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11.
Meyer JS 《Marine environmental research》2002,53(4):417-423
Because concentrations of total or dissolved metal usually are not good predictors of the acute toxicity of metals to aquatic biota (i.e. not all of the metal appears to be bioavailable), it has been tempting for researchers and regulators to attempt to identify a form or combination of forms of a metal that is the bioavailable fraction. But from geochemical, biological, and analytical perspectives, the term 'bioavailable fraction" is context-specific (i.e. not generalizable) and quantitatively elusive. Although the term "bioavailability" conveys a useful, general concept and should be retained in the aquatic-toxicology lexicon, the term "bioavailable fraction" should be avoided. 相似文献
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程素华 《矿物岩石地球化学通报》2008,27(Z1)
太古宙地幔的热状态是研究早期历史的核心问题之一,而科马提岩是研究早期热状态最直接的标本.科马提岩是一种无水MgO含量大于18%,具鬣刺结构的一种超镁铁质火山岩[1];它是太古代绿岩带的重要标志,被认为是高度熔融的地幔柱的产物[2,3],记录了大量地球深部过程的直接信息,其成分特征可以用来示踪太古宙地幔熔融的深度和温度并反演其形成过程[4,5].因此对了解太古代地幔的组成、热状态以及太古代绿岩带的层序和构造背景具有重要的地球化学和动力学意义6. 相似文献
15.
Hollander DJ Sinninghe Damste JS Hayes JM de Leeuw JW Huc AY 《Organic Geochemistry》1993,20(8):1253-1263
Contents of 13C in kerogens and carbonates in 21 samples from a core of the MAX borehole, Mulhouse Evaporite Basin, range from -27.3 to -23.5 and -3.7 to -1.8% vs PDB, respectively. Organic nitrogen in the same samples is enriched in 15N relative to atmospheric N2 by 12.2-15.7%. Hydrogen indices and delta values for kerogens vary systematically with facies, averaging 493 mg HC/g Corg and -25.7% in the most saline facies (dominated by inputs from aquatic sources) and 267 mg HC/g Corg and -23.7% in the least saline facies (50/50 aquatic/terrigenous). Values of delta were measured for individual aliphatic hydrocarbons from three samples representing three different organic facies. For all samples, terrigenous inputs were unusually rich in 13C, the estimated delta value for bulk terrigenous debris, apparently derived partly from CAM plants, being -22.5%. In the most saline facies, isotopic evidence indicates the mixing of 13C-depleted products of photosynthetic bacteria with 13C-enriched products of halotolerant eukaryotic algae. At lower salinities, a change in the producer community is marked by a decrease in the 13C content of algal lipids. The content of 13C in algal lipids increases in the least saline facies, due either to succession of different organisms or to decreased concentrations of dissolved CO2. 相似文献
16.
中亚造山带南缘如何向南扩展,对深入理解增生型造山作用和大陆地壳生长机制以及中亚构造域与特提斯构造域的衔接具有重要科学意义。作为中亚造山带南缘的关键构造单元,敦煌构造带大地构造属性长期备受关注且颇有争议。传统观点认为敦煌构造带是古亚洲洋南侧的前寒武纪稳定大陆地块,以刚性块体的形式参与了中亚造山带南缘的最终拼贴过程。然而,近年来研究认为敦煌构造带卷入了古亚洲洋南部的俯冲增生造山过程,属于中亚造山带南缘的增生系统。显然,这一争议限制了对中亚造山带南缘向南扩展方式及增生造山过程的理解。敦煌北部三危山地区出露一套古生代岩浆-变质杂岩,是解开这一争论的关键。本文综合前人研究基础及新的资料,归纳了这套岩浆-变质杂岩的野外岩石-构造组合、地球化学和年代学等方面特征:该岩浆-变质杂岩整体显示"二元结构"特征,即较老的增生杂岩为基底,弧岩浆岩侵入或不整合覆盖其上;其中岩浆岩属于中钾-高钾钙碱性系列中酸性岩浆岩,富集大离子亲石元素(LILE)和轻稀土元素(LREE),亏损高场强元素(HFSE),与典型的弧岩浆岩类似,并且微量元素组成特征反映中酸性岩浆的源区与俯冲沉积物部分熔融有关;岩浆作用大致归为510Ma、460~410Ma和370~360Ma三期。岩浆岩中结晶锆石不一致的εHf(t)值(既有正值,又有负值)以及继承锆石的存在表明,岩浆源区既有古老地壳物质的加入,也有新生地壳物质的形成。以上这些特征与发育在增生杂岩之上的增生弧十分类似,因此本文提出敦煌北部岩浆-变质杂岩的属性为古生代增生弧,并且该增生弧与其南部的红柳峡俯冲增生杂岩共同勾勒出敦煌构造带自北向南增生弧-增生杂岩的基本构造格架,即敦煌构造带的大地构造属性实为造山带而非稳定地块。结合区域地质背景及敦煌地区与北山地区古生代至早中生代构造-热事件的对应关系,认为敦煌造山带属于中亚造山带中段南缘的增生系统,中亚造山带中段以增生弧-增生杂岩的形式向南扩展至敦煌地区。 相似文献
17.
The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline. 相似文献
18.
近年来在新疆巴喀勒萨依地区发现一套含少量火山碎屑岩的含铜砂岩地层,由于该地层位于近东西向的断裂夹块中,其含矿层位的确定就成了难题。在该地层中发现了一些腕足类、珊瑚、腹足类、植物化石,经中国科学院南京地质古生物研究所鉴定,时代属晚石炭世晚期。介绍了巴喀勒萨依地区晚石炭世伊什基里克组含铜砂岩剖面及铜矿特征,并获得铜资源量19 797 t,银铜资源量371 t,提出了该区铜、银富集在红色含铜砂岩中有机质聚集处的新观点。 相似文献
19.
青藏高原羌塘地区几个关键地质问题的思考 总被引:32,自引:33,他引:32
羌塘地区是青藏高原最大的一块中比例尺地质调查空白区,许多关键地质问题集中于此。综合多年羌塘地区的地质实践,结合近年来1:25万地质调查的初步成果,提出龙木错一双湖板块缝合带、蛇绿岩、高压变质带、羌塘的基底、南北羌塘地层序列及地层格架、盆地成因类型、羌塘盆地与油气资源、羌塘地区的深部地质结构、羌塘地区生态与环境等方面存在的问题.期望起到抛砖引玉的作用,提供给在羌塘地区从事地质调查的同行们参考。 相似文献
20.
藏北申扎地区奥陶纪鹦鹉螺类一新属(Variabioceras) 总被引:1,自引:0,他引:1
文中材料是采自西藏申扎县塔尔玛乡桥东—扎扛一带鹦鹉螺化石的一部分。描述了3属6种。其中有1个新属Variabioceras gen.nov.和3个新种V.typicum gen.etsp.nov.,V.zangbeiense gen.et sp.nov.,V.robustum gen.et sp.nov. 相似文献