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121.
Effects of natural and calcined poultry waste on Cd, Pb and As mobility in contaminated soil 总被引:1,自引:0,他引:1
Jung Eun Lim Mahtab Ahmad Adel R. A. Usman Sang Soo Lee Weon-Tai Jeon Sang-Eun Oh Jae E. Yang Yong Sik Ok 《Environmental Earth Sciences》2013,69(1):11-20
The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO3 and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO3 and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO3 in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg?1 to below warning level of 1.5 mg kg?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO3 also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg?1 to below warning level of 100 mg kg?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization. 相似文献
122.
To better constrain sampling strategies for observing biologically sensitive parameters in ground water, we vigorously pumped for 120 h a lightly pumped well completed in a confined glacial aquifer while observing how various physical and chemical parameters evolve in the water produced. The parameters commonly monitored when sampling a well stabilized within about an hour, after 5 wellbore volumes were produced; these parameters include temperature, pH, dissolved oxygen, oxidation-reduction potential (Eh), and electrical conductivity. The concentrations of ferrous iron, sulfide, and sulfate and various biological or biologically sensitive parameters, including the concentrations of dissolved hydrogen and methane, direct cell counts, and the microbial community profile, in contrast, required more than 8 h or 36 well volumes to stabilize. We interpret this result to mean that the zone of influence of the wellbore on biologic processes in the aquifer extends beyond the commonly recognized zone where physical properties are affected. A second period of adjustment of these biologically sensitive parameters began after about 50 h of pumping, following displacement of 230 wellbore volumes, and continued to the end of the experiment. During this period, the cell density and the composition of the microbial community suspended in the water samples changed. This finding indicates that the microbial community in and near the wellbore changed in response to pumping and the changes affected aspects of the composition of water produced from the well. The study demonstrates the importance of allowing adequate pumping time when sampling ground water for the analysis of biologically sensitive parameters. 相似文献
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125.
Nguyen Thi Hoang Ha Masayuki Sakakibara Sakae Sano Rie S. Hori Koichiro Sera 《洁净——土壤、空气、水》2009,37(3):203-208
Phytoremediation, a plant‐based and cost‐effective technology for the cleanup of contaminated soil and water, is receiving increasing attention. In this study, the aquatic macrophyte Eleocharis acicularis was examined for its ability to take up multiple heavy metals and its potential application for phytoremediation at an abandoned mining area in Hokkaido, Japan. Elemental concentrations were measured in samples of E. acicularis, water, and soil collected from areas of mine tailing and drainage. The results reveal that Pb, Fe, Cr, Cu, Ni, and Mn accumulation in the plants increased over the course of the experiment, exceeding their initial concentrations by factors of 930, 430, 60, 25, 10, and 6, respectively. The highest concentrations of Fe, Pb, Zn, Mn, Cr, Cu, and Ni within the plants were 59500, 1120, 964, 388, 265, 235, and 47.4 mg/kg dry wt., respectively, for plants growing in mine drainage after 11 months of the experiment. These results indicate that E. acicularis is a hyperaccumulator of Pb. We also found high Si concentrations in E. acicularis (2.08%). It is likely that heavy metals exist in opal‐A within cells of the plant. The bioconcentration factors (BCF: ratio of metal concentration in the plant shoots to that in the soil) obtained for Cr, Cu, Zn, Ni, Mn, and Pb were 3.27, 1.65, 1.29, 1.26, 1.11, and 0.82, respectively. The existence of heavy metals as sulphides is thought to have restricted the metal‐uptake efficiency of E. acicularis at the mine site. The results of this study indicate that E. acicularis shows great potential in the phytoremediation of mine tailing and drainage rich in heavy metals. 相似文献
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127.
Trace metals in seawater and copepods in the ocean outfall area off the northern Taiwan coast 总被引:3,自引:0,他引:3
The distribution, partitioning and concentrations of trace metals (Cd, Cr, Cu, Fe, Mn, Pb and Zn) in seawater, including dissolved and particulate phases, and in copepods in the ocean outfall area off the northern coast of Taiwan were investigated. Normalization of metal concentrations to the background metal concentration to yield relative enrichment factors (EF), which were used to evaluate the contamination of dissolved and particulate trace metals in seawater around the ocean outfall. The EF results indicated that the outfall area was significantly contaminated by dissolved Fe and Zn, and by particulate Fe, Cr, Cu, Pb and Zn. In addition, most trace metals were chiefly in the particulate phase. The average percentage of total metal concentrations (dissolved plus particulate phases) bound by suspended particulate matter followed the sequence Al(95%) = Mn(95%) > Pb(88%) > Cu(86%) > Fe(72%) > Zn(32%) > Cr(17.5%) > Cd(3.4%). Therefore, metal contamination is better evaluated in solid phase than in the dissolved phase. The concentration ranges of trace metals in the copepods, Temora turbinata, Oncaea venusta and Euchaeta rimana, near the outfall were: Cd, 0.23-1.81 microg g(-1); Cr, 16.5-195 microg g(-1); Cu, 14-160 microg g(-1); Fe, 256-7255 microg g(-1); Mn, 5.5-80.8 microg g(-1); Pb, 2.6-56.2 microg g(-1); Zn, 132-3891 microg g(-1); and Al, 0.21-1.13%. Aluminum, and probably Fe, seemed to be the major elements in copepods. The concentrations of trace metals in copepods, especially Temora turbinata, near the outfall were generally higher than those obtained in the background station. The mean increase in bioconcentration factor of metals in copepods ranged from 4 to 7 and followed the sequence Al(6.4) > Cu(6.2) > Fe(6.0) > Zn(5.7) > Pb(5.6) > Cr(5.5) > Cd(5.1) > Mn(4.7). Therefore, marine copepods in the waters of northern Taiwan can accumulate trace metals over background concentrations and act as contamination indicators. 相似文献
128.
Chang?-Woong?ShinEmail author Cheolsoo?Kim Sang?-Kyung?Byun Dongchull?Jeon Sang?-Chull?Hwang 《Ocean Science Journal》2006,41(4):291-299
Hydrographic surveys were carried out four times in the western channel of the Korea Strait in March and August 2003 and in
June and November 2004. The bottom cold water, which was lower than 10°C, appeared in the channel trough except in March 2003.
It flowed southwestward along the shelf of Korean coasts in August 2003 and in November 2004. The width and the maximum speed
of the intrusion current were about 20 km and approximately 25 cm s-1, respectively, off Ulsan, Korea. The volume transport of the bottom cold water was estimated 0.019 Sv (Sv≡106 m3 s-1) in August 2003 and 0.026 Sv in November 2004. 相似文献
129.
Ha H. Bui Jayantha K. Kodikara Abdelmalek Bouazza Asadul Haque Pathegama G. Ranjith 《国际地质力学数值与分析法杂志》2014,38(13):1321-1340
Segmental retaining wall (SRW) systems are commonly used in geotechnical practice to stabilize cut and fill slopes. Because of their flexibility, these systems can tolerate minor movements and settlements without incurring damage or crack. Despite these advantages, very few numerical studies of large deformations and post‐failure behavior of SRW systems are found in the current literature. Traditional numerical methods, such as the finite element method, suffer from mesh entanglement, thus are unable to simulate large deformations and flexible behavior of retaining wall blocks in SRW systems. To overcome the above limitations, a novel computational framework based on the smoothed particle hydrodynamics (SPH) method was developed to simulate large deformations and post‐failure behavior of soils and retaining wall blocks in SRW systems. The proposed numerical framework is a hybrid continuum/discontinuum approach that can model soil as an elasto‐plastic material and retaining wall blocks as independent rigid bodies associated with both translational and rotational degrees of freedom. A new contact model is proposed within the SPH framework to simulate the interaction between the soil and the blocks and between the blocks. As an application of the proposed numerical method, a two‐dimensional simulation of an SRW collapse was simulated and compared to experimental results conducted under the same conditions. The results showed that the proposed computational approach provided satisfactory agreement with the experiment. This suggests that the new framework is a promising numerical approach to model SRW systems. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
130.
In-Hyuk Kwon Hyo-Jong Song Ji-Hyun Ha Hyoung-Wook Chun Jeon-Ho Kang Sihye Lee Sujeong Lim Youngsoon Jo Hyun-Jun Han Hanbyeol Jeong Hui-Nae Kwon Seoleun Shin Tae-Hun Kim 《Asia-Pacific Journal of Atmospheric Sciences》2018,54(1):319-335
This study introduces the operational data assimilation (DA) system at the Korea Institute of Atmospheric Prediction Systems (KIAPS) to the numerical weather prediction community. Its development history and performance are addressed with experimental illustrations and the authors’ previously published studies. Milestones in skill improvements include the initial operational implementation of three-dimensional variational data assimilation (3DVar), the ingestion of additional satellite observations, and changing the DA scheme to a hybrid four-dimensional ensemble-variational DA using forecasts from an ensemble based on the local ensemble transform Kalman filter (LETKF). In the hybrid system, determining the relative contribution of the ensemble-based covariance to the resultant analysis is crucial, particularly for moisture variables including a variety of horizontal scale spectra. Modifications to the humidity control variable, partial rather than full recentering of the ensemble for humidity further improves moisture analysis, and the inclusion of more radiance observations with higher-level peaking channels have significant impacts on stratosphere temperature and wind performance. Recent update of the operational hybrid DA system relative to the previous 3DVar system is described for detailed improvements with interpretation. 相似文献