Removal of lead(II) from aqueous stream by hydrophilic modified kapok fiber using the Fenton reaction     

Dongfang Wang  Daeik Kim  Chul-Ho Shin  Yufeng Zhao  Joon-Seok Park  Moonhee Ryu 《Environmental Earth Sciences》2018,77(18):653

A hydrophilic kapok fiber was prepared by a chemical process of the Fenton reaction and used as an adsorbent to remove Pb(II) from aqueous solution. The effects of experimental parameters including pH, contact time, Pb(II) concentration, and coexisting heavy metals were estimated as well as evaluated. The optimum concentrations of FeSO₄ and H₂O₂ for the Fenton reaction-modified kapok fiber (FRKF) were 0.5 mol L^?1 and 1 mol L^?1, respectively. The adsorption kinetic models and isotherm equations of Langmuir and Freundlich were conducted to identify the most optimum adsorption rate and adsorption capacity of Pb(II) on FRKF. The FRKF displayed an excellent adsorption rate for Pb(II) in single metal solution with the maximum adsorption capacity of 94.41?±?7.56 mg g^?1 at pH 6.0. Moreover, the FRKE still maintained its adsorption advantage of Pb(II) in the mixed metal solution. The FRKF exhibited a considerable potential in removal of metal content in wastewater streams.  相似文献   

A numerical study of the interactions of urban breeze circulation with mountain slope winds     

Gantuya Ganbat  Jong-Jin Baik  Young-Hee Ryu 《Theoretical and Applied Climatology》2015,120(1-2):123-135

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Experimental investigation of dry density effects on dielectric properties of soil–water mixtures with different specific surface areas     

Orangi  A.  Narsilio  G. A.  Wang  Y. H.  Ryu  D. 《Acta Geotechnica》2020,15(5):1153-1172

The dielectric constant of soil is used to estimate its water content in a range of applications. Unlike the widely known effect of water content on the soil dielectric constant (consistent direct proportionality), only a limited number of studies have reported the effects of soil dry density, however, with equivocal results. This paper, therefore, investigates the effects of dry density or degree of compaction on the dielectric constant of five different soil types. The results of the experimental work for the soils ranging from sand to Bentonite clay with distinct specific surface areas were evaluated based on the use of two simple mixture models (De Loor and Birchak). The effects of dry density on the soil dielectric constant were found to be soil type dependent. This is demonstrated by the experimental data and further proven by the modified De Loor model. The behavior is shown to be defined by the changes in the free water, bound water, and solid particle volume fractions, ultimately controlled by the soil specific surface area. The dielectric constant changes from being directly proportional to dry density to inversely proportional at a threshold specific surface area of between 122 and 147 m²/g. Supported by the experimental observations, parametric analysis has revealed that the range for the dielectric constant of bound water was found to be 9–37, while the geometrical parameter α in the Birchak model was found to be 0.4–0.8.

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Diversity and Assemblage Structure of Marine Fish Species Collected by Set Net in Korean Peninsula During 2009–2013     

Ryu  Jung-Hwa  Kim  Jin-Koo 《Ocean Science Journal》2020,55(4):581-591

Ocean Science Journal - Assemblage structure analysis was conducted based on seasonal fish species composition data collected four times a year during 2009–2013 from 10 stations around Korea...  相似文献   

Improved Chlorophyll-a Algorithm for the Satellite Ocean Color Data in the Northern Bering Sea and Southern Chukchi Sea     

Sang Heon Lee  Jongseong Ryu  Jung-woo Park  Dabin Lee  Jae-Il Kwon  Jingping Zhao  SeungHyun Son 《Ocean Science Journal》2018,53(3):475-485

The Bering and Chukchi seas are an important conduit to the Arctic Ocean and are reported to be one of the most productive regions in the world’s oceans in terms of high primary productivity that sustains large numbers of fishes, marine mammals, and sea birds as well as benthic animals. Climate-induced changes in primary production and production at higher trophic levels also have been observed in the northern Bering and Chukchi seas. Satellite ocean color observations could enable the monitoring of relatively long term patterns in chlorophyll-a (Chl-a) concentrations that would serve as an indicator of phytoplankton biomass. The performance of existing global and regional Chl-a algorithms for satellite ocean color data was investigated in the northeastern Bering Sea and southern Chukchi Sea using in situ optical measurements from the Healy 2007 cruise. The model-derived Chl-a data using the previous Chl-a algorithms present striking uncertainties regarding Chl-a concentrations – for example, overestimation in lower Chl-a concentrations or systematic overestimation in the northeastern Bering Sea and southern Chukchi Sea. Accordingly, a simple two band ratio (R_rs(443)/R_rs(555)) algorithm of Chl-a for the satellite ocean color data was devised for the northeastern Bering Sea and southern Chukchi Sea. The MODIS-derived Chl-a data from July 2002 to December 2014 were produced using the new Chl-a algorithm to investigate the seasonal and interannual variations of Chl-a in the northern Bering Sea and the southern Chukchi Sea. The seasonal distribution of Chl-a shows that the highest (spring bloom) Chl-a concentrations are in May and the lowest are in July in the overall area. Chl-a concentrations relatively decreased in June, particularly in the open ocean waters of the Bering Sea. The Chl-a concentrations start to increase again in August and become quite high in September. In October, Chl-a concentrations decreased in the western area of the Study area and the Alaskan coastal waters. Strong interannual variations are shown in Chl-a concentrations in all areas. There is a slightly increasing trend in Chl-a concentrations in the northern Bering Strait (SECS). This increasing trend may be related to recent increases in the extent and duration of open waters due to the early break up of sea ice and the late formation of sea ice in the Chukchi Sea.  相似文献   

Quantitative estimation of intertidal sediment characteristics using remote sensing and GIS     

Jong-Kuk Choi  Joo-Hyung Ryu  Yoon-Kyung Lee  Hong-Rhyong Yoo  Han Jun Woo  Chang Hwan Kim 《Estuarine, Coastal and Shelf Science》2010

High spatial resolution satellite data (IKONOS) combined with in situ data was used to quantitatively estimate the spatial distribution of tidal flat characteristics for the Hwangdo tidal flat, Cheonsu Bay, Korea. The classification result was accurate in terms of a comparison with the in situ data, and the overall accuracy was 90.7%, which confirmed the validity of the classification. GIS analysis based on a probabilistic model was applied to a quantitative estimation of the relationship between each surface sediment facies and the spectral reflectance. Mud flat facies showed a high positive correlation (R² = 0.91), and sand flat facies showed a high negative correlation (R² = 1.00), which was a good reflection of the sedimentary characteristics of Hwangdo tidal flat. Relationships between each sediment facies and DEM also showed good agreement with the topographic characteristics in the study area. The study revealed that intertidal surface sediment classification using high resolution remote sensing imagery and in situ data successfully shows spectral and topographic characteristics of the study area. It was noted that spectral reflectance was affected by a combination of environmental factors, including grain size, topography, and remnant surface water. It is possible to determine the type of tidal flat through quantitative estimates of the spatial distribution of surface sediments according to their spectral reflectance.  相似文献   

An evaluation of inversion models for retrieval of inherent optical properties from ocean color in coastal and open sea waters around Korea     

Palanisamy Shanmugam  Yu-Hwan Ahn  Joo-Hyung Ryu  Balasubramanian Sundarabalan 《Journal of Oceanography》2010,66(6):815-830

This study was aimed to investigate three inversion models (currently in use with Moderate Resolution Imaging Spectroradiometer and Sea-viewing Wide Field-of-view Sensor data processing), namely constrained Linear Matrix (LM), Quasi-analytical algorithm (QAA) and GSM semi-analytical models (GSM). These models were applied to large bio-optical data sets (collected from coastal and open sea waters around Korea) to retrieve inherent optical properties (IOPs) such as absorption coefficients of phytoplankton (a _ph ), colored dissolved and detrital organic matters (a _cdm ), and particulate backscattering coefficient (b _bp ) at five wavelengths (412, 443, 490, 510, and 555 nm). The derived IOP products were compared with in situ a _ph , a _cdm and b _bp coefficients measured for the same remote sensing reflectance (R _rs (λ)) data sets used in the models and the uncertainties of the three models were assessed based on the standard statistical procedures (mean relative error MRE, root mean square error RMSE, slope, and coefficient of determination R ²). It was found that all the three models tended to yield significant errors with varying magnitude at different wavelengths. Overall performance of the models assessed based on the above statistical means was found in the following order: LM > GSM > QAA for retrieving the a _ph , LM > GSM > QAA for retrieving the a _cdm , and QAA > GSM > LM for retrieving the b _bp . Our analyses suggest that these models will require additional refinements with a full parameterization by a fully suited data set in order to produce accurate retrievals of IOPs in coastal and open sea waters around Korea.  相似文献   

Geochemical characterization of the organic matter, pore water constituents and shallow methane gas in the eastern part of the Ulleung Basin, East Sea (Japan Sea)     

Ji-Hoon  Kim  Myong-Ho  Park  Urumu  Tsunogai  Tae-Jin  Cheong  Byong-Jae  Ryu  Young-Joo  Lee  Hyun-Chul  Han  Jae-Ho  Oh  Ho-Wan  Chang 《Island Arc》2007,16(1):93-104

Abstract Geochemical analyses of sediments, pore water and headspace gas of the piston cores taken from the eastern part of Ulleung Basin of the East Sea (Japan Sea) were carried out to assess the origin of the sedimentary organic matter and interstitial fluid. Several tephra layers within the core are identified as the Ulleung‐Oki (10.1 ka), the Aira‐Tanzawa (23 ka) and the Ulleung‐Yamato (30.9 ka) tephras. With the exception of these volcanic layers, the cores consist predominantly of muddy sediments that contain >0.5% total organic carbon. Atomic C/N ratios and δ¹³C_org values suggest that the organic matter originated from marine algae rather than from land vascular plants, whereas Rock‐Eval pyrolysis suggests that the organic matter is thermally immature and comes from a land vascular plant (Type III). These conflicting results seem to be caused by the heavy oxidization of the marine organic matter. Sulphate concentration profiles of pore waters show strongly linear depletion (r² > 0.97) with sediment depth. The estimated sulphate–methane interface (SMI) depth using the sulphate concentration gradient was nearly 3.5 m below seafloor (mbsf) in the southern part of the study area, and deeper than 6 mbsf in the northern part of the area. The difference in SMI depths is likely associated with the amount of the methane flux. The methane concentration below the SMI in the two southern cores increases rapidly, implying the occurrence of methanogenesis and anaerobic methane oxidation (AMO). In contrast, the two northern cores have a low methane concentration below the SMI. values measured from all cores were in the range of −83.5 to −69.5‰, which suggests that the methane derives from a methanogenic microbe. values become decreased toward SMI, but increased below SMI; therefore, has eventually the minimum value near the SMI. The values are also decreased when the methane concentration is increased. These phenomena support the typical occurrence of AMO in the study area.  相似文献   

Sequence stratigraphy and hydrocarbon potential of the southern Tyee basin,Oregon Coast Range,USA     

Inchang Ryu  Heejung JangSujeong Lee 《Journal of Geochemical Exploration》2009

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The major ion, δCa, δCa, and δMg geochemistry of granite weathering at pH = 1 and T = 25 °C: power-law processes and the relative reactivity of minerals     

Jong-Sik Ryu  Andrew D. Jacobson  Craig Lundstrom 《Geochimica et cosmochimica acta》2011,75(20):6004-7046

We dissolved Boulder Creek Granodiorite in a plug flow reactor for 5794 h at pH = 1 and T = 25 °C. The primary purpose of the experiment was to identify controls on dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values during granite weathering. Herein, we also examine the origin of Ca and Mg isotopic variability among minerals composing the Boulder Creek Granodiorite, and we constrain fundamental characteristics of granite weathering important for quantifying the elemental and isotopic geochemistry of the reactor output. Nine Ca-bearing minerals display an 8.80‰ range of δ^44/40Ca values and a 0.51‰ range of δ^44/42Ca values. Three Mg-bearing minerals display a 1.53‰ range of δ^26/24Mg values. These ranges expressed at the mineralogical scale are higher than the ranges thus far reported for bulk igneous rocks. Most of the δ^44/40Ca variability reflects ⁴⁰Ca enrichment in K-feldspar, and to a lesser extent, biotite, due to the radioactive decay of ⁴⁰K over the 1.7 Ga age of the rock, whereas the entire range of δ^44/42Ca values reflects mass-dependent isotope fractionation during igneous differentiation and crystallization. The range of δ^26/24Mg values may represent either fractionation during the chloritization of biotite or interaction of the Boulder Creek Granodiorite with Mg-rich metamorphic fluids having low δ^26/24Mg values.The elemental and isotopic composition of the reactor output varied substantially during the experiment. We synthesize the mineralogical and fluid data using coupled mass-conservation equations solved at non-steady-state. Model calculations reveal an intricate balance between increasing specific surface area and decreasing mineral concentrations. While surface area normalized dissolution rate constants were time-invariant, specific surface area increased as a power-law function of time through positive feedbacks between mechanical disaggregation, chemical dissolution, and mineral depletion. Variations in dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values reflect conservative mixing rather than fractionation. Apatite and calcite initially control δ^44/40Ca and δ^44/42Ca values, followed by biotite, titanite, epidote, hornblende, and plagioclase. The release of radiogenic ⁴⁰Ca clearly defines the period where biotite dissolution dominates. The brucite layer of chlorite initially controls δ^26/24Mg values, followed by biotite, the TOT layer of chlorite, and hornblende. Through direct isotopic tracking, these results demonstrate that trace minerals, such as apatite and calcite in the case of Ca and brucite in the case of Mg, dominate elemental release during the incipient stages of granite weathering. The results further show that biotite dissolution dominates the middle stages of granite weathering and that plagioclase dissolution only becomes important during relatively late stages. The Ca and Mg isotope variations associated with these stages are distinct and potentially resolvable in soil mineral weathering studies.  相似文献