From seamount to oceanic island, Porto Santo, central East-Atlantic     

Ralf Schmidt  Hans-Ulrich Schmincke 《International Journal of Earth Sciences》2002,91(4):594-614

The uplifted and deeply eroded volcanic succession of Porto Santo (central East-Atlantic) is the product of a wide spectrum of dynamic processes that are active in shoaling to emergent seamounts. Two superimposed lapilli cones marking the base of the exposed section are interpreted as having formed from numerous submarine to subaerial phreatomagmatic explosions, pyroclastic fragmentation being subordinate. The lower basaltic and the upper mugearitic to trachytic sections are dominated by redeposited tephra and are called 'lapilli cone aprons'. Vertical growth due to accumulation of tephra, voluminous intrusions, and minor pillowed lava flows produced ephemeral islands which were subsequently leveled by wave erosion, as shown by conglomerate beds. Periods of volcanic quiescence are represented by abundant biocalcarenite lenses at several stratigraphic levels. The loose tephra piles became stabilized by widespread syn-volcanic intrusions such as dikes and trachytic to rhyolitic domes welding the volcanic and volcaniclastic ensemble into a solid edifice. Shattering of a submarine extrusive trachytic dome by pyroclastic and phreatomagmatic explosions, accentuated by quench fragmentation, resulted in pumice- and crystal-rich deposits emplaced in a prominent submarine erosional channel. The dome must have produced an island as indicated by a collapse breccia comprising surf-rounded boulders of dome material. Subaerial explosive activity is represented by scoria cones and tuff cones. Basaltic lava flows built a resistant cap that protected the island from wave erosion. Some lava flows entered the sea and formed two distinct types of lava delta: 1. closely-packed pillow lava and massive tabular lava flows along the southwestern coast of Porto Santo, and 2. a steeply inclined pillow-hyaloclastite breccia prism composed of foreset-bedded hydroclastic breccia, variably-shaped pillows, and thin sheet flows capped by subhorizontal submarine to subaerial lava flows along the eastern coast of Porto Santo.The facies architectures indicate emplacement: 1. on a gently sloping platform in southwestern Porto Santo, and 2. on steep offshore slopes along high energy shorelines in eastern Porto Santo.Growth of the pillow-hyaloclastite breccia prism is dominated by the formation of foreset beds but various types of syn-volcanic intrusions contributed significantly. Submarine flank eruptions occurred in very shallow water on the flanks of the hyaloclastite prism in eastern Porto Santo. The island became consolidated by intrusion of numerous dikes and by emplacement of prominent intrusions that penetrate the entire volcanic succession. Volcanic sedimentation ended with the emplacement of a debris avalanche that postdates the last subaerial volcanic activity.  相似文献   

Solution-precipitation creep and fluid flow in halite: a case study of Zechstein (Z1) rocksalt from Neuhof salt mine (Germany)     

Zsolt Schléder  János L. Urai  Sofie Nollet  Christoph Hilgers 《International Journal of Earth Sciences》2008,97(5):1045-1056

Zechstein (Z1) rocksalt from the Fulda basin, from the immediate vicinity of the Hessen potash bed is folded into tight to isoclinal folds which are cut by an undeformed, 1 cm thick, coarse-grained halite vein. Microstructures were investigated in etched, gamma-irradiated thin sections from both the wall rock and the vein. The lack of synsedimentary dissolution structures and the widespread occurrence of plate-shaped and hopper grains in the wall-rock suggests that the sedimentary environment was perennial lake. Deformation microstructures are in good agreement with solution-precipitation creep process, and salt flow under very low differential stress. Strength contrast between anhydrite-rich and anhydrite-poor layers caused the small scale folding in the halite beds. The vein is completely sealed and composed mainly of euhedral to subhedral halite grains, which often overgrow the wall-rock grains. Those microstructures, together with the presence of occasional fluid inclusion bands, suggest that the crystals grew into a solution-filled open space. Based on considerations on the maximum value of in-situ differential stress, the dilatancy criteria, the amount of released fluids from the potash bed during metamorphism and the volume change, it is proposed that the crack was generated by hydrofracturing of the rocksalt due to the presence of the salt-metamorphic fluid at near-lithostatic pressure.  相似文献   

The AD 1717 rock avalanche deposits in the upper Ferret Valley (Italy): a dating approach with cosmogenic 10Be     

Naki Akçar  Philip Deline  Susan Ivy‐Ochs  Vasily Alfimov  Irka Hajdas  Peter W. Kubik  Marcus Christl  Christian Schlüchter 《第四纪科学杂志》2012,27(4):383-392

On 12 September AD 1717, a rock volume larger than 10 million m³ collapsed onto the Triolet Glacier, mobilized a mass composed of ice and sediment and travelled more than 7 km downvalley in the upper Ferret Valley, Mont Blanc Massif (Italy). This rock avalanche destroyed two small settlements, causing seven casualties and loss of livestock. No detailed maps were made at the time. Later investigators attributed accumulations of granitic boulders and irregular ridges on the upper valley floor to either glacial deposition, or the AD 1717 rock avalanche, or a complex mixture of glacial deposition, earlier rock avalanche and AD 1717 rock avalanche origin. In this study, we present cosmogenic ¹⁰Be exposure ages from nine boulders in the extensive chaotic boulder deposit with irregular ridges, two from Holocene glacier‐free areas, and one from a Little Ice Age moraine. Exposure ages between 330 ± 23 and 483 ± 123 a from eight of nine boulders from the chaotic deposit indicate that at least seven were deposited by the AD 1717 rock avalanche. The other three boulders yielded ¹⁰Be exposure ages of 10 900 ± 400, 9700 ± 400 and 244 ± 97 a, respectively. Our results are in good agreement with the existing chronology from dendrochronology and lichenometry, and radiocarbon analysis of wood samples, but not with older ¹⁴C ages from a peat bog in the upper part of the valley. Based on the new age control, the rock avalanche deposits cover the whole bottom of the upper Ferret valley. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Trace element diffusion and incorporation in quartz during heating experiments     

B.?RottierEmail author  H.?Rezeau  V.?Casanova  K.?Kouzmanov  R.?Moritz  K.?Schl?glova  M.?W?lle  L.?Fontboté 《Contributions to Mineralogy and Petrology》2017,172(4):23

Heating of quartz crystals in order to study melt and high-temperature fluid inclusions is a common practice to constrain major physical and chemical parameters of magmatic and hydrothermal processes. Diffusion and modification of trace element content in quartz and its hosted melt inclusions have been investigated through step-heating experiments of both matrix-free quartz crystals and quartz crystals associated with sulfides and other minerals using a Linkam TS1500 stage. Magmatic and hydrothermal quartz were successively analyzed after each heating step for Cu, Al, and Ti using electron probe micro-analyzer. After the last heating step, quartz crystals and their hosted melt inclusions were analyzed by laser ablation inductively coupled plasma mass spectrometry and compared to unheated samples. Heated samples reveal modification of Cu, Li, Na, and B contents in quartz and modification of Cu, Li, Ag, and K concentrations in melt inclusions. Our results show that different mechanisms of Cu, Li, and Na incorporation occur in magmatic and hydrothermal quartz. Heated magmatic quartz records only small, up to a few ppm, enrichment in Cu and Na, mostly substituting for Li. By contrast, heated hydrothermal quartz shows enrichment up to several hundreds of ppm in Cu, Li, and Na, which substitute for originally present H. This study reveals that the composition of both quartz and its hosted melt inclusions may be significantly modified upon heating experiments, leading to erroneous quantification of elemental concentrations. In addition, each quartz crystal also becomes significantly enriched in Cu in the sub-surface layer during heating. We propose that sub-surface Cu enrichment is a direct indication of Cu diffusion in quartz externally sourced from both the surrounding sulfides as well as the copper pins belonging to the heating device. Our study shows that the chemical compositions of both heated quartz and its hosted inclusions must be interpreted with great caution to avoid misleading geological interpretations.  相似文献   

The REE-Ti mineral chevkinite in comenditic magmas from Gran Canaria,Spain: a SYXRF-probe study   总被引：2，自引：0，他引：2  

Valentin?R.?TrollEmail author  Peter?M.?Sachs  Hans-Ulrich?Schmincke  Mari?Sumita 《Contributions to Mineralogy and Petrology》2003,145(6):730-741

The REE-Ti silicate chevkinite has been recognised previously in Miocene ignimbrites from Gran Canaria, and in correlative offshore syn-ignimbrite turbidites. We have estimated the partition coefficients of REE, Y, Zr and Nb for chevkinite and co-existing peralkaline rhyolitic (comendite) glass using synchrotron-XRF-probe analyses (SYXRF) in order to evaluate the role of this mineral in the REE budget of felsic peralkaline magmas. The Zr/Nb ratio of the chevkinite is 1.55–1.7, strongly contrasting with Zr/Nb of 6.5 in the associated glass. Zr shows a three-fold enrichment in chevkinite relative to the residual melt, whereas Nb is enriched by a factor >10. The enrichment of Ce and La in chevkinite is even more significant, namely 19 wt(%) Ce and 12 wt(%) La, compared to 236 ppm Ce and 119 ppm La in the glass. Chevkinite/glass ratios are 988±30 for La, 806±30 for Ce, 626±30 for Pr, 615±40 for Nd, 392±50 for Sm, 225±30 for Eu, 142±25 for Gd, 72±20 for Dy. For trace elements, we derived Kd_TE of 74±25 for Y, >8 for Hf, >50 for Th, 15±5 for Nb and 3.55±0.4 for Zr. Mineral/glass ratios for co-existing titanite are 28±10 for La, 86±20 for Ce, 98±30 for Pr, 134±35 for Nd, 240±50 for Sm, 50±20 for Eu, 96±25 for Gd, 82±25 for Dy, 99±30 for Y, 45±10 for Nb and 3±0.5 for Zr. Based on these data, the removal of only 0.05 wt% of chevkinite from a magma with initially 300 ppm Ce would deplete the melt by 93 ppm to yield 207 ppm Ce in the residual liquid. Chevkinite thus appears, when present, to be the controlling mineral within the LREE budget of evolved peralkaline magmas.Editorial responsibility: I. Parsons

---

Valentin R. TrollEmail: Phone: +353-1-6083856Fax: +353-1-6081199

  相似文献   

Transport of terrestrial organic carbon to the oceans by rivers: re-estimating flux- and burial rates   总被引：5，自引：0，他引：5  

B. Schlünz  R. R. Schneider 《International Journal of Earth Sciences》2000,88(4):599-606

 This study re-estimates one important component in the global carbon cycle: the modern global fluviatile organic carbon discharge- and burial rates. According to these results, approximately 430×10¹² g of terrestrial organic carbon are transported to the ocean in modern times. This amount is higher than the latest estimates but takes into account new data from Oceania not previously considered in global flux studies. However, only the minor amount of 10% or approximately 43×10¹² gC year^–1 is most likely buried in marine sediments. This amount is similar to the burial of marine organic carbon in the coastal ocean (55×10¹² gC year^–1). Adding both estimates gives approximately 100×10¹² gC year^–1, which is the value calculated by Berner (1982) for "terrestrial" deltaic-shelf sediments. However, the results in this study suggest that on a global scale the organic carbon content in coastal ocean sediments is not solely of terrestrial origin but a mixture of nearly equal amounts of marine and terrestrial organic carbon. The major part of the terrestrial organic carbon that enters the ocean by rivers (approximately 400×10¹² gC year^–1) seems to be either (a) remineralised in the ocean, whereas the mechanism by which the terrestrial organic carbon is oxidised in the ocean are unknown; or (b) is dispersed throughout the oceans and accumulates in pelagic sediments. Received: 9 November 1998 / Accepted: 25 May 1999  相似文献   

Microstructural evolution of deformation-modified primary halite from the Middle Triassic Röt Formation at Hengelo, The Netherlands     

Zsolt Schléder  János L. Urai 《International Journal of Earth Sciences》2005,94(5-6):941-955

The microstructure of halite from the subhorizontal, bedded Main Röt Evaporite Member at Hengelo, The Netherlands (AKZO well 382, depth interval of 420–460 m), was studied by transmitted and reflected light microscopy of gamma-irradiation decorated samples. Primary microstructures compare favourably with those found in recent ephemeral salt pans. Large, blocky, fluid-inclusion-poor halite grains and elongated chevrons are interpreted to have formed in the saline lake stage, while void-filling clear halite is interpreted to have formed during the desiccation stage of the salt pan. In addition, in all layers the grains are rich in deformation-related substructures such as slip bands and subgrains indicating strains of a few percent. The study of gamma-irradiation decorated thin sections shows that the main recrystallization mechanism is grain boundary migration. Grain boundary migration removes primary fluid inclusions and produces clear, strain-free new grains. Differential stresses as determined by subgrain size piezometry were 0.45–0.97 MPa. The deformation of the salt layers is probably related to Cretaceous inversion in the area.  相似文献   

Holocene evolution of the Triftje- and the Oberseegletscher (Swiss Alps) constrained with <Superscript>10</Superscript>Be exposure and radiocarbon dating     

Olivia Kronig  Susan Ivy-Ochs  Irka Hajdas  Marcus Christl  Christian Wirsig  Christian Schlüchter 《Swiss Journal of Geoscience》2018,111(1-2):117-131

To develop a more precise understanding of Alpine glacier fluctuations during the Holocene, the glacier forefields of the Triftjegletscher and the Oberseegletscher east of Zermatt in the Valais Alps, Switzerland, were investigated. A multidisciplinary approach of detailed geological and geomorphological field mapping combined with ¹⁰Be exposure and radiocarbon dating was applied. A total of twelve samples of boulders and bedrock were taken from both Little Ice Age (LIA) landforms, as documented by the Dufour map published in 1862, and from landforms outside of the LIA. The resulting ¹⁰Be ages range between 12590 ± 350 a and 420 ± 170 a. A piece of wood found embedded in the Little Ice Age moraine gave radiocarbon ages that range between 293 cal years BP up to modern (356–63 cal years before 2013). Based on these results, four tentative steps of the Holocene evolution could be distinguished. An early Holocene stage, which documents the decay of the Egesen stadial glaciers when the first parts of the study area became ice free. This was followed by a phase with no evidence of glacier advance. Then in the late Holocene, the glaciers advanced (at least) twice. An advance around 1200 a, as shown by several moraine ages, coincides with the Göschenen II cold phase. A more extensive readvance occurred during the LIA as shown on the historical maps and underpinned by one ¹⁰Be exposure age and the radiocarbon age. This later advance destroyed or overprinted the earlier landforms in most parts of the area.  相似文献   

A 16-ka δ18O record of lacustrine sugar biomarkers from the High Himalaya reflects Indian Summer Monsoon variability     

Michael Zech  Mario Tuthorn  Roland Zech  Frank Schlütz  Wolfgang Zech  Bruno Glaser 《Journal of Paleolimnology》2014,51(2):241-251

We investigated a late glacial–Holocene lacustrine sediment archive located at 4,050 m a.s.l. in the small carbonate-free catchment of Lake Panch Pokhari, Helambu Himal, Nepal. A δ¹⁸O sugar biomarker record was established by applying novel compound-specific δ¹⁸O analysis of plant sugar biomarkers (Zech and Glaser in Rapid Commun Mass Spectrom 23:3522–3532, 2009). This method overcomes analytical challenges such as extraction and purification faced by previous methods aimed at using δ¹⁸O of aquatic cellulose as a paleoclimate proxy. The δ¹⁸O results for sugar biomarkers arabinose, xylose and fucose agree well and reveal a pronounced trend towards lower δ¹⁸O values during the deglaciation and the onset of the Bølling/Allerød interstadial. By contrast, the period of the Younger Dryas is characterized by higher δ¹⁸O values. The early Holocene again reveals lower δ¹⁸O values. We suggest that our lacustrine δ¹⁸O record reflects coupled hydrological and thermal control. It is strongly related to changes in the oxygen isotopic composition of paleo-precipitation and resembles the δ¹⁸O records of Asian speleothems. With respect to the ‘amount effect,’ the record is interpreted as reflecting the Indian Summer Monsoon intensity. The precipitation signal is, however, amplified in our record by evaporative ¹⁸O enrichment that is controlled by the ratio of precipitation to evaporation. We suggest that our δ¹⁸O record reflects the variability of the Indian Summer Monsoon, which was strong during the Bølling/Allerød interstadial and early Holocene, but weak during the Younger Dryas stadial. This interpretation is corroborated by a pollen-based index for Lake Panch Pokhari that estimated the strength of the Indian Summer Monsoon versus the strength of the Westerlies. Millennial-scale synchronicity with the Greenland δ¹⁸O temperature records highlights the previously suggested strong teleconnections between the Asian Monsoon system and North Atlantic climate variability.  相似文献   

Deposition of rheomorphic ignimbrite D (Mogán Formation), Gran Canaria, Canary Islands, Spain     

Gustav Kobberger  Hans-Ulrich Schmincke 《Bulletin of Volcanology》1999,60(6):465-485

 Rheomorphic ignimbrite D (13.4 Ma, Upper Mogán Formation on Gran Canaria), a multiple flow–single cooling unit, is divided into four major structural zones that differ in fabric and finite strain of deformed pyroclasts. Their structural characteristics indicate contrasting deformation mechanisms during rheomorphic flow. The zones are: (a) a basal zone (vitrophyre) with pure uniaxial flattening perpendicular to the foliation; (b) an overlying shear zone characterized by asymmetric fabrics and a significantly higher finite strain, with an ellipsoid geometry similar to stretched oblate bodies; (c) a central zone with a finite strain geometry similar to that of the underlying shear zone but without evidence of a rotational strain component; and (d) a slightly deformed to non-deformed top zone where the almost random orientation of subspherical pyroclasts suggests preservation of original, syn-depositional clast shapes. Rheomorphic flow in D is the result of syn- to post-depositional remobilization of a hot pyroclastic flow as shown by kinematic modeling based on: (a) the overall vertical structural zonation suggested by finite strain and fabric analysis; (b) the relation of shear sense to topography; (c) the interrelationship of the calculated vertical cooling progression at the base of the flow (formation of vitrophyre) and the related vertical changes in strain geometry; (d) the complex lithification history; and (e) the consequent mechanisms of deformational flow. Rheomorphic flow was caused by load pressure due to an increase in the vertical accumulation of pyroclastic material on a slope of generally 6–8°. We suggest that every level of newly deposited pyroclastic flow material of D first passed through a welding process that was dominated by compaction (pure flattening) before rheomorphic deformation started. Received: 25 June 1997 / Accepted: 28 October 1998  相似文献