Early Permian extensional shearing of an Ordovician granite: The Saint-Eutrope “C/S-like” orthogneiss (Montagne Noire,French Massif Central)     

Pavel Pitra  Marc Poujol  Jean Van Den Driessche  Jean-Charles Poilvet  Jean-Louis Paquette 《Comptes Rendus Geoscience》2012,344(8):377-384

Dating the magmatic events in the Montagne Noire gneiss dome is a key point to arbitrate between the different interpretations of the Late Carboniferous–Early Permian tectonics in this southern part of the Variscan belt. The Saint-Eutrope orthogneiss crops out along the northern flank of the dome. We show that the protolith of this orthogneiss is an Ordovician granite dated at 455 ± 2 Ma (LA-ICP-MS U-Pb dating on zircon). This age is identical to that previously obtained on the augen orthogneiss of the southern flank, strongly suggesting that both orthogneiss occurrences have the same Ordovician protolith. The Saint-Eutrope orthogneiss experienced intense shearing along the Espinouse extensional detachment at ca. 295 Ma (LA-ICP-MS U-Pb-Th on monazite), an age close to that determined previously on mica by the ³⁹Ar-⁴⁰Ar method and contemporaneous with the emplacement age of the syntectonic Montalet granite farther to the west. This normal sense shearing reworked previous fabrics related to Variscan thrusting that can be still observed in the augen orthogneiss of the southern flank, and is responsible for the spectacular “C/S-like” pattern of the Saint-Eutrope orthogneiss. This work also shows that care is needed when dealing with C/S-type structures, since they can develop not only in syntectonic intrusions, but also in orthogneisses affected by an intense secondary deformation, at decreasing temperature.  相似文献   

Post-injection trapping of mobile CO<Subscript><Emphasis Type="Bold">2</Emphasis></Subscript> in deep aquifers: Assessing the importance of model and parameter uncertainties     

JC. Manceau  J. Rohmer 《Computational Geosciences》2016,20(6):1251-1267

Predicting the fate of the injected CO₂ is crucial for the safety of carbon storage operations in deep saline aquifers: especially the evolution of the position, the spreading and the quantity of the mobile CO₂ plume during and after the injection has to be understood to prevent any loss of containment. Fluid flow modelling is challenging not only given the uncertainties on subsurface formation intrinsic properties (parameter uncertainty) but also on the modelling choices/assumptions for representing and numerically implementing the processes occurring when CO₂ displaces the native brine (model uncertainty). Sensitivity analysis is needed to identify the group of factors which contributes the most to the uncertainties in the predictions. In this paper, we present an approach for assessing the importance of model and parameter uncertainties regarding post-injection trapping of mobile CO₂. This approach includes the representation of input parameters, the choice of relevant simulation outputs, the assessment of the mobile plume evolution with a flow simulator and the importance ranking for input parameters. A variance-based sensitivity analysis is proposed, associated with the ACOSSO-like meta-modelling technique to tackle the issues linked with the computational burden posed by the use of long-running simulations and with the different types of uncertainties to be accounted for (model and parameter). The approach is tested on a potential site for CO₂ storage in the Paris basin (France) representative of a project in preliminary stage of development. The approach provides physically sound outcomes despite the challenging context of the case study. In addition, these outcomes appear very helpful for prioritizing the future characterisation efforts and monitoring requirements, and for simplifying the modelling exercise.  相似文献   

The impact of climate change on the fish community structure of the eastern continental shelf of the Bay of Biscay   总被引：2，自引：1，他引：2  

Poulard  Jean-Charles; Blanchard  Fabian 《ICES Journal of Marine Science》2005,62(7):1436-1443

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Climate policies as a hedge against the uncertainty on future oil supply   总被引：2，自引：2，他引：0  

Julie Rozenberg  Stéphane Hallegatte  Adrien Vogt-Schilb  Olivier Sassi  Céline Guivarch  Henri Waisman  Jean-Charles Hourcade 《Climatic change》2010,101(3-4):663-668

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Analysis of the Major Fe Bearing Mineral Phases in Recent Lake Sediments by EXAFS Spectroscopy   总被引：1，自引：0，他引：1  

Lorenzo Spadini  Markus Bott  Bernhard Wehrli  Alain Manceau 《Aquatic Geochemistry》2003,9(1):1-17

Extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical analyses were combined to determine the Fe bearing minerals in recent lake sediments from Baldeggersee (Switzerland). The upper section of a laminated sediment core, deposited under eutrophic conditions, was compared to the lower part from an oligotrophic period. Qualitative analysis of FeK EXAFS agreed well with chemical data: In the oligotrophic section Fe(II)–O and Fe(III)–O specieswere present, whereas a significant fraction of Fe(II)–S sulfides was strongly indicated in the eutrophic part. A statistical analysis was performed by least square fitting of normalized reference spectra. The set of reference minerals included Fe(III) oxides and Fe(II) sulfides, carbonates and phosphates. In the oligotrophic regime no satisfying fit was obtained using the set of reference spectra, indicating that siderite (FeCO₃) was not present in a significant amount in these carbonate-rich sediments. Simulated EXAFS spectra for a(Ca_x, Fe_1-x)CO₃solid solution allowed reconstructing the specificfeatures of the experimental spectra, suggesting that this phase was the dominant Fe carrier in the oligotrophic section of the core. In the eutrophic part, mackinawite was positively identified and represented the dominant Fe(II) sulfide phase. This finding agreed with chemical extraction, which indicated that18–40 mol% of Fe was contained in the acid volatile iron sulfide fraction. EXAFS spectra of the eutrophic section were best fitted by considering the admixture of mackinawite and the Fe–Ca carbonate phase inferred to be predominant in the oligotrophic regime.  相似文献   

Ba and Ni speciation in a nodule of binary Mn oxide phase composition from Lake Baikal     

Alain Manceau  Michael Kersten  Nicolas Geoffroy 《Geochimica et cosmochimica acta》2007,71(8):1967-1981

The partitioning and incorporation mechanism of Ni and Ba in a ferromanganese nodule from Lake Baikal were characterized by X-ray microfluorescence, microdiffraction, and absorption spectroscopy. Fe is speciated as goethite, and Mn as romanechite (psilomelane) and 10 Å-vernadite (turbostratic buserite) with minor 7 Å-vernadite (turbostratic birnessite). Barium is associated with romanechite and Ni with vernadite in distinct and irregularly distributed layers, and each type of Mn oxide is separated from the other type by goethite. The binary Mn oxide banding pattern is interpreted by a two-mode accretionary model, in which the variation in Ba flux induced by hydrothermal water pulses determines whether a tectomanganate (romanechite) or phyllomanganate (vernadite) is formed during the ferromanganese nodule accretion. Consistent with the dependence of Ni sorption on pH and the circumneutral pH of the lake water, nickel is mainly substituted isomorphically for Mn in the manganese layer, and is not sorbed at vacant Mn layer sites in the interlayer.  相似文献   

Isotope palaeohydrology and the prediction of long-term repository behaviour     

Jean-Charles Fontes 《地学学报》1994,6(1):20-36

There are considerable, well-recognized difficulties involved in the investigation of very low permeability rocks by conventional measurements of water potentials and spatial distribution of hydrological parameters such as permeability and effective porosity. Therefore, most studies of predictive behaviour are based on models which, when unconstrained by data, are often worse than no model at all. Geochemistry and environmental isotope geochemistry are techniques well suited for hydrological investigations of potential sites of nuclear waste isolation and for constraining predictive models. Stable isotopes constitutive of the water molecule (²H and ¹⁸O) may give information on the origin of the water, especially ²H which is practically uninvolved in isotope exchange with rock-forming minerals. Variations in stable isotope contents can be related to palaeohydrological and palaeoclimatic conditions whereas ³H is indicative of recent recharge. The ¹³C content of dissolved carbon is related to its origin(s) and the ¹⁴C activity gives a time-scale. However, the initial carbon isotope contents can be modified by various diagenetic effects such as precipitation/dissolution of secondary calcite and oxidation of reduced carbon. The heavy isotope content of the Total Dissolved Inorganic Carbon (TDIC) cannot be interpreted without a detailed knowledge of the carbon chemistry and of the mineralogy and isotope contents of secondary carbonates. Species of Dissolved Organic Carbon (DOC), with high molecular weights (HMW) can generally be attributed to soil derived compounds. Their ¹⁴C content may be measured by AMS (Accelerator Mass Spectrometry) thus providing an estimate of the time elapsed since recharge took place. Chlorine-36 is an interesting potential tool for dating old ground waters because of its long half-life (301 kyr) and its hydrophilic behaviour. It can be also produced in situ in significant amount if the rocks are rich (some tens of ppm) in U and Th. In such cases, this time dependent build-up provides a more systematic radiochronometer of CI^- residence time in the rock than the decay of cosmic input ³⁶CI, provided no Cl^- is leached from the rock. The isotopic composition of aqueous sulphur compounds depends on their origin and on their diagenetic evolution. The redox reactions of SO^2-₄ reduction or of S^2- oxidation are marked by strong isotope effects especially when generated by bacteria. Sulphate reduction by organic matter is a potential source of dissolved inorganic carbon and may thus interfere with ¹⁴C age interpretations. After discussion of the possible age and origin of waters and solutes, some scenarios of evolution of local and regional palaeohydrological conditions are proposed. Examples are given with special emphasis on detailed results from the Fennoscanian shield (Stripa project), and from northern Switzerland.  相似文献   

A Comparative Study of Radiation Fog and Quasi-Fog Formation Processes During the ParisFog Field Experiment 2007     

Martial Haeffelin  Jean-Charles Dupont  Neda Boyouk  Darrel Baumgardner  Laurent Gomes  Greg Roberts  Thierry Elias 《Pure and Applied Geophysics》2013,170(12):2283-2303

Fog is an atmospheric phenomenon that has important environmental consequences related to visibility, air quality and climate change on local and regional scales. The formation of radiation fog results from a complex balance between surface radiative cooling, turbulent mixing in the surface layer, aerosol growth by deliquescence and activation of fog droplets. During the ParisFog field experiment, out of 16 events forecasted for radiation fog, activated fog materialized in seven events, while in five other events the visibility dropped to 1–2 km but haze particle size remained below the critical size of activation. To better understand the conditions that lead to or do not lead to sustained fog droplet activation, we performed a comparative study of dynamic, thermal, radiative and microphysical processes occurring between sunset and fog (or quasi-fog) onset. We selected two radiation fog events and two quasi-radiation fog events that occurred under similar large-scale conditions for this comparative study. We identified that aerosol growth by deliquescence and droplet activation actually occurred in both quasi-fog events, but only during <1 h. Based on ParisFog measurements, we found that the main factors limiting sustained activation of droplets at fog onset in the Paris metropolitan area are (1) lack of mixing in the surface layer (typically wind speed <0.5 ms^?1), (2) relative humidity exceeding 90 % throughout the residual layer, (3) low cooling rate in the surface layer (typically less than ?1 °C per hour on average) due to weak radiative cooling (0 to ?30 Wm^?2) and near zero sensible heat fluxes, and (4) a combination of the three factors listed above during the critical phase of droplet activation preventing the transfer of cooling from the surface to the liquid layer. In addition, we found some evidence of contrasted aerosol growth by deliquescence under high relative humidity conditions in the four events, possibly associated with the chemical nature of the aerosols, which could be another factor impacting droplet activation.  相似文献   

SPICES: spectro-polarimetric imaging and characterization of exoplanetary systems     

Anthony Boccaletti  Jean Schneider  Wes Traub  Pierre-Olivier Lagage  Daphne Stam  Raffaele Gratton  John Trauger  Kerri Cahoy  Frans Snik  Pierre Baudoz  Raphael Galicher  Jean-Michel Reess  Dimitri Mawet  Jean-Charles Augereau  Jenny Patience  Marc Kuchner  Mark Wyatt  Eric Pantin  Anne-Lise Maire  Christophe Vérinaud  Samuel Ronayette  Didier Dubreuil  Michiel Min  Michiel Rodenhuis  Dino Mesa  Russ Belikov  Olivier Guyon  Motohide Tamura  Naoshi Murakami  Ingrid Mary Beerer 《Experimental Astronomy》2012,34(2):355-384

SPICES (Spectro-Polarimetric Imaging and Characterization of Exoplanetary Systems) is a five-year M-class mission proposed to ESA Cosmic Vision. Its purpose is to image and characterize long-period extrasolar planets and circumstellar disks in the visible (450?C900 nm) at a spectral resolution of about 40 using both spectroscopy and polarimetry. By 2020/2022, present and near-term instruments will have found several tens of planets that SPICES will be able to observe and study in detail. Equipped with a 1.5 m telescope, SPICES can preferentially access exoplanets located at several AUs (0.5?C10?AU) from nearby stars (<25 pc) with masses ranging from a few Jupiter masses to Super Earths (??2 Earth radii, ??10 M_??) as well as circumstellar disks as faint as a few times the zodiacal light in the Solar System.  相似文献   

Geoid anomalies across Pacific fracture zones     

Jean-Charles Marty  Anny Cazenave  Bernard Lago 《Geophysical Journal International》1988,93(1):1-23

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