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11.
12.
A single large volume water sample taken at the mouth of the Upper Rhone River on Lake Geneva was processed directly in parallel through two continuous flow centrifuges, a Westphalia and an Alfa-Laval. Sediment was recovered from the Westphalia, and separately from the bowl and brass core of the Alfa-Laval. The three sediment samples were analyzed for particle size and the following elements: Zn, Cu, Mn, Cr, P, Co, B, V, Be, Sr, Na, Pb, Ni, Ba, Fe, Ca, and Mg. Results indicate that the particle size recovery of both machines is similar when sediment from the brass core and bowl of the Alfa-Laval are combined, and that the recovery for all elements other than Cu, V, B, and Pb are the same when the particle size differences are taken into account. Sediment from the Alfa-Laval brass core is clearly contaminated by Cu, B and is also elevated in V and Pb but not to a significant extent. The sediment recovered from the bowl of the Alfa-Laval is contaminated only with Cu, with a 10 ppm increase over the 52 ppm recovered in the Westphalia sediment. Operating procedures involve the discarding of the brass core sediment and the mixing of the Alfa-Laval bowl sediment with that from the Westphalia. The consequent increase in Cu is estimated at less than 5 ppm or within the confidence level of the analysis. These procedures are recommended to all operators of non modified Alfa-Laval units. 相似文献
13.
We have measured apatite solubility in calcic carbonatitic liquids and determined apatite/melt partition coefficients for a series of trace elements, including the rare earth elements (REE), high field strength elements (HFSE), Rb, Sr, U-Th-Pb. Experiments were performed between 4 and 6 GPa, from 1200 to 1380 °C, using the multianvil apparatus. Trace element concentrations were determined by laser ablation ICP-MS and electron microprobe. In addition, a specific protocol was designed to measure carbon concentration in the apatites, using the electron microprobe. Two starting apatite samples were used in order to test for the effect of apatite chemistry on partitioning behavior.Apatite solubility is lower in calcitic melts by a factor 3-5 compared to dolomitic melts (3-5.5 vs. 10-18 wt.% P2O5 in melt). We interpret this difference in terms of solubility product in the liquid and propose an empirical model for apatite saturation that takes into account melt calcium content. We conclude that calcitic melts that may form by melting of carbonated eclogites could be saturated with residual apatite, contrary to dolomitic melts formed in carbonated peridotites.Compatibility behavior of the REE depends on apatite silica content: REE are compatible in apatites containing 3.5-5 wt.% SiO2, with values between 1.5 and 4, whereas REE are incompatible in apatites containing 0.2 wt.% SiO2. HFSE, U, Th, and Y are compatible in silica-rich apatite, with while . Strontium is always retained in the melt, with of the order of 0.5. Lead appears to be incompatible in apatite, although this finding is weakened by almost complete Pb loss to sample container. High silica concentration favors REE incorporation in apatite by allowing for charged balanced coupled substitution. Sulfur and carbonate may also favor REE incorporation in apatite. Our results allow to reconcile previously published experimental determinations of REE partitioning. We use our experimentally determined partition coefficients to investigate the impact of residual apatite during partial melting of recycled carbonated material (eclogite + sediments) and discuss how the chemical characteristics of the produced liquids can be affected by residual apatite. 相似文献
14.
Martin R. Bates Rebecca M. Briant Jean-Luc Schwenninger 《Proceedings of the Geologists' Association. Geologists' Association》2010,121(4):369-392
The unique Middle and Late Pleistocene sedimentary record preserved along the Sussex/Hampshire Coastal Corridor between Romsey and Brighton contains a wealth of deposits including highstand marine sediments associated with a variety of different aged beaches, fluvial sediments associated with rivers crossing the coastal plain and cold stage deposits accumulating above the marine and fluvial sediments. Although quarrying activity has been extensive across much of the area it has been undertaken in flooded workings due to the high level of the watertable. Consequently little is known in detail about the sequences except where they outcrop on the foreshore around the coast. This paper examines recent work from the lower coastal plain using a multi-disciplinary approach these deposits to elucidate the age of the sequences and their associated environments of deposition.OSL dates from two of the beaches, the Aldingbourne and Brighton/Norton Beaches, place both within MIS 7. Although these OSL dates cannot differentiate between sub-stages within MIS 7, coupling these results with inferences from local geography, lithology and contained microfossils it is clear that the beaches belong to two different phases within MIS 7. These two beaches are clearly divided by a major phase of erosion and downcutting associated with a fall in sea-level. Fluvial sediments from Solent Terrace 2 and Arun Terrace 4 also date within MIS 7 and are tentatively ascribed to the downcutting event between the beaches. Together this information allows us to propose, for the first time, a robust independently dated framework for the lower parts of the coastal plain integrating for the first time the marine and terrestrial record. 相似文献
15.
Véronique Lavastre Corinne Le Gal La Salle Jean-Luc Michelot Sophie Giannesini Lucilla Benedetti Joël Lancelot Bernard Lavielle Marc Massault Bertrand Thomas Eric Gilabert Didier Bourlès Norbert Clauer Pierre Agrinier 《Applied Geochemistry》2010
Groundwaters from the Tithonian/Kimmeridgian, Oxfordian and Upper Dogger aquifers, within the eastern part of the Paris basin (France), were characterised using 3H, 14C and 36Cl, and noble gases tracers, to evaluate their residence times and determine their recharge period. This information is an important prerequisite to evaluating the confinement properties of the Callovo-Oxfordian clay formation sandwiched between the Oxfordian aquifer and the Dogger aquifer, currently being investigated by the French nuclear waste management agency (Andra) for radioactive waste disposal. Data presented in this paper are used to test 4 hypotheses. 相似文献
16.
17.
Basement lithostratigraphy of the Adula nappe: implications for Palaeozoic evolution and Alpine kinematics 总被引:1,自引:0,他引:1
Mattia Cavargna-Sani Jean-Luc Epard François Bussy Alex Ulianov 《International Journal of Earth Sciences》2014,103(1):61-82
The Adula nappe belongs to the Lower Penninic domain of the Central Swiss Alps. It consists mostly of pre-Triassic basement lithologies occurring as strongly folded and sheared gneisses of various types with mafic boudins. We propose a new lithostratigraphy for the northern Adula nappe basement that is supported by detailed field investigations, U–Pb zircon geochronology, and whole-rock geochemistry. The following units have been identified: Cambrian clastic metasediments with abundant carbonate lenses and minor bimodal magmatism (Salahorn Formation); Ordovician metapelites associated with amphibolite boudins with abundant eclogite relicts representing oceanic metabasalts (Trescolmen Formation); Ordovician peraluminous metagranites of calc-alkaline affinity ascribed to subduction-related magmatism (Garenstock Augengneiss); Ordovician metamorphic volcanic–sedimentary deposits (Heinisch Stafel Formation); Early Permian post-collisional granites recording only Alpine orogenic events (Zervreila orthogneiss). All basement lithologies except the Permian granites record a Variscan + Alpine polyorogenic metamorphic history. They document a complex Paleozoic geotectonic evolution consistent with the broader picture given by the pre-Mesozoic basement framework in the Alps. The internal consistency of the Adula basement lithologies and the stratigraphic coherence of the overlying Triassic sediments suggest that most tectonic contacts within the Adula nappe are pre-Alpine in age. Consequently, mélange models for the Tertiary emplacement of the Adula nappe are not consistent and must be rejected. The present-day structural complexity of the Adula nappe is the result of the intense Alpine ductile deformation of a pre-structured entity. 相似文献
18.
Martin R. Bates Carl Champness Andrew Haggart Richard I. Macphail Simon A. Parfitt Jean-Luc Schwenninger 《Proceedings of the Geologists' Association. Geologists' Association》2014
This paper discusses the results of the investigation of Pleistocene sediments at the Royal Oak Portal (ROP) site on the new Crossrail scheme near Paddington Station, London. The site was sampled and recorded in May 2011 by archaeologists from Oxford Archaeology commissioned by Crossrail Ltd. The investigation revealed a sedimentary sequence associated with cool climate waterlain deposition towards the edge of the River Westbourne floodplain. During excavation an assemblage of around 100 identifiable large mammal bones was recovered, dating to the Late Pleistocene. The major concentration of bones, from bison and reindeer, was located and excavated from a shallow sequence of sediments. Analysis of the bones indicates that they represent a natural death assemblage, scavenged and subsequently disarticulated, transported by water, exposed and further dispersed and broken by trampling. The site is of regional and national importance because the assemblage derives from a well-constrained geological context, with associated dating evidence suggesting accumulation during the later parts of Marine Isotope Stage (MIS) 5 and continuing within MIS 4. The site is also of significance because it is one of a growing number of recently discovered sites away from the main fluvial archive for the British Middle and Upper Pleistocene. These sites have the potential to add significantly to our understanding of parts of the Pleistocene record that remain difficult to document through the investigation of the more active systems associated with major rivers such as the Thames, Severn or Trent. 相似文献
19.
Aude Lemonsu Raphaëlle Kounkou-Arnaud Julien Desplat Jean-Luc Salagnac Valéry Masson 《Climatic change》2013,116(3-4):679-692
The evolution of the Parisian urban climate under a changing climate is analyzed from long-term offline numerical integrations including a specific urban parameterization. This system is forced by meteorological conditions based on present-climate reanalyses (1970–2007), and climate projections (2071–2099) provided by global climate model simulations following two emission scenarios (A1B and A2). This study aims at quantifying the impact of climate change on air temperature within the city and in the surroundings. A systematic increase of 2-meter air temperature is found. In average according to the two scenarios, it reaches +?2.0/2.4°C in winter and +?3.5/5.0°C in summer for the minimum and maximum daily temperatures, respectively. During summer, the warming trend is more pronounced in the surrounding countryside than in Paris and suburbs due to the soil dryness. As a result, a substantial decrease of the strong urban heat islands is noted at nighttime, and numerous events with negative urban heat islands appear at daytime. Finally, a 30% decrease of the heating degree days is quantified in winter between present and future climates. Inversely, the summertime cooling degree days significantly increase in future climate whereas they are negligible in present climate. However, in terms of accumulated degree days, the increase of the demand in cooling remains smaller than the decrease of the demand in heating. 相似文献
20.
Vincent?GuenardEmail author Philippe?Drobinski Jean-Luc?Caccia Bernard?Campistron Bruno?Bench 《Boundary-Layer Meteorology》2005,115(2):263-288
We investigate the mesoscale dynamics of the mistral through the wind profiler observations of the MAP (autumn 1999) and ESCOMPTE (summer 2001) field campaigns. We show that the mistral wind field can dramatically change on a time scale less than 3 hours. Transitions from a deep to a shallow mistral are often observed at any season when the lower layers are stable. The variability, mainly attributed in summer to the mistral/land–sea breeze interactions on a 10-km scale, is highlighted by observations from the wind profiler network set up during ESCOMPTE. The interpretations of the dynamical mistral structure are performed through comparisons with existing basic theories. The linear theory of R. B. Smith [Advances in Geophysics, Vol. 31, 1989, Academic Press, 1–41] and the shallow water theory [Schär, C. and Smith, R. B.: 1993a, J. Atmos. Sci. 50, 1373–1400] give some complementary explanations for the deep-to-shallow transition especially for the MAP mistral event. The wave breaking process induces a low-level jet (LLJ) downstream of the Alps that degenerates into a mountain wake, which in turn provokes the cessation of the mistral downstream of the Alps. Both theories indicate that the flow splits around the Alps and results in a persistent LLJ at the exit of the Rhône valley. The LLJ is strengthened by the channelling effect of the Rhône valley that is more efficient for north-easterly than northerly upstream winds despite the north–south valley axis. Summer moderate and weak mistral episodes are influenced by land–sea breezes and convection over land that induce a very complex interaction that cannot be accurately described by the previous theories. 相似文献