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31.
Mountain-rescue operations require rapid response whilst also ensuring the security of the rescue teams. Rescuing people in a big rock-face is even more difficult if night or fog prevent sight. The paper presents a technical solution to optimally support, under these aggravated conditions, the location of the casualties and the navigation of the rescue team(s) in a rock-face from a coordination station. In doing so, standard components like a smartphones with GPS functionality, a data communication on a client–server basis and VR visualisation software have been adapted to the specific requirements. Remote support of the navigation in steep rocky terrain requires a highly accurate wall model which permits the local experts of the coordination station to dependably estimate geometry and structure of the rock along the rescue route and to convey necessary directives to the retrieval team. Based on terrestrial laser-scans from different locations, such a model has been generated for the mighty Dachstein South Face (Austria) and texturised with digital photographs. Over a twelve-month period, a transdisciplinary team of the Dresden University of Technology (Informatics, Electrical Engineering, Cartography) developed and integrated the various technical modules of the mountain-rescue support-system (digital rock-face model, optimised GPS data transmission between mobile device, server and client, data filtering, and dynamic visualisation component). In summer 2011 the proper functioning of the prototype was demonstrated in a rescue exercise under foggy dusk conditions.  相似文献   
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High-pressure metamorphic (HPM) rocks (derived from igneous protoliths) and their metasomatised rinds from the island of Syros (Greece) were analysed for their B and Cl whole-rock abundances and their H2O content by prompt-gamma neutron-activation analysis (PGNAA) and for their Li and Be whole-rock abundances by ICP-OES. In the HPM rocks, B?/Be and Cl?/Be ratios correlate with H2O contents and appear to be controlled by extraction of B and Cl during dehydration and prograde metamorphism. In contrast, samples of the metasomatised rinds show no such correlation. B?/Be ratios in the rinds are solely governed by the presence or absence of tourmaline, and Cl?/Be ratios vary significantly, possibly related to fluid inclusions. Li/Be ratios do not correlate with H2O contents in the HPM rocks, which may in part be explained by a conservative behaviour of Li during dehydration. However, Li abundances exceed the vast majority of published values for Li abundances in fresh, altered, or differentiated oceanic igneous rocks and presumably result from metasomatic enrichment of Li. High Li concentrations and highly elevated Li/Be ratios in most metasomatised samples demonstrate an enrichment of Li in the Syros HP mélange during fluid infiltration. This study suggests that B and Cl abundances of HPM meta-igneous rocks can be used to trace prograde dehydration, while Li concentrations seem to be more sensitive for retrograde metasomatic processes in such lithologies.  相似文献   
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Transfer functions describing the coprecipitation of various trace elements (TE; As, Cd, Co, Cu, Cr, Mo, Ni, Pb, Zn), precipitating with iron(oxihydr)oxides from an aqueous solution, were developed and implemented in the computer model ‘Seeper’. ‘Seeper’ was developed to predict the progression of the concentrations of inorganic pollutants in unsaturated soils underneath contaminated areas and to evaluate the prospective contamination of the groundwater. Transfer functions provide a straight and simple relation between the coprecipitation of TE and easy to obtain standard soil parameters, without excessive repercussions on the usability and computation time of the model. Laboratory experiments were conducted to quantify coprecipitation in solutions with pH values ranging from 5 to 12 and containing various iron and TE concentrations. For the examined TE, the transfer functions describe the coprecipitated fraction as a function of the pH value and the concentration ratio between precipitated iron and a TE. The transfer functions yielded a good prediction of cadmium, cobalt, copper, molybdenum, nickel, and zinc (R 2 from 0.73 to 0.83). As for arsenic, chromium, and lead the correlation was not as good albeit a significant influence of precipitating iron on the mobility of these elements was observed and represented in the corresponding transfer functions.  相似文献   
36.
To quantify landscape change resulting from processes of erosion and deposition and to establish spatially distributed sediment budgets, ‘models of change’ can be established from a time series of digital elevation models (DEMs). However, resolution effects and measurement errors in DEMs may propagate to these models. This study aimed to evaluate and to modify remotely‐sensed DEMs for an improved quantification of initial sediment mass changes in an artificially‐created catchment. DEMs were constructed from photogrammetry‐based, airborne (ALS) and ground‐based laser scanning (TLS) data. Regions of differing morphological characteristics and vegetation cover were delineated. Three‐dimensional (3D) models of volume change were established and mass change was derived from these models. DEMs were modified region‐by‐region for rill, interrill and alluvial areas, based on logical and hydro‐geomorphological principles. Additional DEMs were constructed by combining multi‐source, modified data. Models were evaluated by comparison with d‐GPS reference data and by considering sediment budget plausibility. Comprehensive evaluation showed that DEM usability depends on a relation between the technique used to obtain elevation data, surface morphology and vegetation cover characteristics. Photogrammetry‐based DEMs were suited to quantification of change in interrill areas but strongly underestimated surface lowering in erosion rills. TLS DEMs were best suited to rill areas, while ALS DEMs performed best in vegetation‐covered alluvial areas. Agreement with reference data and budget plausibility were improved by modifications to photogrammetry‐ and TLS‐based DEMs. Results suggest that artefacts in DEMs can be reduced and hydro‐geomorphic surface structures can be better represented by applying region‐specific modifications. Photogrammetry‐based DEMs can be improved by combining higher and lower resolution data in defined structural units and applying modifications based on principles given by characteristic hydro‐geomorphic evolution. Results of the critical comparative evaluation of remotely‐sensed elevation data can help to better interpret DEM‐based quantifications of earth‐surface processes. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
37.
Ground motion scenarios for Mt. Etna are created using synthetic simulations with the program EXSIM. A large data set of weak motion records is exploited to identify important input parameters which govern the modeling of wave propagation effects, such as Q-values, high frequency cut-off and geometrical spreading. These parameters are used in the simulation of ground motion for earthquakes causing severe damage in the area. Two seismotectonic regimes are distinguished. Volcano-tectonic events, though being of limited magnitude (Mmax ca. 5), cause strong ground shaking for their shallow foci. Being rather frequent, these events represent a considerable threat to cities and villages on the flanks of the volcano. A second regime is related to earthquakes with foci in the crust, at depths of 10–30 km, and magnitudes ranging from 6 to 7. In our synthetic scenarios, we chose two examples of volcano-tectonic events, i.e. the October 29, 2002, Bongiardo event (I = VIII) and the May 8, 1914, Linera earthquake (I = IX–X). A further scenario regards the February 20, 1818 event, considered representative for stronger earthquakes with foci in the crust. We were able to reproduce the essential features of the macroseismic field, in particular accounting for the possibility of strong site effects. We learned that stress drop estimated for weak motion events is probably too low to explain the intensity of ground motion during stronger earthquakes. This corresponds to findings reported in the literature claiming an increase of stress drop with earthquake size.  相似文献   
38.
The interaction of Cs(I), Eu(III), Th(IV) and U(VI) with montmorillonite colloids was investigated in natural Grimsel Test Site groundwater over a 3 years period. The asymmetric flow field-flow fractionation combined with various detectors was applied to study size variations of colloids and to monitor colloid association of trace metals. The colloids suspended directly in the low ionic strength (I), slightly alkaline granitic groundwater (I = 10−3 mol/L, pH 9.6) showed a gradual agglomeration with a size distribution shift from initially 10-200 nm to 50-400 nm within over 3 years. The Ca2+ concentration of 2.1 × 10−4 mol/L in the ground water is believed to be responsible for the slow agglomeration due to Ca2+ ion exchange against Li+ and Na+ at the permanently charged basal clay planes. Furthermore, the Ca2+ concentration lies close to the critical coagulation concentration (CCC) of 10−3 mol L−1 for clay colloids. Slow destabilization may delimit clay colloid migration in this specific groundwater over long time scales. Eu(III) and Th(IV) are found predominantly bound to clay colloids, while U(VI) prevails as the UO2(OH)3 complex and Cs(I) remains mainly as aquo ion under our experimental conditions. Speciation calculations qualitatively represent the experimental data. A focus was set on the reversibility of metal ion-colloid binding. Addition of humic acid as a competing ligand induces rapid metal ion dissociation from clay colloids in the case of Eu(III) even after previous aging for about 3 years. Interestingly only partial dissociation occurs in the case of Th(IV). Experiments and calculations prove that the humate complexes dominate the speciation of all metal ions under given conditions. The partial irreversibility of clay bound Th(IV) is presently not understood but might play an important role for the colloid-mediated transport of polyvalent actinides over wide distances in natural groundwater.  相似文献   
39.
This study provides new structural data that show that the Adaminaby Group is part of the Narooma accretionary complex and has been overprinted by HT/LP metamorphism associated with Middle Devonian Moruya Suite intrusions. The grade of metamorphism based on Kübler Indices is the same in the Wagonga and Adaminaby Groups at Batemans Bay inferring that these rocks were involved in the same accretionary event. White micas in slates of the Adaminaby Group record apparent K–Ar ages of 384.6 ± 7.9 Ma and 395.8 ± 8.1 Ma. These ages are believed to represent the age of Middle to Upper Devonian Buckenbowra Granodiorite. Kübler Index values indicate lower epizonal (greenschist facies) metamorphic conditions and are not influenced by heating in metamorphic aureoles of the plutons. All b cell lattice parameter values are characteristic of intermediate pressure facies conditions although they are lower in the metamorphic aureole of the Buckenbowra Granodiorite than in the country rock, defining two areas with dissimilar baric conditions. East of the Buckenbowra Granodiorite, b cell lattice parameter values outside the contact aureole (x = 9.033 Å; n = 8) indicate P = 4 kb, and assuming a temperature of 300°C, infer a depth of burial of approximately 15 km for these rocks with a geothermal gradient of 20°C/km. In the metamorphic aureole of the Buckenbowra Granodiorite, b cell lattice parameter values (x = 9.021 Å; n = 41) indicate P = 3.1 kb inferring exhumation of the Adaminaby Group rocks to a depth of approximately 11 km prior to intrusion. A geothermal gradient of 36°C/km operated in the aureole during intrusion. An extensional back-arc environment prevailed in the Adaminaby Group during the Middle to Upper Devonian.  相似文献   
40.
Representatives of the Antarctic food web (krill, cephalopod, fish, penguin, seal) of the area around Elephant Island and from the Weddell Sea were analysed for the most recalcitrant organochlorine compounds. Due to sorption of the compounds to sinking particles and accumulation in sediments, two benthic fish species (Gobionotothen gibberifrons, Chaenocephalus aceratus) feeding on benthos invertebrates and fish reflected significantly increasing concentrations within a decade (1987-1996), while a benthopelagic species (Champsocephalus gunnari) feeding on krill did not. In the pelagic food chain, lipid normalised concentrations of all compounds increased from Antarctic krill to fish proving that biomagnification of highly lipophilic pollutants (log octanol-water partition coefficient>5) occurs in water-breathing animals. As top predators Weddell and southern elephant seals (Leptonychotes weddellii, Mirounga leonina) biomagnified the persistent organic pollutants relative to krill 30-160 fold with the exception of hexachlorobenzene, the levels of which were lower than in fish indicating its intense specific elimination.  相似文献   
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