CaO-MgO-Al₂o₃-SiO₂ liquids: chemical and isotopic effects of Mg and Si evaporation in a closed system of solar composition     

L. Grossman  A.V. Fedkin 《Geochimica et cosmochimica acta》2003,67(21):4205-4221

A method is shown for calculating vapor pressures over a CMAS droplet in a gas of any composition. It is applied to the problem of the evolution of the chemical and Mg and Si isotopic composition of a completely molten droplet having the composition of a likely refractory inclusion precursor during its evaporation into the complementary, i.e. modified solar, gas from which it originally condensed, a more realistic model than previous calculations in which the ambient gas is pure H_2(g). Because the loss rate of Mg is greater than that of Si, the vapor pressure of Mg_(g) falls and its ambient pressure rises faster than those of SiO_(g) during isothermal evaporation, causing the flux of Mg_(g) to approach zero faster and MgO to approach its equilibrium concentration sooner than SiO₂. As time passes, δ²⁵Mg and δ²⁹Si increase in the droplet and decrease in the ambient gas. The net flux of each isotope crossing the droplet/gas interface is the difference between its outgoing and incoming flux. δ²⁵Mg and δ²⁹Si of this instantaneous gas become higher, first overtaking their values in the ambient gas, causing them to increase with time, and later overtaking their values in the droplet itself, causing them to decrease with time, ultimately reaching their equilibrium values. If the system is cooling during evaporation and if mass transfer ceases at the solidus temperature, 1500 K, final MgO and SiO₂ contents of the droplet are slightly higher in modified solar gas than in pure H_2(g), and the difference increases with decreasing cooling rate and increasing ambient pressure. During cooling under some conditions, net fluxes of evaporating species become negative, causing reversal of the evaporation process into a condensation process, an increase in the MgO and/or SiO₂ content of the droplet with time, and an increase in their final concentrations with increasing ambient pressure and/or dust/gas ratio. At cooling rates <∼3 K/h, closed-system evaporation at P^tot ∼ 10⁻³ bar in a modified solar gas, or at lower pressure in systems with enhanced dust/gas ratio, can yield the same δ²⁵Mg in a residual CMAS droplet for vastly different evaporated fractions of Mg. The δ²⁵Mg of a refractory residue may thus be insufficient to determine the extent of Mg loss from its precursor. Evaporation of Mg into an Mg-bearing ambient gas causes δ²⁶Mg and δ²⁵Mg of the residual droplet to fall below values expected from Rayleigh fractionation for the amount of ²⁴Mg evaporated, with the degree of departure increasing with increasing fraction evaporated and ambient pressure of Mg. δ²⁶Mg and δ²⁵Mg do not depart proportionately from Rayleigh fractionation curves, with δ²⁵Mg being less than expected on the basis of δ²⁶Mg by up to ∼1.2‰. Such departures from Rayleigh fractionation could be used in principle to distinguish heavily from lightly evaporated residues with the same δ²⁵Mg.  相似文献   

Volatilization kinetics of silicon carbide in reducing gases: an experimental study with applications to the survival of presolar grains in the solar nebula     

R.A. Mendybaev  J.R. BeckettL. Grossman  E. StolperR.F. Cooper  J.P. Bradley 《Geochimica et cosmochimica acta》2002,66(4):661-682

The volatilization kinetics of single crystal α-SiC, polycrystalline β-SiC, and SiO₂ (cristobalite or glass) were determined in H₂-CO₂, CO-CO₂, and H₂-CO-CO₂ gas mixtures at oxygen fugacities between 1 log unit above and 10 log units below the iron-wüstite (IW) buffer and temperatures in the range 1151 to 1501°C. Detailed sets of experiments on SiC were conducted at 2.8 and 6.0 log units below IW (IW-2.8 and IW-6.0) at a variety of temperatures, and at 1300°C at a variety of oxygen fugacities. Transmission electron microscopic and Rutherford backscattering spectroscopic characterization of run products shows that the surface of SiC exposed to IW-2.8 is characterized by a thin (<1 μm thick), continuous layer of cristobalite. SiC exposed to IW-6.0 lacks such a layer (or its thickness is <0.01 μm), although some SiO₂ was found within pits and along incised grain boundaries.In H₂-CO₂ gas mixtures above ∼IW-3, the similarity of the SiC volatilization rate and of its dependence on temperature and fO₂ to that for SiO₂ suggests that SiC volatilization is controlled by volatilization of a SiO₂ layer that forms on the surface of the SiC. With decreasing log fO₂ from ∼IW-3 to ∼IW-6, the SiC volatilization rate is constant at constant temperature, whereas that for SiO₂ increases. The independence of the SiC volatilization rate from the gas composition under these conditions suggests that the rate-controlling step is a solid-solid reaction at the internal SiC/SiO₂ interface. For gas compositions more reducing than ∼IW-6, the SiC volatilization rate increases with decreasing fO₂, with both bare SiC surfaces and perhaps silica residing in pits and along incised grain boundaries contributing to the overall reaction rate.If the volatilization mechanism and reaction rate in the solar nebula were the same as in our H₂-CO₂ experiments at IW-6.0, then estimated lifetimes of 1-μm-diameter presolar SiC grains range from several thousand years at ∼900°C, to ∼1 yr at 1100°C, ∼1 d at 1300°C, and ∼1 h at 1400°C. The corresponding lifetimes for 10-μm SiC grains would be an order of magnitude longer. If the supply of oxidants to surfaces of presolar SiC grains were rate limiting—for example, at T > 1100°C for P^tot= 10⁻⁶ atm and sticking coefficient = 0.01, then the calculated lifetimes would be about 10 yr for 10-μm-diameter grains, essentially independent of temperature. The results thus imply that presolar SiC grains would survive short heating events associated with formation of chondrules (minutes) and calcium-, aluminum-rich inclusions (days), but would have been destroyed by exposure to hot (≥900°C) nebular gases in less than several thousand years unless they were coated with minerals inert to reaction with a nebular gas.  相似文献   

安徽巢湖凤凰山剖面石炭系微相和层序地层特征   总被引：9，自引：1，他引：9  

林春明  黄志诚  刘家润  凌洪飞  张顺  赵彦彦 《岩石学报》2002,18(3):424-432

应用露头层序地层学基本原理和方法 ,对巢湖凤凰山石炭系剖面进行重新研究。巢湖凤凰山石炭系总厚度为79.0 2 m ,在这个剖面中可以识别出 6种主要岩相、18种微相和 11个三级沉积层序 ,其中六个三级沉积层序属于 I型沉积层序 ,三个属于 II型沉积层序 ,缺失第 9和第 10沉积层序。三级沉积层序在不同的古地理单元和不同的沉积环境中可以进行对比。根据各微相特征和成因 ,揭示了沉积间断面上存在的多期古岩溶现象。阐述了三级层序及其对应的三级海平面升降旋回的特征  相似文献   

Coupling of deformation and reactions during mid-crustal shear zone development: an in situ frictional–viscous transition     

J. H. MARSH  S. E. JOHNSON  M. G. YATES  D. P. WEST JR 《Journal of Metamorphic Geology》2009,27(8):531-553

A well preserved strain and reaction gradient records the progressive transformation of a megacrystic Kfs+Cpx+Opx+Bt₁±Qtz syenitic pluton to a strongly sheared Kfs+Act+Bt₂+Ab+Qtz tectonite within the exhumed Norumbega Fault System, Maine, USA. Detailed microstructural analysis indicates that fracturing and localized fluid infiltration initiated the deconstruction of the existing K-feldspar and two-pyroxene load-bearing framework, and that feedback among metamorphic reactions, fabric development and enhanced permeability during progressive shearing led to the development of an interconnected, biotite- and actinolite-rich foliation. The activation of dislocation creep in biotite and quartz, and dissolution–precipitation creep in actinolite and feldspar, with increasing strain ultimately resulted in a transition from dominantly frictional to dominantly viscous deformation processes. Petrological data show that various scales of geochemical disequilibrium exist across the strain and reaction gradient, and that reaction progress was limited by slow chemical diffusion during the early stages of deformation. Petrological modelling results indicate that the existing plutonic assemblage was metastable at mid-crustal conditions, and that fluid infiltration and deformation allowed the product assemblage to advance towards chemical equilibration. Comparison of the observed microstructures and deformation mechanisms with experimental and numerical modelling results suggest that the development of an interconnected biotite-dominated fabric probably caused a major (up to three fold) reduction in bulk rock strength and localization of strain into the foliated margin.  相似文献   

Channel braiding and stability of the Brahmaputra River, Bangladesh, since 1967: GIS and remote sensing analyses   总被引：1，自引：1，他引：1  

T. Takagi  T. Oguchi  J. Matsumoto  M.J. Grossman  M.H. Sarker  M.A. Matin 《Geomorphology》2007,85(3-4):294

Spatial and temporal changes in channel distribution in the large, sandy, braided system of the Brahmaputra River, Bangladesh, were analyzed using satellite images and GIS. Supervised classification of the images within the braided belt, i.e., channels and bars between the bank-lines, provided raster land cover data for 14 different years between 1967 and 2002. The width of the braided-belt, the number and width of channels, the distribution of land cover attributes and land stability change were examined from the data. The results indicate that the recent history of the dynamics of the Brahmaputra can be divided into four phases: 1) the late 1960s to early 1970s, 2) the mid-1970s to early 1980s, 3) the mid-1980s to early 1990s, and 4) the mid-1990s to early 2000s. Spatial distributions of the land cover and channels in Phase 4 were the least complex suggesting a state of dynamic equilibrium. Land cover and channel distributions during Phase 2 were partly less complex indicating quasi-dynamic equilibrium. Phases 1 and 3 can be regarded as transitional phases with more complex conditions. Frequent large floods may have triggered significant changes in the river system during Phases 1 and 3.  相似文献   

Composition and provenance of the Upper Cretaceous to Eocene sandstones in Central Palawan, Philippines: Constraints on the tectonic development of Palawan     

Shigeyuki Suzuki  Shizuo Takemura  Graciano P. Yumul JR    Sevillo D. David JR    Daniel K. Asiedu 《Island Arc》2000,9(4):611-626

Abstract Sandstones from the Upper Cretaceous to Eocene succession of Central Palawan are rich in quartz grains and acidic volcanic rock fragments. Potassium feldspar grains and granitic rock fragments are commonly observed. The moderate to high SiO₂ and low FeO plus MgO contents of the sandstones support the proposal that clasts were derived from a continental source region. Southern China (Kwangtung and Fukien regions) is inferred to be the source area of the sandstones. The sedimentary facies of the Upper Cretaceous to Eocene succession consist of turbidite and sandstones, suggesting that they were deposited in the deep sea portions of submarine-fans and basin plains situated along a continental margin. These features indicate that the Upper Cretaceous to Eocene succession of the Central Palawan were derived and drifted from the southern margin of China. The tectonic history related to the formation of Palawan Island is also discussed.  相似文献   

Front affecting the distribution of seabirds in the northern Bering Sea     

NANCY M. HARRISON  GEORGE L HUNT  JR.  ROBERT T. COONEY 《Polar research》1990,8(1):29-31

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Stable nitrogen isotope ratios in wet and dry nitrate deposition collected with an artificial tree     

CHARLES T. GARTEN  JR  . 《Tellus. Series B, Chemical and physical meteorology》1996,48(1):60-64

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Directory of Paleontologists of the World Fifth Edition, 1989     

REX A. DOESCHER  JR.  WILLIAM A. OLIVER 《Boreas: An International Journal of Quaternary Research》1987,16(3):323-324

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Investigation of high-level glaciofluvial terraces and re-evaluation of the established soil stratigraphy for Early and Middle Pleistocene surfaces, central Yukon, Canada     

CRYSTAL A. HUSCROFT  BRENT C. WARD  LIONEL E. JACKSON JR.  CHARLES E. TARNOCAI 《Boreas: An International Journal of Quaternary Research》2006,35(1):96-105

Palaeosols developed on the highest Yukon River glaciofluvial terraces were investigated in order to reconstruct the Plio-Pleistocene evolution of the river valley beyond Late Pleistocene glacial limits. A record of at least two pre-Reid (> 311 kyr) glaciations is chronicled by the presence of two populations of glaciofluvial terraces within the study area. The populations of pre-Reid terraces were identified based on their degree of soil development and elevation. Pre-Reid terraces 200–250 m above river level have preserved morphological and mineralogical features of the Wounded Moose palaeosol, a palaeosol previously associated with pre-Reid surfaces in central Yukon. Clay mineralogy and colour indicate that the Wounded Moose palaeosol developed in part during warm and sub-humid as well as temperate and humid interglacials. A second set of pre-Reid terraces between 110 and 30 m above river level are characterized by the presence of the less-developed Diversion Creek palaeosol, a palaeosol previously associated with only Reid-aged (< 311 kyr) surfaces in central Yukon. In contrast to the Wounded Moose palaeosol, the Diversion Creek palaeosol developed during comparatively cool and humid interglacial conditions. The presence of Diversion Creek palaeosols on pre-Reid outwash terraces suggests that a transition from dominantly warmer to cooler interglacial conditions occurred prior to 311 kyr in Yukon Territory. In addition, the presence of a Diversion Creek palaeosol cannot be used to differentiate stable Reid and stable pre-Reid surfaces across central Yukon.  相似文献