Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers     

Hans G. Machel 《Hydrogeology Journal》1999,7(1):94-107

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998  相似文献   

Nonlinear wave coupling in type IV solar radio bursts     

Claudio Chiuderi  Riccardo Giachetti  Hans Rosenberg 《Solar physics》1973,33(1):225-238

In order to explain a fine structure of parallel ridges in stationary type IV continua, the emission due to the coupling of electrostatic upper hybrid waves and Bernstein waves at the sum frequency of the upper hybrid and harmonics of the gyro frequency has been calculated. If the energy density of these electrostatic waves is of the order of 10^-3 times the thermal energy density, then the observed zebra pattern can be emitted by a region with a diameter of 10³ km.  相似文献   

The period of rotation and the photoelectric lightcurve of the minor planet 79 eurynome     

Hans Josef Schober 《Icarus》1976,28(3):415-420

The minor planet 79 Eurynome was observed during the 1974 opposition for four nights in November, using a photoelectric photometer attached to the 60 cm telescope at the Observatoire de Haute Provence, France. A synodic period of P_syn = 5^h 58^m46^s ± 6^s m.e. was derived. The total amplitude of the lightcurve is only 0.05 mag. The lightcurve shows a double maximum and double minimum. Both minima appear to be at the same level. Observations were carried out in an instrumental filter system (UBV)' Results are shown only for V′, but U′ and B′ measurements supplement the conclusions concerning the rotation. The phase angle α, covered by the observations, ranges from 3 to 5°. The present results for 79 Eurynome rule out the longer period of 0^d.49830 derived by F. Scaltriti and V. Zappalà in favor of their possible period of 0^d.24915.  相似文献   

A candidate of the Induan-Olenekian boundary stratotype in the Tethyan region   总被引：10，自引：0，他引：10  

童金南  Yuri D.Zakharov  殷鸿福  Hans J.Hansen 《中国科学D辑(英文版)》2003,46(11):1182-1200

The Olenekian Stage was proposed by Kiparisova and Popov[1] based on the type section along the lower reaches of the Olenek River, Siberia. Later research showed that this section con-tains only the Olenikites spiniplicatus Zone of the Upper Olenekian Sta…  相似文献   

Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Tracer measurements in groyne fields for the quantification of mean hydraulic residence times and of the exchange with the stream     

Hans‐Peter Kozerski  Ren Schwartz  Thomas Hintze 《洁净——土壤、空气、水》2006,34(3):188-200

Tracer experiments were carried out in groyne fields (GF) of the river Elbe near Havelberg (Germany) in order to estimate the hydraulic connectivity with the river channel. The characteristic times of the five groyne fields, which were estimated from the exponentially declining tracer curves in 43 runs, ranged between 15 min and 69 min and did not correlate with the water level. Methodological investigations show that single point injection and two measurements (in the outflowing water and in the dominant region) are sufficient to provide robust in‐situ tracer curves. Using simplified mathematical simulations with connected stirred tanks, the conditions are investigated for the development of breaks in tracer curves and for the occurrence of significant errors in the estimation of intrinsic residence times. It was shown that an initial uniform dye distribution is not mandatory for the estimation during steady states. In special cases, point injections are more advisable. Moreover, the mean hydraulic residence time was found to be not equivalent to the estimated characteristic time. In fact, it is mostly overestimated by tracer experiments. The degree of overestimation depends on mixing and the volumetric proportions between the different parts of the GF and can be calculated from measured dye concentration differences. For example, an overestimation of 32% was calculated for a groyne field with a commonly found circulation flow pattern.  相似文献   

The GW-Fauna-Index: A first approach to a quantitative ecological assessment of groundwater habitats   总被引：6，自引：1，他引：6  

Hans Jürgen Hahn   《Limnologica》2006,36(2):119-137

Between June 2001 and December 2002, 18 hyporheic and groundwater bores were sampled for fauna and environmental data using phreatic traps. The bores were situated in three different natural geographic regions in Palatinate, Southwestern Germany.Faunal data correlated with the relative amount of detritus, bacterial abundances and the standard deviation of temperature, while very few and weak correlations were found with physical–chemical variables. Dissolved oxygen was assumed to be a limiting factor for most metazoans with a critical concentration at around 0.5–1 mg l⁻¹.To quantify the strength of the hydrological exchange with surface water and its effects on fauna, a so-called GW-Fauna-Index was developed and calculated using the relative amount of detritus, standard deviation of temperature, and oxygen concentration. From all environmental data and on all spatial scales, this index best explained the total faunal abundance and taxonomic richness.To describe the availability of organic aliments in the groundwater, the terms of “alimonic” and “alimony” [from lat. alimonium=(food) supply] were proposed.Although stygofauna was different in the geographic regions investigated, the GW-Fauna-Index was independent from these regional particularities. Using the GW-Fauna-Index, three groups of groundwater habitats could be classified according to the alimonic conditions. From oligo-alimonic group I samples, fauna was mostly absent, while meso-alimonic group II samples were prevailingly populated by stygobites, and eu-alimonic group III samples by ubiquists and stygoxenes. Total abundances and taxonomic richness increased significantly from group I to group III. Group I samples were characterized by low index values, group II samples by intermediate and group III samples by high values.The GW-Fauna-Index provides promising perspectives for application, but needs some improvement. First of all, detritus should be analysed quantitatively and qualitatively, rather than semi-quantitatively. Also, a standard protocol for sampling has to be developed.  相似文献   

Climate change and North Sea storm surge extremes: an ensemble study of storm surge extremes expected in a changed climate projected by four different regional climate models   总被引：5，自引：0，他引：5  

Katja Woth  Ralf Weisse  Hans von Storch 《Ocean Dynamics》2006,56(1):3-15

The coastal zones are facing the prospect of changing storm surge statistics due to anthropogenic climate change. In the present study, we examine these prospects for the North Sea based on numerical modelling. The main tool is the barotropic tide-surge model TRIMGEO (Tidal Residual and Intertidal Mudflat Model) to derive storm surge climate and extremes from atmospheric conditions. The analysis is carried out by using an ensemble of four 30-year atmospheric regional simulations under present-day and possible future-enhanced greenhouse gas conditions. The atmospheric regional simulations were prepared within the EU project PRUDENCE (Prediction of Regional scenarios and Uncertainties for Defining EuropeaN Climate change risks and Effects). The research strategy of PRUDENCE is to compare simulations of different regional models driven by the same global control and climate change simulations. These global conditions, representative for 1961–1990 and 2071–2100 were prepared by the Hadley Center based on the IPCC A2 SRES scenario. The results suggest that under future climatic conditions, storm surge extremes may increase along the North Sea coast towards the end of this century. Based on a comparison between the results of the different ensemble members as well as on the variability estimated from a high-resolution storm surge reconstruction of the recent decades it is found that this increase is significantly different from zero at the 95% confidence level for most of the North Sea coast. An exception represents the East coast of the UK which is not affected by this increase of storm surge extremes.  相似文献   

Using paleoclimate proxy-data to select optimal realisations in an ensemble of simulations of the climate of the past millennium   总被引：1，自引：0，他引：1  

Hugues Goosse  Hans Renssen  Axel Timmermann  Raymond S. Bradley  Michael E. Mann 《Climate Dynamics》2006,27(2-3):165-184

We present and describe in detail the advantages and limitations of a technique that combines in an optimal way model results and proxy-data time series in order to obtain states of the climate system consistent with model physics, reconstruction of past radiative forcing and proxy records. To achieve this goal, we select among an ensemble of simulations covering the last millennium performed with a low-resolution 3-D climate model the ones that minimise a cost function. This cost function measures the misfit between model results and proxy records. In the framework of the tests performed here, an ensemble of 30 to 40 simulations appears sufficient to reach reasonable correlations between model results and reconstructions, in configurations for which a small amount of data is available as well as in data-rich areas. Preliminary applications of the technique show that it can be used to provide reconstructions of past large-scale temperature changes, complementary to the ones obtained by statistical methods. Furthermore, as model results include a representation of atmospheric and oceanic circulations, it can be used to provide insights into some amplification mechanisms responsible for past temperature changes. On the other hand, if the number of proxy records is too low, it could not be used to provide reconstructions of past changes at a regional scale.  相似文献   

A high-resolution reconstruction of Storglaciären mass balance back to 1780/81 using tree-ring data and circulation indices     

Hans W. Linderholm  Peter Jansson 《Quaternary Research》2007,67(1):12-20

Storglaciären in northernmost Sweden has the world's longest ongoing continuous mass-balance record, starting in 1946. To extend this mass-balance record, we have reconstructed summer (b_S) and winter (b_W) mass balances separately back to the mass balance year 1780/81 with annual resolution. We used tree-ring data for b_S and a set of circulation indices, based on the sea-level pressure, for b_W. Both proxies have correlation coefficients with respective mass balance components of ca. 0.7. The reconstructed net balance (b_N) of Storglaciären was well correlated to the observations during 1946-1980 (r = 0.8, p < 0.05). Our reconstruction agrees well with previously obtained results of northern Sweden glacier variability, where the predominantly positive b_N years between 1890 and 1910 correspond to the well documented post-Little Ice Age advance of Storglaciären. Furthermore, the results suggest that b_S, as a function of summer temperatures, is more important than b_W in determining the b_N, which is contrary to glaciers in the maritime parts of western Scandinavia. In general, b_N has been negative over the last 220 yr, suggesting a predomination of continental conditions over northern Sweden. However, the influence of b_W increased in the late twentieth century, indicating a shift to a more oceanic climate regime.  相似文献