似文献   

Approximate copula-based estimation and prediction of discrete spatial data   总被引：1，自引：1，他引：0  

Hannes Kazianka 《Stochastic Environmental Research and Risk Assessment (SERRA)》2013,27(8):2015-2026

The present paper reports on the use of copula functions to describe the distribution of discrete spatial data, e.g. count data from environmental mapping or areal data analysis. In particular, we consider approaches to parameter point estimation and propose a fast method to perform approximate spatial prediction in copula-based spatial models with discrete marginal distributions. We assess the goodness of the resulting parameter estimates and predictors under different spatial settings and guide the analyst on which approach to apply for the data at hand. Finally, we illustrate the methodology by analyzing the well-known Lansing Woods data set. Software that implements the methods proposed in this paper is freely available in Matlab language on the author’s website.  相似文献   

Emplacement and inflation of natrocarbonatitic lava flows during the March–April 2006 eruption of Oldoinyo Lengai,Tanzania     

Hannes B. Mattsson  Jaana Vuorinen 《Bulletin of Volcanology》2009,71(3):301-311

The most voluminous eruption of natrocarbonatite lava hitherto recorded on Earth occurred at Oldoinyo Lengai in March–April 2006. The lava flows produced in this eruption range from blocky 'a'a type to smooth-surfaced inflated pahoehoe. We measured lava inflation features (i.e. one tumulus and three pressure ridges) that formed in the various pahoehoe flows emplaced in this event. The inflation features within the main crater of Oldoinyo Lengai are relatively small-scale, measuring 1-5 m in width, 2.5–24.4 m in length and with inflation clefts less than 0.4 m deep. Their small sizes are in contrast to a tumulus that formed on the northwestern slope of the volcano (situated ~1140 m below the crater floor). The tumulus is roughly circular, measures 17.5 × 16.0 m, and is cut by a 4.4 m deep axial inflation cleft exposing two separate flow units. We measured the elastic properties (i.e. shear- and bulk moduli) of natrocarbonatitic crust and find that these are similar to those reported for basaltic crust, and that there is no direct correlation between magmastatic head and pressure required to form tumuli. All inflated flows in the 2006 event were confined by lateral barriers (main crater, erosional channel or erosional gully) suggesting that the two most important factors for endogenous growth in natrocarbonatitic lava flows are (1) lateral barriers that prevent widening of the flow, and (2) influx of new material beneath the viscoelastic and brittle crust.  相似文献   

Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania   总被引：1，自引：0，他引：1  

Jörg Keller  Jurgis Klaudius  Matthieu Kervyn  Gerald G. J. Ernst  Hannes B. Mattsson 《Bulletin of Volcanology》2010,72(8):893-912

With a paroxysmal ash eruption on 4 September 2007 and the highly explosive activity continuing in 2008, Oldoinyo Lengai (OL) has dramatically changed its behavior, crater morphology, and magma composition after 25 years of quiet extrusion of fluid natrocarbonatite lava. This explosive activity resembles the explosive phases of 1917, 1940–1941, and 1966–1967, which were characterized by mixed ashes with dominantly nephelinitic and natrocarbonatitic components. Ash and lapilli from the 2007–2008 explosive phase were collected on the slopes of OL as well as on the active cinder cone, which now occupies the entire north crater having buried completely all earlier natrocarbonatite features. The lapilli and ash samples comprise nepheline, wollastonite, combeite, Na-åkermanite, Ti-andradite, resorbed pyroxene and Fe–Ti oxides, and a Na–Ca carbonate phase with high but varying phosphorus contents which is similar, but not identical, to the common gregoryite phenocrysts in natrocarbonatite. Lapilli from the active cone best characterize the erupted material as carbonated combeite–wollastonite–melilite nephelinite. The juvenile components represent a fundamentally new magma composition for OL, containing 25–30 wt.% SiO₂, with 7–11 wt.% CO₂, high alkalies (Na₂O 15–19%, K₂O 4–5%), and trace-element signatures reminiscent of natrocarbonatite enrichments. These data define an intermediate composition between natrocarbonatite and nephelinite, with about one third natrocarbonatite and two thirds nephelinite component. The data are consistent with a model in which the carbonated silicate magma has evolved from the common combeite–wollastonite nephelinite (CWN) of OL by enrichment of CO₂ and alkalies and is close to the liquid immiscible separation of natrocarbonatite from carbonated nephelinite. Material ejected in April/May 2008 indicates reversion to a more common CWN composition.  相似文献   

Fundamental changes in the activity of the natrocarbonatite volcano Oldoinyo Lengai, Tanzania     

Matthieu Kervyn  Gerald G. J. Ernst  Jörg Keller  R. Greg Vaughan  Jurgis Klaudius  Evelyne Pradal  Frederic Belton  Hannes B. Mattsson  Evelyne Mbede  Patric Jacobs 《Bulletin of Volcanology》2010,72(8):913-931

On September 4, 2007, after 25 years of effusive natrocarbonatite eruptions, the eruptive activity of Oldoinyo Lengai (OL), N Tanzania, changed abruptly to episodic explosive eruptions. This transition was preceded by a voluminous lava eruption in March 2006, a year of quiescence, resumption of natrocarbonatite eruptions in June 2007, and a volcano-tectonic earthquake swarm in July 2007. Despite the lack of ground-based monitoring, the evolution in OL eruption dynamics is documented based on the available field observations, ASTER and MODIS satellite images, and almost-daily photos provided by local pilots. Satellite data enabled identification of a phase of voluminous lava effusion in the 2 weeks prior to the onset of explosive eruptions. After the onset, the activity varied from 100 m high ash jets to 2–15 km high violent, steady or unsteady, eruption columns dispersing ash to 100 km distance. The explosive eruptions built up a ∼400 m wide, ∼75 m high intra-crater pyroclastic cone. Time series data for eruption column height show distinct peaks at the end of September 2007 and February 2008, the latter being associated with the first pyroclastic flows to be documented at OL. Chemical analyses of the erupted products, presented in a companion paper (Keller et al. 2010), show that the 2007–2008 explosive eruptions are associated with an undersaturated carbonated silicate melt. This new phase of explosive eruptions provides constraints on the factors causing the transition from natrocarbonatite effusive eruptions to explosive eruptions of carbonated nephelinite magma, observed repetitively in the last 100 years at OL.  相似文献   

Copula-based geostatistical modeling of continuous and discrete data including covariates   总被引：4，自引：3，他引：1  

Hannes Kazianka  Jürgen Pilz 《Stochastic Environmental Research and Risk Assessment (SERRA)》2010,24(5):661-673

It is common in geostatistics to use the variogram to describe the spatial dependence structure and to use kriging as the spatial prediction methodology. Both methods are sensitive to outlying observations and are strongly influenced by the marginal distribution of the underlying random field. Hence, they lead to unreliable results when applied to extreme value or multimodal data. As an alternative to traditional spatial modeling and interpolation we consider the use of copula functions. This paper extends existing copula-based geostatistical models. We show how location dependent covariates e.g. a spatial trend can be accounted for in spatial copula models. Furthermore, we introduce geostatistical copula-based models that are able to deal with random fields having discrete marginal distributions. We propose three different copula-based spatial interpolation methods. By exploiting the relationship between bivariate copulas and indicator covariances, we present indicator kriging and disjunctive kriging. As a second method we present simple kriging of the rank-transformed data. The third method is a plug-in prediction and generalizes the frequently applied trans-Gaussian kriging. Finally, we report on the results obtained for the so-called Helicopter data set which contains extreme radioactivity measurements.  相似文献