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Generation of CO2-rich melts during basalt magma ascent and degassing   总被引:1,自引:0,他引:1  
To test mechanisms of basaltic magma degassing, continuous decompressions of volatile-bearing (2.7–3.8 wt% H2O, 600–1,300 ppm CO2) Stromboli melts were performed from 250–200 to 50–25 MPa at 1,180–1,140 °C. Ascent rates were varied from 0.25 to ~1.5 m/s. Glasses after decompression show a wide range of textures, from totally bubble-free to bubble-rich, the latter with bubble number densities from 104 to 106 cm?3, similar to Stromboli pumices. Vesicularities range from 0 to ~20 vol%. Final melt H2O concentrations are homogeneous and always close to solubilities. In contrast, the rate of vesiculation controls the final melt CO2 concentration. High vesicularity charges have glass CO2 concentrations that follow theoretical equilibrium degassing paths, whereas glasses from low vesicularity charges show marked deviations from equilibrium, with CO2 concentrations up to one order of magnitude higher than solubilities. FTIR profiles and maps reveal glass CO2 concentration gradients near the gas–melt interface. Our results stress the importance of bubble nucleation and growth, and of volatile diffusivities, for basaltic melt degassing. Two characteristic distances, the gas interface distance (distance either between bubbles or to gas–melt interfaces) and the volatile diffusion distance, control the degassing process. Melts containing numerous and large bubbles have gas interface distances shorter than volatile diffusion distances, and degassing proceeds by equilibrium partitioning of CO2 and H2O between melt and gas bubbles. For melts where either bubble nucleation is inhibited or bubble growth is limited, gas interface distances are longer than volatile diffusion distances. Degassing proceeds by diffusive volatile transfer at the gas–melt interface and is kinetically limited by the diffusivities of volatiles in the melt. Our experiments show that CO2-oversaturated melts can be generated as a result of magma decompression. They provide a new explanation for the occurrence of CO2-rich natural basaltic glasses and open new perspectives for understanding explosive basaltic volcanism.  相似文献   
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We investigate the influence of a stellar fly-by encounter on the Edgeworth-Kuiper belt objects through numerical orbital calculations, in order to explain both mass depletion and high orbital inclinations of the classical Edgeworth-Kuiper belt (CEKB) objects, which have semimajor axis of 42-48 AU and perihelia beyond 35 AU. The observationally inferred total mass of the CEKB is ∼1/10 Earth masses, which is only ∼0.02 of that extrapolated from the minimum-mass solar nebula model. The CEKB consists of bimodal population: “hot population” with inclinations i?0.2-0.6 radians and “cold population” with i?0.1. The observationally suggested difference in size and color of objects between the two populations may imply different origins of the two populations. We find that both the depletion of solid materials in the CEKB and the formation of the hot population are accounted for by a single close stellar encounter with pericenter distance of 80-100 AU and inclination relative to the initial protoplanetary disk ?50°-70°. Such a stellar encounter highly pumps up eccentricities of most objects in the CEKB and then their perihelia migrate within 35 AU. These objects would be removed by Neptune's perturbations after Neptune is formed at or migrates to the current position (30 AU). Less than 10% of the original objects remain in stable orbits with small eccentricities and perihelion distances larger than 35 AU, in the CEKB, which is consistent with the observation. We find that i of the remaining objects are as large as that of the observed hot population. The only problem is how to stop Neptune's migration at ∼30 AU, which is addressed in a separate paper. The depletion by the stellar encounter extends deeply into ∼30-35 AU, which provides the basis of the formation model for the cold population through Neptune's outward migration by Levison and Morbidelli (2003, Nature, 426, 419-421). The combination of our model with Levison and Morbidelli's model could consistently explain the mass depletion, truncation at 50 AU, bimodal distribution in i, and differences in size and color between the hot and the cold populations in the CEKB.  相似文献   
67.
Core P1‐003MC was retrieved from 851 m water depth on the southern Norwegian continental margin, close to the boundary between the Norwegian Current (NC) and the underlying cold Norwegian Sea Deep Water. The core chronology was established by using 210Pb measurements and 14C dates, suggesting a sampling resolution of between 2 and 9 yr. Sea‐surface temperature (SST) variations in the NC are reconstructed from stable oxygen isotope measurements in two planktonic Foraminifera species, Neogloboquadrina pachyderma (d.) and Globigerina bulloides. The high temporal resolution of the SST proxy records allows direct comparison with instrumental ocean temperature measurements from Ocean Weather Ship (OWS) Mike in the Norwegian Sea and an air temperature record from the coastal island Ona, western Norway. The comparison of the instrumental and the proxy SST data suggests that N. pachyderma (d.) calcify during summer, whereas G. bulloides calcify during spring. The δ18O records of both species suggest that the past 70 yr have been the warmest throughout the past 600 yr. The spring and summer proxy temperature data suggest differences in the duration of the cold period of the Little Ice Age. The spring temperature was 1–3°C colder throughout most of the period between ca. AD 1400 and 1700, and the summer temperature was 1–2°C colder throughout most of the period between ca. AD 1400 and 1920. Fluctuations in the depth of the lower boundary of the NC have been investigated by examining grain size data and benthic foraminiferal assemblages. The data show that the transition depth of the lower boundary of the NC was deeper between ca. AD 1400 and 1650 than after ca. AD 1750 until present. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
68.
The vertical transport of contaminants from source areas is employed in many risk assessment models and screening tools in order to estimate the contaminant mass discharge (CMD) into underlying aquifers. The key parameters for estimating CMD are the contaminant source area and concentration, and the vertical water flux, the latter of which depends on the vertical hydraulic conductivity and the vertical hydraulic gradient in the subsurface. This study focuses on advancing the use of the combined membrane interface probe hydraulic profiling tool (MiHPT) to investigate the vertical hydraulic gradient across a clay till overlying a sandy aquifer at a contaminated site in Denmark. Only the HPT is necessary for the estimate of vertical hydraulic gradient. The hydraulic head, clay till thickness, and resulting vertical hydraulic gradients found using the MiHPT compared well with observations from nearby nested wells. The parameter with the largest discrepancy was the thickness of the clay till. The advantage of the MiHPT is its relatively quick depth discrete access to information regarding subsurface permeability, vertical hydraulic gradients and contaminant distribution across a site. In this case study, performance of additional dissipationtests during the HPT log to acquire determination of the vertical hydraulic gradient increased the cost by 3% compared to standard HPT logs.  相似文献   
69.
The management of fishing capacity—in both inland and marine fisheries—is a major policy concern in most countries in Southeast Asia. Excess capacity leads to a number of negative impacts, such as resource use conflicts, overfishing, environmental degradation, economic wastage, and security threats. This paper presents the results of a regional study that examined various approaches to managing excess fishing capacity in small-scale fisheries in Southeast Asia. More specifically, the paper presents an analysis of perceptions of stakeholders in Cambodia, Philippines and Thailand regarding preferred solutions to addressing excess capacity. The paper concludes with a discussion of policy guidance for addressing excess fishing capacity based on the stakeholder-preferred solutions.  相似文献   
70.
Long‐term hydrological data are key to understanding catchment behaviour and for decision making within water management and planning. Given the lack of observed data in many regions worldwide, such as Central America, hydrological models are an alternative for reproducing historical streamflow series. Additional types of information—to locally observed discharge—can be used to constrain model parameter uncertainty for ungauged catchments. Given the strong influence that climatic large‐scale processes exert on streamflow variability in the Central American region, we explored the use of climate variability knowledge as process constraints to constrain the simulated discharge uncertainty for a Costa Rican catchment, assumed to be ungauged. To reduce model uncertainty, we first rejected parameter relationships that disagreed with our understanding of the system. Then, based on this reduced parameter space, we applied the climate‐based process constraints at long‐term, inter‐annual, and intra‐annual timescales. In the first step, we reduced the initial number of parameters by 52%, and then, we further reduced the number of parameters by 3% with the climate constraints. Finally, we compared the climate‐based constraints with a constraint based on global maps of low‐flow statistics. This latter constraint proved to be more restrictive than those based on climate variability (further reducing the number of parameters by 66% compared with 3%). Even so, the climate‐based constraints rejected inconsistent model simulations that were not rejected by the low‐flow statistics constraint. When taken all together, the constraints produced constrained simulation uncertainty bands, and the median simulated discharge followed the observed time series to a similar level as an optimized model. All the constraints were found useful in constraining model uncertainty for an—assumed to be—ungauged basin. This shows that our method is promising for modelling long‐term flow data for ungauged catchments on the Pacific side of Central America and that similar methods can be developed for ungauged basins in other regions where climate variability exerts a strong control on streamflow variability.  相似文献   
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