Contribution of Secondary VOC to the Composition of Aqueous Atmospheric Particles: A Modeling Approach     

Bernard Aumont  Sasha Madronich  Isabelle Bey  Geoffrey S. Tyndall 《Journal of Atmospheric Chemistry》2000,35(1):59-75

Measurements show that 20–60% of the carbon mass present in fine atmospheric particulate matter consists of water soluble organic compounds (WSOC). However, only 5–20% of this WSOC has been identified, mainly as dicarboxylic acids. Because of their high solubility in water, multifunctional secondary compounds derived from the gas-phase oxidation of volatile organic compounds (VOC) are suspected to be key contributors to the WSOC. To test this assumption, an estimate of aqueous uptake of secondary VOC was included in a highly detailed gas-phase mechanism which treats explicitly the formation of the secondary VOC from a set of representative primary species. Simulations were conducted for 2 scenarios, representing typical rural and urban areas. It was observed that the uptake of secondary VOC can lead to WSOC mass concentrations in the range of a few C m^–3, in fairly good agreement with typical WSOC mass concentrations measured. Speciation of WSOC was found to be mainly as tri- or higher multifunctional hydroxy-carbonyl species and hydroxy-hydroperoxide-carbonyl species, in urban and rural environments, respectively. However, it was also found that taking into account only the absorption of secondary VOC does not bring the carboxylic acids mass concentration in agreement with measurements. An attempt was made to explain this discrepancy by introducing chemistry occurring within deliquescent aerosols.  相似文献   

Complete metamorphic cycle and long-lived anatexis in the c. 2.1 Ga Mistinibi Complex,Canada     

Antoine Godet  Carl Guilmette  Loic Labrousse  Donald W. Davis  Matthijs A. Smit  Jamie A. Cutts  Marc-Antoine Vanier  Isabelle Lafrance  Benoit Charette 《Journal of Metamorphic Geology》2020,38(3):235-264

Secular changes in the architecture, thermal state, and metamorphic style of global orogens are thought to have occurred since the Archean; however, despite widespread research, the driving mechanisms for such changes remain unclear. The Paleoproterozoic may prove to be a key era for investigating secular changes in global orogens, as it marks the earliest stage of an eon that saw the onset of modern-style global tectonics. The 2.1 Ga granulite-facies Mistinibi-Raude Domain (MRD), located in the Southeastern Churchill Province, Canada, offers a rare exposure of Paleoproterozoic high metamorphic grade supracrustal sequences (Mistinibi Complex, MC). Rocks from this domain were subjected to petrochronological investigations to establish P–T–t–X evolutions and to provide first order thermal state, burial and exhumation rates, and metamorphic gradients for the transient Paleoproterozoic times. To obtain comprehensive insight into the P–T–t–X evolution of the MRD, we used multi-method geochronology—Lu–Hf on garnet and U–Pb on zircon and monazite—integrated with detailed petrography, trace element chemistry, and phase equilibria modelling. Despite the extensive use of zircon and monazite as geochronometers, their behaviour in anatectic conditions is complex, leading to substantial ambiguity in interpreting the timing of prograde metamorphism. Our results indicate a clockwise metamorphic path involving significant melt extraction from the metasedimentary rocks, followed by cooling from >815°C to ~770°C at ~0.8 GPa. The timing of prograde burial and cooling from supra- to subsolidus conditions is constrained through garnet, monazite, and zircon petrochronology at 2,150–2,120 Ma and at 2,070–2,080 Ma, respectively. These results highlight long-lived residence of the rocks at mid-crustal supra-solidus conditions (55–70 Ma), with preserved prograde and retrograde supra-solidus monazite and zircon. The rocks record extremely slow burial rates (0.25–0.30 km/Ma) along a high metamorphic gradient (900–1,000°C/GPa), which appears symptomatic of Paleoproterozoic orogens. The MC did not record any significant metamorphism after 2,067 Ma, despite having collided with terranes that record high-grade metamorphism during the major 1.9–1.8 Ga Trans-Hudson orogeny. The MC would therefore represent a remnant of a local early Paleoproterozoic metamorphic infrastructure, later preserved as superstructure in the large hot Trans-Hudson orogen.  相似文献   

Modelling evaporation processes in soils from the Huasco salt flat basin,Chile          下载免费PDF全文

María Fernanda Hernández‐López  Isabelle Braud  Jorge Gironás  Francisco Suárez  José Francisco Muñoz 《水文研究》2016,30(25):4704-4719

The need to understand and simulate hydrological phenomena and their interactions, and the impact of anthropogenic and climate changes on natural environments have promoted the study of evaporation from bare soils in arid climates. In closed Altiplano basins, such as those encountered in arid and hyper arid basins in northern Chile, evaporation from shallow groundwater is the main source of aquifer depletion, and thus, its study is crucial for water resources management. The objective of this work is to understand the mechanisms of evaporation in saline soils with shallow water tables, in order to better quantify evaporation fluxes and improve our understanding of the water balance in these regions. To achieve this objective, a model that couples fluid flow with heat transfer was developed and calibrated using column experiments with saline soils from the Huasco salt flat basin, Chile. The model enables determination of both liquid and water vapour fluxes, as well as the location of the evaporation front. Experimental results showed that salt transport inside the soil profile modified the water retention curve, highlighting the importance of including salt transport when modelling the evaporation processes in these soils. Indeed, model simulations only agreed with the experimental data when the effect of salt transport on water retention curves was taken into account. Model results also showed that the evaporation front is closer to the soil surface as the water table depth reduces. Therefore, the model allows determining the groundwater level depth that results in disconnection of liquid fluxes in the vadose zone. A sensitivity analysis allowed understanding the effect of water‐flux enhancements mechanisms on soil evaporation. The results presented in this study are important as they allow quantifying the evaporation that occurs in bare soils from Altiplano basins, which is typically the main water discharge in these closed basins. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Lead Bioavailability to Freshwater Microalgae in the Presence of Dissolved Organic Matter: Contrasting Effect of Model Humic Substances and Marsh Water Fractions Obtained by Ultrafiltration     

Isabelle A. M. Worms  Vera I. Slaveykova  Kevin J. Wilkinson 《Aquatic Geochemistry》2015,21(2-4):217-230

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Reindeer management during the colonization of Sami lands: A long-term perspective of vulnerability and adaptation strategies     

Isabelle Brännlund  Per Axelsson 《Global Environmental Change》2011,21(3):1095-1105

Reindeer husbandry's strong connection to the land, together with the ongoing climate-change debate, has generated growing interest in its socio-ecological resilience and vulnerability. The ability of indigenous societies and their activities to respond to change is widely recognized to be dependent on several factors, such as socioeconomic forces and aspects of governance, all of which have long historical backgrounds. However, although historians constantly address questions about human societies, there have been very few historical studies on their resilience, vulnerability and adaptation strategies. Here, using historical sources, we analyze the vulnerability of reindeer husbandry (and the Sami societies that depended on it) in Sweden during the 19th century. We demonstrate that although reindeer management was a much more diverse enterprise at that time than it is now, the major adaptation strategy and constraining forces were similar to those of today. The foremost adaptation strategy was, and still is, the flexible use of pasture area, and the clearest constraints during the 19th century were the loss of authority over the land and the imposed regulation of reindeer management-both of which were strongly connected to the process of colonization.

Terminology

Throughout this paper we use the terms reindeer management and reindeer pastoralism interchangeably. Sami reindeer pastoralism has been described as a complex system with two different aspects of management: herding and husbandry. Husbandry has been defined as the accumulations of profit whereas herding has been defined as the control of the animals in the terrain (Paine, 1970, p. 53). In a Swedish context husbandry questions concerning slaughter and castration of reindeer were discussed within the household and herding matters were resolved jointly within the traditional working community Siida. The Siida consisted of households working together on traditional pasturelands and these constellations were grouped together into administrative reindeer pasture districts (Sami villages) ( [Ingold, 1978], [Fellman, 1910] and [Beach, 1981]).  相似文献   

Scale-dependent habitat use by a large free-ranging predator,the Mediterranean fin whale     

Cédric Cotté  Christophe Guinet  Isabelle Taupier-Letage  Bruce Mate  Estelle Petiau 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(5):801-811

Since the heterogeneity of oceanographic conditions drives abundance, distribution, and availability of prey, it is essential to understand how foraging predators interact with their dynamic environment at various spatial and temporal scales. We examined the spatio-temporal relationships between oceanographic features and abundance of fin whales (Balaenoptera physalus), the largest free-ranging predator in the Western Mediterranean Sea (WM), through two independent approaches. First, spatial modeling was used to estimate whale density, using waiting distance (the distance between detections) for fin whales along ferry routes across the WM, in relation to remotely sensed oceanographic parameters. At a large scale (basin and year), fin whales exhibited fidelity to the northern WM with a summer-aggregated and winter-dispersed pattern. At mesoscale (20–100 km), whales were found in colder, saltier (from an on-board system) and dynamic areas defined by steep altimetric and temperature gradients. Second, using an independent fin whale satellite tracking dataset, we showed that tracked whales were effectively preferentially located in favorable habitats, i.e. in areas of high predicted densities as identified by our previous model using oceanographic data contemporaneous to the tracking period. We suggest that the large-scale fidelity corresponds to temporally and spatially predictable habitat of whale favorite prey, the northern krill (Meganyctiphanes norvegica), while mesoscale relationships are likely to identify areas of high prey concentration and availability.  相似文献   

Dust Formation Chemistry in Carbon-Rich Wolf-Rayet Winds     

Yoann H. Le Teuff  Isabelle Cherchneff 《Astrophysics and Space Science》1997,251(1-2):389-392

Dust formation processes are investigated in the hot hydrogen-deficient wind of carbon-rich Wolf-Rayet (WC) stars. Results show that dust precursors (small linear carbon chains) form in large quantities only at high gas densities. This suggests that a clumpy wind or an equatorial disc are necessary to trigger dust formation in WC stars. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Contrasting conditions preceding MIS3 and MIS2 Heinrich events   总被引：2，自引：0，他引：2  

Elsa Jullien  Francis E. Grousset  Sidney R. Hemming  Victoria L. Peck  Ian R. Hall  Cdric Jeantet  Isabelle Billy 《Global and Planetary Change》2006,54(3-4):225-238

This paper presents an integrated multi-tracer study performed on piston cores recovered in the glacial ice-rafted detritus belt, stretching from Newfoundland to the Irish margin across the North Atlantic (40–55°N), in order to compare in detail the internal structure of each Heinrich event (HE). These tracers are IRD counts (quartz, dolomite, volcanic grains), their Nd isotopic composition and Ar–Ar datings of individual hornblende grains. A focus on the detailed structure of HE confirms that all intervals of massive sediment flux, specifically Heinrich layers HL1-to-5 (HLs), were dominated by North American, Laurentide ice-sheet surges from Hudson Strait, that are evident as far east as the Bay of Biscay (European margin). The sequences of events leading up to the HLs, however, present significant dissimilarities. One important difference is that HL2 and HL1 were preceded by “precursor events” (increases in the number of lithic grains per gram from non-Laurentide sediment sources). Sediment debris derived from near-simultaneous iceberg releases originating from the European ice-sheet are only detectable close to the European margin. In contrast there are no comparable precursor events before HL5 and HL4. This observation implies that precursor events are unlikely to be mechanistically linked to the triggering of HEs. The similarity of the HLs, against contrasting background conditions, is a significant observation that should add constraints to their origin.  相似文献   

Evaluation of sulfate reduction at experimentally induced mixing interfaces using small-scale push–pull tests in an aquifer–wetland system     

Tara A. Kneeshaw  Jennifer T. McGuire  Erik W. Smith  Isabelle M. Cozzarelli 《Applied Geochemistry》2007,22(12):2618-2629

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Centimeter-scale characterization of biogeochemical gradients at a wetland–aquifer interface using capillary electrophoresis     

Susan Bez-Cazull  Jennifer T. McGuire  Isabelle M. Cozzarelli  Anne Raymond  Lisa Welsh 《Applied Geochemistry》2007,22(12):2664-2683

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