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51.
Comparative stable isotope geochemistry of Ni, Cu, Zn, and Fe in chondrites and iron meteorites 总被引:2,自引:0,他引:2
Frédéric Moynier Janne Blichert-Toft Jean-Marc Luck 《Geochimica et cosmochimica acta》2007,71(17):4365-4379
High-precision Ni isotopic variations are reported for the metal phase of equilibrated and unequilibrated ordinary chondrites, carbonaceous chondrites, iron meteorites, mesosiderites, and pallasites. We also report new Zn and Cu isotopic data for some of these samples and combine them with literature Fe, Cu, and Zn isotope data to constrain the fractionation history of metals during nebular (vapor/solid) and planetary (metal/sulfide/silicate) phase changes.The observed variations of the 62Ni/58Ni, 61Ni/58Ni, and 60Ni/58Ni ratios vary linearly with mass difference and define isotope fractionation lines in common with terrestrial samples. This implies that Ni was derived from a single homogeneous reservoir. While no 60Ni anomaly is detected within the analytical uncertainties, Ni isotopic fractionation up to 0.45‰ per mass-difference unit is observed. The isotope compositions of Ni and Zn in chondrites are positively correlated. We suggest that, in ordinary chondrites, exchange between solid phases, in particular metal and silicates, and vapor followed by mineral sorting during accretion are the main processes controlling these isotopic variations. The positive correlation between Ni and Zn isotope compositions contrasts with a negative correlation between Ni (and Zn) and Cu isotope compositions, which, when taken together, do not favor a simple kinetic interpretation. The observed transition element similarities between different groups of chondrites and iron meteorites are consistent with the genetic relationships inferred from oxygen isotopes (IIIA/pallasites and IVA/L chondrites). Copper is an exception, which we suggest may be related to separate processing of sulfides either in the vapor or during core formation. 相似文献
52.
Franck Poitrasson Eric Oelkers Jean-Marc Montel 《Geochimica et cosmochimica acta》2004,68(10):2207-2221
The solubility of synthetic NdPO4 monazite end-member has been determined experimentally from 21 to 300°C in aqueous solutions at pH = 2, and at 21°C and pH = 2 for GdPO4. Measurements were performed in batch reactors, with regular solution sampling for pH measurement, rare earths and phosphorous analysis by inductively coupled plasma mass spectrometry (ICP-MS) coupled with a desolvation system. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were employed to check that no reprecipitation of secondary phases occurred and that the mineral surfaces remained those of a monazite. Coupled with speciation calculations, measured solution compositions permitted the determination of NdPO4 and GdPO4 solubility products which are in general agreement with previous experimental determination on rhabdophane at 25°C, but showing that monazite is more than two orders of magnitude less soluble than inferred on the basis of previous thermodynamic estimates. The temperature evolution from 21 to 300°C of the equilibrium constant (K) of the NdPO4 monazite end-member dissolution reaction given by:
53.
Jean-Marc Ecoutin Emilie Richard Monique Simier Jean-Jacques Albaret 《Estuarine, Coastal and Shelf Science》2005,64(4):623-635
The fish assemblages of the Ebrié lagoon (Ivory Coast) were sampled by experimental fishing over the entire lagoon using a purse seine net. The sampling was conducted in the two main hydroclimatic seasons for this ecosystem, i.e. in the dry season (March–April) and in the wet season (August–September). The results obtained showed a fish assemblage organized around a consistently occurring group of twenty species. When analysed in terms of ecological categories, the seasonal influence led to a cycle in the assemblages from freshwater to marine around this permanent species pool, with a seasonal renewal of the assemblage. At the scale of the lagoon, there were variations in the composition of the assemblages that clearly distinguished the western part from the eastern one. The limit was situated at the Vridi canal, a wide artificial channel permanently connecting the lagoon to the sea. To the west, the assemblage was characterised by a strong spatial uniformity and low seasonal variability. To the east, the assemblage formed two different entities; one assemblage with pronounced freshwater affinities occurring in a side arm and the other assemblage with great seasonal variability under the alternating influence of seawater in the dry season and freshwater in the wet season. This part of the lagoon functioned somewhat like a typical estuary. 相似文献
54.
The nature of synmetamorphic fluids and their flow is examined in the granulitic lower crust of Madagascar, part of a Precambrian crustal-scale network of vertical ductile shear zones. Based on three independent data sets - field and satellite mapping, C-, O- and H-isotope geochemistry and gravimetry - this crust is divided into three zones: outside of shear zones, minor shear zones (<140 km long and 7 km wide), and major shear zones (>350 km long and 20–35 km wide). The major shear zones are rooted in and are controlled by the mantle. They tapped mantle-derived CO2 with carbon fluxes of the same order of magnitude as oceanic ridge degassing. One major shear zone shows abundant phlogopite-diopside-apatite-calcite mineralizations (a well known paragenesis in mantle metasomatism) due to mantle-fluid infiltration and their interaction with the crust. Carbonatitic magmas possibly collected in the major shear zones at the base of the crust and may be the source for CO2 upwellings as well as other metasomatic agents. Small-scale minor shear zones were controlled by crustal deformation processes and focused crustally-derived H2O-rich fluids. Pervasive fluid circulation was restricted to the vicinity (< 100 m) of synmetamorphic plutons. Fluid absent conditions dominate everywhere else. Mantle-CO2 flushing is not required for granulite genesis but is a consequence of the high associated heat flux. Fluid transfer at the mantle/crust interface is controlled by the tectonic setting and the associated geothermal gradient. The C- and O- isotope systematics of metamorphosed carbonates sampled on a regional scale within a known petrological and structural framework are shown to be of great help to identify the distribution of major fluid-rock interaction processes associated with plate tectonics. 相似文献
55.
Der Sarkissian Rita Abdallah Chadi Zaninetti Jean-Marc Najem Sara 《Natural Hazards》2020,103(1):121-137
Natural Hazards - Estimating the resilience of a road network (one of the essential critical infrastructures in times of crisis) to natural hazards is crucial in achieving the goals of disaster... 相似文献
56.
Clément Yonta-Ngoune Charles Nkoumbou Pierre Barbey Nicole Le Breton Jean-Marc Montel Frédéric Villieras 《Comptes Rendus Geoscience》2010,342(2):108-115
The talcschists of the Boumnyebel area (southern Cameroon) form ≤ 30 m thick discontinuous layers within a Pan-African nappe unit (Yaoundé group), which includes, at the base, muscovite + biotite ± garnet micaschists associated with amphibolites and pyroxenites, and, at the top, muscovite + biotite + garnet + kyanite micaschists locally associated with marble and amphibolites. The metamorphic peak (∼650 °C/9.5 kbar; ca. 620 Ma) postdates nappe emplacement. Isograds are in normal position, micaschists passing downwards to migmatites in the northwestern part of the area studied. The rock types in the lower part of this nappe suggest active margin environments with detrital input from a nearby continental crust (arc or back-arc context). 相似文献
57.
Vincent Grgoire Anne Ndlec Patrick Moni Jean-Marc Montel Jrme Ganne Bruno Ralison 《Tectonophysics》2009,477(3-4):197
The basement of central Madagascar displays two contrasted structural patterns. The first one (D1) is characterized by north-striking foliations that are gently dipping to the west and carry W- to WSW-plunging lineations, whereas the second one (D2) is characterized by steeper foliations that are striking to the NNE and lineations that are either subhorizontal or gently plunging to the SSW. The younger pattern is related to late-Panafrican tectonics along the major Angavo shear zone that is about 1000 km in length and 40 km in width with apparently little offset. Deformation in the Angavo zone induced interference folding on both sides. The D2 event is characterized by low pressures (ca 400 MPa) and high temperatures (up to 790 °C) responsible for prograde granulite facies conditions, that resulted from heat transfer due to magma and fluid advection in the Angavo shear zone. The D2 event is pinned at 550 ± 11 Ma by a new monazite age from a reoriented Andringitrean granite near Ankaramena. A new suite of amphibole and biotite Ar–Ar geochronological data enables to retrace the thermochronogical evolution inside and outside the Angavo shear zone. Combined with new structural results from the western interference zone, these ages yield a better understanding of the late-Panafrican history of central Madagascar. No diachronism is observed along the strike of the Angavo shear zone. Conversely, amphibole and especially biotite ages decrease from West to East, i.e. towards the shear zone. These new ages range from 511 to 469 Ma. A 1-D conductive model constrains the thermal effect in relation with the Angavo shear zone to be restricted to a lateral distance of ca 60 km (in map view) for a maximum heating duration of 20 Myr. This is in agreement with the Ar–Ar data and with the width of the observed interference zone. Following this episode of deformation and heat transfer, the estimated cooling rates of the Angavo shear zone range from to 15 to 6 °C/Myr, respectively before and after 515 Ma. A post-collision intracontinental setting is suggested for the Angavo shear zone, which is regarded as a remote effect of the Kuunga Orogeny between India and Antarctica. 相似文献
58.
Earth and space-based NEO survey simulations: prospects for achieving the spaceguard goal 总被引:1,自引:0,他引:1
We have used an improved model of the orbit and absolute magnitude distribution of Near Earth Objects (NEOs) to simulate the performance of asteroid surveys. Our results support general conclusions of previous studies using preliminary Near Earth Asteroid (NEA) orbit and magnitude distributions and suggest that meeting the Spaceguard Goal of 90% completion for Near Earth Objects (NEOs) greater than 1 km diameter by 2008 is impossible given contemporary surveying capabilities.The NEO model was derived from NEO detections by the Spacewatch Project. For this paper we developed a simulator for the Catalina Sky Survey (CSS) for which we had a complete pointing history and NEO detection efficiency. The good match between the output of the simulator and the actual CSS performance gives confidence that both the NEO model and simulator are correct. Then, in order to determine if existing surveys can meet the Spaceguard Goal, we developed a simulator to mimic the LINEAR survey, for which detailed performance characteristics were unavailable. This simulator serendipitously provided an estimate for the currently undiscovered population of NEOs upon which we base all our estimates of time to 90% completion. We also developed a set of idealized NEO surveys in order to constrain the best possible survey performance in contrast to more realistic systems.A 100% efficient, all-sky, every night survey, subject only to the constraints of detection above a specified air mass and when the Sun is 18° below the horizon provides a benchmark from which to examine the effect of imposing more restrictions and the efficacy of some simple survey strategies. Such a survey must have a limiting V-magnitude of 20.1 ± 0.2 to meet the Spaceguard Goal.More realistic surveys, limited by latitude, the galaxy, minimum rates of NEO motion, etc., require fainter limiting magnitudes to reach the same completion. Our most realistic simulations, which have been normalized to the performance of the LINEAR detector system’s operation in the period 1999-2000, indicate that it would take them another 33 ± 5 years to reach 90% completeness for the larger asteroids (?1 km diameter). They would need to immediately increase the limiting magnitude to about 24 in order to meet the Spaceguard Goal.The simulations suggest that there may be little need for distributing survey telescopes in longitude and latitude as long as there is sufficient sky coverage from a telescope or network of telescopes which may be geographically close. An idealized space-based survey, especially from a satellite orbit much interior to Earth, would offer an advantage over their terrestrial counterparts. We do not consider a cost-benefit analysis for any of the simulations but suspect that a local-area network of telescopes capable of covering much of the sky in a month to V ∼ 21.5 may be administratively, financially, and scientifically the best compromise for reaching 90% completion of NEOs larger than 1 km diameter. 相似文献
59.
Julien Jouanno Julio Sheinbaum Bernard Barnier Jean-Marc Molines 《Ocean Modelling》2009,26(3-4):226-239
The processes which drive the production and the growth of the strong mesoscale eddy field in the Caribbean Sea are examined using a general circulation model. Diagnostics of the simulations suggest that:(1) The mean currents in the Caribbean Sea are intrinsically unstable. The nature of the instability and its strength vary spatially due to strong differences of current structure among basins.(2) The greatest and most energetic eddies of the Caribbean Sea originate in the Venezuela Basin by mixed barotropic-baroclinic instability of an intense jet, formed with waters mostly from the surface return flow of the Meridional Overturning Circulation and the North Equatorial Current which converge and accelerate through the Grenada Passage. The vertical shear of this inflow is enhanced by an eastward undercurrent, which flows along the south American Coast between 100 and 250 m depth. The shallow eddies (less than 200 m depth) formed in the vicinity of the Grenada Passage get rapidly deeper (down to 1000 m depth) and stronger by their interaction with the deep interior flow of the Subtropical Gyre, which enters through passages north of St. Lucia. These main eastern Caribbean inflows merge and form the southern Caribbean Current, whose baroclinic instability is responsible for the westward growth and strengthening of these eddies from the Venezuela to the Colombia Basin.(3) Eddies of lesser strength are produced in other regions of the Caribbean Sea. Their generation and growth is also linked with instability of the local currents. First, cyclones are formed in the cyclonic shear of the northern Caribbean Current, but appear to be rapidly dissipated or absorbed by the large anticyclones coming from the southern Caribbean. Second, eddies in the Cayman Sea, which impact the Yucatan region, are locally produced and enhanced by barotropic instability of the deep Cayman Current.(4) The role of the North Brazil Current (NBC) rings is mostly to act as a finite perturbation for the instability of the mean flow. Their presence near the Lesser Antilles is ubiquitous and they appear to be linked with most of the Caribbean eddies. There are some evidences that the frequency at which they form near the Grenada Passage is influenced by the frequency at which the NBC rings impinge the Lesser Antilles. But large Caribbean eddies also form without a close influence of any ring, and comparison between simulations shows that mean eddy kinetic energy and eddy population in the Caribbean Sea are not substantially different in absence or presence of NBC rings: their presence is not a necessary condition for the generation and growth of the Caribbean eddies. 相似文献
60.