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231.
232.
The subsurface counter current beneath the Tsushima Warm Current is simulated using a three-dimensional circulation model. The model well reproduces the counter current beneath the Tsushima Warm Current on the shelf break. The counter current appears as nearshore parts of the subsurface clockwise circulations from spring to early winter. The clockwise circulations are separated by developed shelves such as the Oki Spur and the Noto Peninsula, thus the counter current is not a continuous flow along the Japanese coast in this model. The vertical structure of the counter current can be explained by a density structure with the thermal wind relationship. The permanent and seasonal pycnoclines form mutually opposite horizontal density gradients near the Japanese coast in summer. Such a density structure results in a speed maximum of the counter current away from the bottom. It is remarkable that the second baroclinic mode is dominant in nearshore parts of the subsurface clockwise circulations in summer, which are attributed to the density structure. Similar density structures are also found in some coastal regions of the world oceans where subsurface counter currents are expected.  相似文献   
233.
A vertical one-dimensional ecosystem model with vertical migration of zooplankton was constructed and applied to Station A-7 off Sanriku district of Japan in the northwest Pacific Ocean. The model consists of an eight-compartment ecosystem model coupled with a physical model of the oceanic mixed layer. The transition of phytoplankton species responsible for the spring bloom is well reproduced by this model with vertical migration of zooplankton but is not simulated by the model without vertical migration. This new model also simulates an observed inter-annual variability of the spring bloom, with the timing and intensity of the simulated bloom in a given year depending upon the strength of mixing during the preceding winter. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
234.
The northward migration of spring bloom was observed in the Sea of Japan from April to May 1997 by the Ocean Color and Temperature Scanner (OCTS) on board the Advanced Earth Observing Satellite (ADEOS). This phenomenon is well simulated with a numerical ecosystem model coupled with a hydrodynamic model. The hydrodynamic model is the Geophysical Fluid Dynamics Laboratory (GFDL) Modular Ocean Model (MOM). The ecosystem model consists of five components: dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), phytoplankton, zooplankton and detritus. Results of the numerical ecosystem model suggest that the mesoscale development of the spring bloom in the Sea of Japan is related to that of sea water temperature, and that the bloom is limited by the depletion of DIN. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   
235.
The long-term mean (31-year mean) surface heat fluxes over the Japan Sea are estimated by the bulk method using the most of the available vessel data with the resolution of 1o×1o. The long-term annual mean net heat flux is about –53 W m–2 (negative sign means upward heat flux) with the annual range from 133 W m–2 in May to –296 W m–2 in December. The small gain of heat in the area near Vladivostok seems to indicate the existence of cold water flowing from the north. In that area in winter, the mean loss of heat attains about 200 W m–2, and the Bowen's ratio is over the unity. The largest insolation occurs in May in the Japan Sea, and the upward latent heat flux becomes the largest in November in this area. The heat flux of Haney type is also calculated, and the result, shows that the constantQ 1 has the remarkable seasonal and spatial variation, while the coefficientQ 2 has relatively small variation throughout all seasons. Under the assumption of constant volume transport of 1.35×106 m3s–1 through the Tsugaru Strait, the long-term averages of the volume transport through the Tsushima and Soya Straits are estimated to be about 2.20 and 0.85×106 m3s–1 from the result of the mean surface heat flux, respectively.  相似文献   
236.
We investigated the sea level response of the Japan Sea to changes in atmospheric pressure using barotropic shallow water models driven by idealized synoptic pressure forcing. The regional response lags behind the synoptic pressure forcing because the adjustment is slowly established by water exchange through narrow, shallow straits. The sea level response of the realistic Japan Sea to the idealized forcing varies with geographical location and shows zonally asymmetric variations in amplitude and phase. The simulated response is in good agreement with the observed response of sea level recorded at Japanese coastal tide gauges. The results of a simple one-dimensional model indicate that the zonally asymmetric pattern, with an eastward-propagating pressure system, is essentially caused by bottom friction in shallow straits. This asymmetry arises if the typical wavelength of the synoptic pressure system is slightly larger than the spatial scale of the Japan Sea.  相似文献   
237.
The authors report here halogen concentrations in pore waters and sediments collected from the Mallik 5L-38 gas hydrate production research well, a permafrost location in the Mackenzie Delta, Northwest Territories, Canada. Iodine and Br are commonly enriched in waters associated with CH4, reflecting the close association between these halogens and source organic materials. Pore waters collected from the Mallik well show I enrichment, by one order of magnitude above that of seawater, particularly in sandy layers below the gas hydrate stability zone (GHSZ). Although Cl and Br concentrations increase with depth similar to the I profile, they remain below seawater values. The increase in I concentrations observed below the GHSZ suggests that I-rich fluids responsible for the accumulation of CH4 in gas hydrates are preferentially transported through the sandy permeable layers below the GHSZ. The Br and I concentrations and I/Br ratios in Mallik are considerably lower than those in marine gas hydrate locations, demonstrating a terrestrial nature for the organic materials responsible for the CH4 at the Mallik site. Halogen systematics in Mallik suggest that they are the result of mixing between seawater, freshwater and an I-rich source fluid. The comparison between I/Br ratios in pore waters and sediments speaks against the origin of the source fluids within the host formations of gas hydrates, a finding compatible with the results from a limited set of 129I/I ratios determined in pore waters, which gives a minimum age of 29 Ma for the source material, i.e. at the lower end of the age range of the host formations. The likely scenario for the gas hydrate formation in Mallik is the derivation of CH4 together with I from the terrestrial source materials in formations other than the host layers through sandy permeable layers into the present gas hydrate zones.  相似文献   
238.
Cementitious materials used for radioactive waste repository construction complicate the performance assessment of radioactive waste systems because the use of cement may greatly alter the pH (8–13) of groundwater and release constituents such as calcium ions. Under such conditions, it is important to clarify also the dynamic behavior of silica (silicic acid), in order to evaluate the alteration in the chemical and physical properties of the fractured layer or the host rock surrounding the repository. Since silica undergoes polymerization, precipitation or dissolution depending on the pH and/or temperature, the behavior of silica would be greatly complicated in the presence of other ions. This study is focused on the deposition rates of polysilicic acid and soluble silicic acid with up to 10−3 M Ca ions. In the experiment, Na2SiO3 solution (250 mL, pH > 10, 298 K) was poured into a polyethylene vessel containing amorphous silica powder (0.5 g), and a buffer solution, HNO3, and CaNO3 as Ca ions were sequentially added into the vessel. The pH of the solution was set to 8. The silica, initially in a soluble form at pH > 10 (1.4 × 10−2 M), became supersaturated and either deposited on the solid surface or changed into the polymeric form. Then the concentrations of both poly- and soluble silicic acid were monitored over a 40-day period. The decrease of polysilicic acid became slow with an increase in the concentration of Ca ions in the range of up to 10−3 M. In general, the addition of electrolytes to a supersaturated solution accelerates the aggregation and precipitation of polymeric species. However, the experimental result showed that polysilicic acid in the presence of Ca ions is apparently stable in solution, compared with that under a Ca-free condition. On the other hand, the concentration of soluble silicic acid in the presence of Ca ions immediately became metastable, that is, slightly higher than the solubility of soluble silicic acid. Its dynamic behavior was similar to that in the Ca-free condition.  相似文献   
239.
Abstract: Interstitial water expelled from gas hydrate-bearing and -free sediments in the Nankai Trough are analyzed in terms of Cl-, SO42-, δ18O and δD. The baselines for the Cl- concentration and δ18O value are close to seawater values (530 mM and 0%), indicating that the interstitial water is of seawater origin. The δD values decrease with depth, implying isotopic exchange of hydrogen between upwelling biogenic methane depleted in D and interstitial water. The Cl- concentrations in gas hydrate-bearing sediments are anomalously low, while the δ18O and δD values are both high, suggesting that the water forming these gas hydrates was poor in Cl- and enriched in 18O and D during gas hydrate formation. Calculation of the gas hydrate saturations using Cl "and δ18O anomalies gives results of up to 80 % in sand, and shows that the δ18O baseline is not consistent with the Cl" baseline. The δ18O baseline increases by +1% in gas hydrate-free clay and silt. This is considered to be caused by clustering of water molecules after gas hydrate dissociation in response to the upward migration of the base of gas hydrate stability, as indicated by the presence of a double bottom-simulating reflector at this site. The water clusters enriched in 18O are responsible for the increase in the δ18O baseline with normal Cl". The abrupt shallowing of the base of gas hydrate stability may induce the dissociation of gas hydrates and the accumulation of gases in the new stability zone, representing a geological process that increases gas hydrate saturation.  相似文献   
240.
Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ34S and δ18O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids.  相似文献   
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