Première datation UPb des orthogneiss œillés de la zone axiale de la Montagne noire (Sud du Massif central) : nouveaux témoins du magmatisme ordovicien dans la chaı̂ne Varisque     

Françoise Roger  Jean-Patrick Respaut  Maurice Brunel  Philippe Matte  Jean-Louis Paquette 《Comptes Rendus Geoscience》2004,336(1):19-28

We present new U–Pb results on felsic Augen orthogneisses from the Axial Zone of the Montagne Noire (French Massif Central). The data indicate Ordovician ages, 456±3 and 450±6 Ma for two samples collected at ‘Pont-de-Larn’ and ‘Gorges d'Héric’, respectively. These ages are interpreted as the igneous emplacement age of the granitic protolith. To cite this article: F. Roger et al., C. R. Geoscience 336 (2004).  相似文献   

Experimental study of arsenic speciation in vapor phase to 500°C: implications for As transport and fractionation in low-density crustal fluids and volcanic gases     

Gleb S PokrovskiDenis Testemale  Jean-Louis HazemannAndrew Y.u Bychkov  Galina V Golikova 《Geochimica et cosmochimica acta》2002,66(19):3453-3480

The stoichiometry and stability of arsenic gaseous complexes were determined in the system As-H₂O ± NaCl ± HCl ± H₂S at temperatures up to 500°C and pressures up to 600 bar, from both measurements of As^(III) and As^(V) vapor-liquid and vapor-solid partitioning, and X-ray absorption fine structure (XAFS) spectroscopic study of As^(III)-bearing aqueous fluids. Vapor-aqueous solution partitioning for As^(III) was measured from 250 to 450°C at the saturated vapor pressure of the system (P_sat) with a special titanium reactor that allows in situ sampling of the vapor phase. The values of partition coefficients for arsenious acid (H₃AsO₃) between an aqueous solution (pure H₂O) and its saturated vapor (K = mAs_vapor /mAs_liquid) were found to be independent of As^(III) solution concentrations (up to ∼1 to 2 mol As/kg) and equal to 0.012 ± 0.003, 0.063 ± 0.023, and 0.145 ± 0.020 at 250, 300, and 350°C, respectively. These results are interpreted by the formation, in the vapor phase, of As(OH)₃(gas), similar to the aqueous As hydroxide complex dominant in the liquid phase. Arsenic chloride or sulfide gaseous complexes were found to be negligible in the presence of HCl or H₂S (up to ∼0.5 mol/kg of vapor). XAFS spectroscopic measurements carried out on As^(III)-H₂O (±NaCl) solutions up to 500°C demonstrate that the As(OH)₃ complex dominates As speciation both in dense H₂O-NaCl fluids and low-density supercritical vapor. Vapor-liquid partition coefficients for As^(III) measured in the H₂O-NaCl system up to 450°C are consistent with the As speciation derived from these spectroscopic measurements and can be described by a simple relationship as a function of the vapor-to-liquid density ratio and temperature. Arsenic^(III) partitioning between vapor and As-concentrated solutions (>2 mol As/kg) or As₂O₃ solid is consistent with the formation, in the vapor phase, of both As₄O₆ and As(OH)₃. Arsenic^(V) (arsenic acid, H₃AsO₄) vapor-liquid partitioning at 350°C for dilute aqueous solution was interpreted by the formation of AsO(OH)₃ in the vapor phase.The results obtained were combined with the corresponding properties for the aqueous As(III) hydroxide species to generate As(OH)₃(gas) thermodynamic parameters. Equilibrium calculations carried out by using these data indicate that As(OH)₃(gas) is by far the most dominant As complex in both volcanic gases and boiling hydrothermal systems. This species is likely to be responsible for the preferential partition of arsenic into the vapor phase as observed in fluid inclusions from high-temperature (400 to 700°C) Au-Cu (-Sn, -W) magmatic-hydrothermal ore deposits. The results of this study imply that hydrolysis and hydration could be also important for other metals and metalloids in the H₂O-vapor phase. These processes should be taken into account to accurately model element fractionation and chemical equilibria during magma degassing and fluid boiling.  相似文献   

High Precision Hf-W Isotopic Measurements in Meteoritic Material Using Negative Thermal Ionisation Mass Spectrometry (NTIMS)   总被引：1，自引：0，他引：1  

Ghylaine Quitté  Jean-Louis Birck  Françoise Capmas  Claude J. Allègre 《Geostandards and Geoanalytical Research》2002,26(2):149-160

This paper presents a two-stage anion-exchange procedure for tungsten extraction, an improved mass spectrometric procedure for tungsten analysis and a simplified chemical separation and TIMS procedure for the determination of Hf concentrations. The chemical separation of tungsten is based on its complexing properties with HF and H₂O₂. The blank level for a sample size of 300 mg is about 80 pg for tungsten. The procedure is designed for the high sensitivity of negative thermal ionisation mass spectrometry (NTIMS) provided by the use of Mg oxide as an emitter on Ir filaments. Tungsten can be readily measured with a high precision in various meteoritical material and especially in small W-poor silicate fractions. Samples containing as little as a few ng g^-1 tungsten can be analysed reliably with this method.  相似文献   

Geodynamic significance of the Raspas Metamorphic Complex (SW Ecuador): geochemical and isotopic constraints     

Delphine Bosch  Piercarlo Gabriele  Henriette Lapierre  Jean-Louis Malfere  Etienne Jaillard   《Tectonophysics》2002,345(1-4)

The Raspas Metamorphic Complex of southwestern Ecuador is regarded as the southernmost remnant of oceanic and continental terranes accreted in the latest Jurassic–Early Cretaceous. It consists of variably metamorphosed rock types. (1) Mafic and ultramafic rocks metamorphosed under high-pressure (HP) conditions (eclogite facies) show oceanic plateau affinities with flat REE chondrite-normalized patterns, Nd_{150 Ma} ranging from +4.6 to 9.8 and initial Pb isotopic ratios intermediate between MORB and OIB. (2) Sedimentary rocks metamorphosed under eclogitic conditions exhibit LREE enriched patterns, strong negative Eu anomalies, Rb, Nb, U, Th, Pb enrichments, low Nd_{150 Ma} values (from −6.4 to −9.5), and high initial ⁸⁷Sr/⁸⁶Sr and ^206,207,208Pb/²⁰⁴Pb isotopic ratios suggesting they were originally sediments derived from the erosion of an old continental crust. (3) Epidote-bearing amphibolites show N-MORB affinities with LREE depleted patterns, LILE, Zr, Hf and Th depletion, high Nd_{150 Ma} (>+10) and low initial Pb isotopic ratios.The present-day well defined internal structure of the Raspas Metamorphic Complex seems to be inconsistent with the formerly proposed interpretation of a “tectonic mélange”. The association of oceanic plateau rocks and continent-derived sediments both metamorphosed in HP conditions suggests that the thin edge of the oceanic plateau first entered the subduction zone and dragged sediments downward of the accretionary wedge along the Wadatti–Benioff zone. Subsequently, when its thickest part arrived into the subduction zone, the oceanic plateau jammed the subduction processes, due to its high buoyancy.In Ecuador and Colombia, the latest Jurassic–Early Cretaceous suture involves HP oceanic plateau rocks and N-MORB rocks metamorphosed under lower grades, suggesting a composite or polyphase nature for the latest Jurassic–Early Cretaceous accretionary event.  相似文献   

Simulation des changements climatiques au cours du XXI^e siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone     

Jean-François Royer  Daniel Cariolle  Fabrice Chauvin  Michel Déqué  Hervé Douville  Rong-Ming Hu  Serge Planton  Annie Rascol  Jean-Louis Ricard  David Salas Y Melia  Florence Sevault  Pascal Simon  Samuel Somot  Sophie Tyteca  Laurent Terray  Sophie Valcke 《Comptes Rendus Geoscience》2002,334(3):147-154

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.  相似文献   

Hyperspectral core logging for fire reconstruction studies     

Antonin Van Exem  Maxime Debret  Yoann Copard  Boris Vannière  Pierre Sabatier  Stephane Marcotte  Benoit Laignel  Jean-Louis Reyss  Marc Desmet 《Journal of Paleolimnology》2018,59(3):297-308

Lacustrine sediments contain a wide range of proxies that enable paleoenvironmental reconstructions. For instance, charcoal can be used to document past fire regime changes. In order to analyse high-temporal- and spatial-resolution records, however, it is necessary to develop fast, low-cost and high-stratigraphic-resolution methods. We developed a new paleo-fire proxy by studying a lacustrine core from the Esterel Massif, SE France, an area affected by two recent fire events, in AD 1987 and 2003. For this purpose, we searched for charcoal deposited and preserved in the lake sediments by combining a number of complementary methods, including: classic macrocharcoal tallying, scanning spectrophotometry, scanning hyperspectral imaging and high pressure liquid chromatography analyses. Macrocharcoal quantification is efficient, but time-consuming, and only provides intermediate-resolution data (cm scale). Spectrophotometry, used classically to quantify colour, is very fast, provides high-resolution data (4 mm) and is non-destructive (core preservation). Hyperspectral data have the same advantages as spectrophotometry, but offer higher spatial resolution (64-µm pixel size) and higher spectral resolution (6 nm) for core logging applications. The main result of this research is based on hyperspectral analysis at very high stratigraphic resolution using the I-band index. This index usually measures reflectance values at [660, 670 nm] corresponding to the trough in red reflectance produced by Chlorophyll a and its diagenetic products. This [660, 670 nm] reflectance trough, however, is also affected by the presence of altered organic matter and decreases with altered organic matter such as charcoal particles. Charcoal effect on the reflectance of Chlorophyll a and its diagenetic products is identified on first derivative spectra by a characteristic pattern around 675 nm, which is also in agreement with the Chlorophyll a concentrations measured by high-pressure liquid chromatography and charcoal particles. The I-band index is hence suitable for detecting burned organic matter, by quantifying the dilution of the chlorophyll signal by the charcoal signal. Thus, this adaptation of the I-band index can be applied in fire reconstruction studies.  相似文献   

Solar Magnetic Activity and Total Irradiance Since the Maunder Minimum     

K. F. Tapping  D. Boteler  P. Charbonneau  A. Crouch  A. Manson  H. Paquette 《Solar physics》2007,246(2):309-326

We develop a model for estimating solar total irradiance since 1600 AD using the sunspot number record as input, since this is the only intrinsic record of solar activity extending back far enough in time. Sunspot number is strongly correlated, albeit nonlinearly with the 10.7-cm radio flux (F _10.7), which forms a continuous record back to 1947. This enables the nonlinear relationship to be estimated with usable accuracy and shows that relationship to be consistent over multiple solar activity cycles. From the sunspot number record we estimate F _10.7 values back to 1600 AD. F _10.7 is linearly correlated with the total amount of magnetic flux in active regions, and we use it as input to a simple cascade model for the other magnetic flux components. The irradiance record is estimated by using these magnetic flux components plus a very rudimentary model for the modulation of energy flow to the photosphere by the subphotospheric magnetic flux reservoir feeding the photospheric magnetic structures. Including a Monte Carlo analysis of the consequences of measurement and fitting errors, the model indicates the mean irradiance during the Maunder Minimum was about 1 ± 0.4 W m⁻² lower than the mean irradiance over the last solar activity cycle.  相似文献   

U–Pb zircon dating of post-obduction volcanic-arc granitoids and a granulite-facies xenolith from New Caledonia. Inference on Southwest Pacific geodynamic models     

Jean-Louis Paquette  Dominique Cluzel 《International Journal of Earth Sciences》2007,96(4):613-622

In New Caledonia, the occurrence of one of the World’s largest and best-exposed subduction/obduction complex is a key point for the understanding of the geodynamic evolution of the whole Southwest Pacific region. Within the ophiolite, pre-and post-obduction granitoids intrude the ultramafic allochthon and provide new time constraints for the understanding of obduction processes. At 27.4 Ma, a new East-dipping subduction generated the active margin magmatism along the western coast of the island (Saint-Louis massif). At 24.3 Ma, the eastward shift of the magma activity and slightly different geochemical features (Koum-Borindi massif) was either related to the older slab break-off; or alternatively, due to the eastward migration of the mantle wedge following the collision of the eastern margin of the Low Howe rise. Finally, the occurrence of a granulite-facies xenolith in the Koum-Borindi massif with comparable 24.5 Ma U–Pb zircon age and isotopic features (initial ε_Nd = 5.1) suggests that these evolved magmas were generated within the lithospheric mantle beneath a continental crust of normal thickness. Geochronological evidence for continuous convergence during the Oligocene infers an East-dipping Eocene-Oligocene subduction/obduction system to have existed in the Southwest Pacific from the d’Entrecasteaux zone to the North Island of New Zealand.  相似文献   

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join     

Giancarlo Della Ventura  Günther J. Redhammer  Gianluca Iezzi  Frank C. Hawthorne  Arnaud Papin  Jean-Louis Robert 《Physics and Chemistry of Minerals》2005,32(2):103-113

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.  相似文献   

Ion microprobe and ID-TIMS U–Pb dating on zircon grains from leg 173 amphibolites: evidence for Permian magmatism on the West Iberian margin     

V. Gardien  J. L. Paquette 《地学学报》2004,16(4):226-231

In this paper, we report evidence for Permian magmatism at the ocean–continent transition zone of the West Iberian margin, by dating magmatic intrusion of amphibolite precursors drilled at site 1067 during ODP leg 173. The P–T conditions recorded by the amphibolites indicate that the latter was emplaced at the bottom of a 25‐km‐thick crust. Subhedral to rounded and colourless zircon grains were obtained from samples at the base of the cored section. ID‐TIMS dating on these zircon grains yielded a lower intercept age of 247 ± 5 Ma and a poorly defined upper intercept around 2 Ga. In situ dating of single zircons by ion‐microprobe (CAMECA IMS 1270) provided an age of 246 ± 5 Ma. This Permian age is interpreted as a minimum estimate for the emplacement of the gabbroic melts at the base of the Hercynian crust during the early stage of rifting between the Iberia–Newfoundland conjugate margins.  相似文献