The distribution of mineral deposits, characterised as barite deposits, hematite-rich auriferous deposits and auriferous tourmaline–sulfide deposits, displays a regional sulfate–hematite–sulfide zoning along the thrust-delineated limbs of the Mariana anticline, in the south-eastern part of the Quadrilátero Ferrífero of Minas Gerais, Brazil. Cross-cut relationships of barite veins and sulfide lodes indicate that sulfidation occurred in a late-tectonic context, which is here attributed to the collapse of the ~0.6-Ga Brasiliano thrust front. Reconnaissance S-isotopic data from barite and pyrite (Antônio Pereira barite deposit and its adjacent gold deposit, respectively), and arsenopyrite (Passagem de Mariana gold deposit), suggest a new interpretation for the hydrothermal fluid overprint in the Mariana anticline. The Antônio Pereira barite has Δ33S values that are near zero, constraining the sulfate source to rocks younger than 2.45 Ga. The barite-δ34S values are between +19.6 and +20.8?‰. The Passagem arsenopyrite and tourmaline have Co/Ni ratios that define a positive linear trend with the Antônio Pereira pyrite. The latter has homogenous δ34S values, between +8.8 and +8.9?‰, which are compatible with thermochemical reduction of aqueous sulfate with the S-isotopic composition of the Antônio Pereira barite. 相似文献
Earth's oldest preserved conglomerates and basaltic pillow lavas at Isua, Greenland, provide robust field evidence for deep- and shallow-water environments on our planet within the first billion years of its formation. The conglomerates represent the first Paleoarchaean archive of sub-aerial erosion and shallow water sedimentation. These ca. 3700 million year old sedimentary rocks, now metamorphosed at amphibolite grade, comprise units of rounded quartz pebbles set in a sandy to muddy matrix that unconformably overlie an ophiolite sequence. The pillow lavas of the ophiolite are variolitic and essentially vesicle-free, indicative of formation in a deep water environment. Locally, an unconformity separates the conglomerates from the deformed ophiolite-related rocks; elsewhere the contact between these units is tectonic. Such field relationship between deep and shallow water environments resemble those preserved in younger orogenic belts, where obducted oceanic crust has been tectonically emplaced across terrestrial platforms or subaerial parts of forearc and backarc basins. 相似文献
An interdisciplinary study (major and minor elements, C and O isotopes, heavy and light minerals, phyllosilicates, wireline logs) in northern Namibia unraveled the hydrographic and hydraulic evolution of alluvial–fluvial sediments of the Kunene and Cubango megafans (Etosha-Cuvelai Basin). Three principal aquatic regimes were operative within the megafan complex: (1) the hydrographic regime, (2) the proximal hydraulic regime, (3) the distal hydraulic regime. The allogenic mineral assemblages mirror the hydrographic variation or drainage system and the lithological evolution of the fan sediments (alluvial–fluvial fan, lacustrine environment with evaporites, fan delta progradation). Authigenic heavy minerals are markers of the physical–chemical condition (Eh and pH values) of the hydraulic regime within the proximal fan at the basin margin. Authigenic heavy, light and clay minerals equally contribute to the determination of the fluid chemistry and temperature, as well as the source of chemical constituents of the former pore fluids percolating through the distal fan. Carbonatization was the most pronounced event in the distal hydraulic system and controlled by the presence of biogenic as well as atmospheric carbon. The isotope-based determination of the temperatures, albeit strongly fluctuating, do not exceed 40 °C. The overall pH values determined for the hydraulic regime within the distal fan range from slightly acidic to alkaline. The presence of zeolites attests to some short-lasting but strong deviations from the pH range, mainly towards more alkaline conditions. Heavy, light and clay mineral analyses proved to be a useful tool to determine the (paleo)hydrology of alluvial–fluvial fan systems in tropical arid to semiarid climates. 相似文献
This study presents a reconstruction of the tectonic history of an Upper Rotliegend tight gas field in Northern Germany. Tectonism of the greater study area was influenced by multiple phases of salt movement, which produced a variety of salt-related structural features such as salt walls, salt diapirs as well as salt glaciers (namakiers). A sequential 2D retro-deformation and stratal backstripping methodology was used to differentiate mechanisms inducing salt movement and to discuss their relation to regional tectonics. The quantitative geometric restoration included sedimentary balancing, decompaction, fault-related deformation, salt movement, thermal subsidence, and isostasy to unravel the post-depositional tectonic overprint of the Rotliegend reservoir rock. The results of this study indicate that reactive salt diapirism started during an Early Triassic interval of thin-skinned extensional tectonics, followed by an active diapirism stage with an overburden salt piercement in the Late Triassic, and finally a period of intensive salt surface extrusion and the formation of salt glaciers (namakiers) in Late Triassic and Jurassic times. Since the Early Cretaceous, salt in the study area has been rising by passive diapirism. 相似文献
During geothermal power production using a borehole doublet consisting of a production and injection well, the reservoir conditions such as permeability k, porosity φ and Skempton coefficient B at the geothermal research site Gross Schoenebeck/Germany will change. Besides a temperature decrease at the injection well and a change of the chemical equilibrium, also the pore pressure pp will vary in a range of approximately 44 MPa ± 10 MPa in our reservoir at ?3850 to ?4258 m depth. This leads to a poroelastic response of the reservoir rocks depending on effective pressure peff (difference between mean stress and pore pressure), resulting in a change in permeability k, porosity φ and the poroelastic parameter Skempton coefficient B. Hence, we investigated the effective pressure dependency of Flechtinger sandstone, an outcropping equivalent of the reservoir rock via laboratory experiments. The permeability decreased by 21% at an effective pressure range from 3 to 30 MPa, the porosity decreased by 11% (peff = 6 to 65 MPa) and the Skempton coefficient decreased by 24% (peff = 4 to 25 MPa). We will show which mechanisms lead to the change of the mentioned hydraulic and poroelastic parameters and the influence of these changes on the productivity of the reservoir. The most significant changes occur at low effective pressures until 15 to 20 MPa. For our in situ reservoir conditions peff = 43 MPa a change of 10 MPa effective pressure will result in a change in matrix permeability of less than 4% and in matrix porosity of less than 2%. Besides natural fracture systems, fault zones and induced hydraulic fractures, the rock matrix its only one part of geothermal systems. All components can be influenced by pressure, temperature and chemical reactions. Therefore, the determined small poroelastic response of rock matrix does not significantly influence the sustainability of the geothermal reservoir. 相似文献
Poverty among inner‐city residents is associated with their marginal status in the labor market. Marginalization in the labor market begins during youth when important educational and employment decisions are made. Analysis of 1990 U.S. Census tract data for San Antonio, Texas identifies the lack of a high school diploma, poverty, non‐employment, and non‐enrollment in school as conditions of marginality for youth. Spatial patterns of youth labor market marginalization show concentrations in the inner city and in sectors on the West, South, and Eastside. Regression analysis reveals that levels of youth marginalization are associated with neighborhood context represented by the employment, behavioral, and ethnic characteristics of the overall residential population of a census tract. 相似文献
The ability to deduce exhumation mechanisms from thermochronological data is hampered by the fact that assumptions on the thermal state of the lithosphere have to be made. Additional argumentation is generally required to discriminate between erosion-controlled and tectonically induced exhumation. This problem can be overcome by studying the spatial distribution of zircon and apatite (U-Th)/He and fission track data. In this work the variation of four different low temperature isotopic systems generating age trends along a sampling line is used to infer mechanisms of Quaternary exhumation in the Central High Himalayan Metamorphic Belt. Observed zircon age trends with southwards increasing cooling ages (from 0.5 to 1.7 Ma) are attributed to tectonically induced exhumation. The uniform apatite cooling ages clustered c. 0.5 Ma are attributed to erosion. 相似文献
This study investigates the influence of low ozone episodes on UV-B radiation in Austria during the period 1999 to 2015. To this aim observations of total column ozone (TCO) in the Greater Alpine Region (Arosa, Switzerland; Hohenpeissenberg, Germany; Hradec Kralove, Czech Republic; Sonnblick, Austria), and erythemal UV-B radiation, available from 12 sites of the Austrian UV-B monitoring network, are analyzed. As previous definitions for low ozone episodes are not particularly suited to investigate effects on UV radiation, a novel threshold approach—considering anomalies—is developed to provide a joint framework for the analysis of extremes. TCO and UV extremes are negatively correlated, although modulating effects of sunshine duration impact the robustness of the statistical relationship. Therefore, information on relative sunshine duration (SDrel), available at (or nearby) UV-B monitoring sites, is included as explanatory variable in the analysis. The joint analysis of anomalies of both UV index (UVI) and total ozone (∆UVI, ∆TCO) and SDrel across sites shows that more than 65% of observations with strongly negative ozone anomalies (∆TCO < −1) led to positive UVI anomalies. Considering only days with strongly positive UVI anomaly (∆UVI > 1), we find (across all sites) that about 90% correspond to negative ∆TCO. The remaining 10% of days occurred during fair weather conditions (SDrel ≥ 80%) explaining the appearance of ∆UVI > 1 despite positive TCO anomalies. Further, we introduce an anomaly amplification factor (AAF), which quantifies the expected change of the ∆UVI for a given change in ∆TCO.
Precise positioning with the current Chinese BeiDou Navigation Satellite System is proven to be of comparable accuracy to the Global Positioning System, which is at centimeter level for the horizontal components and sub-decimeter level for the vertical component. But the BeiDou precise point positioning (PPP) shows its limitation in requiring a relatively long convergence time. In this study, we develop a numerical weather model (NWM) augmented PPP processing algorithm to improve BeiDou precise positioning. Tropospheric delay parameters, i.e., zenith delays, mapping functions, and horizontal delay gradients, derived from short-range forecasts from the Global Forecast System of the National Centers for Environmental Prediction (NCEP) are applied into BeiDou real-time PPP. Observational data from stations that are capable of tracking the BeiDou constellation from the International GNSS Service (IGS) Multi-GNSS Experiments network are processed, with the introduced NWM-augmented PPP and the standard PPP processing. The accuracy of tropospheric delays derived from NCEP is assessed against with the IGS final tropospheric delay products. The positioning results show that an improvement in convergence time up to 60.0 and 66.7% for the east and vertical components, respectively, can be achieved with the NWM-augmented PPP solution compared to the standard PPP solutions, while only slight improvement in the solution convergence can be found for the north component. A positioning accuracy of 5.7 and 5.9 cm for the east component is achieved with the standard PPP that estimates gradients and the one that estimates no gradients, respectively, in comparison to 3.5 cm of the NWM-augmented PPP, showing an improvement of 38.6 and 40.1%. Compared to the accuracy of 3.7 and 4.1 cm for the north component derived from the two standard PPP solutions, the one of the NWM-augmented PPP solution is improved to 2.0 cm, by about 45.9 and 51.2%. The positioning accuracy for the up component improves from 11.4 and 13.2 cm with the two standard PPP solutions to 8.0 cm with the NWM-augmented PPP solution, an improvement of 29.8 and 39.4%, respectively. 相似文献