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The vibrational spectrum of Mg2SiO4 olivine was calculated at the Γ point by using the periodic ab initio CRYSTAL program. An all electron localized Gaussian-type basis set and the B3LYP Hamiltonian were employed. The full set of frequencies (35 IR active, 36 Raman active, 10 “silent” modes) was computed and compared to experimental data from different sources (four for IR and four for Raman). A generally good agreement is observed with experiment (the mean absolute difference ranging from 7 to 10 cm−1 for the various sets), when some of the experimental frequencies, whose attribution is uncertain or appears to be affected by large errors, are not taken into account. A small number of observed peaks are not consistent with calculated frequencies, and a few theoretical peaks do not correspond to measured values. The implications are discussed in detail. The full set of modes are characterized using different tools, namely isotopic substitution, direct inspection of the eigenvectors and graphical representation, so as to obtain a consistent mode assignment. 相似文献
137.
The tectonic evolution of the Por’ya Guba segment of the White Sea Rift System began in the late Paleoproterozoic, i.e., soon
after completion of the Svecofennian collision. The fracture system that controlled localization of the lamproite dike complex
was formed under conditions of horizontal compression combined with shear. Subsequently, this system predetermined the location
of a rift-graben segment that formed as a result of simple shear. The reactivation of the rift system in the Middle Paleozoic
proceeded in two stages. The first stage, when strike-slip movements along previously formed faults predominated, resulted
in formation of quartz-carbonate veins bearing base-metal mineralization. The veins that filled the shear fractures opened
owing to local reorientation of the stress field. The second stage fitted the transtension conditions, and the Late Devonian
alkaline ultramafic dikes of this stage introded into the already existing fracture system, which was oriented at a roughly
right angle to the predominant stress orientation. 相似文献
138.
We have mapped three star-forming regions (G265.14+1.45, G269.16?1.14, G291.27?0.71) in the CS(3–2) and C34S(2–1) lines using the 15 m SEST telescope (Chile), and analyzed the relative positions of methanol and H2O masers, IRAS sources, and emission maxima in the CS lines. In most cases, the maser positions are close to those of the IRAS sources. We compared the radial velocities of the maser sources and high-density CS cores, and estimated the CS column densities assuming LTE. The sizes, densities, and masses of the dense core are estimated; the masses obtained in the LTE approximation agree with the virial masses. 相似文献
139.
E. O. Groznova M. G. Dobrovol’skaya V. A. Kovalenker K. V. Davydov V. T. Bitarov M. V. Razin 《Geology of Ore Deposits》2006,48(2):108-133
The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ~120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry. 相似文献
140.
科尔沁沙地土地利用与耕作方式对土壤风蚀的影响 总被引:2,自引:1,他引:2
土壤风蚀造成的直接生态后果是土地资源的退化。在春播前两次沙尘暴事件中,对科尔沁沙地几种具有代表性的土地类型的土壤风蚀量及土壤特性进行了野外测定、分析,结果表明:(1)在同一沙尘暴天气下,由于土地利用和耕作方式的不同,土壤风蚀量存在着差异,新垦农地和翻耕农地的风蚀量显著高于未垦草地、免耕农地和麻黄地;免耕农地则与未垦草地的风蚀量相差不大,风蚀危害较轻;麻黄地几乎不受风蚀侵害。新垦农地、翻耕农地、免耕农地、未垦草地、麻黄地两次观测的土壤风蚀量平均值依次为24.59、15.60、2.26、1.46和0.22 g/h.cm2。(2)基于土壤特性计算的土壤退化指数结果表明,新垦农地和翻耕农地发生了较为严重的退化。 相似文献