Geodynamic significance of the Raspas Metamorphic Complex (SW Ecuador): geochemical and isotopic constraints     

Delphine Bosch  Piercarlo Gabriele  Henriette Lapierre  Jean-Louis Malfere  Etienne Jaillard   《Tectonophysics》2002,345(1-4)

The Raspas Metamorphic Complex of southwestern Ecuador is regarded as the southernmost remnant of oceanic and continental terranes accreted in the latest Jurassic–Early Cretaceous. It consists of variably metamorphosed rock types. (1) Mafic and ultramafic rocks metamorphosed under high-pressure (HP) conditions (eclogite facies) show oceanic plateau affinities with flat REE chondrite-normalized patterns, Nd_{150 Ma} ranging from +4.6 to 9.8 and initial Pb isotopic ratios intermediate between MORB and OIB. (2) Sedimentary rocks metamorphosed under eclogitic conditions exhibit LREE enriched patterns, strong negative Eu anomalies, Rb, Nb, U, Th, Pb enrichments, low Nd_{150 Ma} values (from −6.4 to −9.5), and high initial ⁸⁷Sr/⁸⁶Sr and ^206,207,208Pb/²⁰⁴Pb isotopic ratios suggesting they were originally sediments derived from the erosion of an old continental crust. (3) Epidote-bearing amphibolites show N-MORB affinities with LREE depleted patterns, LILE, Zr, Hf and Th depletion, high Nd_{150 Ma} (>+10) and low initial Pb isotopic ratios.The present-day well defined internal structure of the Raspas Metamorphic Complex seems to be inconsistent with the formerly proposed interpretation of a “tectonic mélange”. The association of oceanic plateau rocks and continent-derived sediments both metamorphosed in HP conditions suggests that the thin edge of the oceanic plateau first entered the subduction zone and dragged sediments downward of the accretionary wedge along the Wadatti–Benioff zone. Subsequently, when its thickest part arrived into the subduction zone, the oceanic plateau jammed the subduction processes, due to its high buoyancy.In Ecuador and Colombia, the latest Jurassic–Early Cretaceous suture involves HP oceanic plateau rocks and N-MORB rocks metamorphosed under lower grades, suggesting a composite or polyphase nature for the latest Jurassic–Early Cretaceous accretionary event.  相似文献   

Simulation des changements climatiques au cours du XXI^e siècle incluant l'ozone stratosphériqueSimulation of climate changes during the 21st century including stratospheric ozone     

Jean-François Royer  Daniel Cariolle  Fabrice Chauvin  Michel Déqué  Hervé Douville  Rong-Ming Hu  Serge Planton  Annie Rascol  Jean-Louis Ricard  David Salas Y Melia  Florence Sevault  Pascal Simon  Samuel Somot  Sophie Tyteca  Laurent Terray  Sophie Valcke 《Comptes Rendus Geoscience》2002,334(3):147-154

Two climate simulations of 150 years, performed with a coupled ocean/sea-ice/atmosphere model including stratospheric ozone, respectively with and without heterogeneous chemistry, simulate the tropospheric warming associated with an increase of the greenhouse effect of carbon dioxide and other trace gases since 1950 and their impact on sea–ice extent, as well as the stratospheric cooling and its impact on ozone concentration. The scenario with heterogeneous chemistry reproduces the formation of the ozone hole over the South Pole from the 1970s and its deepening until the present time, and shows that the ozone hole should progressively fill during the coming decades. To cite this article: J.-F. Royer et al., C. R. Geoscience 334 (2002) 147–154.  相似文献   

Hyperspectral core logging for fire reconstruction studies     

Antonin Van Exem  Maxime Debret  Yoann Copard  Boris Vannière  Pierre Sabatier  Stephane Marcotte  Benoit Laignel  Jean-Louis Reyss  Marc Desmet 《Journal of Paleolimnology》2018,59(3):297-308

Lacustrine sediments contain a wide range of proxies that enable paleoenvironmental reconstructions. For instance, charcoal can be used to document past fire regime changes. In order to analyse high-temporal- and spatial-resolution records, however, it is necessary to develop fast, low-cost and high-stratigraphic-resolution methods. We developed a new paleo-fire proxy by studying a lacustrine core from the Esterel Massif, SE France, an area affected by two recent fire events, in AD 1987 and 2003. For this purpose, we searched for charcoal deposited and preserved in the lake sediments by combining a number of complementary methods, including: classic macrocharcoal tallying, scanning spectrophotometry, scanning hyperspectral imaging and high pressure liquid chromatography analyses. Macrocharcoal quantification is efficient, but time-consuming, and only provides intermediate-resolution data (cm scale). Spectrophotometry, used classically to quantify colour, is very fast, provides high-resolution data (4 mm) and is non-destructive (core preservation). Hyperspectral data have the same advantages as spectrophotometry, but offer higher spatial resolution (64-µm pixel size) and higher spectral resolution (6 nm) for core logging applications. The main result of this research is based on hyperspectral analysis at very high stratigraphic resolution using the I-band index. This index usually measures reflectance values at [660, 670 nm] corresponding to the trough in red reflectance produced by Chlorophyll a and its diagenetic products. This [660, 670 nm] reflectance trough, however, is also affected by the presence of altered organic matter and decreases with altered organic matter such as charcoal particles. Charcoal effect on the reflectance of Chlorophyll a and its diagenetic products is identified on first derivative spectra by a characteristic pattern around 675 nm, which is also in agreement with the Chlorophyll a concentrations measured by high-pressure liquid chromatography and charcoal particles. The I-band index is hence suitable for detecting burned organic matter, by quantifying the dilution of the chlorophyll signal by the charcoal signal. Thus, this adaptation of the I-band index can be applied in fire reconstruction studies.  相似文献   

U–Pb zircon dating of post-obduction volcanic-arc granitoids and a granulite-facies xenolith from New Caledonia. Inference on Southwest Pacific geodynamic models     

Jean-Louis Paquette  Dominique Cluzel 《International Journal of Earth Sciences》2007,96(4):613-622

In New Caledonia, the occurrence of one of the World’s largest and best-exposed subduction/obduction complex is a key point for the understanding of the geodynamic evolution of the whole Southwest Pacific region. Within the ophiolite, pre-and post-obduction granitoids intrude the ultramafic allochthon and provide new time constraints for the understanding of obduction processes. At 27.4 Ma, a new East-dipping subduction generated the active margin magmatism along the western coast of the island (Saint-Louis massif). At 24.3 Ma, the eastward shift of the magma activity and slightly different geochemical features (Koum-Borindi massif) was either related to the older slab break-off; or alternatively, due to the eastward migration of the mantle wedge following the collision of the eastern margin of the Low Howe rise. Finally, the occurrence of a granulite-facies xenolith in the Koum-Borindi massif with comparable 24.5 Ma U–Pb zircon age and isotopic features (initial ε_Nd = 5.1) suggests that these evolved magmas were generated within the lithospheric mantle beneath a continental crust of normal thickness. Geochronological evidence for continuous convergence during the Oligocene infers an East-dipping Eocene-Oligocene subduction/obduction system to have existed in the Southwest Pacific from the d’Entrecasteaux zone to the North Island of New Zealand.  相似文献   

A Mössbauer and FTIR study of synthetic amphiboles along the magnesioriebeckite – ferri-clinoholmquistite join     

Giancarlo Della Ventura  Günther J. Redhammer  Gianluca Iezzi  Frank C. Hawthorne  Arnaud Papin  Jean-Louis Robert 《Physics and Chemistry of Minerals》2005,32(2):103-113

A series of amphiboles along the magnesioriebeckite—Na₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)₂– ferri-clinoholmquistite—Li₂Mg₃Fe³⁺ ₂Si₈O₂₂(OH)2 - join, defined by the ^BLi^B Na_–1 exchange vector, were hydrothermally synthesized at 700°C, 0.4 GPa, NNO + 1 redox conditions. Powder XRD and SEM-EDAX showed a very high (> 90%) amphibole yield for all samples. X-ray patterns were indexed in the C2/m space group; refined cell-parameters show a linear decrease of a and as a function of chemistry. IR spectra in the OH-stretching region show four main and rather sharp bands; these are assigned to Mg and Fe²⁺ at M(1,3), and indicate that the obtained amphiboles depart from the nominal octahedral composition (^M1,3Mg₃). The IR spectra also show that there is an increasing filling-up of the A-site for increasing Na in the system (increasing solid-solution toward, arfvedsonite). Mössbauer spectra show four well-defined quadrupole doublets which are assigned to Fe³⁺ at M2 and to Fe²⁺ at M1, M3 and M4, respectively. The Fe³⁺/Fe²⁺ content derived from fitted peak areas show variable Fe³⁺ concentration along the series. Mössbauer spectra also show a distinct alteration of ⁵⁷Fe hyperfine parameters with changing Na–Li at M4. The most evident variation is observed for the quadrupole splitting of Fe³⁺ at M2, which increases by 50% from ferri-clinoholmquistite to magnesio-riebeckite; this suggest that the M2 octahedron in ferri-clinoholmquistite is much closer to the ideal geometry than the M2 octahedron in magnesio-riebeckite. Mössbauer spectra show also a well-defined increase in the Fe²⁺ quadrupole splitting of the M1 and M3 octahedra, which is attributed to the Na–Li distribution at the B-sites.  相似文献   

Pre-eruptive migration of earthquakes at the Piton de la Fournaise volcano (Réunion Island)     

Jean Battaglia  Valérie Ferrazzini  Thomas Staudacher  Keiiti Aki  Jean-Louis Cheminée 《Geophysical Journal International》2005,161(2):549-558

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The Multiscale TROPIcal CatchmentS critical zone observatory M-TROPICS dataset III: Hydro-geochemical monitoring of the Mule Hole catchment,south India     

Jean Riotte  Laurent Ruiz  Stéphane Audry  Benjamin Baud  Jean-Pierre Bedimo Bedimo  Laurie Boithias  Jean-Jacques Braun  Bernard Dupré  Jean-Louis Duprey  Mikael Faucheux  Christelle Lagane  Jean-Christophe Marechal  Hemanth Moger  Mandalagiri Subbarayappa Mohan Kumar  Harshad Parate  Olivier Ribolzi  Emma Rochelle-Newall  Buvaneshwari Sriramulu  Murari Varma  Muddu Sekhar 《水文研究》2021,35(5):e14196

Despite the importance of tropical ecosystems for climate regulation, biodiversity, water and nutrient cycles, only a few Critical Zone Observatories (CZOs) are located in the tropics. Among these, most are in humid climates, while very few data exist for semi-arid and sub-humid climates, due to the difficulty of estimating hydro-geochemical balances in catchments with ephemeral streams. We contribute to fill this gap by presenting a meteorological and hydro-geochemical dataset acquired at the Mule Hole catchment (4.1 km²), a pristine dry deciduous forest located in a biosphere reserve in south India. The dataset consists of time series of variables related to (i) meteorology, including rainfall, air temperature, relative humidity, wind speed and direction, and global radiation, (ii) hydrology, including water level and discharge at the catchment outlet, (iii) hydrogeology, including manual (monthly) and/or automated (from 15 min to hourly) groundwater levels in nine piezometers and (iv) geochemistry, including suspended sediment content in the stream and chemical composition of rainfall (event based), groundwater (monthly sampling) and stream water (storm events, 15 min to hourly frequency with an automatic sampler). The time series extend from 2003 to 2019. Measurement errors are minimized by frequent calibration of sensors and quality checks, both in the field and in the laboratory. Despite these precautions, several data gaps exist, due to occasional access restriction to the site and instrument destruction by wildlife. Results show that large seasonal and interannual variations of climatic conditions were reflected in the large variations of stream flow and groundwater recharge, as well as in water chemical composition. Notably, they reveal a long-term evolution of groundwater storage, suggesting hydrogeological cycles on a decadal scale. This dataset, alone or in combination with other data, has already allowed to better understand water and element cycling in tropical dry forests, and the role of forest diversity on biogeochemical cycles. As tropical ecosystems are underrepresented by Critical Zone Observatories, we expect this data note to be valuable for the global scientific community.  相似文献   

Report on the 4th International Meeting of the IUGS Lower Cretaceous Ammonite Working Group, the “Kilian Group” (Dijon, France, 30th August 2010)     

Stéphane Reboulet  Peter F. Rawson  Josep A. Moreno-Bedmar  Maria B. Aguirre-Urreta  Ricardo Barragán  Yuri Bogomolov  Miguel Company  Celestina González-Arreola  Vyara Idakieva Stoyanova  Alexander Lukeneder  Bertrand Matrion  Vasily Mitta  Hasina Randrianaly  Zdenek Vaši?ek  Evgenij J. Baraboshkin  Didier Bert  Stéphane Bersac  Tamara N. Bogdanova  Luc G. Bulot  Jean-Louis Latil  Irina A. Mikhailova  Pierre Ropolo  Ottilia Szives 《Cretaceous Research》2011,32(6):786-793

The 4th Kilian Group meeting (Dijon, France, 30th August 2010) focused on the Aptian and Albian Stages. For the Aptian, a two-fold division of the stage was adopted for the Mediterranean area with a boundary between the Dufrenoyia furcata and Epicheloniceras martini Zones. The main changes to the zonal scheme concern the Lower Aptian with: the introduction of a Deshayesites luppovi Subzone in the upper part of the Deshayesites oglanlensis Zone; the replacement of Deshayesites weissi by Deshayesites forbesi as new index-species of the second interval zone; the introduction of a Roloboceras hambrovi Subzone in the upper part of the D. forbesi Zone; and the subdivision of the D. furcata Zone into the D. furcata and Dufrenoyia dufrenoyi Subzones. For the Albian, the upper part of the Douvilleiceras mammillatum Zone (Lower Albian) is now characterized by a Lyelliceras pseudolyelli Subzone. The main amendments concern the Upper Albian. The base of this substage is defined by the base of the Dipoloceras cristatum Zone. Above it, the Upper Albian zonal scheme comprises in stratigraphic order the Mortoniceras pricei, Mortoniceras inflatum, Mortoniceras fallax, Mortoniceras rostratum, Mortoniceras perinflatum and Arrhaphoceras briacensis Zones.  相似文献   

The Pliensbachian ammonites of the Algarve Basin (Portugal) and their palaeobiogeographical significance for the “Iberia-Newfoundland” conjugate margins     

Jean-Louis Dommergues  Christian Meister  Rogério B. Rocha 《Swiss Journal of Geoscience》2011,104(1):81-96

A review of the Pliensbachian ammonite faunas of the Algarve Basin is given covering their taxonomy, stratigraphy and palaeobiogeography (palaeobiodiversity). This review is based on both an extensive revision of the previously collected and/or published material and on new finds precisely located within the ammonite succession. This new material allows us to clarify the variations within the most abundant species—a new species Reynesocoeloceras elmii nov. sp. is described—and to improve our understanding (palaeobiodiversity, palaeobiogeography and bio- or chrono-stratigraphy) of the two single known Pliensbachian fossiliferous assemblages in the Algarve Basin. The first of these assemblages is relatively diverse and is ascribed to the upper half of the Luridum Subchronozone. The second assemblage is less diversified and probably partly condensed. It is broadly attributed to the upper half of the Stokesi Subchronozone. Despite the newly collected ammonites and extensive prospecting, our knowledge of the Pliensbachian ammonite faunas of the Algarve remains fragmentary. Therefore, it is difficult to propose an incontrovertible extensive palaeobiogeographical interpretation for these faunas, but it seems that Tethyan (Mediterranean) affinities were of major importance whereas there were probably no NW European influences via the Lusitanian Basin.  相似文献   

LMDZ5B: the atmospheric component of the IPSL climate model with revisited parameterizations for clouds and convection     

Frédéric Hourdin  Jean-Yves Grandpeix  Catherine Rio  Sandrine Bony  Arnaud Jam  Frédérique Cheruy  Nicolas Rochetin  Laurent Fairhead  Abderrahmane Idelkadi  Ionela Musat  Jean-Louis Dufresne  Alain Lahellec  Marie-Pierre Lefebvre  Romain Roehrig 《Climate Dynamics》2013,40(9-10):2193-2222

Based on a decade of research on cloud processes, a new version of the LMDZ atmospheric general circulation model has been developed that corresponds to a complete recasting of the parameterization of turbulence, convection and clouds. This LMDZ5B version includes a mass-flux representation of the thermal plumes or rolls of the convective boundary layer, coupled to a bi-Gaussian statistical cloud scheme, as well as a parameterization of the cold pools generated below cumulonimbus by re-evaporation of convective precipitation. The triggering and closure of deep convection are now controlled by lifting processes in the sub-cloud layer. An available lifting energy and lifting power are provided both by the thermal plumes and by the spread of cold pools. The individual parameterizations were carefully validated against the results of explicit high resolution simulations. Here we present the work done to go from those new concepts and developments to a full 3D atmospheric model, used in particular for climate change projections with the IPSL-CM5B coupled model. Based on a series of sensitivity experiments, we document the differences with the previous LMDZ5A version distinguishing the role of parameterization changes from that of model tuning. Improvements found previously in single-column simulations of case studies are confirmed in the 3D model: (1) the convective boundary layer and cumulus clouds are better represented and (2) the diurnal cycle of convective rainfall over continents is delayed by several hours, solving a longstanding problem in climate modeling. The variability of tropical rainfall is also larger in LMDZ5B at intraseasonal time-scales. Significant biases of the LMDZ5A model however remain, or are even sometimes amplified. The paper emphasizes the importance of parameterization improvements and model tuning in the frame of climate change studies as well as the new paradigm that represents the improvement of 3D climate models under the control of single-column case studies simulations.  相似文献