Experimental petrology of alkalic lavas: constraints on cotectics of multiple saturation in natural basic liquids     

Richard O. Sack  David Walker  Ian S. E. Carmichael 《Contributions to Mineralogy and Petrology》1987,96(1):1-23

Experimental study of natural alkalic lava compositions at low pressures (pO₂QFM) reveals that crystallization of primitive lavas often occurs in the sequence olivine, plagioclase, clinopyroxene, nepheline without obvious reaction relation. Pseudoternary liquidus projections of multiply saturated liquids coexisting with plagioclase (±olivine±clinopyroxene±nepheline) have been prepared to facilitate graphical analysis of the evolution of lava compositions during hypabyssal cooling. Use of (TiAl₂)(MgSi₂)_–1 and Fe³⁺ (Al)_–1 exchange components is a key aspect of the projection procedure which is succesful in reducing a wide range of compositions to a systematic graphical representation. These projections, and the experiments on which they are based, show that low pressure fractionation plays a significant role in the petrogenesis of many alkalic lava suites from both continental and oceanic settings. However, the role of polybaric fractionation is more evident in the major element chemistry of these lava suites than in many tholeiitic suites of comparable extent. For example, the lavas of Karisimbi, East Africa, show a range of compositions reflecting a polybaric petrogenesis from primitive picrites at 1360° C/18 kb and leading to advanced low pressure differentiates. Evolved leucite-bearing potassic members of this and other suites may be treated in a nepheline-diopside-kspar (+olivine+leucite) projection. Compositional curvature on the plagioclase+clinopyroxene+olivine+leucite cotectic offers a mechanism to explain resorption of plagioclase in alkalic groundmass assemblages and the incompatibility of albite and leucite. This projection is useful for evaluating the extent of assimilation of the alkalic portions of crustal granulites. Assimilation appears to have played some role in the advanced differentiates from Karisimbi.  相似文献   

Compositional and thermal convection in magma chambers   总被引：7，自引：1，他引：7  

Daniel Martin  Ross W. Griffiths  Ian H. Campbell 《Contributions to Mineralogy and Petrology》1987,96(4):465-475

Magma chambers cool and crystallize at a rate determined by the heat flux from the chamber. The heat is lost predominantly through the roof, whereas crystallization takes place mainly at the floor. Both processes provide destabilizing buoyancy fluxes which drive highly unsteady, chaotic convection in the magma. Even at the lowest cooling rates the thermal Rayleigh number Ra is found to be extremely large for both mafic and granitic magmas. Since the compositional and thermal buoyancy fluxes are directly related it can be shown that the compositional Rayleigh number Rs (and therefore a total Rayleigh number) is very much greater than Ra. In the case of basaltic melt crystallizing olivine Rs is up to 10⁶ times greater than Ra. However compositional and thermal buoyancy fluxes are roughly equal. Therefore thermal and compositional density gradients contribute equally to convection velocities in the interior of the magma. Effects of thermal buoyancy generated by latent heat release at the floor are included.The latent heat boundary layer at the floor of a basaltic chamber is shown to be of the order of 1 m thick with very low thermal gradients whereas the compositional boundary layer is about 1 cm thick with large compositional gradients. As a consequence, the variation in the degree of supercooling in front of the crystal-liquid interface is dominated by compositional effects. The habit and composition of the growing crystals is also controlled by the nature of the compositional boundary layer. Elongate crystals are predicted to form when the thickness of the compositional boundary layer is small compared with the crystal size (as in laboratory experiments with aqueous solutions). In contrast, equant crystals form when the boundary layer is thicker than the crystals (as in most magma chambers). Instability of the boundary layer in the latter case gives rise to zoning within crystals. Diffusion of compatible trace elements through the boundary layer can also explain an inverse correlation, observed in layered intrusions, between Ni concentration in olivine and the proportion of Ni-bearing phases in the crystallizing assemblage.  相似文献   

GROUND-WATER DISPERSION CALCULATIONS WITH A PROGRAMMABLE CALCULATOR     

William E. Kelly 《Ground water》1982,20(6):736-739

Abstract. A simple and convenient method for calculating two-dimensional dispersion on a TI 58 or 59 programmable calculator utilizing the normal distribution program available in the Solid State Software Master Library module as a subroutine is presented with an example.  相似文献   

Ordered mixed-layer structures in the Mighei carbonaceous chondrite matrix     

Ian D.R. Mackinnon 《Geochimica et cosmochimica acta》1982,46(4):479-489

High resolution transmission electron microscopy of the Mighei carbonaceous chondrite matrix has revealed the presence of a new mixed layer structure material. This mixed-layer material consists of an ordered arrangement of serpentine-type (S) and brucite-type (B) layers in the sequence … SBBSBB. … Electron diffraction and imaging techniques show that the basal periodicity is ~ 17 Å. Discrete crystals of SBB-type material are typically curved, of small size (<1 μm) and show structural variations similar to the serpentine group minerals. Mixed-layer material also occurs in association with planar serpentine. Characteristics of SBB-type material are not consistent with known terrestrial mixed-layer clay minerals. Evidence for formation by a condensation event or by subsequent alteration of preexisting material is not yet apparent.  相似文献   

The geochemistry and petrogenesis of the Lower Paleozoic granitoids of the Lleyn Peninsula,North Wales     

Ian W. Croudace 《Geochimica et cosmochimica acta》1982,46(4):609-621

The Lleyn Peninsula of North Wales is penetrated by at least twenty stocks varying from microtonalite through to microgranite and these are closely associated with Caradocian volcanic rocks which include andesitic lavas.Major and trace element analyses show that the sample population may be separated into a peralkaline group and a sub-alkaline group. This latter group may be sub-divided into three compositional series which range from andesite to granite. The andesites are represented by the Caradocian lavas of the Moel y Penmaen district and these plot at one end of major and trace element variation diagrams. Their coherent relationships to the granitoids demonstrate the latter to be Ordovician and therefore ends a longstanding controversy concerning their age. The distinctive geochemistry of the andesites indicates the strong probability that they have evolved from transitional tholeiitic magma by low-pressure crystal fractionation. Apatite fractionation has strongly controlled the rare earth element abundances in the granitoids and for most compositions from andesite through granite their bulk distribution coefficient is greater than unity.The association of peralkaline granites, transitional tholeiites and other geological and geophysical evidence suggests that the area was a region of ensialic crustal tension during the mid-Ordovician.  相似文献   

${}^{40}\text{Ar}{}^{39}\text{Ar}$ and KAr dating of altered glassy volcanic rocks: the Dabi Volcanics,P.N.G.     

David A. Walker  Ian McDougall 《Geochimica et cosmochimica acta》1982,46(11):2181-2190

KAr and ${}^{40}\text{Ar}{}^{39}\text{Ar}$ ages have been determined for altered submarine tholeiitic and boninite (high-Mg andesite) lavas from the Dabi Volcanics, Cape Vogel Peninsula, Papua New Guinea. ${}^{40}\text{Ar}{}^{39}\text{Ar}$ whole rock total fusion and plateau ages identify a Late Paleocene age for the tholeiitic lavas (58.9 ± 1.1 Ma) and also for the boninitic lavas (58.8 ± 0.8 Ma). Apparent KAr ages for the same samples range from 27.2 ± 0.7 to 63.9 ± 4.5 Ma, and young KAr ages for glassy boninites are probably due to variable radiogenic ⁴⁰Ar (⁴⁰Ar¹) loss. These new ages effectively reconcile previously ambiguous age data for the Dabi Volcanics and indicate contemporaneous tholeiitic and boninitic volcanism occurring in southeast PNG during the Late Paleocene.Smectites, developed as alteration products after glass in oceanic lavas commonly do not retain ³⁹Ar during or subsequent to irradiation, but in some cases may contain ⁴⁰Ar1. In the absence of other factors modifying K and Ar contents, samples which have not lost ⁴⁰Ar¹ from smectite and suffer ³⁹Ar loss only, are interpreted to have been altered immediately subsequent to the crystallization of the lava; whereas samples which have lost ⁴⁰Ar¹ as well as ³⁹Ar may be the result of either recent alteration, or of continuous ⁴⁰Ar¹ loss since the time of crystallization.  相似文献   

Reply to Gruhn and Bryan's comments on “Cave sites,faunal analysis,and big-game hunters of the Great Basin: A caution”     

Kelly R. McGuire 《Quaternary Research》1982,18(2):240-242

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Some geophysical constraints on the chemical composition of the earth's lower mantle     

Ian Jackson 《Earth and Planetary Science Letters》1983,62(1):91-103

The physical properties(?, K, K′) of the adiabatically decompressed lower mantle are interpreted in terms of an (Mg,Fe)SiO₃ perovskite + magnesiowüstite mineralogy. The approach employed in this paper involves the removal of the relatively better characterised magnesiowüstite component from the two-phase mixture in order to highlight the physical properties required of the perovskite phase for consistency between the seismological data and any proposed compositional model. It is concluded that a wide tradeoff (emphasized by Davies [1]) between composition, temperature and the physical properties (especially thermal expansion) of the perovskite phase accommodates most recently proposed compositional models including Ringwood's [2] pyrolite and the more silicic models of Burdick and Anderson [3], Anderson [4], Sawamoto [5], Butler and Anderson [6], Liu [7,8] and Watt and Ahrens [9].  相似文献   

A friction damped base isolation system with fail-safe characteristics     

James M. Kelly  Karl E. Beucke 《地震工程与结构动力学》1983,11(1):33-56

An experimental study of a Coulomb friction damped aseismic base isolation system with fail-safe characteristics is described in this paper. The base isolation system utilized commercially made natural rubber bearings and a skid system which comes into operation at preset-levels of relative horizontal displacement between the structure and the foundation. The fail-safe skid provides hysteretic damping and prevents failure of the isolation system in the event of displacements larger than those assumed in the original design. The isolation system can be designed for an earthquake which can be reasonably expected within the lifetime of the structure; in the event of an earthquake of unanticipated intensity the failsafe system will prevent collapse of the structure. The testing of the system involved an 80,000lb model, approximately 1/3 scale to a real structure mounted on the 20′ × 20′ shaking table at EERC and subject to a variety of earthquake inputs. The results show that the hysteretic effect of the fail-safe system does not greatly increase the accelerations experienced by the structure but considerably reduces the relative displacements at the isolation bearings. The action of the fail-safe system was tested by using an earthquake input that produced a resonant response in the isolated mode of the model. The stability limit of the isolation system was exceeded and the bearings failed but complete failure of the isolation system and thus collapse of the model was prevented by the fail-safe system. The implementation of the system in full scale structures poses no technical or construction problems. An equivalent linearization technique was developed for this system for design purposes using response spectra. The accuracy of this approach was verified by comparison with the experimental results.  相似文献   

Chironomid-based paleosalinity records in southern British Columbia, Canada: a comparison of transfer functions     

Markus L. Henrichs  Ian R. Walker  Rolf W. Mathewes 《Journal of Paleolimnology》2001,26(2):147-159

Chironomid remains from Big Lake, British Columbia were analysed and paleosalinities were estimated using a pre-existing transfer function and several developed using new regression methods. A two component partial-least-squares model (PLS-2) had the highest coefficient of determination (R² _(Jackknifed) = 0.75) and lowest root-mean-squared error-of-prediction (RMSEP). As compared to the pre-existing model, it was also less sensitive to the influence of rare taxa. Nevertheless, the marginally larger R² _(Jackknifed) and lower RMSEP do not clearly identify a single best model. The models were applied to Big, Mahoney and Kilpoola lakes, revealing the sensitivity of paleosalinity inferences to model selection. A synopsis of chironomid-based paleosalinities in British Columbia and their correspondence with other paleoclimatic data are presented and discussed.  相似文献