Influence of non-photosynthetic pigments on light absorption and quantum yield of photosynthesis in the western equatorial Pacific and the Subarctic North Pacific     

Anil Kumar Vijayan  Takashi Yoshikawa  Shigeki Watanabe  Hiroaki Sasaki  Kazuhiko Matsumoto  Sei-Ichi Saito  Shigenobu Takeda  Ken Furuya 《Journal of Oceanography》2009,65(2):245-258

Regional variations in the contribution of non-photosynthetic pigments (ā _np^*) to the total light absorption of phytoplankton (ā _ph^*) and its influence on the maximum quantum yield of photosynthesis (φ _m) were investigated. In the western equatorial Pacific, the surface ā _np^* : ā _ph^* ratio was higher in the western warm pool than that in the upwelling region. This difference appears to be attributable to severe nitrate depletion and higher percentage of prokaryotes, which can accumulate very high concentrations of zeaxanthin in the western warm pool. In the subarctic North Pacific, the ā _np^* : ā _ph^* ratio was expected to be higher in the Alaskan Gyre where the thermocline is sharper and iron limitation may possibly be more severe than in the Western Subarctic Gyre. However, the ratio was actually higher in the Western Subarctic Gyre, contradictory to our expectations. This east-west variation appears to be attributable to changes in the taxonomic composition; cyanobacteria were more abundant in the Western Subarctic Gyre. The values of ā _np^* : ā _ph^* and its vertical variations were relatively small in the subarctic North Pacific compared to those in the western equatorial Pacific. These inter-regional variations appear to be attributable to the lower solar radiation intensity, smaller percentage of cyanobacteria, and relatively strong vertical mixing in the subarctic North Pacific. The spatial variations in ā _np^* : ā _ph^* significantly influence φ _m. In comparison with φ _m based on the total light absorption (φ _{m ph}), the values corrected for the contribution of non-photosynthetic pigments (φ _{m ps}) showed an increase in both the western equatorial Pacific and the subarctic North Pacific.  相似文献   

Thermochronology for the Granitic Pluton Related to Lead-Zinc Mineralization in Tsushima, Japan     

Hiroaki IKEMI  Nobutaka SHIMADA  Hitoshi CHIBA 《Resource Geology》2001,51(3):229-238

Abstract: K–Ar datings and oxygen isotope analyses revealed a cooling history of the Uchiyama granitic pluton, which is genetically related to the Pb-Zn deposits (Taishu mine) in the Tsushima Islands, Japan. The pluton intrudes into the Paleogene Taishu Group to form the biotite-hornfels zone, while the Taishu vein-type Pb–Zn deposits occur in fissures developed in the non-hornfels zone about 1 to 3 km westward from the contact. Amphibole and biotite K-Ar ages of the pluton have a wide range from 19 to 13 Ma. Oxygen isotopes of the biotite and coexisting quartz grains indicate that isotopic exchange reactions have occurred under subsolidus conditions, and that the K-Ar ages are affected by various cooling rates in the pluton. The mineralization age of the Taishu ore deposits is obtained for the first time to be 15.40.8 Ma by a K-Ar age of 2 M ₁–muscovite in a calcite–quartz–muscovite–chlorite veinlet of the Shintomi orebody. Whole rock K-Ar ages of biotite-hornfels near the pluton represent similar ages to the ore deposits. Using blocking temperature calculated from reported diffusivity for argon, the pluton was cooled from 560 to 350C in the period of 17 to 14 Ma. The vein formation took place after the time when temperature in wall rocks of the pluton had dropped below the brittle-plastic transition (about 400C). These results imply that the cooling of the pluton has caused injection of magmatic fluids into meteoric hydrothermal systems, and the Pb-Zn mineralization has occurred due to this mixing at the age of about 15 Ma.  相似文献   

Distribution of arsenic and other trace elements in the Holocene sediments of the Meghna River Delta, Bangladesh     

M. Hawa Bibi  Faruque Ahmed  Hiroaki Ishiga 《Environmental Geology》2006,50(8):1243-1253

Geochemical study of the Holocene sediments of the Meghna River Delta, Chandpur, Bangladesh was conducted to investigate the distribution of arsenic and related trace and major elements. The work carried out includes analyses of core sediments and provenance study by rare earth element (REE) analysis. Results showed that the cores pass downward from silty clays and clays into fine to medium sands. The uppermost 3 m of the core sediments are oxidized [average oxidation reduction potential (ORP) + 230 mV], and the ORP values gradually become negative with depths (−45 to −170 mV), indicating anoxic conditions prevail in the Meghna sediments. The REE patterns of all lithotypes in the study areas are similar and are comparable to the average upper continental crust. Arsenic and other trace elements (Pb, Zn, Cu, Ni, and Cr) have greater concentrations in the silts and clays compared to those in the sands. Positive correlation between As and Fe was found in the sediments, indicating As may be adsorbed on Fe oxides in aquifer sediments.  相似文献   

Speciation of Chromium in Artificially Contaminated Soil Reference Material GSJ JSO-2 Using XANES and Chemical Extraction Methods     

Hiroshi Tsuno  Atsuyuki Ohta  Hiroyuki Kagi  Noboru Imai  Hiroaki Tao  Masaharu Nomura 《Geostandards and Geoanalytical Research》2006,30(1):55-62

The oxidation states of chromium in GSJ JSO-2 (artificially contaminated soil) and three other geochemical reference materials (GSJ JSO-1, JLS-1 and JMS-1) were observed using X-ray near edge structure (XANES). For comparison, other artificially contaminated soil materials (mimic-JSO-2) were prepared by adding Cr(VI) into JSO-1. Their oxidation states of chromium were determined using XANES. The chromium contents were 1118 μg g^-1 for JSO-2, 1352 μg g^-1 for mimic-JSO-2 and 69-113 μg g^-1 for the other reference materials. Most chromium was present as hexavalent in mimic-JSO-2. No hexavalent species were detected in other samples. These results for chromium oxidation state in JSO-2 and mimic-JSO-2 obtained with XANES resembled those obtained from a chemical extraction method. The present JSO-2 has no trace of Cr(VI), although Cr(VI) was added as a major species during preparation. On the other hand, the content of Cr(VI) obtained in mimic-JSO-2 agreed with the original Cr(VI) content. A time-elapse study showed that Cr(VI) contents in mimic-JSO-2 decreased gradually to 70% of the original abundance during 240-day preservation in dry conditions. Moreover, the abundance of Cr(VI) decreased markedly to 15% after 240 days in the wet mimic-JSO-2 containing 20% m/m of water. These experiments suggested that soil humidity enhanced the reduction of Cr(VI) and that Cr(VI) was reduced even in dry conditions. Consequently, it is reasonable to infer that Cr(VI) doped into JSO-2 was completely reduced to Cr(III) during the preservation period of 5 years. The certification of the long-term stability of the chemical form in reference materials will be much more important in future.  相似文献   

High precision slip distribution of the 1944 Tonankai earthquake inferred from tsunami waveforms: Possible slip on a splay fault     

Toshitaka Baba  Phil R. Cummins  Takane Hori  Yoshiyuki Kaneda 《Tectonophysics》2006,426(1-2):119

Inversion of tsunami waveforms is a well-established technique for estimating the slip distributions of subduction zone earthquakes, with some of the most detailed results having been obtained for earthquakes in the Nankai Trough, SW Japan. The present study, although it uses a method and tsunami waveform data set almost identical to previous study, aims to improve on previous work by using a more precise specification of initial conditions for the calculation of tsunami Green's functions. Specifically, we incorporated four improvements in the present study: (1) we used a realistic plate model based only on seismic survey results, and assumed it to be the fault plane of the 1944 Tonankai earthquake; (2) the smallest subfaults consistent with the long wavelength approximation were used in the tsunami inversion analysis; (3) we included the effect of horizontal displacement of the ocean bottom on tsunami generation; and (4) we performed a checkerboard resolution test. As obtained in previous studies, a zone of high slip (> 2.0 m) was resolved off the Shima Peninsula. However, the more precise calculation of tsunami Green's functions has revealed additional detail that was not evident in previous studies, which we demonstrate is resolvable and correlates with the position of known faults in the accretionary prism. While there was little or no slip near the trench axis in the eastern part of the rupture zone, there was up to 1.5 m of slip resolved within 30 km of the trough axis in the western part, along the coast of the Kii Peninsula. This troughward slip zone coincides with the position of a large splay fault mapped in multichannel reflection surveys. Furthermore, it is also clear that the upper edge of the Enshu fault off Shima and Atsumi peninsulas is consistent with the up-dip limit of slip in the eastern part of our model. We tested the possibility that slip occurred on the former splay fault instead of on the plate interface during the 1944 Tonankai earthquake, and find that slip on this splay fault is also consistent with the data, although we cannot distinguish whether slip was dominant on the splay fault or on the plate interface. We further suggest that the position of the Enshu fault may be determined by the subduction of topographic highs, and that such faults may have an important influence on the up-dip rupture limit of the 1944 Tonankai and, potentially, other subduction zone earthquakes.  相似文献   

Ore value-tonnage diagrams for resource assessment   总被引：4，自引：0，他引：4  

Tetsuya Shoji  Hiroaki Kaneda 《Natural Resources Research》1998,7(1):25-36

An ore value-tonnage diagram has been proposed for assessing mineral resources. Diagrams of W+Mo, and Pb+Zn deposits show a good linearity between ore value and logarithms of cumulative ore tonnage. Diagrams of the massive sulfide, orthomagmatic, placer, porphyry, replacement, and stratabound types are also linear. It is assumed, therefore, that deposits of each of these commodities and these types belong to a single population. In contrast, the ore value-tonnage relations of all the deposits analyzed here is approximated by the combination of two exponential functions. The same feature is seen for deposits of the Cu+W+Mo, Cu+Pb+Zn, and Au+Ag commodities, and of the vein and unconformity-related types. This suggests that deposits belonging to each of such categories are divided into the high and low value groups. We can expect, accordingly, to find high value deposits of such categories.  相似文献   

Rapid change in nitrate and sulfate concentrations observed in early stage of precipitation and their deposition processes     

Hiroaki Minoura  Yasunobu Iwasaka 《Journal of Atmospheric Chemistry》1996,24(1):39-55

The concentrations of H⁺, nitrate (NO₃ ^-), and sulfate (SO₄ ^2-) in rainwater and their temporal changes were analyzed on the basis of continuous observation from 1 July 1991 to 30 June 1992 at a suburb of Nagoya, Japan. The yearly average for pH was 4.4. In general, an increasing pH with increase in precipitation amount was observed for rain events. Relatively high pH rainwater was sometimes observed at the beginning of rainfall, even though high concentrations of NO₃ ^- and SO₄ ^2- were involved. The high pH values were considered to be caused by the neutralization process with particulate matter containing cations. The yearly averaged ratio of equivalent concentration of nitrate to sulfate (N/S) in rainwater was 0.58. In the early stage of rain, the N/S value was usually more than 1.0 due to the difference of scavenging process between NO₃ ^- and SO₄ ^2-. High values of N/S ranging from 5 to 10 were found under the atmospheric conditions of calm winds and low humidity, during which it is possible that atmospheric particles float for a long time in the air before a rain event. The adsorption of NO₃ ^- in the early stage of rainfall by particulate matter was suggested from the difference in scavenging processes of NO₃ ^- and SO₄ ^2-. A possible scavenging process, called limb cloud scavenging, is presented to explain the interaction of particles and nitrate ions at the early stage of rain. In limb cloud scavenging, the repeated migration of cloud particles or raindrops between the inside and outside of clouds increases the absorption of ions to a highly condensed level, thus increasing the N/S value of rainwater. The influence of global scale seasonal phenomena with large amounts of particulates, such as typhoons or Asian dust storms, was also studied.  相似文献   

Impact of fish net pen culture on the benthic environment of a cove in South Japan     

Hiroaki Tsutsumi 《Estuaries and Coasts》1995,18(1):108-115

Over the past three decades, fish net pen culture has been developed in the coastal waters of Japan. However, serious organic pollution of the surrounding water and sediment followed the development of this new style of fishery. This paper reports a typical example of the environmental disturbance that has occurred due to the organic pollution resulting from fish net pen culture. Since fish cultivation was initiated in 1973, oxygen depletion of the bottom water and extremely reducing conditions within the sediment have occurred during the summer. These environmental disturbances resulted in unusual dynamics of the benthic communities including defaunation in the summer and recolonization of the azoic areas from autumn to the next spring. Significant changes in the benthic fauna were observed between benthic communities before and after organic pollution of the sediment. Molluscs were originally the most dominant benthic fauna. As organic pollution of the bottom sediment progressed, the molluscs were replaced by polychaetes. Likewise, total biomass of the benthic fauna decreased markedly over the past two decades. Prior to contamination, the organic matter deposited on the sediment was decomposed by the action of bacteria, ciliates, meiofauna, and macrofauna. The addition of organic material resulting from fish culture has overwhelmed these decomposition mechanisms, and conditions have worsened as organic matter is continuously added to the sediment. Contamination of marine sediment by the net pen cultivation of fish sets up a vicious cycle: the addition of exogenous sources of organic material increases the need for a more vigorous decomposition process while actually creating conditions that limit the rate of the necessary decomposition activity. The sustainable development of fish net pen culture will require the creation of a new technology that efficiently promotes the decomposition of organic matter deposited below the pen nets.  相似文献   

Stability of pentlandite in the Fe-Ni-Co-S system     

H. Kaneda  S. Takenouchi  T. Shoji 《Mineralium Deposita》1986,21(3):169-180

Pentlandite has a wide compositional range in the Fe-Ni-Co-S system and the Fe-Ni-S system. The metal : sulfur atomic ratio is approximately 9 : 8. The Co content of pentlandite from the Kamaishi ore deposit and one from the Outokumpu ore deposit (Knop et al. 1965) varies from a Co-free to nearly a Co₉S₈ composition. Pentlandite forms a complete solid solution between (Fe, Ni)_9±x S₈ and Co_9±x S₈ in the 600°–300°C temperature range. On the other hand, it is presumed that the pentlandite solid solution decomposes into two fields toward the (Fe, Ni)₉S₈ and Co₉S₈ members at 200°C. The field of solid solution at 500°C is the most extensive and includes all of the other solid-solution fields. The metal : sulfur ratio of the solid solution varies systematically, i.e., the Fe-rich field sinks toward the Fe-Ni-Co plane away from the M₉S₈ section, and contrarily the Ni-rich field shifts toward the sulfur apex. The d ₀₄₄ value decreases with increasing S, Ni, or Co contents in pentlandite. The Kamaishi pentlandites, Iwate Prefecture, Japan, lie within or close to the solid-solution field at 300°C, showing a very good correlation with the Co : Ni ratio of the homogeneous natural pyrrhotite phase.  相似文献   

Inland penetration of the sea breeze over the suburban area of Tokyo     

Hiroshi Yoshikado  Hiroaki Kondo 《Boundary-Layer Meteorology》1989,48(4):389-407

Observational results of the structure of the sea breeze over the urban and suburban areas of Tokyo for four summer days are presented.On two of these days, the inland penetration of the sea breeze front could be clearly traced. In one case, the sea breeze was first observed along the shores of Tokyo Bay around 0900 JST, and propagated in three hours through the Tokyo City area, the width of which is about 20 km. It then advanced inland at a rate of 16 km h^–1. Prior to the arrival of the sea breeze at the suburban site, the mixing height had remained at about 600 m for four hours. With the arrival of the sea breeze front, accompanied by an abrupt change in wind speed and direction, the mixing height increased sharply to 1700 m. It is suggested that this behavior and the structure of the front are intensified due to the urban effect, or the difference in the thermal characteristics between the urban and rural areas.On the days without a sea breeze front, the land breeze system during the early morning was less intense, allowing the sea breeze to develop simultaneously with the inland valley wind and easily form a large-scale local wind system during the morning hours. In both cases, the vertical motion accompanying the local wind system works as a feedback mechanism to control the local winds by modifying the thermal and pressure fields.  相似文献