Formation of radical species in photolyzed CH₄:N₂ ices     

Robert Hodyss  Heather R. Howard  Jay D. Goguen 《Icarus》2011,214(2):748-753

We report photochemical studies of thin cryogenic ice films composed of N₂, CH₄ and CO in ratios analogous to those on the surfaces of Neptune’s largest satellite, Triton, and on Pluto. Experiments were performed using a hydrogen discharge lamp, which provides an intense source of ultraviolet light to simulate the sunlight-induced photochemistry on these icy bodies. Characterization via infrared spectroscopy showed that C₂H₆ and C₂H₂, and HCO are formed by the dissociation of CH₄ into H, CH₂ and CH₃ and the subsequent reaction of these radicals within the ice. Other radical species, such as C₂, , CN, and CNN, are observed in the visible and ultraviolet regions of the spectrum. These species imply a rich chemistry based on formation of radicals from methane and their subsequent reaction with the N₂ matrix. We discuss the implications of the formation of these radicals for the chemical evolution of Triton and Pluto. Ultimately, this work suggests that , CN, HCO, and CNN may be found in significant quantities on the surfaces of Triton and Pluto and that new observations of these objects in the appropriate wavelength regions are warranted.  相似文献   

Incorporating uncertainty into the estimation of biological reference points for a spiny lobster (Panulirus penicillatus) fishery     

Yi‐Jay Chang  Chi‐Lu Sun  Yong Chen  Su‐Zan Yeh  Wei‐Chuan Chiang 《新西兰海洋与淡水研究杂志》2013,47(1):429-442

The status of a fishery is often defined as the probability of fishing mortality rate exceeding a perilous level for long‐term sustainability. Lobster stock assessments are often subject to large uncertainty in input data and high levels of natural variability in lobster life history processes, which calls for incorporating uncertainty associated with both indicator and management reference points in an evaluation of biological risk of overfishing. Using a Monte Carlo simulation approach, we evaluated the impacts of uncertainty in modelling on the determination of the status of the Taitung spiny lobster (Panulirus penicillatus) fishery (Taiwan), which has not been quantitatively determined despite its commercial importance. The commonly used biological reference points derived from the per recruit model (F _0.1 the fishing mortality rate where the slope of the curve of yield‐per‐recruit model is 10% of the maximum slope and F _4Q%, the fishing mortality rate that reduces the expected egg production for a cohort of female lobsters to 40% of that produced in the absence of a fishery of the egg‐per‐recruit model) were influenced by uncertainties associated with lobster life history and fishery parameters. A large uncertainty in the current fishing mortality rate (F _cnr) and estimates of biological reference points (F _BRPs) increased the uncertainty in determining the risk of overexploitation throughout the confidence levels of the stochastic decision‐making framework. This simulation study suggests that the target reference point of F _40% is less sensitive to the input parameters’ uncertainty than F _0.1 We suggest a further evaluation of other F‐based references points and development of biomass‐based reference points before final selection and implementation for the management of the Taitung lobster fishery.  相似文献   

Degradation of wetlands on the Qinghai-Tibet Plateau: A comparison of the effectiveness of three indicators   总被引：1，自引：1，他引：0  

GAO Jay  LI Xi-lai  CHEUNG Alan  YANG Yuan-wu 《山地科学学报》2013,10(4):658-667

The Qinghai-Tibet Plateau encompasses a large quantity of wetlands, some of which have been degraded to varying severity levels. In the literature, a number of degradation indicators have been proposed to evaluate ecological health of wetlands, but their effectiveness in the plateau environment remains unknown. In this study, we assessed the effectiveness of three degradation indicators, soil moisture content at 10 cm deep, vegetative cover, and density of pika burrows. The degradation severity of wetlands in Maduo County on the Qinghai-Tibet Plateau is enumerated at four levels, intact, slight, moderate and severe. Analysis of 106 samples collected in the field demonstrates that the density of pika burrows is the least reliable indicator. By comparison, vegetative cover and underlying soil moisture content are more reliable, even though neither is a perfect indicator as the difference among adjacent levels of severity as revealed by t-test is not always statistically significant. The imperfection of vegetative cover as an indicator is due to its variation among different types of wetlands. The limitation of moisture content is attributed to its non-linear relationship with wetland degradation. Above the threshold of about 50% in moisture content wetlands are unlikely to be degraded. It is recommended that moisture be measured at the point near the surface and vegetative cover be further differentiated by species in order to improve their effectiveness.  相似文献   

Elasticity of antigorite,seismic detection of serpentinites,and anisotropy in subduction zones     

Lucile Bezacier  Bruno Reynard  Jay D. Bass  Carmen Sanchez-Valle  Bertrand Van de Moortèle 《Earth and Planetary Science Letters》2010,289(1-2):198-208

Serpentinization of the mantle wedge is an important process that influences the seismic and mechanical properties in subduction zones. Seismic detection of serpentines relies on the knowledge of elastic properties of serpentinites, which thus far has not been possible in the absence of single-crystal elastic properties of antigorite. The elastic constants of antigorite, the dominant serpentine at high-pressure in subduction zones, were measured using Brillouin spectroscopy under ambient conditions. In addition, antigorite lattice preferred orientations (LPO) were determined using an electron back-scattering diffraction (EBSD) technique. Isotropic aggregate velocities are significantly lower than those of peridotites to allow seismic detection of serpentinites from tomography. The isotropic V_P/V_S ratio is 1.76 in the Voigt–Reuss–Hill average, not very different from that of 1.73 in peridotite, but may vary between 1.70 and 1.86 between the Voigt and Reuss bonds. Antigorite and deformed serpentinites have a very high seismic anisotropy and remarkably low velocities along particular directions. V_P varies between 8.9 km s^? 1 and 5.6 km s^? 1 (46% anisotropy), and 8.3 km s^? 1 and 5.8 km s^? 1 (37%), and V_S between 5.1 km s^? 1 and 2.5 km s^? 1 (66%), and 4.7 km s^? 1 and 2.9 km s^? 1 (50%) for the single-crystal and aggregate, respectively. The V_P/V_S ratio and shear wave splitting also vary with orientation between 1.2 and 3.4, and 1.3 and 2.8 for the single-crystal and aggregate, respectively. Thus deformed serpentinites can present seismic velocities similar to peridotites for wave propagation parallel to the foliation or lower than crustal rocks for wave propagation perpendicular to the foliation. These properties can be used to detect serpentinite, quantify the amount of serpentinization, and to discuss relationships between seismic anisotropy and deformation in the mantle wedge. Regions of high V_P/V_S ratios and extremely low velocities in the mantle wedge of subduction zones (down to about 6 and 3 km.s^?1 for V_P and V_S, respectively) are difficult to explain without strong preferred orientation of serpentine. Local variations of anisotropy may result from kilometer-scale folding of serpentinites. Shear wave splittings up to 1–1.5 s can be explained with moderately thick (10–20 km) serpentinite bodies.  相似文献   

FIELDWORK AND GRAPHIC NARRATIVES     

Jeff Wilson  Jay Jacot 《Geographical review》2013,103(2):143-152

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Spatial analysis of linguistic data with GIS functions     

Jay Lee  William A. Kretzschmar Jr 《International journal of geographical information science》2013,27(6):541-560

Abstract

During the 1980s techniques for analysis of geographical patterns have been refined to the point that they may be applied to data from many fields. Quantitative spatial analysis and existing functions available in geographical information systems (GIS) enable computerized implementations of these spatial analysis methods. This paper describes the application of quantitative spatial analysis and GIS functions to analysis of language data, using the extensive files of the Linguistic Atlas of the Middle and South Atlantic States (LAMSAS). A brief review of recent development of using quantitative and statistical methods for analysing linguistic data is also included.  相似文献   

Delineating groundwater potential zones in a hard-rock terrain using geospatial tool     

Prafull Singh  Jay Krishana Thakur  Suyash Kumar 《水文科学杂志》2013,58(1):213-223

Abstract

Geospatial techniques have become one of the leading tools in the field of natural sciences for assessment, monitoring and management of natural resources, particularly in groundwater research. The paper discusses the demarcation and assessment of groundwater potential zones using geospatial techniques in the Deccan Volcanic Province of Maharashtra, India, using multi-criteria analyses. The study incorporates integration of thematic information (geomorphology, lithology, drainage density, slope and lineaments) in a GIS environment in order to identify groundwater potential zones. The methodology adopted can be used as a rapid assessment tool in groundwater exploration and is helpful in predictive groundwater resource management. Multi-criteria evaluation techniques were used to integrate all the thematic layers. Individual themes and their corresponding categories were assigned a knowledge base ranking from 1 to 5, depending on their importance for groundwater potential. Using the Raster calculator tool in Arc GIS software, all thematic maps were integrated to produce a composite groundwater potential map of the study area. The identified groundwater potential zones were classified into four classes, from excellent to poor. The generated groundwater potential zones were validated with field checks and borewell/dugwell yield data, and showed consistency with the observations.

Citation Singh, P., Thakur, J. K., and Kumar, S. (2013) Delineating groundwater potential zones in a hard-rock terrain using geospatial tools. Hydrological Sciences Journal, 58 (1), 1–11.  相似文献   

SOIL,SUBSOIL, AND FOREST COMPOSITION IN SOUTH-CENTRAL MICHIGAN,USA     

Sheridan L. Dodge  Jay R. Harman 《自然地理学》2013,34(1):85-101

Although soil texture is an important predictor of upland forest composition in southern Michigan, the relationship in some areas is weak and other environmental factors may exert stronger control on species composition. One of these may be concealed subsoil lithology where coarse-textured glaciofluvial sediments are buried beneath finer-textured till. Samples of forest composition, soil, and subsoil characteristics from 48 less-disturbed woodlots in the south-central Lower Peninsula reveal that upland oaks and hickories are predominant where the till veneer is thin and sand and gravel are relatively near the surface. Where till is relatively thick and outwash is deeply buried, woodlot composition is sugar maple-beech. In each of these cases, soil texture is unrelated to stand composition. The likely effect of buried near-surface glaciofluvial sediments is moisture stress such that xeric species dominate these drier sites. The influence of subsoil on forest geography is a significant new finding with regard to southern Michigan and has possible application elsewhere in glaciated eastern North America.  相似文献   

Application of the Ti-in-quartz thermobarometer to rutile-free systems. Reply to: a comment on: ‘TitaniQ under pressure: the effect of pressure and temperature on the solubility of Ti in quartz’ by Thomas et al.   总被引：2，自引：1，他引：1  

Jay B. Thomas  E. Bruce Watson 《Contributions to Mineralogy and Petrology》2012,164(2):369-374

The premise of the Wilson et al. comment is that the Ti-in-quartz solubility calibration (Thomas et al. in Contrib Mineral Petrol 160:743–759, 2010) is fundamentally flawed. They reach this conclusion because P–T estimates using the Ti-in-quartz calibration differ from their previous interpretations for crystallization conditions of the Bishop and Oruanui rhyolites. If correct, this assertion has far-reaching implications, so a careful assessment of the Wilson et al. reasoning is warranted. Application of the Ti-in-quartz calibration as a thermobarometer in rutile-free rocks requires an estimation of TiO₂ activity in the liquid ( (liquid–rutile); referenced to rutile saturation) and an independent constraint on either P or T to obtain the crystallization temperature or pressure, respectively. The foundation of Wilson et al.’s argument is that temperature estimates obtained from Fe–Ti oxide thermometry accurately reflect crystallization conditions of quartz in the two rhyolites discussed. We maintain that our experimental approach is sound, the thermodynamic basis of the Ti-in-quartz calibration is fundamentally correct, and our experimental results are robust and reproducible. We suggest that the reason Wilson et al. obtain implausible pressure estimates is because estimates for T and they used as input values for the Ti-in-quartz calibration are demonstrably too high. Numerous studies show that Fe–Ti oxide temperature estimates of some rhyolites are substantially higher than those predicted by well-constrained phase equilibria. In this reply, we show that when reasonable input values for T and (liquid–rutile) are used, pressure estimates obtained from the Ti-in-quartz calibration are well aligned with phase equilibria and essentially identical to melt inclusion volatile saturation pressures.  相似文献   

Sublethal Effects of Crude Oil on the Community Structure of Estuarine Phytoplankton   总被引：1，自引：0，他引：1  

Kailen Gilde  James L. Pinckney 《Estuaries and Coasts》2012,35(3):853-861

While the ecological impacts of crude oil exposure have been widely studied, its sublethal effects on phytoplankton community structure in salt marsh estuaries have not been well documented. The purpose of this study was to simulate oil spill conditions using a microcosm design to examine short-term (2 day) changes in phytoplankton community composition and total biomass following exposure to crude oil obtained from the Deepwater Horizon oil spill and a mixture of Texas crude oils. Microcosm experiments were performed in situ in North Inlet Estuary near Georgetown, SC. A control and six replicated experimental treatments of crude oil additions at final concentrations of 10, 50, or 100 μl l⁻¹ of either Deepwater Horizon spill oil or the Texas crude mixture were incubated under in situ conditions. Photopigments were analyzed using high-performance liquid chromatography and community composition was determined using ChemTax. Total phytoplankton biomass (as chl a) declined with increasing crude oil concentrations. Prasinophytes, the most abundant microalga in both experiments, showed no response to oil exposure in one experiment and a significant negative response in the other. Diatoms euglenophytes and chlorophytes appeared relatively resistant to oil contamination at the exposure levels used in this study, maintaining or increasing their relative abundance with increasing oil concentrations. Chlorophytes and cyanobacteria increased in relative abundance while cryptophyte abundance decreased with increasing oil concentrations. The results of these experiments suggest that low levels of crude oil exposure may reduce total biomass and alter phytoplankton community composition with possible cascade effects at higher trophic levels in salt marsh estuaries.  相似文献