Spatiotemporal changes in cadmium contamination in the Seine estuary (France)     

Jean-François Chiffoleau  Dominique Auger  Emmanuelle Chartier  Pierre Michel  Isabelle Truquet  André Ficht  Jean-Louis Gonzalez  Louis-Alexandre Romana 《Estuaries and Coasts》2001,24(6):1029-1040

Cadmium (Cd) is among the major contaminants in the Seine estuary. In the biota, the RNO (Réseau National d’Observation, the French Mussel-Watch) has shown that Cd concentrations in mussels living at the mouth of the estuary are related to changes in inputs to this area of phosphogypsum, a calcium sulphate that is a by-product of the phosphoric acid naturally enriched with Cd. In the water column, Cd concentrations at several key estuary sites show a very marked trend toward decreased contamination in the particles as well as in the dissolved phase. The behavior of Cd in the estuary has been studied between 1991 and 1998 in the framework of the scientific program Seine-Aval. This program has highlighted punctual Cd inputs in the estuarine water column. The partition of Cd between the dissolved and the particulate phase, previously described in various estuaries, is characterized by an intense phenomenon of solubilization in the mixing zone freshwater-seawater, but the colloidal Cd fraction remains low along the whole salinity gradient, about 5% to 10% of the apparent dissolved fraction. Although the decrease of inputs induced a fall of Cd concentrations in the water column, laboratory experiments show that the estuarine particles are far from being exhausted in Cd. Despite continuous efforts to reduce the urban and industrial inputs into the estuarine and coastal waters, the Seine estuary still remains very contaminated by Cd.  相似文献   

Volume contents     

Christian Bigler  Evastina Grahn  Isabelle Larocque  Adam Jeziorski  Roland Hall 《Journal of Paleolimnology》2003,29(4):509-510

Volume Contents

Volume contents  相似文献   

Petrology,geochemistry and U–Pb geochronology of magmatic rocks from the high-sulfidation epithermal Au–Cu Chelopech deposit,Srednogorie zone,Bulgaria     

Isabelle Chambefort  Robert Moritz  Albrecht von Quadt 《Mineralium Deposita》2007,42(7):665-690

The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat–Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz–sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na₂O, CaO, P₂O₅, and Sr and enrichment in K₂O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U–Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant ²⁰⁶Pb/²³⁸U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean ²⁰⁶Pb/²³⁸U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant ²⁰⁶Pb/²³⁸U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. ¹⁷⁶Hf/¹⁷⁷Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the Chelopech area and the about 92-Ma-old Elatsite porphyry–Cu deposit, suggest two different magma sources in the Chelopech–Elatsite magmatic area. Magmatic rocks associated with the Elatsite porphyry–Cu deposit and the dacitic dome-like body north of Chelopech are characterized by zircons with ɛHf_T90 values of ∼5, which suggest an important input of mantle-derived magma. Some zircons display lower ɛHf_T90 values, as low as −6, and correlate with increasing ²⁰⁶Pb/²³⁸U ages up to about 350 Ma, suggesting assimilation of basement rocks during magmatism. In contrast, zircon grains in andesitic rocks from Chelopech are characterized by homogeneous ¹⁷⁶Hf/¹⁷⁷Hf isotope ratios with ɛHf_T90 values of ∼1 and suggest a homogeneous mixed crust–mantle magma source. We conclude that the Elatsite porphyry–Cu and the Chelopech high-sulfidation epithermal deposits were formed within a very short time span and could be partly contemporaneous. However, they are related to two distinct upper crustal magmatic reservoirs, and they cannot be considered as a genetically paired porphyry–Cu and high-sulfidation epithermal related to a single magmatic–hydrothermal system centered on the same intrusion.  相似文献   

A comparative mineralogical and geochemical study of sulfide mine tailings at two sites in New Mexico, USA   总被引：5，自引：0，他引：5  

Michelle P. Boulet  A. C. L. Larocque 《Environmental Geology》1998,33(2-3):130-142

A comparative study of sulfide mine tailings from two sites near Silver City in southwest New Mexico has shown the need for environmental monitoring in a geological context. The Cyprus-Piños Altos and Cleveland deposits consist of Cu and Zn skarn mineralization in the Piños Altos Mountains of New Mexico. Primary ore minerals in both deposits include chalcopyrite, sphalerite, and galena. The Cyprus-Piños Altos Mine ceased operation in 1995 and the Cleveland Mill closed in 1950. The deposits have similar mineralogical characteristics; however, the tailings are different in terms of age, degree of oxidation and method of disposal. The Cyprus-Piños Altos tailings (CPAT) are stored in a lined, bermed impoundment. They are dominantly water-saturated and exhibit no secondary-phase formation. The grains are not cemented and show no evidence of primary-mineral dissolution. The geochemical data show a predominantly primary signature. The tailings pond water is neutral to slightly alkaline (pH?from 7 to 8.3), partly as a result of processing methods. The Cleveland mill tailings (CMT) were deposited in a valley at the headwaters of an ephemeral stream. They are highly oxidized and differentially cemented. They have undergone numerous wet/dry cycles resulting in extensive oxidation. Secondary minerals predominate, and consist mainly of jarosite, goethite, hematite, and Fe-oxyhydroxides and -oxyhydroxysulfates. The pH of the stream draining the CMT is as high as 2.15. Maximum metal contents in the stream immediately downstream from the tailings are 5305?ppm Zn, 454?ppm Cu, 1.16?ppm Pb, 17.5?ppm Cd, 1.4?ppm As, and 0.01?ppm Hg.  相似文献   

Metal-residence sites in lavas and tuffs from Volcán Popocatépetl, Mexico: implications for metal mobility in the environment     

A. C. L. Larocque  James A. Stimac  Claus Siebe 《Environmental Geology》1998,33(2-3):197-208

 Volcan Popocatépetl is a Quaternary stratovolcano located 60 km southeast of Mexico City. The summit crater is the site of recent ash eruptions, excess degassing, and dacite dome growth. The modern cone comprises mainly pyroclastic flow deposits, airfall tephras, debris flows, and reworked deposits of andesitic composition; it is flanked by more mafic monogenetic vents. In least-degassed fallout tuffs and mafic scoria, transition metals are concentrated in phases formed before eruption, during eruption, and after eruption. Preeruptive minerals occur in both lavas and tephra, and include oxides and sulfides in glass and phenocrysts. The magmatic oxides consist of magnetite, ilmenite, and chromite; the sulfides consist of both (Fe,Ni)_1-xS (MSS) and Cu–Fe sulfide (ISS). Syn- and posteruptive phases occur in vesicles in both lavas and tephra, and on surfaces of ash and along fractures. The mineral assemblages in lavas include Cu–Fe sulfide and Fe–Ti oxide in vesicles, and Fe sulfide and Cu–Fe sulfide in segregation vesicles. Assemblages in vesicles in scoria include Fe–Ti oxide and rare Fe–Cu–Sn sulfide. Vesicle fillings of Fe–Ti oxide, Ni-rich chromite, Fe sulfide, Cu sulfide, and barite are common to two pumice samples. The most coarse-grained of the vesicle fillings are Cu–Fe sulfide and Cu sulfide, which are as large as 50 μ in diameter. The youngest Plinian pumice also contains Zn(Fe) sulfide, as well as rare Ag–Cu sulfide, Ag–Fe sulfide, Ag bromide, Ag chloride, and Au–Cu telluride. The assemblage is similar to those typically observed in high-sulfidation epithermal mineralization. The fine-grained nature and abundance of syn- and/or posteruptive phases in porous rocks makes metals susceptible to mobilization by percolating fluids. The abundance of metal compounds in vesicles indicates that volatile exsolution prior to and/or during eruption played an important role in releasing metals to the atmosphere. Received: March 1997 · Accepted: 27 May 1997  相似文献   

The role of amphibole in the evolution of arc magmas and crust: the case from the Jurassic Bonanza arc section, Vancouver Island, Canada   总被引：6，自引：4，他引：2  

Jeff Larocque  Dante Canil 《Contributions to Mineralogy and Petrology》2010,159(4):475-492

The Jurassic Bonanza arc, on Vancouver Island, British Columbia, represents an exhumed island arc crustal section of broadly diorite composition. We studied bodies of mafic and ultramafic cumulates within deeper levels of the arc to constrain the conditions and fractionation pathways leading from high-Mg basalt to andesite and dacite. Major element trends coupled with textural information show the intercumulus crystallization of amphibole, as large oikocrysts enclosing olivine in primitive cumulates controls the compositions of liquids until the onset of plagioclase crystallization. This process is cryptic, occurring only in the plutonic section, and explains the paucity of amphibole in mafic arc volcanics and the change in the Dy/Yb ratios in many arc suites with differentiation. The correlation of octahedral Al in hornblende with pressure in liquidus experiments on high-Mg basalts is applied as an empirical barometer to hornblendes from the Bonanza arc. It shows that crystallization took place at 470–880 MPa in H₂O-saturated primitive basaltic magmas. There are no magmatic equivalents to bulk continental crust in the Bonanza arc; no amount of delamination of ultramafic cumulates will shift the bulk arc composition to the high-Mg# andesite composition of bulk continental crust. Garnet removal from wet magmas appears to be the key factor in producing continental crust, requiring high pressures and thick crust. Because oceanic island arcs are built on thinner crust, the long-term process generating the bulk continental crust is the accretion of island arcs to continental margins with attendant tectonic thickening.  相似文献   

Dynamic vulnerability factors for impact-based flash flood prediction   总被引：1，自引：1，他引：0  

Galateia Terti  Isabelle Ruin  Sandrine Anquetin  Jonathan J. Gourley 《Natural Hazards》2015,79(3):1481-1497

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Benchmarks for multicomponent reactive transport across a cement/clay interface     

Nicolas C. M. Marty  Olivier Bildstein  Philippe Blanc  Francis Claret  Benoit Cochepin  Eric C. Gaucher  Diederik Jacques  Jean-Eric Lartigue  Sanheng Liu  K. Ulrich Mayer  Johannes C. L. Meeussen  Isabelle Munier  Ingmar Pointeau  Danyang Su  Carl I. Steefel 《Computational Geosciences》2015,19(3):635-653

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Finite difference computation of traveltimes in very contrasted velocity models: a massively parallel approach and its associated tools   总被引：14，自引：0，他引：14  

Pascal Podvin  Isabelle Lecomte 《Geophysical Journal International》1991,105(1):271-284

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A simple method for calculating growth rates of petroleum hydrocarbon plumes   总被引：3，自引：0，他引：3  

Bekins BA  Cozzarelli IM  Curtis GP 《Ground water》2005,43(6):817-826

Consumption of aquifer Fe(III) during biodegradation of ground water contaminants may result in expansion of a contaminant plume, changing the outlook for monitored natural attenuation. Data from two research sites contaminated with petroleum hydrocarbons show that toluene and xylenes degrade under methanogenic conditions, but the benzene and ethylbenzene plumes grow as aquifer Fe(III) supplies are depleted. By considering a one-dimensional reaction front in a constant unidirectional flow field, it is possible to derive a simple expression for the growth rate of a benzene plume. The method balances the mass flux of benzene with the Fe(III) content of the aquifer, assuming that the biodegradation reaction is instantaneous. The resulting expression shows that the benzene front migration is retarded relative to the ground water velocity by a factor that depends on the concentrations of hydrocarbon and bioavailable Fe(III). The method provides good agreement with benzene plumes at a crude oil study site in Minnesota and a gasoline site in South Carolina. Compared to the South Carolina site, the Minnesota site has 25% higher benzene flux but eight times the Fe(III), leading to about one-sixth the expansion rate. Although it was developed for benzene, toluene, ethylbenzene, and xylenes, the growth-rate estimation method may have applications to contaminant plumes from other persistent contaminant sources.  相似文献