Characterisation of organic matter and microbial communities in contrasting arsenic-rich Holocene and arsenic-poor Pleistocene aquifers,Red River Delta,Vietnam     

Wafa M. Al Lawati  Athanasios Rizoulis  Elisabeth Eiche  Christopher Boothman  David A. Polya  Jonathan R. Lloyd  Michael Berg  Patricio Vasquez-Aguilar  Bart E. van Dongen 《Applied Geochemistry》2012

High concentrations of geogenic As in the groundwaters of south and SE Asia, which are used as drinking waters, are causing severe health impacts to the exposed human populations. It is widely accepted that As mobilisation from sediments into these shallow reducing groundwaters requires active metal-reducing microbes and electron donors such as organic matter (OM). Although OM in such Holocene aquifers has been characterised, there is a dearth of data on Pleistocene aquifers from the same areas. Reported here are preliminary studies of OM and microbial communities present in two aquifers, one of Pleistocene and one of Holocene age, with contrasting concentrations of As (viz. Pleistocene: low As <10 μg/L; Holocene: high As up to 600 μg/L) from Van Phuc village in the Red River Delta, Vietnam. Results revealed OM inputs from multiple sources, including potential contributions from naturally occurring petroleum seeping into the shallow aquifer sediments from deeper thermally mature source rocks. Although concentrations vary, no noticeable systematic differences in biomarker distribution patterns within the OM were observed between the two sites. Microbial analyses did not show a presence of microbial communities previously associated with As mobilisation. All clone libraries were dominated by α-, β-, and γ-Proteobacteria not known to be able to reduce Fe(III) or sorbed As(V). Furthermore, representatives of the Fe(III)-reducing genus Geobacter could only be detected at very low abundance by PCR, using highly selective 16S rRNA gene primers, supporting the hypothesis that metal reduction is not a dominant in situ process in these sediments. No correlation between As concentration in groundwater and OM composition nor microbial community in the host sediments was found. This suggests that either (i) As is not being significantly mobilised in situ in these sediments, instead As appears to be mobilised elsewhere and transported by groundwater flow to the sites or (ii) sorption/desorption processes, as implicated by geochemical data from the cores, play a critical role in controlling As concentrations at these sites.  相似文献   

Implications of spatial reservoir uncertainty for CO2 sequestration in the east Snake River Plain, Idaho (USA)   总被引：1，自引：1，他引：0  

Ryan M. Pollyea  Jerry P. Fairley 《Hydrogeology Journal》2012,20(4):689-699

Basalt-hosted hydrogeologic systems have been proposed for geologic CO₂ sequestration based on laboratory research suggesting rapid mineralization rates. However, despite this theoretical appeal, little is known about the impacts of basalt fracture heterogeneity on CO₂ migration at commercial scales. Evaluating the suitability of basalt reservoirs is complicated by incomplete knowledge of in-situ fracture distributions at depths required for CO₂ sequestration. In this work, a numerical experiment is used to investigate the effects of spatial reservoir uncertainty for geologic CO₂ sequestration in the east Snake River Plain, Idaho (USA). Two criteria are investigated: (1) formation injectivity and (2) confinement potential. Several theoretical tools are invoked to develop a field-based approach for geostatistical reservoir characterization and their implementation is illustrated. Geologic CO₂ sequestration is simulated for 10?years of constant-rate injection at ~680,000 tons per year and modeled by Monte Carlo simulation such that model variability is a function of spatial reservoir heterogeneity. Results suggest that the spatial distribution of heterogeneous permeability structures is a controlling influence on formation injectivity. Analysis of confinement potential is less conclusive; however, in the absence of confining sedimentary interbeds within the basalt pile, rapid mineralization may be necessary to reduce the risk of escape.  相似文献   

Weathering of phlogopite in simulated bioleaching solutions     

Tariq M. Bhatti  Jerry M. Bigham  Antti Vuorinen  Olli H. Tuovinen 《International Journal of Mineral Processing》2011,98(1-2):30-34

The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH₄⁺, K⁺, or Na⁺) in the culture solution. NH₄⁺ and K⁺ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na⁺ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.  相似文献   

Volatile loss from melt inclusions in pyroclasts of differing sizes     

Alexander S. Lloyd  Terry Plank  Philipp Ruprecht  Erik H. Hauri  William Rose 《Contributions to Mineralogy and Petrology》2013,165(1):129-153

We have investigated the loss of H₂O from olivine-hosted melt inclusions (MIs) by designing an experiment using tephra samples that cooled at different rates owing to their different sizes: ash, lapilli, and bomb samples that were deposited on the same day (10/17/74) of the sub-Plinian eruption of Volcán de Fuego in Guatemala. Ion microprobe, laser ablation-ICPMS, and electron probe analyses show that MIs from ash and lapilli record the highest H₂O contents, up to 4.4 wt%. On the other hand, MIs from bombs indicate up to 30 % lower H₂O contents (loss of ~1 wt% H₂O) and 10 % post-entrapment crystallization of olivine. This evidence is consistent with the longer cooling time available for a bomb-sized clast, up to 10 min for a 3–4-cm radius bomb, assuming conductive cooling and the fastest H diffusivities measured in olivine (D~10^?9 to 10^?10 m²/s). On the other hand, several lines of evidence point to some water loss prior to eruption, during magma ascent and degassing in the conduit. Thus, results point to both slower post-eruptive cooling and slower magma ascent affecting MIs from bombs, leading to H₂O loss over the timescale of minutes to hours. The important implication of this study is that a significant portion of the published data on H₂O concentrations in olivine-hosted MIs may reflect unrecognized H₂O loss via diffusion. This work highlights the importance of reporting clast and MI sizes in order to assess diffusive effects and the potential benefit of using water loss as a chronometer of magma ascent.  相似文献   

Response and recovery of the Eel River, California, and its tributaries to floods in 1955, 1964, and 1997     

Jan Sloan  Jerry R. Miller  Nicholas Lancaster 《Geomorphology》2001,36(3-4)

Northwestern California is prone to regional, high magnitude winter rainstorms, which repeatedly produce catastrophic floods in the basins of the northern Coast Ranges. Major floods on the Eel River in 1955 and 1964 resulted in substantial geomorphic changes to the channel, adjacent terraces, and tributaries. This study evaluated the changes and the effects of a moderate flood in 1997 through field observations and examination of aerial photographs that spanned from 1954 to 1996. The purpose was to document the nature and magnitude of geomorphic responses to these three floods and assess the rates and controls on the recovery of the Eel River and its tributaries. Channel widening from extensive bank erosion was the dominant geomorphic change along the lower Eel River during major floods. As a result of the 1964 flood, the largest amount of widening was 195 m and represented an 80% change in channel width. Channel narrowing characterized the periods after the 1955 and 1964 floods. More than 30 years after the 1964 flood, however, the river had not returned to pre-flood width, which suggests that channel recovery required decades to complete. A long recovery time is unusual given that the Eel River is located in an area with a “superhumid” climate and has an exceptionally high sediment yield. This long recovery time may reflect highly seasonal precipitation and runoff, which are concentrated in 3–5 months each winter. In contrast to the main stem of the Eel River, the dominant effects of floods on the tributaries of the Eel River were rapid aggradation of channel bed and valley floor followed by immediate downcutting. Dendrogeomorphic data, aerial photographs, and field observations indicate that thick wedges of gravel, derived largely from hillslope failures in upper reaches of the tributaries, are deposited at and immediately upstream of the mouths of tributaries as the stage of the Eel River exceeded that of the tributaries during major floods. In the waning stages of the flood, the tributaries cut through the gravel at a rate equal to the lowering of the Eel and generated unpaired terraces and nickpoints. The complete process of deposition and incision can occur within a few days of peak discharge. Although reworking of some sediment on the valley floor may continue for years after large floods, channel morphology in the tributaries appears to be a product of infrequent, high magnitude events. The morphology of the tributary channel also appears to be greatly influenced by the frequency and magnitude of mass wasting in headwater areas of small basins.  相似文献   

Glacial isostatic adjustment in 3-D earth models: Implications for the analysis of tide gauge records along the U.S. east coast     

Jonathan E. Davis  Konstantin Latychev  Jerry X. Mitrovica  Roblyn Kendall  Mark E. Tamisiea 《Journal of Geodynamics》2008,46(3-5):90

Tide gauge records of recent sea-level change along the U.S. east coast have received significant attention within the literature of glacial isostatic adjustment (GIA). Geographic trends in these tide gauge rates are not reduced by a GIA correction based on a commonly adopted radial viscosity profile (characterized, in particular, by a lower mantle viscosity 1−2×10²¹ Pa s), and this has led to speculation that the residual trends reflect contributions from neotectonics or oceanographic processes. While the trends can be significantly reduced by adopting an Earth model with a stiffer lower mantle, such a model appears to be incompatible with independent constraints from post-glacial decay times in Hudson Bay. We use a finite-element model of the GIA process to investigate whether 3-D viscosity variations superimposed onto the “common” radial viscosity profile may provide a route to reconciling the east coast sea-level trends. We find that the specific 3-D structure we impose has little impact on the geographic trends in the GIA-corrected rates. However, we do find that the imposed lateral variations in lower mantle viscosity introduce a nearly uniform upward shift of 0.5 mm/yr in GIA-induced sea-level rates along the U.S. east coast. Thus, inferences of regional (U.S. east coast) sea-level rise due to modern melting of ice reservoirs, based on tide gauge rates corrected using 1-D GIA models, may be significantly biased by this simplifying assumption.  相似文献   

Utility of the 2-D Multi-Electrode Resistivity Imaging Technique in Groundwater Exploration in the Voltaian Sedimentary Basin, Northern Ghana   总被引：2，自引：0，他引：2  

Anthony Ewusi  Jerry S. Kuma  Hans J. Voigt 《Natural Resources Research》2009,18(4):267-275

Guinea worm and other water borne diseases associated with untreated surface water use have necessitated that communities are supplied with groundwater in the Northern Region of Ghana. The Electrical Resistivity Survey (ERS) method is one of the common geophysical survey techniques used for borehole siting in Ghana. Various groundwater exploration programs have utilized it by employing the four electrode system. However, the ERS has not been able to locate potential borehole sites successfully in the Voltaian Sedimentary Basin (VSB) in the Northern Region of Ghana although it has been successful in other geological formations. Unsatisfactory results obtained from the employment of the ERS system in the VSB therefore necessitated an experiment with the 2-D Multi-Electrode Resistivity Imaging (2-D MERI) technique. Field results show that the 2-D MERI is a robust and efficient technique: an improvement on the four electrode ERS system in terms of amount and quality of data obtained. The 2-D MERI interpretations were confirmed with a much improved borehole drilling success rate of 60% compared to 38% obtained using the ERS within the mudstone and shale formations. The 2-D MERI also indicated that very low resistivity layers in the VSB may not necessarily be good targets for borehole drilling and the generally held notion that groundwater cannot be found at depths more than 25 m is no longer tenable.  相似文献   

Turbulence Statistics Above And Within Two Amazon Rain Forest Canopies   总被引：1，自引：1，他引：0  

B. Kruijt  Y. Malhi  J. Lloyd  A. D. Norbre  A. C. Miranda  M. G. P. Pereira  A. Culf  J. Grace 《Boundary-Layer Meteorology》2000,94(2):297-331

The turbulence structure in two Amazon rain forestswas characterised for a range of above-canopystability conditions, and the results compared withprevious studies in other forest canopies and recenttheory for the generation of turbulent eddies justabove forest canopies. Three-dimensional wind speedand temperature fluctuation data were collectedsimultaneously at up to five levels inside and abovetwo canopies of 30–40 m tall forests, during threeseparate periods. We analysed hourly statistics, jointprobability distributions, length scales, spatialcorrelations and coherence, as well as power spectraof vertical and horizontal wind speed.The daytime results show a sharp attenuation ofturbulence in the top third of the canopies, resultingin very little movement, and almost Gaussianprobability distributions of wind speeds, in the lowercanopy. This contrasts with strongly skewed andkurtotic distributions in the upper canopy. At night,attenuation was even stronger and skewness vanishedeven in the upper canopy. Power spectral peaks in thelower canopy are shifted to lower frequencies relativeto the upper canopy, and spatial correlations andcoherences were low throughout the canopy. Integrallength scales of vertical wind speed at the top of thecanopy were small, about 0.15 h compared to avalue of 0.28 h expected from the shear lengthscale at the canopy top, based on the hypothesis that theupper canopy air behaves as a plane mixing layer. Allthis suggests that, although exchange is not totallyinhibited, tropical rain forest canopies differ from other forests in that rapid, coherentdownward sweeps do not penetrate into the lowercanopy, and that length scales are suppressed. This isassociated with a persistent inversion of stability inthat region compared to above-canopy conditions. Theinversion is likely to be maintained by strong heatabsorption in the leaves concentrated near thecanopy top, with the generally weak turbulence beingunable to destroy the temperature gradients over thelarge canopy depth.  相似文献   

Surface loading of a viscoelastic planetIII. Aspherical models     

Jeroen Tromp  & Jerry X. Mitrovica 《Geophysical Journal International》2000,140(2):425-441

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Comments on the misuse of SPMDs in recent articles by Springman et al. (2008a,b) and Short et al. (2008)     

Paul D. Boehm  David S. Page  Jerry M. Neff 《Marine environmental research》2009,67(4-5):262-267

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