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151.
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153.
Wilfrido Solano-Acosta Arndt Schimmelmann Maria Mastalerz Irene Arango 《International Journal of Coal Geology》2008,73(3-4):219-236
Cleats and fractures in southwestern Indiana coal seams are often filled with authigenic kaolinite and/or calcite. Carbon- and oxygen-stable isotope ratios of kaolinite, calcite, and coalbed CO2 were evaluated in combination with measured values and published estimates of δ18O of coalbed paleowaters that had been present at the time of mineralization. δ18Omineral and δ18Owater values jointly constrain the paleotemperature of mineralization. The isotopic evidence and the thermal and tectonic history of this part of the Illinois Basin led to the conclusion that maximum burial and heat-sterilization of coal seams approximately 272 Ma ago was followed by advective heat redistribution and concurrent precipitation of kaolinite in cleats at a burial depth of < 1600 m at 78 ± 5 °C. Post-Paleozoic uplift, the development of a second generation of cleats, and subsequent precipitation of calcite occurred at shallower burial depth between 500 to 1300 m at a lower temperature of 43 ± 6 °C. The available paleowater in coalbeds was likely ocean water and/or tropical meteoric water with a δ18Owater − 1.25‰ versus VSMOW. Inoculation of coalbeds with methanogenic CO2-reducing microbes occurred at an even later time, because modern microbially influenced 13C-enriched coalbed CO2 (i.e., the isotopically fractionated residue of microbial CO2 reduction) is out of isotopic equilibrium with 13C-depleted calcite in cleats. 相似文献
154.
Leanne Elchyshyn Jean-Olivier Goyette Émilie Saulnier-Talbot Roxane Maranger Christian Nozais Christopher T. Solomon Irene Gregory-Eaves 《Journal of Paleolimnology》2018,60(3):361-379
Declining water quality in reservoirs is of growing concern in many regions, yet there is still little understanding of long-term water quality trends in these systems. Across the landscape, reservoirs have diverse origins, functions, and operational strategies. In temperate environments, winter water-level drawdown is a common operational practice in reservoirs but the long-term impacts of this hydrological modification has not been extensively studied. We paired a comparative, pre-dam-to-contemporary study (i.e. a top–bottom design) of 12 reservoirs with a detailed paleolimnological study of a focal lake to generate quantitative insights into the relative effect of hydrological changes vs. landscape and climatic drivers on water quality. The focal reservoir, Grand Lac Saint-François, is of relatively similar morphometry, geography, and limnology to our other sites, and has experienced annual winter water-level drawdown of?~?5 m since it was dammed approximately 100 years ago. Based on our top–bottom analysis, we did not find strong correlations between long-term changes in water quality (i.e. diatom-inferred TP estimates) and winter water-level drawdown amplitudes. Instead, reservoir morphometry and watershed characteristics (i.e. geography, maximum depth, and cropland areas) appeared to be stronger drivers of trends across the region. From the detailed paleolimnological analysis, we found that sedimentary pigments and DI-TP concentrations significantly increased over the last century based on Mann–Kendall trend analyses. Breakpoint analyses showed that changes in biological-proxy trends, as well as the sedimentology (i.e. lithology and accumulations rates), coincided with dam construction and the onset of water level regulation. However, given the high variability in metrics and the extent of water level monitoring records, we were unable to quantitatively associate the impacts of drawdown with water quality trends at Grand Lac Saint-François. Conversely, we did find that watershed nutrient surpluses from livestock farming, and warming temperatures were significant explanatory variables of water quality metrics. 相似文献
155.
W. Irene C. Rijpstra J.W. De Leeuw P.A. Schenck 《Geochimica et cosmochimica acta》1976,40(10):1289-1290
BF3-methanol, commonly used for esterification of carboxylic acids, also reacts with some alcohols to give a mixture of methyl ethers. The reaction appears to be limited to allylic alcohols with an alkyl branch at the allylic alcohol group (e.g. phytol). Neither straight chain alcohols nor saturated isoprenoid alcohols react under the prescribed reaction conditions. 相似文献
156.
Public Views on Climate Change: European and USA Perspectives 总被引:5,自引:1,他引:5
If uncontrolled, human influences on the climate system may generate changes that will endanger various aspects of life on Earth. The precise implications of the scientific claims about climate change, and the extent to which they pose dangers to various populations, are becoming intensely debated at many levels in relation to policy. How `danger' is interpreted will ultimately affect which actions are taken. In this paper, we examine how climate change is conceptualised by publics in Europe and in the USA. Although there is widespread concern about climate change, it is of secondary importance in comparison to other issues in people's daily lives. Most individuals relate to climate change through personal experience, knowledge, the balance of benefits and costs, and trust in other societal actors. We analyse these factors through findings from various surveys and studies, which highlight both the distinctiveness and some shared perspectives at a generalised level. We reflect upon these in relation to trust and responsibility for climate change action, and risk communication, supporting the call for discourses about climate change to also be situated in people's locality, as a means of increasing its saliency. 相似文献
157.
A map indicating zones related to groundwater on the mountainous terrain of the island of Naxos, Greece, was produced, using statistics, remote sensing and geographic information system (GIS) techniques. Naxos mainly consists of polydeformed and polymetamorphosed crystalline formations where groundwater is restricted to secondary porosity; its movement is erratic and occurs along lithological contacts, solution openings, faults and fractures. As in the most central Aegean islands, water in Naxos is a scarce commodity. Many dry holes have been drilled. It is known that in areas of such geology, linear features may play a significant role in their hydrogeological regime. Various lineaments’ directional properties were calculated and statistically tested against collected spring data using GIS techniques in an attempt to evaluate the hydrogeological significance of remotely sensed lineaments. Based on the results achieved, a map was prepared to contribute to conventional ground surveys in the selection of drilling sites. The reliability of the map was tested with existing borehole data. The results obtained encourage the use of statistical analysis on remotely sensed lineaments for groundwater targeting studies in crystalline mountainous areas. 相似文献
158.
M. Irene B. Raposo Manoel S. D'Agrella-Filho Jos Paulo P. Pinese 《Tectonophysics》2007,443(1-2):53-71
Magnetic fabric and rock magnetism studies were performed on three mafic dike swarms (total of 38 dikes) from the southernmost part of the São Francisco Craton (SFC) (Minas Gerais State, SE Brazil). They cut Archaean granite–gneiss–migmatite and paleoprototerozoic terranes. These swarms are classified as basic–noritic (Sm–Nd age 2.65 Ga), basic (Rb–Sr age 1.87 Ga) and metamorphic (Rb–Sr age 1.87 Ga) suites, in which the second is the most important. Magnetic fabrics were determined by applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). In most sites magnetic susceptibility is dominantly carried by ferromagnetic minerals, however, in some sites the paramagnetic contribution exceeds 70% of bulk susceptibility. Mainly coarse to fine-grained Ti-poor titanomagnetite up to pure magnetite carry the magnetic fabrics.Three primary AMS fabrics are recognized which are all coaxial with the AARM fabric. Normal AMS fabric is dominant in the basic suite (16 of 20 analyzed dikes) and occurs in 4 and 3 dikes from the basic–noritic and metamorphic suites, respectively. This fabric is interpreted as a result of magma flow in which the analysis of Kmax inclination permitted to infer that the majority of dikes were fed by inclined flows (30° < Kmax < 60°), although 44% of dikes from the basic suite were fed by horizontal or sub-horizontal flows (Kmax < 30°). Intermediate AMS fabric was found in 50% of dikes from the basic–noritic and metamorphic suites, but in only 2 dikes from the basic suite. It is interpreted as due to vertical compaction of a static magma column with the minimum stress along the dike strike. Inverse AMS fabric is a minority (2 dikes from each suite). The parallelism between AMS and AARM tensors for dikes with abnormal fabrics suggests a primary origin for them. Gyroremanent magnetization (GRM) effect was negligible for the majority of dikes, but it was found in two dikes from the basic suite with normal AMS fabric.Magnetic fabrics recognized for the three studied swarms do not depend on magnetic mineralogy, geochemical composition, dike strikes, nor the age of the swarms since the same magnetic minerals and magnetic fabric types are found in dikes from all suites. Inclined and horizontal flows allow us to infer the relative position of at least three magma sources (or magma chambers) from which the dikes were fed. 相似文献
159.
Alessandro Amorosi Giulia Barbieri Luigi Bruno Bruno Campo Tina M. Drexler Wan Hong Veronica Rossi Irene Sammartino Daniele Scarponi Stefano Claudio Vaiani Kevin M. Bohacs 《Sedimentology》2019,66(7):3029-3052
Although general trends in transgressive to highstand sedimentary evolution of river‐mouth coastlines are well‐known, the details of the turnaround from retrogradational (typically estuarine) to aggradational–progradational (typically coastal/deltaic) stacking patterns are not fully resolved. This paper examines the middle to late Holocene eustatic highstand succession of the Po Delta: its stratigraphic architecture records a complex pattern of delta outbuilding and coastal progradation that followed eustatic stabilization, since around 7·7 cal kyr bp . Sedimentological, palaeoecological (benthic foraminifera, ostracods and molluscs) and compositional criteria were used to characterize depositional conditions and sediment‐dispersal pathways within a radiocarbon‐dated chronological framework. A three‐stage progradation history was reconstructed. First, as soon as eustasy stabilized (7·7 to 7·0 cal kyr bp ), rapid bay‐head delta progradation (ca 5 m year?1), fed mostly by the Po River, took place in a mixed, freshwater and brackish estuarine environment. Second, a dominantly aggradational parasequence set of beach‐barrier deposits in the lower highstand systems tract (7·0 to 2·0 cal kyr bp ) records the development of a shallow, wave‐dominated coastal system fed alongshore, with elongated, modestly crescent beaches (ca 2·5 m year?1). Third, in the last 2000 years, the development of faster accreting and more rapidly prograding (up to ca 15 m year?1) Po delta lobes occurred into 30 m deep waters (upper highstand systems tract). This study documents the close correspondence of sediment character with stratal distribution patterns within the highstand systems tract. Remarkable changes in sediment characteristics, palaeoenvironments and direction of sediment transport occur across a surface named the ‘A–P surface’. This surface demarcates a major shift from dominantly aggradational (lower highstand systems tract) to fully progradational (upper highstand systems tract) parasequence stacking. In the Po system, this surface also reflects evolution from a wave‐dominated to river‐dominated deltaic system. Identifying the A–P surface through detailed palaeoecological and compositional data can help guide interpretation of highstand systems tracts in the rock record, especially where facies assemblages and their characteristic geometries are difficult to discern from physical sedimentary structures alone. 相似文献
160.
Gradual Fault Weakening with Seismic Slip: Inferences from the Seismic Sequences of L’Aquila, 2009, and Northridge, 1994 总被引:1,自引:0,他引:1
Luca Malagnini Irene Munafo’ Massimo Cocco Stefan Nielsen Kevin Mayeda Enzo Boschi 《Pure and Applied Geophysics》2014,171(10):2709-2730
We estimate seismological fracture energies from two subsets of events selected from the seismic sequences of L’Aquila (2009), and Northridge (1994): 57 and 16 selected events, respectively, including the main shocks. Following Abercrombie and Rice (Geophys J Int 162: 406–424, 2005), we postulate that fracture energy (G) represents the post-failure integral of the dynamic weakening curve, which is described by the evolution of shear traction as a function of slip. Following a direct-wave approach, we compute mainshock-/aftershock-source spectral ratios, and analyze them using the approach proposed by Malagnini et al. (Pure Appl. Geophys., this issue, 2014) to infer corner frequencies and seismic moment. Our estimates of source parameters (including fracture energies) are based on best-fit grid-searches performed over empirical source spectral ratios. We quantify the source scaling of spectra from small and large earthquakes by using the MDAC formulation of Walter and Taylor (A revised Magnitude and Distance Amplitude Correction (MDAC2) procedure for regional seismic discriminants, 2001). The source parameters presented in this paper must be considered as point-source estimates representing averages calculated over specific ruptured portions of the fault area. In order to constrain the scaling of fracture energy with coseismic slip, we investigate two different slip-weakening functions to model the shear traction as a function of slip: (i) a power law, as suggested by Abercrombie and Rice (Geophys J Int 162: 406–424, 2005), and (ii) an exponential decay. Our results show that the exponential decay of stress on the fault allows a good fit between measured and predicted fracture energies, both for the main events and for their aftershocks, regardless of the significant differences in the energy budgets between the large (main) and small earthquakes (aftershocks). Using the power-law slip-weakening function would lead us to a very different situation: in our two investigated sequences, if the aftershock scaling is extrapolated to events with large slips, a power law (a la Abercrombie and Rice) would predict unrealistically large stress drops for large, main earthquakes. We conclude that the exponential stress evolution law has the advantage of avoiding unrealistic stress drops and unbounded fracture energies at large slip values, while still describing the abrupt shear-stress degradation observed in high-velocity laboratory experiments (e.g., Di Toro et al., Fault lubrication during earthquakes, Nature 2011). 相似文献