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21.
In a context of growing fishing pressures and recommendations for an ecosystem approach to fisheries, there is a need to monitor changes in fish communities over time. In this study, we analysed data from scientific trawl surveys carried out on the continental shelf off Guinea between 1985 and 2012. We performed factorial analyses and calculated biodiversity indices to characterise the changes in the structure and composition of fish communities that occurred over the 28-year period in this area, particularly given intensive fishing activities. We show that, over the study period, fish communities on the Guinean shelf were structured primarily according to spatial factors, with temporal changes being less pronounced than expected. However, a temporal analysis of biodiversity indices and species dominance showed that the intensification of fishing had significant effects on the general ecological features of the fish assemblages under study. There was a decrease in fish density and in mean trophic level. In addition, there were changes in species dominance, whereby large, slow-growing species with high commercial value were gradually replaced by smaller, fast-growing species of lesser commercial interest. These results from field observations are in line with some conclusions from previous modelling studies in the same geographical area, and provide further support for the hypothesis of a progressive ‘ecosystem effect of fishing’ occurring in Guinean waters.  相似文献   
22.
Zooplankton biomass and distribution in the KwaZulu-Natal Bight were investigated in relation to environmental parameters during summer (January–February 2010) and winter (July–August 2010). Mean zooplankton biomass was significantly higher in winter (17.1 mg dry weight [DW] m–3) than in summer (9.5 mg DW m?3). In summer, total biomass was evenly distributed within the central bight, low off the Thukela River mouth and peaked near Durban. In winter, highest biomass was found offshore between Richards Bay and Cape St Lucia. Zooplankton biomass in each size class was significantly, negatively related to sea surface temperature and integrated nitrate, but positively related to surface chlorophyll a and dissolved oxygen. Zooplankton biomass was significantly related to bottom depth, with greatest total biomass located inshore (<50 m). Distribution across the shelf varied with zooplankton size. Seasonal differences in copepod size composition suggest that a smaller, younger community occupied the cool, chlorophyll-rich waters offshore from the St Lucia upwelling cell in winter, and a larger, older community occurred within the relatively warm and chlorophyll-poor central bight in summer. Nutrient enrichment from quasi-permanent upwelling off Durban and Richards Bay appears to have a greater influence on zooplankton biomass and distribution in the bight than the strongly seasonal nutrient input from the Thukela River.  相似文献   
23.
We have carried out a small-scale (∼20 l) CO2 sequestration experiment off northern California (684 m depth, ∼5°C, background ocean pH ∼7.7) designed as an initial investigation of the effects of physical forcing of the fluid, and the problem of sensing the formation of a low pH plume. The buoyant CO2 was contained in a square frame 1.2 m high, exposing 0.21 m2 to ocean flow. Two pH electrodes attached to the frame recorded the signal; a second frame placed 1.9 m south of the CO2 pool was also equipped with two recording pH electrodes. An additional pH electrode was held in the ROV robotic arm to probe the fluid interface. Local water velocities of up to 40 cm sec−1 were encountered, creating significant eddies within the CO2 box, and forcing wavelets at the fluid interface. This resulted in rapid CO2 dissolution, with all CO2 being depleted in a little more than 2 days. The pH record from the sensor closest (∼10 cm) to the CO2 showed many spikes of low pH water, the extreme value being ∼5.9. The sensor 1 m immediately below this showed no detectable response. The electrodes placed 1.9 m distant from the source also recorded very small perturbations. The results provide important clues for the design of future experiments for CO2 disposal and biogeochemical impact studies. These include the need for dealing with the slow CO2 hydration kinetics, better understanding of the fluid dynamics of the CO2-water interface, and non-point source release designs to provide more constant, controlled local CO2 enrichments within the experimental area. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
24.
Pollen data are well established for quantitative climate reconstructions over long timescales, including the Holocene and older interglacials. However, anthropogenically induced environmental change in central Europe was strong during the last 4 ka, challenging quantitative reconstructions of this time period. Here we present quantitative climate reconstructions based on pollen analyses and evaluate them with the peat humification record and the stable carbon isotopes of Sphagnum plant material (δ13Ccellulose). All analyses were carried out on the same 7.5 m long, largely ombrotrophic peat bog section from Dürres Maar. Three different methods were used for the quantitative climate reconstructions on the basis of the pollen data: (1) a probabilistic indicator taxa approach (the ‘pdf method’); (2) a modern analogue technique based on pollen taxa from modern surface samples (cMAT); and (3) a modern analogue technique expanded by plant functional types (pMAT). At Dürres Maar the peat humification is only affected by peat cutting during the Roman period and the Middle Ages. The stable carbon isotopes are seemingly unaffected by human impact. Thus both proxies provide independent data to evaluate the reconstructions on the basis of pollen data. The quantitative climate reconstructions on the basis of the individual methods are in general relatively similar. Nevertheless, distinct differences between the individual approaches are also apparent, which could be attributed to taxa that reflect human impact on a local to regional scale. While the pdf method appears to be relatively robust to all observed anthropogenically induced vegetation changes, it potentially underestimates climate variability. This method is therefore expected to be independent of local site characteristics and to provide robust quantitative estimates of climatic trends rather than of climatic variability of small amplitude. This is of value for palaeoclimate reconstructions of older interglacials, for which neither multiple sites nor independent climate proxies are available for comparison. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   
25.
Little is known about the impacts of mine waste disposal, including deep-sea tailings, on tropical marine environments and this study presents the first account of this impact on deepwater fish communities. The Lihir gold mine in Papua New Guinea has deposited both excavated overburden and processed tailings slurry into the coastal environment since 1997. The abundances of fish species and trace metal concentrations in their tissues were compared between sites adjacent to and away from the mine. In this study (1999-2002), 975 fish of 98 species were caught. Significantly fewer fish were caught close to the mine than in neighbouring regions; the highest numbers were in regions distant from the mine. The catch rates of nine of the 17 most abundant species were lowest, and in three species were highest, close to the mine. There appears to be limited contamination in fish tissues caused by trace metals disposed as mine waste. Although arsenic (several species) and mercury (one species) were found in concentrations above Australian food standards. However, as in the baseline (pre-mine) sampling, it appears they are accumulating these metals mostly from naturally-occurring sources rather than the mine waste.  相似文献   
26.
Orbital forcing of the climate system is clearly shown in the Earths record of glacial–interglacial cycles, but the mechanism underlying this forcing is poorly understood. Traditional Milankovitch theory suggests that these cycles are driven by changes in high latitude summer insolation, yet this forcing is dominated by precession, and cannot account for the importance of obliquity in the Ice Age record. Here, we investigate an alternative forcing based on the latitudinal insolation gradient (LIG), which is dominated by both obliquity (in summer) and precession (in winter). The insolation gradient acts on the climate system through differential solar heating, which creates the Earths latitudinal temperature gradient (LTG) that drives the atmospheric and ocean circulation. A new pollen-based reconstruction of the LTG during the Holocene is used to demonstrate that the LTG may be much more sensitive to changes in the LIG than previously thought. From this, it is shown how LIG forcing of the LTG may help explain the propagation of orbital signatures throughout the climate system, including the Monsoon, Arctic Oscillation and ocean circulation. These relationships are validated over the last (Eemian) Interglacial, which occurred under a different orbital configuration to the Holocene. We conclude that LIG forcing of the LTG explains many criticisms of classic Milankovitch theory, while being poorly represented in climate models.  相似文献   
27.
We have developed, deployed, and tested a novel probe for study of the geochemistry of sediment pore waters based upon Raman spectroscopy. The Raman technique has already been used successfully for in situ measurements of targets of scientific interest including gas and hydrothermal vents and complex gas hydrates, but sediment geochemistry has so far been an intractable problem since the sediments themselves are strongly fluorescent and typically only very small sample volumes are obtainable. The 35 cm long probe extracts pore fluids through a 10 μm sintered metallic frit and draws the sample through a 2 mm diameter channel into a sapphire windowed optical cell within which the laser beam is focused and the spectrum recorded. The dead volume of the system is ~1 ml and the instrument is ROV deployable with activation of probe insertion and sample withdrawal under direct operator control. The unique features of this mode of detection include observation of the sulfate gradient in marine pore waters as an indicator of diagenesis, direct measurement of the dissolved sulfide species H2S and HS?, and measurement of dissolved methane; all of which are of primary geochemical interest. Quantitative analysis is achieved by area ratio to known water peaks and from standard calibration curves with a precision of ±5%. We find only very small fluorescence from pore waters measured in situ, but observe rapid increases in fluorescence from cores returned to the surface and exposed to oxygen.  相似文献   
28.
Obtaining an accurate, value for total ozone under a cloudy sky, especially when the sun is not high, is a major remaining problem associated with total ozone measurements. The Toronto spectrophotometer has been designed with this in mind. It has been fitted with a polarizing prism, and measures light at four wavelengths simultaneous which makes it possible to obtain two independent double ratios. Clouds produce two effects on ozone measurements; the first is purely an optical effect which causes an apparent increase in ozone, the second is most likely a real increase in ozone associated with large cumulus-type clouds. By considering the three following points it is possible to distinguish between these two cloud effects and probably measure the true total ozone for solar zenith angles less than 80°: 1. The multiply scattered component of polarized light is used to reduce optical cloud variance. This makes all skies appear like thick coulds. 2. A double difference similar to the AD method is used but the two ratios of the double difference are weighted inversely with(= 1 - 2 for a pair). This further reduces the optical effects of clouds. 3. Real ozone increases due to large clouds are verified by comparing the increase of ozone obtained from one double difference to that of another. Differences between this multiply, polarized curve and the direct sun curve will be given, and a technique to obtain an accurate value of total ozone under all sky conditions, provided that the solar zenith angle is less than 80°, will be given.  相似文献   
29.
As an example of the technique of fingerprint detection of greenhouse climate change, a multivariate signal or fingerprint of the enhanced greenhouse effect is defined using the zonal mean atmospheric temperature change as a function of height and latitude between equilibrium climate model simulations with control and doubled CO2 concentrations. This signal is compared with observed atmospheric temperature variations over the period 1963 to 1988 from radiosonde-based global analyses. There is a significant increase of this greenhouse signal in the observational data over this period.These results must be treated with caution. Upper air data are available for a short period only, possibly too short to be able to resolve any real greenhouse climate change. The greenhouse fingerprint used in this study may not be unique to the enhanced greenhouse effect and may be due to other forcing mechanisms. However, it is shown that the patterns of atmospheric temperature change associated with uniform global increases of sea surface temperature, with El NinoSouthern Oscillation events and with decreases of stratospheric ozone concentrations individually are different from the greenhouse fingerprint used here.  相似文献   
30.
The distribution of210Po and210Po in dissolved (<0.4 μm) and particulate (>0.4 μm) phases has been measured at ten stations in the tropical and eastern North Atlantic and at two stations in the Pacific. Both radionuclides occur principally in the dissolved phase. Unsupported210Pb activities, maintained by flux from the atmosphere, are present in the surface mixed layer and penetrate into the thermocline to depths of about 500 m. Dissolved210Po is ordinarily present in the mixed layer at less than equilibrium concentrations, suggesting rapid biological removal of this nuclide. Particulate matter is enriched in210Po, with210Po/210Pb activity ratios greater than 1.0, similar to those reported for phytoplankton. Box-model calculations yield a 2.5-year residence time for210Pb and a 0.6-year residence time for210Po in the mixed layer. These residence times are considerably longer than the time calculated for turnover of particles in the mixed layer (about 0.1 year). At depths of 100–300 m,210Po maxima occur and unsupported210Po is frequently present. Calculations indicate that at least 50% of the210Po removed from the mixed layer is recycled within the thermocline. Similar calculations for210Pb suggest much lower recycling efficiencies.Comparison of the210Pb distribution with the reported distribution of226Ra at nearby GEOSECS stations has confirmed the widespread existence of a210Pb/226Ra disequilibrium in the deep sea. Vertical profiles of particulate210Pb were used to test the hypothesis that210Pb is removed from deep water by in-situ scavenging. With the exception of one profile taken near the Mid-Atlantic Ridge, significant vertical gradients in particulate210Pb concentration were not observed, and it is necessary to invoke exceptionally high particle sinking velocities to account for the inferred210Pb flux. It is proposed instead that an additional sink for210Pb in the deep sea must be sought. Estimates of the dissolved210Pb/226Ra activity ratio at depths greater than 1000 m range from 0.2 to 0.8 and reveal a systematic increase, in both vertical and horizontal directions, with increasing distance from the sea floor. This observation implies rapid scavenging of210Pb at the sediment-water interface and is consistent with a horizontal eddy diffusivity of 3?6 × 107 cm2/sec. The more reactive element Po, on the other hand, shows evidence of rapid in-situ scavenging. In filtered seawater,210Po is deficient, on the average, by ca. 10% relative to210Pb; a corresponding enrichment is found in the particulate phase. Total inventories of210Pb and210Po over the entire water column, however, show no significant departure from secular equilibrium.  相似文献   
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