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101.
Norimichi Takenaka Tohru Daimon Akihiro Ueda Keiichi Sato Masaru Kitano Hiroshi Bandow Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150
Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10-10 mol dm-3), ca. 10 hr in oxidation by H2O2 (2×10-4 mol dm-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase. 相似文献
102.
Seasonal variability regarding the nature of precipitation and the activity of cumulus convection during the 1991 Meiyu season of Changjiang-Huaihe River Basin(Jianghuai)has been investigated by calculating apparent heat source/apparent moisture sink and analyzing TBB(cloud-top blackody radiation temperature)data.It is found that three periods of strong ascending motion during the Meiyu season lead to three episodes of heavy rain,and the latent heat due to the precipitation is of the sole heat source of the atmosphere.The nature of precipitation shows distinct seasonal variability,from frontal precipitation of the first episode to the extremely strong convective precipitation of the third episode.TBB field of East Asia may well reflect not only the intensity of convection and rainfall,but also the movement of rain belt and convection belt.In the whole Meiyu season.convection belt mainly stays in Jianghuai.but may shift within the domain of East Asia.Its locating in Jianghuai or not determines the maintenance or break of Meiyu.In the third episode,the narrow convection belt over Jianghuai is mainly caused by southwest monsoon which takes moist and convective atmosphere from tropical ocean. 相似文献
103.
Hiroshi Nagasawa Douglas P Blanchard Jeffrey W Jacobs Joyce C Brannon John A Philpotts Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600
Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the 26Al-26Mg chronometer. 相似文献
104.
105.
It has been found that samples consisting of a homogeneous vitrinite show a good ESR correlation of spin concentration with geothermal parameters and that a graph of ESR line width vs g-value can be useful in the identification of the maceral and the determination of the coalification rank. 相似文献
106.
We perform a complete reconstruction of the series of the nutation for a rigid Earth model with the use of the very accurate
theories ELP2000 and VSOP82 for the motion of the Moon and the planets respectively, in such a way that all the individual
contributions up to 0.005 mas should be taken. This implies the introduction of the planetary effects, of the influence of
second-order parts of the potential of the Earth (J3, triaxiality), and some improvements due to an extension of the theory
at the second order. All this increase notably the number of coefficients to be taken in account, and modifies also in a significant
way the value of some of them. 相似文献
107.
M. Chauvin H.-G. Florén M. Jackson T. Kamae T. Kawano M. Kiss M. Kole V. Mikhalev E. Moretti G. Olofsson S. Rydström H. Takahashi J. Lind J.-E. Strömberg O. Welin A. Iyudin D. Shifrin M. Pearce 《Experimental Astronomy》2016,41(1-2):17-41
In the 50 years since the advent of X-ray astronomy there have been many scientific advances due to the development of new experimental techniques for detecting and characterising X-rays. Observations of X-ray polarisation have, however, not undergone a similar development. This is a shortcoming since a plethora of open questions related to the nature of X-ray sources could be resolved through measurements of the linear polarisation of emitted X-rays. The PoGOLite Pathfinder is a balloon-borne hard X-ray polarimeter operating in the 25-240 keV energy band from a stabilised observation platform. Polarisation is determined using coincident energy deposits in a segmented array of plastic scintillators surrounded by a BGO anticoincidence system and a polyethylene neutron shield. The PoGOLite Pathfinder was launched from the SSC Esrange Space Centre in July 2013. A near-circumpolar flight was achieved with a duration of approximately two weeks. The flight performance of the Pathfinder design is discussed for the three Crab observations conducted. The signal-to-background ratio for the observations is shown to be 0.25 ±0.03 and the Minimum Detectable Polarisation (99 % C.L.) is (28.4 ±2.2) %. A strategy for the continuation of the PoGOLite programme is outlined based on experience gained during the 2013 maiden flight. 相似文献
108.
Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H2O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /LCaOCaO and b = /LMgOMgO) but also on the relative rate P = (−2ξ1 − ξ2)/(–ξ1 − 2ξ2) of competing reactions: Dol + 2Qtz = Di + 2CO2 (ξ1) and 2Dol + Qtz = Fo + 2Cal + 2CO2 (ξ2). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer. 相似文献
109.
采用1979—2009年NCEP/NCAR再分析资料、NOAA向外长波辐射(outgoing long-wave radiation,简称OLR)及扩展重建海表面温度资料,对南海大气季节内振荡(Intra-seasonal Oscillation,简称ISO)特征及其与ENSO循环的关系进行了诊断分析。结果表明:1)南海大气ISO的30~60 d周期在5—10月均显著。一般年南海大气ISO的对流传播在纬向上存在东传和西传,在经向上具有南北半球季节性摆动的特征。以低频动能表征的南海大气ISO强度年代际变化特征明显,近31 a来趋势增强,年变化呈单峰结构,峰值在7—8月。2)南海大气ISO的对流与ENSO循环显著相关,其强度在El Nio(La Nia)年减弱(增强)。与一般年对比,南海大气ISO对流在El Nio和La Nia年均表现为西传减弱、北传显著。北传特征表现为强对流活跃带于春季(4—5月)北跳至北半球(在La Nia年最北可至35°N),但在北半球的传播方向与一般年相比存在显著差异。3)南海大气ISO强度与ENSO循环关系密切,在El Nio(La Nia)年减弱(增强),两者表现为约半年(6~8个月)的滞后相关。Nio3区海表面温度异常序列与南海大气ISO强度的相关在中西太平洋地区和El Nio成熟前的春、秋季最显著,同时相关中心伴随低频动能高值区东移。 相似文献
110.
Sohiko Kameyama Satoshi Yoshida Hiroshi Tanimoto Satoshi Inomata Koji Suzuki Hisayuki Yoshikawa-Inoue 《Journal of Oceanography》2014,70(3):225-239
We measured dissolved isoprene (2-methyl-1,3-butadiene; C5H8) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L?1 and from 181 to 313 nmol m?2 day?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r 2 = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r 2 = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO2), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO2 are similar within a physically stable water column. 相似文献