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941.
The concept of the Borehole Diffusive Flux Apparatus (BDFA) is presented herein. The BDFA is an innovative apparatus designed to provide continuous direct access to an undisturbed column of sediment that can be monitored at multiple discrete vertical intervals to provide high-resolution characterization of local-scale mass transfer and attenuation. The conceptual basis and technical design of the device are presented, along with an example of borehole design and installation at a field site. Mathematical simulations are used to illustrate its application for two scenarios. The results of these simulations indicate that test periods of several weeks to a few months should be sufficient to obtain robust results. The device has the potential to improve our ability to characterize critical mass-transfer and attenuation processes and to quantify the associated rates. This information is key to the evaluation of remediation alternatives, for enhancing the accuracy of mathematical models, and to support more effective long-term management of large groundwater contaminant plumes present at many sites.  相似文献   
942.
The advent in satellite altimetry with the most accurate satellite radar altimeter since 1992 and its successive missions have enabled the routine global monitoring of water-level (or stage) for surface waters and changes in the quantities of dammed water reservoirs. However, satellite altimeter measurements typically have spatial resolution capable of observing only large water bodies, such as major lakes and rivers. This paper addresses the challenges of how to investigate water levels in medium (~?1 km in width) to small (~?100 m and narrower) rivers. Comparisons between the ENVISAT altimetry ICE-1 waveform retracking height and standard water-level measurements for multiple sections of Ohio River, Columbia River, and Red River of the North in the United States (US) reveals that the satellite altimetry measured water levels agree well with those observed at nearby US Geological Survey gaging stations over the 10-year period starting from 2002. The significant results include those obtained at Thompson, North Dakota (ND, correlation coefficient or R value of 0.76 between satellite and in situ water-level measurements) and Fargo, ND (R?=?0.74), where the stream channels of Red River are merely?~?50 m and ~?40 m wide, respectively, under normal climatic conditions. In addition, demonstrations of the approach over largely inaccessible portions of Tigris–Euphrates Rivers and Helmand River in the Middle East aided in understanding hydrology in these systems. This study demonstrates the ability of satellite radar altimetry to characterize rivers in these study regions which are much narrower than 100 m in width.  相似文献   
943.
Leachate was a major cause of high risk classification. This landfill was set as one with highest possible risk classification due to high vulnerability of private water wells to contamination from leachate flows. The aim of this study is to determine the present and possible environmental risks of the leachate spreading from solid waste dumping site in Tunceli and offer solutions for those determined environmental risks. For this purpose, the characteristics of the leachate were monitored at two station points detected in the solid waste dumping site for 7 months. The characteristics of the leachate were found for pH between 7.9 and 8.7. Oxidation reduction potential (ORP) occurred between ??143 and ??48 mV while conductivity was between 2.8 and 2.6 mS. Total solid matter (TSM) and suspended solid matter (SSM) were between 1000 and 7000 mg/l, 0.2–22.5 mg/l, respectively, while total volatile solids (TVS) occurred between 300 and 1800 mg/l for the two stations. Alkalinity was approximately between 290 and 5210 mg/l, while biological oxygen demand (BOD5) and chemical oxygen demand (COD) results were 15–606 mg/l and 60–1160 mg/l, respectively, for two stations in all sampling time. In both stations, orthophosphate, ammonium nitrogen, nitrate, sulfate, and chloride analyses stayed between 3.04 and 921.1 mg/l; 0.29–619.36 mg/l; 8.94–135.04 mg/l; 125.9–1360.9 mg/l and 99.9–1249.9 mg/l, respectively, in 6 months. As a result of the characterization studies obtained from the leachate, it was found that the amounts of water entering into the waste mass and the retention period of the water in the mass were very effective in the temporal character change of the leachate. According to the Discharge Standards for Solid Waste Assessment and Disposal Facilities and Discharge to Waste Water Infrastructure Facilities of waste management regulation, the results were found to be risky. Consequently, the site in question needs to be urgently rehabilitated when considering the environmental risks of the leachate spreading from the site.  相似文献   
944.
The occurrence of uranium in groundwater is of particular interest due to its toxicological and radiological properties. It has been considered as a relevant contaminant for drinking water even at a low concentration. Uranium is a ubiquitously occurring radionuclide in the environment. Four hundred and fifty-six (456) groundwater samples from different locations of five districts of South Bihar (SB) were collected and concentrations of uranium (U) were analyzed using a light-emitting diode (LED) fluorimetric technique. Uranium concentrations in groundwater samples varied from 0.1 µg l?1 to 238.2 µg l?1 with an average value of 12.3 µg l?1 in five districts of Bihar in the mid-eastern Gangetic plain. This study used hot spot spatial statistics to identify the distribution of elevated uranium concentration in groundwater. The hypothesis whether spatial distribution of high value and low value of U is more likely spatially clustered due to random process near a uranium hotspot in groundwater was tested based on z score and Getis-Ord Gi* statistics. The method implemented in this study, can be utilized in the field of risk assessment and decision making to locate potential areas of contamination.  相似文献   
945.
Recent studies have indicated that in situ aerobic bioremediation is one of the most effective methods for remediating groundwater contaminated with nitrobenzene (NB). Aerobic bioremediation is largely dependent on the maintenance of adequate dissolved oxygen (DO) levels in the groundwater. Traditional in situ aeration has various disadvantages, such as high operational costs and nonuniform aeration. In this study, integrative cubes were prepared and utilized as a novel biological permeable reactive barrier (bio-PRB) medium to enhance the aerobic bioremediation of NB-contaminated groundwater. The results revealed an NB removal rate greater than 98.68% after 15–20 days of continuous oxygen release from the bio-PRB medium. DO concentrations reached 8.0 mg/L during treatment, and NB-degrading bacteria were able to tolerate a range of pH conditions. This multifaceted bio-PRB medium can simultaneously adsorb and biodegrade NB, release oxygen, and neutralize the pH with phosphate buffer. The results of this study suggest that this bio-PRB medium represents a highly effective in situ bioremediation method for NB-contaminated groundwater.  相似文献   
946.
The plane strain condition is a common, but polyaxial stress state for geotechnical structure designs, in which the selection of an appropriate yield or failure criterion is crucial to reasonably account for the intermediate principal stress. Under plane strain condition, a unified linear yield criterion for seven commonly used geotechnical yield criteria is presented in conjunction with the inductive method. These seven yield criteria considered in this study are the Mohr–Coulomb, Tresca, Drucker–Prager, Mogi–Coulomb, Extended Matsuoka–Nakai, Extended Lade–Duncan criteria, and the Unified Strength Theory. The generalized analytical solutions for earth pressure of retaining walls, critical load of strip foundations as well as stress and displacement of circular tunnels are derived on the basis of the proposed unified yield criterion, and their respective theoretical significance is analyzed. Thereafter, the critical load of strip foundations obtained herein is compared with two numerical results from the literature. Furthermore, the effect of strength theory on result differences of the three typical geotechnical problems by simply selecting constants, which conform to different yield criteria, is explored through a parametric study. It is found that the proposed unified yield criterion is convenient for investigating analytical solutions of the aforementioned geotechnical structures. The strength theory effect due to adopting different yield criteria is considerably significant, which cannot be ignored. Additionally, recommendations are provided on how to make use of these seven yield criteria for an optimum design.  相似文献   
947.
Reservoir regulation and local climate both affect the heat budget of tributary bay. It is difficult for traditional methods to identify the influence of different factors on heat budget quantitatively. In this paper, for analysis of the control mechanisms of the heat budget of a large reservoir tributary, the water temperature distribution, and heat budget processes of the Meixi River, a typical tributary to the Three Gorges Reservoir was measured, and a new method was used to calculate the heat content composition of the tributary bay and identify the key factor of the heat balance. The result shows significant variation in the spatial and temporal distributions of water temperatures in the Meixi River, ranging from 12.4 to 28.9 °C on the surface and 12.0 to 24.4 °C at the bottom. The total heat exchange across the air–water interface that ranges from 0.1 to 6% of the budget is not the primary control factor of the annual tributary heat budget. Rather, the change in water depth produced by regulation of the Three Gorges Reservoir is the primary control factor of the tributary heat budget in the whole year, which ranges from 72 to 99% of the budget. The water temperature difference between the main stream and tributary is the not key factor of the heat budget, which ranges from 0.1 to 28% of the heat budget.  相似文献   
948.
The toxicity and metal bioavailability were studied in dredged sediments from Rodrigo de Freitas Lagoon (Rio de Janeiro, RJ, Brazil) using acute and avoidance tests with Eisenia andrei, and reproduction tests with Folsomia candida. The sediment was mixed with an artificial soil, and two natural soils (ferralsol and chernosol—representative Brazilian tropical soils) to obtain the following doses: 1, 3, 6, 12, 18, 24 and 30%. Total metal concentrations were determined in the sediment to support the interpretation of ecotoxicological data. Metal concentrations in the mixtures were in agreement with the threshold limits established by Brazilian law. However, significant avoidance responses were found on doses ≥?3% and were the most sensitive endpoint. Earthworm mortality found in artificial soil mixtures (LC50?=?3.9) suggests higher toxicity levels than those obtained in ferralsol (LC50?=?7.6%) and chernosol (11.0%) treatments. Earthworm mortality, avoidance responses and collembolan reproduction levels found in ferralsol mixtures (LC50?=?9.2; avoidance EC50?=?2.3%; reproduction EC50?=?2.8%) were higher compared to chernosol treatments (LC50?=?11.0%; avoidance EC50?=?4.3%; reproduction EC50?=?4.9%). The reduction of toxicity levels in chernosol mixtures is probably due to the abundance of expansive clay minerals in chernosols with capacity of adsorbing metals and other xenobiotic substances from soil pore water, decreasing metal bioavailability. Finally, threshold limits defined by Brazilian legislation for soil quality and land disposal of dredged sediments are not sufficient to prevent noxious effects on soil fauna and should be complemented with a preliminary ecotoxicological evaluation.  相似文献   
949.
Because Taiwan is a subtropical island, many pleasure beaches are situated on its coast. However, according to long-term monitoring data, fecal contamination at Taiwanese coastal beaches frequently exceeds the U.S. Environmental Protection Agency (EPA) guidelines. To avoid public health hazards, mapping the spatial extent of this contamination is crucial. This study applied indicator kriging (IK) to probabilistically assess the water quality of bathing beaches on the Taiwanese coast. Moreover, because the discontinuity of the traditional Cartesian coordinate established on an island coastline is difficult for geostatistical estimates, this study proposed a novel kriging estimation approach to deal with this problem. First, a one-dimensional (1-D) cyclic coordinate system of the Taiwanese coast was established using primary and secondary coordinates at each beach site. Escherichia coli (E. coli) and enterococci concentrations at coastal beaches were converted into indicator variables according to the U.S. EPA guidelines. IK was then used to spatially model the occurrence probabilities that exceeded the U.S. EPA guidelines for E. coli and enterococci. Finally, the water quality of bathing beaches on the Taiwanese coast was classified on the basis of the estimated probabilities. The study results indicated that bathing on the central western, northeastern, and southeastern Taiwanese coasts poses a potential threat to human health caused by high levels of fecal contamination. Moreover, primary and secondary coordinates established at beach sites were capable of analyzing the spatial variability and kriging estimates of the 1-D cyclic coordinates along the coastline.  相似文献   
950.
Spectral vegetation indices (VIs) are a well-known and widely used method for crop state estimation. The ability to monitor crop state by such indices is an important tool for agricultural management. Even though differences in imagery and point-based spectroscopy are obvious, their impact on crop state estimation by VIs is not well-studied. The aim of this study was to assess the performance level of the selected VIs calculated from spaceborne multispectral imagery and point-based field spectroscopy in application to crop state estimation. For this purpose, irrigated chickpea field was monitored by RapidEye satellite mission and additional measurements by field spectrometer were obtained. Estimated VIs average and coefficient of variation from each observation were compared with physical crop measurements: leaf water content, LAI and chlorophyll level. The results indicate that indices calculated from spaceborne spectral images regardless of the claimed response commonly react on phenology of the irrigated chickpea. This feature makes spaceborne spectral imagery an appropriate data source for monitoring crop development, crop water needs and yield prediction. VIs calculated from field spectrometer were sensitive for estimating pigment concentration and photosynthesis rate. Yet, a hypersensitivity of field spectral measures might lead to a very high variability (up to 69%) of the calculated values. Consequently, the high spatial variability of field spectral measurements depreciates the estimation agricultural field state by average mean only. Nevertheless, the spatial variability might have certain behavior trend, e.g., a significant increase in the active growth or stress and can be an independent feature for field state assessment.  相似文献   
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