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11.
This article presents a methodology developed to evaluate the instability of submarine slopes that extend over a large area. Special attention was paid to (1) the complex geometry (bathymetry) and the expanse of the slope, (2) the heterogeneity of the sediment, and (3) the distribution of the pore pressure. The safety factor was considered as a spatially varying quantity. The General Formulation (GLE, Fredlund and Krahn 1977), which fully satisfies equilibrium conditions, was used for evaluating the stability of the marine slope. The submarine slope failure, which occurred on 16 October 1979 during the construction of the new Nice airport, was studied in order to test the developed model. Geotechnical parameters were taken from experimental tests carried out by IFREMER on 19 cores extracted at different depths (from 27 m to 1300 m) (Cochonat, Bourillet, and Savoye, 1993; Mulder et al., 1994). Many scenarios were proposed in order to explain the cause of the Nice slope failure (Habib, 1994). In this article, two of those scenarios were tested. Simulation results are presented and discussed.  相似文献   
12.
Pore water aliquots were taken with an in situ close interval sampler: the “Peeper”.We report here the pore water concentration profiles of TCO2, SO4, TH2S, Ca and the trace metals Mn, Cu, Pb, Cd and Cr from sediments of a relatively polluted area, the Villefranche Bay, on the French Riviera (close to Nice).We investigated the major ion concentrations in order to establish geochemical mass balances of organic matter oxidation. ΔTCO2/ΔSO4 was <−2.0, reflecting the precipitation of calcite as confirmed by the calcium profile. Reduction of sulfate led to increasing sulfide concentrations with depth.Trace metal interstitial water concentrations decreased from 63 to 5 nM, 18 to 4 nM and 6.6 to less than 2 nM for Cu, Pb and Cr, respectively. Cd showed a different pattern with top and deep values of 0.7 nM and a minimum of 0.27 nM.Thermodynamic calculations were performed which suggest the potential formation of mineral phases such as sulfides.  相似文献   
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Juvenile turbot (Scophthalmus maximus) were injected intraperitoneally with either corn oil or 5 mg/kg benzo[a]pyrene (BaP) dissolved in corn oil and sampled I and 3 days after injection. After 1 day, no elevation of 7-ethoxyresorufin O-deethylase (EROD) activity was observed, however bile metabolites (BaP-7,8 dihydrodiol representing 70% of the total metabolites) and a single hepatic DNA adduct spot (0.47 adducts/10(8) nucleotides) identified by 32P-postlabelling were formed. No BaP metabolites or DNA adducts were observed in either control or carrier control fish. Fish sampled after 3 days reported 5-fold higher (P < 0.05) levels of EROD activity, a shift in the bile metabolite profile towards BaP phenol formation (1OH and 30H BaP comprising up to 60% of total metabolites detected) and the formation of two adduct spots (0.86 and 0.71 adducts/10(8) nucleotides). These results show that BaP can be metabolised and form hydrophobic DNA adducts in turbot without EROD elevation. Following EROD elevation, a shift in the profile of both BaP metabolites and BaP metabolite-DNA interactions occurs indicative of other oxidative processes.  相似文献   
15.
The spatial distribution of volatiles in the Martian hydrolithosphere   总被引:1,自引:0,他引:1  
In order to quantify the spatial distribution of volatiles on Mars, 2600 fluidized ejecta craters have been systematically measured, classified and mapped over the planet Mars, using 1 : 2 M scale USGS photomosaics. The latitudinal distribution of ejecta craters reveals that flower ejecta deposits (Type 1), together with low mobility ejecta, are frequently observed in the equatorial region and on ridged plains. Rampart craters (Type 2), with high mobility ejecta, occur at mid latitudes and exhibit a spatial relationship with polygonal patterns and pseudocrater areas. The increase of ejecta mobility with latitude attests for a concentration of volatiles at high latitudes. Statistical analysis shows that cratered uplands and ridged plains contain less volatile material near the surface than the underlying materials. In Chryse Planitia and Utopia Planitia the statistical study and the spatial relationships between polygonally fractured patterns, pseudocraters and the great number of high mobility ejecta deposits suggest the presence of a water-rich alluvial deposit close to the surface near the mouth of Chryse and Elysium channels. This result explains, on a more quantitative basis, the idea that fractured patterns were preferentially developed in a volatile-rich sedimentary deposits. The behaviour of volatiles, at 41 S, 257 W near Reull Vallis, exhibits a strong anomaly, with the presence of an abnormally volatile rich layer close to the surface.  相似文献   
16.
After re-examination of data presented by Verma (1984), some misuse of solar parameteres published in Solar Geophysical Data is presented. Consequently some conclusions made by Verma (1984, 1986) on about the longitudinal distribution of cool solar surges based on these misuses are discussed.  相似文献   
17.
Among numerous methods for cation exchange capacity (CEC) determination for soils and sediments, the cobaltihexamine chloride method is frequently used due to its ability to measure CEC at soil pH. After exchange with Co(NH3)63+ ions, CEC is estimated via the measurement of the Co remaining in solution. The modified method proposed allows a more rapid determination of CEC based on the measurement of the absorbance at 472 nm of the cobaltihexamine chloride solution before and after exchange. This method has been applied to various soil's horizons from four sites, selected to cover a wide range of CEC and pH values. The model obtained allows one to calculate CEC from absorbance at 472 nm with 95% confidence intervals. As CEC is of relevant meaning in agronomical and environmental purposes, and more recently in ecotoxicological studies, this modified method can be proposed as a rapid test for CEC evaluation.  相似文献   
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The Muratdagi region is rich in antimony deposits having the following common characteristics: post Miocene age, location on the down-thrown blocks next to normal faults, in the vicinity of active or fossil thermal springs, and in contact with carbonate rocks. The isotopic composition of — 7. SMOW of the mineralizing fluid calculated from the measured ° 18O of quartz and the fluid inclusion microthermometry, is indicative of meteoric water origin. The ° 13C of the inclusion CO2 of — 19.1 to — 25.4 PDB is indicative of interaction with organic material-graphite. The ° 34S of stibnite — 3.6 to — 0.7 is, in view of the mineral assemblage, indicative of magmatic origin of the sulphur. A tightly confined set of structural, lithological, hydrological and geochemical features define a sequence of geochemical processes; formation of acid and reducing fluid, leaching and transport of antimony complexes and precipitation of stibnite within defined lithological units. The set of processes seems to have taken place within a space of 5000 m lateral and 1000 m vertical extension.  相似文献   
20.
Summary Early Proterozoic ultrapotassic dikes, lava flows, and pyroclastic rocks of the Christopher Island Formation (CIF) erupted throughout an area 600 × 300 km within the Churchill Province of the Canadian Shield at 1.84 Ga. The rocks range from mafic lamprophyres (mg # 60; SiO2 47–54%, mean K2O/Na2O > 4) with phenocrysts of phlogopite + diopside + apatite ± olivine ± magnetite, to phenocryst-poor felsic rocks and sanidine porphyries (SiO255–69%). All samples have high incompatible element contents and display large depletions of high field strength elements relative to K, Rb, Sr, Ba, and Th. The CIF has geochemical and petrographic characteristics of both minettes and lamproites, but overall most closely resembles young Mediterranean lamproites. Felsic rocks of the CIF were produced by crystal fractionation and crustal contamination of mafic ultrapotassic magma, and include both high-silica lamproites strongly enriched in Zr, U, and Th, and weakly potassic to sodic rocks of trachytic composition. Flows and feeder dikes have relatively homogeneous Nd, 1840 Ma (–6 to –11) but highly variable ES., 1840 Ma (–40 to + 100); samples classified as lamproites have higher average Sr. Dike samples have highly variable present-day Pb isotope compositions, ranging from moderately to strongly nonradiogenic. Geochemical and isotopic data are consistent with contributions from depleted Archean lithospheric mantle, and OIB-type convecting mantle, both metasomatized by subduction-related processes during the Early Proterozoic. The lithospheric mantle probably contained Archean enriched domains as well. Proterozoic enrichment may have accompanied shallow underplating of subducted oceanic lithosphere beneath the Churchill Province during amalgamation of the Laurentian supercontinent. There are strong analogies in isotopic composition, and interpreted source region history, between the CIF and lamproites and minettes of the Wyoming Province and western Greenland, which suggest the existence of a Laurentian ultrapotassic superprovince.
Geochemie und Entstehung der Proterozoischen ultrapotassischen Gesteine der Churchill Provinz, Kanada
Zusammenfassung Altproterozoische, ultrapotassische Gänge, Lavaströme und pyroklastische Gesteine der Christopher Island Formation (CIF), eruptierten in einem Gebiet von 600 × 300 km in der Churchill Provinz des Kanadischen Schildes vor 1.84 Ga. Die Zusammensetzung dieser Gesteine variiert von mafischen Lamprophyren (mg > 60; SiO2 = 47–54%, durchschnittliches K2O/Na2O > 4) mit Phänokristallent von Phlogopit + Diopsid + Apatit + Olivin + Magnetit, bis zu phänokristallarmen felsischen Gesteinen und Sanidinporphyren (SiO2 = 55–69%). Alle Proben zeigen hohe Gehalte an inkompatiblen Elementen und zeigen beträchtliche Verarmung an high field strength Elementen relativ zu K, Rb, Sr, Ba und Th. Die CIF hat geochemische und petrographische Eigenschaften sowohl von Minetten wie von Lamproiten, aber im allgemeinen ähnelt sie am stärksten jungen mediterranen Lamproiten. Felsische Gesteine der CIF wurden durch Fraktionierung und Krustenkontamination aus mafischen ultrapotassischen Magmen gebildet. Letztere umfassen sowohl siliziumreiche Lamproite, die deutlich an Zr, U und Th angereichert sind und schwach potassische bis sodische Gesteine von trachytischer Zusammensetzung. Lavenergüsse und zufuhrgänge zeigent ein relativ homogenes Nd, 1840 Ma (–6 bis –11) aber ein sehr variables Sr, 1840 Ma (-40 bis + 100); Proben die als Lamproite klassifiziert wurden, zeigent höhere durchschnittliche Sr-Werte. Proben von Gängen haben sehr variable Bleiisotopen-Zusammensetzungen, die von mäßig bis stark nichtradiogen variieren. Geochemische und Isotopendaten weisen auf Beiträge aus verarmtem archaischen lithosphärischen Mantel und aus konvektierendem OIB-Typ Mantel hin, die beide während des Alproterozoikums durch Subduktions-Vorgänge metasomatisiert wurden. Der lithosphärische Mantel enthielt wahrscheinlich auch angereicherte archaische Domänen. Proterozoische Anreicherungsvorgänge dürften seichtes Underplating subduzierter ozeanischer Lithosphäre unter der Churchill Provinz während der Amalgamation des laurentischen Superkontinentes begleitet haben. Es gibt starke Analogien in der Isotopenzusammensetzung und in der interpretierten Geschichte der Ursprungsregion, zwischen den CIF und Lamproiten und Minetten der Wyoming Provinz, und des westlichen Grönland. Diese weisen auf die Existenz einer laurentischen ultrapotassischen Superprovinz hin.


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