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11.
The hydrochemical evolution of an alluvial groundwater located along the Mediterranean seashore is analyzed with respect to its agricultural and climatic environment, including degree of saturation of the soil; types of cultures, chemical fertilizers and phytosanitary treatments; selective irrigations of the cultivated areas; precipitations. It is shown that the environmental effect on the groundwater's vulnerability depends on two groups of factors:
- Transfers from surface to groundwater of nitrates, chlorides, sulfates, and potassium, which are governed by: (a) the climatic conditions before the agricultural activities begin, (b) the kinds of agricultural activities and their distribution in time with respect to a given climatic context. Phenomena of retention of and/or rapid diffusion are related to the sedimentary heterogeneities of the reservoir and to the differences of temperatures between irrigation waters and precipitations.
- Cationic exchanges related to the presence of clays of Montmorillonite-Kaolinite type.
12.
A newly developed technique which allows the down-hole sampling and subsequent analysis of ground water for trace organic contaminants was tested during an investigation of contaminant migration at an inactive landfill site in Burlington, Ontario, Canada. The sampling device, which is lowered down piezometers with a tube, consists of a small cylindrical cartridge of sorbent material attached to a syringe. Vacuum or pressure applied at the surface controls the movement of the plunger in the syringe. The volume of the syringe determines the volume of sample water that passes through the cartridge. The cartridge is removed from the syringe at the surface. One cartridge is used for each sampling; the syringe is reusable. The residual water in the cartridge is removed in the laboratory, and the cartridge is desorbed to a fused silica capillary column for analysis by gas chromatography (GC). The analyses discussed here were performed on a GC/mass spectrometer/data system (GC/MS/DS). Of the many organic compounds that were identified in the samples, three compounds were clearly landfill-related: 1,1,1-trichloroethane, chlorobenzene, and para-dichlorobenzene. The three compounds were found at levels substantially above blank levels in 9, 5, and 5 piezometers, respectively. The average concentrations were 14., 5.3, and 0.88μg/1 (ppb), respectively. The pooled coefficients of variation for the analyses for the three compounds were 27., 6.9, and 6.4%, respectively. The volatility of 1,1,1-trichloroethane was probably the cause of the greater variability in its analytical data. The main advantages of the technique over most conventional sampling methods include: (1) down-hole sampling in a manner which minimizes the potential for volatilization losses; (2) avoidance of passage of the sample through long sections of tubing that may contaminate the sample or cause adsorptive losses; (3) convenience of sample handling, storage, and shipping; and (4) high sensitivity. 相似文献
13.
14.
Coseismic and post-seismic signatures of the Sumatra 2004 December and 2005 March earthquakes in GRACE satellite gravity 总被引:2,自引:0,他引:2
Isabelle Panet Valentin Mikhailov Michel Diament Fred Pollitz Geoffrey King Olivier de Viron Matthias Holschneider Richard Biancale Jean-Michel Lemoine 《Geophysical Journal International》2007,171(1):177-190
The GRACE satellite mission has been measuring the Earth's gravity field and its temporal variations since 2002 April. Although these variations are mainly due to mass transfer within the geofluid envelops, they also result from mass displacements associated with phenomena including glacial isostatic adjustment and earthquakes. However, these last contributions are difficult to isolate because of the presence of noise and of geofluid signals, and because of GRACE's coarse spatial resolution (>400 km half-wavelength). In this paper, we show that a wavelet analysis on the sphere helps to retrieve earthquake signatures from GRACE geoid products. Using a wavelet analysis of GRACE geoids products, we show that the geoid variations caused by the 2004 December ( M w = 9.2) and 2005 March ( M w = 8.7) Sumatra earthquakes can be detected. At GRACE resolution, the 2004 December earthquake produced a strong coseismic decrease of the gravity field in the Andaman Sea, followed by relaxation in the area affected by both the Andaman 2004 and the Nias 2005 earthquakes. We find two characteristic timescales for the relaxation, with a fast variation occurring in the vicinity of the Central Andaman ridge. We discuss our coseismic observations in terms of density changes of crustal and upper-mantle rocks, and of the vertical displacements in the Andaman Sea. We interpret the post-seismic signal in terms of the viscoelastic response of the Earth's mantle. The transient component of the relaxation may indicate the presence of hot, viscous material beneath the active Central Andaman Basin. 相似文献
15.
Isabelle Letard Philippe Sainctavit Catherine Deudon 《Physics and Chemistry of Minerals》2007,34(2):113-120
Pyrrhotite (Fe7S8) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described.
X-ray magnetic circular dichroism (XMCD) at Fe L2,3 edges on Fe7S8, coupled with multiplet calculations, shows that iron is present only as Fe2+ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong
polarization of both Fe and S in Fe7S8. 相似文献
16.
Emmanuelle Montarges-Pelletier Laurent Jeanneau Pierre Faure Isabelle Bihannic Odile Barres Bruno S. Lartiges 《Environmental Geology》2007,53(1):85-102
The Moselle river flows in the north-east of France, from Vosges Mountains to neighboring countries Luxembourg and Germany.
One of its tributaries, the Fensch river, drains a highly industrialized watershed, strongly impacted by mining, smelting
and surfacing activities. The objective of this work, part of a general research program on Moselle watershed (Zone Atelier
Moselle) was to assess the impact of the polluted Fensch river on the global quality of the Moselle river. For that purpose,
water, sediments and suspended particulate matter were sampled in both rivers, upstream and downstream the junction. Four
main sampling campaigns were carried out, in winter during a flood event and in spring at low water level. On a first step,
mineralogical analyses (XRD and FTIR) and chemical analyses (ICP-MS, ICP-AES), were performed on sediments, suspended particulate
matters and filtered waters. Major and trace elements concentrations were obtained on two different granulometric fractions
(0–2 mm and 0–50 μm) revealing the enrichment in heavy metals of fine particles. From one collecting campaign to another,
seasonal variations could be evidenced on suspended matter composition even though major minerals (calcite, quartz and kaolinite)
were always present. Furthermore, spatial variations were evidenced for Fensch and Moselle downstream sediments. Thus, very
fine-grained sediments, poorly crystallized, displaying at the same time higher metal concentrations and higher organic matter
content than in Fensch river material, were collected downstream, in a low hydrodynamic conditions zone, assumed as a preferential
sedimentary zone or even as a placer. Strong correlations could be revealed between iron content and contaminant concentrations,
confirming the origin of polluted material. 相似文献
17.
18.
Pierre Le Hir Andre Ficht Ricardo Silva Jacinto Patrick Lesueur Jean-Paul Dupont Robert Lafite Isabelle Brenon Benedicte Thouvenin Philippe Cugier 《Estuaries and Coasts》2001,24(6):950-963
A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year. 相似文献
19.
Jean-François Chiffoleau Dominique Auger Emmanuelle Chartier Pierre Michel Isabelle Truquet André Ficht Jean-Louis Gonzalez Louis-Alexandre Romana 《Estuaries and Coasts》2001,24(6):1029-1040
Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd. 相似文献
20.
Christian Bigler Evastina Grahn Isabelle Larocque Adam Jeziorski Roland Hall 《Journal of Paleolimnology》2003,29(4):509-510