Phase-equilibrium geobarometers for silicic rocks based on rhyolite-MELTS. Part 4: Plagioclase,orthopyroxene, clinopyroxene,glass geobarometer,and application to Mt. Ruapehu,New Zealand     

Lydia?J.?HarmonEmail authorView author&#;s OrcID profile  James?Cowlyn  Guilherme?A.?R.?Gualda  Mark?S.?Ghiorso 《Contributions to Mineralogy and Petrology》2018,173(1):7

A new phase equilibria geobarometer determines magmatic storage and crystallization conditions, including pressure, temperature, oxygen fugacity (\({f_{{{\text{o}}_2}}}\)), and the presence of a fluid phase for glass-bearing rocks containing the assemblage plagioclase?+?pyroxene(s). This newly developed geobarometer can better constrain crystallization conditions of shallow (<?500 MPa; <~?20 km), glass-bearing andesites to dacites. The geobarometer utilizes rhyolite-MELTS to determine crystallization conditions in natural pumice and scoria samples. The validity of the geobarometer is tested by comparing it to results from experiments. Uncertainties are assessed using Monte Carlo simulations. We apply the geobarometer to the plag?+?opx?+?cpx-bearing system of Mt. Ruapehu, in the southern Taupo Volcanic Zone, New Zealand. The samples from Mt. Ruapehu are tested from ~?5 to ~?400 MPa and from super-liquidus to 90% crystalline (~ 1200 to ~ 700 °C). Mt. Ruapehu serves as a methodological testing ground for the geobarometer, and results from our geobarometer agree with recent Mt. Ruapehu studies. Results show a distribution of crystallization pressures ranging from 50 to 150 MPa (~?2.0 to 5.9 km) for different eruptions, with modes of 110 MPa (~ 4.3 km) and 130 MPa (~ 5.1 km). These are consistent with field interpretations of different eruptive styles based on juvenile clast textures and previous knowledge of the magma plumbing system. Mt. Ruapehu magmas are fluid saturated, with \({f_{{{\text{o}}_2}}}\) of ΔQFM ~ + 1 (NNO).  相似文献   

Crystal nucleation and growth produced by continuous decompression of Pinatubo magma     

Kenneth?S.?BefusEmail author  Benjamin?J.?Andrews 《Contributions to Mineralogy and Petrology》2018,173(11):92

High-temperature decompression experiments demonstrate that crystal textures preserve a record of the style and rate of magmatic ascent. To reinforce this link, we performed a suite of isothermal decompression experiments using starting material from the climactic 1991 Pinatubo eruption. We decompressed experiments from 220 MPa to final, quench pressures of 75 or 30 MPa using continuous decompression rates of 100, 30, 10, 3, 1, and 0.3 MPa h^?1. Amphibole, clinopyroxene, and plagioclase crystallized during the experiments, with plagioclase microlites dominating the assemblage. Total microlite number densities range from 10^7.6±0.4 up to 10^8.2±0.2 cm^?3, with plagioclase accounting for up to 65% of the total number. Plagioclase microlite area increased systematically from 19?±?8 to 937?±?487 µm² with increasing experiment duration. Our textures provide time-integrated records of crystal kinetics. Average nucleation and areal growth rates of plagioclase are highest in the fastest decompressions (~?10^7.5 cm^?3 h^?1 and 10.1?±?4.1 µm² h^?1, respectively) and more than an order of magnitude lower in the slowest experiments (~?10^5.5 cm^?3 h^?1 and 0.8?±?0.2 µm² h^?1, respectively). Both nucleation and growth rates are highest at high degrees of disequilibrium. We find that peak supersaturation-dependent instantaneous rates are generally more than an order of magnitude faster than average rates. We use those instantaneous nucleation and growth rates to introduce an iterative model to evaluate the effects of different decompression rates, decompression paths (continuous, single-step or multistep), and the presence of phenocrysts on final crystallinity and microlite size distribution.  相似文献   

Zoning and exsolution in alkali feldspars from Laacher See volcano (Western Germany): constraints on temperature history prior to eruption     

Smruti?Sourav?RoutEmail authorView author&#;s OrcID profile  Gerhard?W?rner 《Contributions to Mineralogy and Petrology》2018,173(11):95

Compositional zoning and exsolution patterns of alkali feldspars in carbonatite-bearing cognate syenites from the 6.3 km³ (D.R.E) phonolitic Laacher See Tephra (LST) deposit in western Germany (12.9 ka) are reported. These rocks represent the cooler outer portion and crystal-rich products of a cooling magma reservoir at upper crustal levels. Major and trace-element difference between cores and rims in sanidine crystals represent two generations of crystal growth separated by unmixing of a carbonate melt. Trace-element differences measured by LA–ICP–MS are in accordance with silicate–carbonate unmixing. Across the core–rim boundary, we extracted gray-scale profiles from multiple accumulations of back-scattered electron images. Gray scales directly represent K/Na ratios owing to low concentrations of Ba and Sr (<?30 ppm). Diffusion gradients are modeled to solve for temperature using known pre-eruptive U–Th zircon ages (0–20 ky) of each sample (Schmitt et al., J Petrol 51:1053–1085, 2010). Estimated temperatures range from 630 °C to 670 °C. For the exsolution boundaries, a diffusive homogenization model is constrained by the solvus temperature of ~ 712^_725 °C and gives short time scales of only 15–50 days. Based on our results, we present a model for the temperature–time history of these rocks. The model also constrains the thermal variation across the cooling crystal-rich carapace of the magma reservoir over 20 ka and suggests a thermal reactivation of cumulates, the cooling carapace, and probably the entire system only a few years prior to the explosive eruption of the remaining molten core of the phonolitic magma reservoir.  相似文献   

Correction to: Formation by silicate–fluoride + phosphate melt immiscibility of REE-rich globular segregations within aplite dikes     

Charles?R.?SternEmail author  Julien?M.?Allaz  Markus?B.?Raschke  G.?Lang?Farmer  M.?Alexandra?Skewes  Jeremy?T.?Ross 《Contributions to Mineralogy and Petrology》2018,173(10):79

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The accuracy of standard enthalpies and entropies for phases of petrological interest derived from density-functional calculations     

Artur?BenisekEmail authorView author&#;s OrcID profile  Edgar?Dachs 《Contributions to Mineralogy and Petrology》2018,173(11):90

The internal energies and entropies of 21 well-known minerals were calculated using the density functional theory (DFT), viz. kyanite, sillimanite, andalusite, albite, microcline, forsterite, fayalite, diopside, jadeite, hedenbergite, pyrope, grossular, talc, pyrophyllite, phlogopite, annite, muscovite, brucite, portlandite, tremolite, and CaTiO₃–perovskite. These thermodynamic quantities were then transformed into standard enthalpies of formation from the elements and standard entropies enabling a direct comparison with tabulated values. The deviations from reference enthalpy and entropy values are in the order of several kJ/mol and several J/mol/K, respectively, from which the former is more relevant. In the case of phase transitions, the DFT-computed thermodynamic data of involved phases turned out to be accurate and using them in phase diagram calculations yields reasonable results. This is shown for the Al₂SiO₅ polymorphs. The DFT-based phase boundaries are comparable to those derived from internally consistent thermodynamic data sets. They even suggest an improvement, because they agree with petrological observations concerning the coexistence of kyanite?+?quartz?+?corundum in high-grade metamorphic rocks, which are not reproduced correctly using internally consistent data sets. The DFT-derived thermodynamic data are also accurate enough for computing the P–T positions of reactions that are characterized by relatively large reaction enthalpies (>?100 kJ/mol), i.e., dehydration reactions. For reactions with small reaction enthalpies (a few kJ/mol), the DFT errors are too large. They, however, are still far better than enthalpy and entropy values obtained from estimation methods.  相似文献   

The Neogene and Quaternary of England: landscape evolution,tectonics, climate change and their expression in the geological record     

Jonathan R. Lee  Ian Candy  Richard Haslam 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(3):452-481

During the Neogene and Quaternary, tectonic and climatic processes have had a profound impact upon landscape evolution in England and, perhaps as far back as 0.9 Ma, patterns of early human occupation. Until the Late Miocene, large-scale plate tectonic processes were the principal drivers of landscape evolution causing localised basin inversion and widespread exhumation. This drove, in places, the erosion of several kilometres of Mesozoic cover rocks and the development of a regional unconformity across England and the North Sea Basin. By the Pliocene, the relative influence of tectonics on landscape evolution waned as the background tectonic stress regime evolved and climatic influences became more prominent. Global-scale climate-forcing increased step-wise during the Plio-Pleistocene amplifying erosional and depositional processes that operated within the landscape. These processes caused differential unloading (uplift) and loading (subsidence) of the crust (‘denudational isostasy’) in areas undergoing net erosion (upland areas and slopes) and deposition (basins). Denudational isostasy amplified during the Mid-Pleistocene Transition (c.0.9 Ma) as landscapes become progressively synchronised to large-scale 100 ka ‘eccentricity’ climate forcing. Over the past 0.5 Ma, this has led to the establishment of a robust climate record of individual glacial/interglacial cycles enabling comparison to other regional and global records. During the Last Glacial-Interglacial Transition and early Holocene (c.16–7 ka), evidence for more abrupt (millennial/centennial) scale climatic events has been discovered. This indicates that superimposed upon the longer-term pattern of landscape evolution is a more dynamic response of the landscape to local and regional drivers.  相似文献   

The stratigraphical signature of the Anthropocene in England and its wider context     

Jan Zalasiewicz  Colin Waters  Mark Williams  David C. Aldridge  Ian P. Wilkinson 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(3):482-491

The Anthropocene deposits of England, here regarded as those formed after ～1950 CE, are now extensive, take various forms, and may be characterized and recognized by a number of stratigraphic signals, such as artificial radionuclides, pesticide residues, microplastics, enhanced fly ash levels, concrete fragments and a novel variety of ‘technofossils’ and neobiotic species. They include the uppermost parts of both ‘natural’ deposits such as the sediment layers formed in lakes and estuaries, and more directly human-made or human-influenced ones such as landfill deposits and the ‘artificial ground’ beneath urban areas and around major constructions. ‘Negative deposits’ include the worked areas of quarries and regions such as the English Fenland, where thick peat deposits have ablated to leave a strongly modified underlying landscape, and extend beneath into the subterranean realm as mine workings, metro systems and boreholes. The production of these is still rapidly increasing and evolving in character, while the early signs of global change, such as warming, sea level rise, and modifications to biotic assemblages, are beginning to further modify the emerging geology of this new phase of Earth history.  相似文献   

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland          下载免费PDF全文

Yong Chen  Jing Duan  Junling An  Huizhi Liu  Ulrich G?rsdorf  Franz H.Berger 《大气和海洋科学快报》2021,14(5):24-29

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.  相似文献   

Carbon costs and benefits of France’s biomass energy production targets     

Aude?ValadeEmail authorView author&#;s OrcID profile  Sebastiaan?Luyssaert  Patrick?Vallet  Sylvestre?Njakou Djomo  Ingride?Jesus Van Der Kellen  Valentin?Bellassen 《Carbon balance and management》2018,13(1):26

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Design principles for origin-destination flow maps     

Bernhard Jenny  Daniel M. Stephen  Ian Muehlenhaus  Brooke E. Marston  Ritesh Sharma  Eugene Zhang 《制图学和地理信息科学》2018,45(1):62-75

Origin-destination flow maps are often difficult to read due to overlapping flows. Cartographers have developed design principles in manual cartography for origin-destination flow maps to reduce overlaps and increase readability. These design principles are identified and documented using a quantitative content analysis of 97 geographic origin-destination flow maps without branching or merging flows. The effectiveness of selected design principles is verified in a user study with 215 participants. Findings show that (a) curved flows are more effective than straight flows, (b) arrows indicate direction more effectively than tapered line widths, and (c) flows between nodes are more effective than flows between areas. These findings, combined with results from user studies in graph drawing, conclude that effective and efficient origin-destination flow maps should be designed according to the following design principles: overlaps between flows are minimized; symmetric flows are preferred to asymmetric flows; longer flows are curved more than shorter or peripheral flows; acute angles between crossing flows are avoided; sharp bends in flow lines are avoided; flows do not pass under unconnected nodes; flows are radially distributed around nodes; flow direction is indicated with arrowheads; and flow width is scaled with represented quantity.  相似文献