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21.
Core sediment samples collected from the Hess Rise, North Pacific, were analyzed for 20 common amino acids (AA) and two hexosamines (HA) to understand the relation between glacial–interglacial variations and deposition/preservation of sedimentary organic matter (OM). The sediments are predominantly carbonaceous (carbonates 35–80%). AA-based parameters—aspartic acid/glycine ratio and serine+threonine relative mole content—suggest that calcareous plankton was the major source of OM in these sediments. This inference is supported by the similarity in distribution patterns of AA and HA contents with that of organic carbon. Low values of AA/HA and glucosamine/galactosamine ratios (average 4.4 and 1.1, respectively) imply that much of the planktonic OM was replaced by microbial OM. The relative molar concentration of two nonprotein AA (β-alanine and γ-aminobutyric acid) varied with age of sediments; i.e., they were less abundant in recent sediments and more abundant in the oldest sediments. This trend is an indicator of extremely slow but continuous enzymatic degradation of proteinaceous OM within the sediments. So far, bulk OM has been believed to be one of the best proxies for estimation of primary productivity. However, it may be an underestimate, even for the late Quaternary sediments. Comparison of AA and HA content variations with SPECMAP stack revealed their enhanced deposition and preservation during glacial periods relative to interglacial periods. This, in turn, affected not only the planktonic production in surface waters but also the benthic community, including bacteria on the seafloor.  相似文献   
22.
We present oxygen and carbon isotope ratios and the morphological structure of the cultured freshwater pearl mussel (Hyriopsis sp., Unionidae) shell and pearl. The number of first-order fluctuations of δ18O of the outer shell layer along the maximum growth axis was consistent with the number of cultured years. The dominant factor controlling annual δ18O fluctuations was water temperature with a minor contribution from the variation in δ18O of ambient water, especially during the rainy season. The δ13C values were approximately constant throughout the life of the mussel, suggesting that the contributions of body size to δ13C of the shell were minor. We observed nine distinct disturbance rings on the outer surface of the shell. Five rings coincided with the five winter peaks of the δ18O profile, indicating winter growth cessation below approximately 10°C, probably because of either inactive growth at low water temperatures or reproduction. Summer disturbance rings were not observed in all years. Moreover, some summer rings showed discontinuity in the inner structure. These findings suggest that summer growth cessation may be caused by occasional events such as heavy rains, as the decrease of dissolved oxygen concentration. The δ18O profile and shell structures indicated that shell aragonite was precipitated at close to equilibrium conditions with respect to the oxygen isotope composition of the ambient water. Hyriopsis sp. shells can potentially be used for reconstruction of past hydrologic conditions. The δ18O of a pearl indicated that calcification occurred over a temperature range of at least 13–23°C. The optimal temperature for pearl calcification in this species is lower than that for marine pearl calcification.  相似文献   
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Hydrothermal circulation beneath the spreading axis plays a significant role in the exchange of energy and mass between the solid Earth and the oceans. Deep-seated hydrothermal circulation down to the crust/mantle boundary in the fast-spreading axis has been introduced by a number of studies regarding geological investigations and numerical models. In order to assess a reaction between hydrothermal fluid and host rock around the crust/mantle boundary, we conducted bulk trace element and Sr isotope analyses with a series of in situ investigations for crustal anorthosite, a reaction product between hydrothermal fluid and gabbro in the lowermost crustal section along Wadi Fizh, northern Oman ophiolite. In addition, we conducted titanite U–Pb isotope analyses to evaluate timing of the crustal anorthosite formation in the framework of the evolutional process of the Oman ophiolite. We estimated the formation age of the crustal anorthosite at 97.5 Ma ± 5.0 Ma, overlapping with the timing of the crust formation in the paleo spreading axis. The crustal anorthosite shows high-Th/U ratio (~2.5) and high-initial 87Sr/86Sr ratio (0.7050) due to seawater-derived hydrothermal fluid ingress into the precursor gabbro. With using analytical technique of micro-excavation at cryo-temperature, we detected Cl from a few micrometer-sized inclusion of aqueous fluid and chromite grains. The solubility of Cr was enhanced by complexation reactions with Cl in the hydrothermal fluid. Regarding reconstructed three-dimensional mass distribution of the inclusion and chromite composition, maximum Cr content of parental fluid was estimated at ~69 000 μg/g. The exceptionally high-Cr content was achieved locally by leaking of fluid and synchronous chromite crystallization during fluid entrapment. Presence of the deep-seated hydrothermal circulation could be assigned to the segment end, where cold seawater penetrates into the lowermost crust and extract heat along widely spaced network-like fluid channel.  相似文献   
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Time-series data from sediment trap moorings intermittently deployed during 1991–1999 show that the fluxes of biogenic material (carbonate, opal and organic matter, including amino acids) and other related parameters are temporally and spatially distinct across the Western Pacific Warm Pool (WPWP). These variations resulted from the El Niño and La Niña conditions, which alternately prevailed over the equatorial Pacific Ocean during the mooring deployments. The westernmost WPWP (a hemipelagic region) recorded relatively high average total mass and amino acid fluxes during the El Niño event. This was in sharp contrast to the eastern part of the WPWP (oligotrophic and weak upwelling regions) which recorded higher flux values during the La Niña event. Settling particulate organic matter was rich in labile components (amino acids) during La Niña throughout the study area. Relative molar ratios of aspartic acid to β-alanine together with relative molar content of non-protein amino acids β-alanine and γ-aminobutyric acid) suggested that organic matter degradation was more intense during La Niña relative to that during El Niño in the WPWP. This study clearly shows that during an El Niño event the well documented decrease in export flux in the easternmost equatorial Pacific is accompanied by a significant increase in export flux in the westernmost equatorial Pacific Ocean.  相似文献   
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The fluxes of planktonic foraminifera (calcareous shell producing zooplankton) were examined in order to clarify temporal and regional variations in production in the upper ocean in relation to hydrographic conditions. Three time-series sediment traps were deployed in the central North Pacific along 175°E for about one year, beginning in June 1993. Trap sites were located in the subarctic, the transition, and the subtropical water masses, from north to south. The southernmost site was under the influence of the transition zone in January to May. Both temporal and regional fluxes of planktonic foraminifera showed large variations during the experiment. In the subarctic water mass, high total foraminiferal fluxes (TFFs) and high organic matter fluxes (OMFs) were observed during summer to fall, suggesting that food availability is the most important factor for the production of planktonic foraminifera. Furthermore, low TFFs during winter were ascribed to low food availability and low temperatures. The OMFs and TFFs correlated well and increased rapidly after the disruption of the seasonal thermocline during winter, peaking in late February to early March in the transition zone. In the subtropical water mass, both OMFs and TFFs remained low due to lower productivity under oligotrophic conditions. In general, TFFs show a positive correlation with OMFs during the trap experiment, suggesting that food availability is one of the factors controlling the production of planktonic foraminifera in the central North Pacific. Relatively low TFFs during summer to fall in the subtropical water mass may be caused by the thermal structure of the upper ocean. Low SST possibly reduces the production of foraminifera during winter in the subarctic region.  相似文献   
28.
Middle latitudes of the northern and southern hemispheres of the western Pacific are the sensitive areas for the climatic change. We reconstruct the variation in primary productivity to evaluate the shift of the transition zone between the central water mass and cold water in the both hemispheres. In cores S2612 and LH3166, which are located around boreal and austral 35 degree, the mean COrganic/N atomic ratios are 7.8 and 7.2, respectively. Therefore it is suggested that organic matter is mainly of marine origin (excluding the middle Stage 6 to Stage 7 with the high COrganic/N atomic ratios in core LH3166). Primary productivities estimated from these cores in the middle latitudes of the western Pacific during the late Pleistocene demonstrate similar profiles. Maxima are observed at late Stage 2, late Stage 4 (middle Stage 4 for L3187) and late Stage 6 while minimum values were observed at Stage 5. Mass accumulation rates of organic carbon and biogenic opal also show similar profiles in these cores. These results and paleontological evidence show that the transition zone between Subtropical and subarctic waters almost synchronously migrated along the latitudinal transection during the last 150 kyr.  相似文献   
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