Electrokinetic Removal of Petroleum Hydrocarbon from Residual Clayey Soil Following a Washing Process     

Chil‐Sung Jeon  Jung‐Seok Yang  Kyung‐Jo Kim  Kitae Baek 《洁净——土壤、空气、水》2010,38(2):189-193

This study investigates total petroleum hydrocarbon (TPH) removal from residual clayey soil, after a washing procedure, using an electrokinetic process. Eight electrokinetic experiments were carried out to investigate the characteristics of TPH removal. When 0.1 M MgSO₄ or 0.1 M NaOH was used as an electrolyte, the electric current rapidly increased within the first 100 or 200 h, respectively. A negatively charged soil surface resulted in a more negative zeta potential and greater electroosmotic flow toward the cathode. Therefore, the accumulated electroosmotic flow (EOF) when using 0.1 M NaOH as the anolyte‐purging solution was higher than when using 0.1 M MgSO₄. Although the energy consumption for the two purging solutions was similar, the efficiencies of TPH removal when 0.1 M MgSO₄ and 0.1 M NaOH with surfactant were used were 0 and 39%, respectively, because the electroosmotic flow rate increased with TPH removal efficiency. When 5% isopropyl alcohol (IPA) was used as a circulation solution, the electric current increased but the TPH removal was similar to that using water. In terms of energy consumption, the use of a surfactant‐enhanced electrokinetic process with NaOH as electrolyte was effective in removing TPHs from low‐permeability soil.  相似文献   

A new methodology for measuring coastline recession using buffering and non‐linear least squares estimation     

Joon Heo  Jung Hwan Kim  Jin Woo Kim 《International journal of geographical information science》2013,27(9):1165-1177

Coastline recession is one of the best indicators of coastal erosion. Three methods for computing coastline recession – the baseline approach, the dynamic segmentation approach and the area‐based approach – have been used, each of which has one or more drawbacks. To overcome these problems, a new methodology for measuring coastline recession is proposed, using buffering and non‐linear least squares estimation. The proposed method was compared with the three existing methods with respect to two simulated cases and two real coastlines. Test results confirmed that the new method is more reliable than the three other methods, all of which are susceptible to variability of recession, scale, number of line segments, length of coastlines and direction of the baseline. The proposed method, incorporating two physically meaningful values – magnitude and variability of coastline recession according to the mean and standard deviation of coastline offsets, respectively – presents itself as an effective alternative method of assessing coastline recession.  相似文献   

Development of a simultaneous search-based pilot point method for subsurface characterization     

Yong Jung  G. Mahinthakumar  Ranji Ranjithan 《Stochastic Environmental Research and Risk Assessment (SERRA)》2013,27(8):2003-2013

Strategically applied geo-environmental clean-up methods require a better groundwater flow and transport model. Hydraulic conductivity of the subsurface is one of great sources of uncertainty of this model. In order to search hydraulic conductivities, the simultaneous search-based pilot point method (SSBM) was developed to reduce computational procedure of pilot point method and increase characterization accuracy using a global optimization tool (genetic algorithm). SSBM searches pilot point locations and hydraulic conductivities at selected pilot points simultaneously. In the four different scenarios, the comparison between random pilot point locations and SSBM showed that SSBM produced less than two orders magnitude differences in terms of average of minimum fitness for thirty trials (e.g. 4.05E?02 for scenario 2). With respect to average minimum fitness and average hydraulic conductivity difference, SSBM was comparable to D-optimality based pilot point method (DBM). SSBM produced lower average minimum fitness values and similar average hydraulic conductivity difference but it had more variance. Through these results, SSBM showed the potential to replace the DBM through reduced computational procedures in sensitivity calculation with consideration of variance minimization.  相似文献   

Application of singular spectrum analysis to identify the degrading structure using deteriorating distributed element model     

Chin‐Hsiung Loh  Jung‐Huan Li  Shu‐Hsien Chao 《地震工程与结构动力学》2013,42(5):743-761

Reinforced concrete structure may exhibit significant inelastic hysteretic behavior when subject to strong earthquake excitation. To investigate such an inelastic behavior, in this study, a new system identification technique is applied by using the deteriorating distributed element (DDE) model to simulate the hysteretic behavior of a degrading structure. Through the advanced signal processing technique, the multiple singular spectrum analysis (SSA) and the nonlinear SSA, the recorded inelastic restoring force of a deteriorating structure can be decomposed into several independent additive components in its sequentially degrading order and with decreasing weight. With each decomposed hysteresis loop, the model parameters of the DDE model are identified. The evolutionary properties of the progressive stiffness degradation behavior of reinforced concrete structure can be observed from the identified model parameters. Finally, comparison on the physical properties of the identified DDE model with respect to the seismic response data of the deteriorating structure is also discussed. The result shows that the proposed identification technique can have a good estimation on the seismic behavior of the degrading structure. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

The legacy of crystal-plastic deformation in olivine: high-diffusivity pathways during serpentinization   总被引：1，自引：1，他引：0  

Oliver Plümper  Helen E. King  Christian Vollmer  Quentin Ramasse  Haemyeong Jung  Håkon Austrheim 《Contributions to Mineralogy and Petrology》2012,163(4):701-724

Crystal-plastic olivine deformation to produce subgrain boundaries composed of edge dislocations is an inevitable consequence of asthenospheric mantle flow. Although crystal-plastic deformation and serpentinization are spatio-temporally decoupled, we identified compositional readjustments expressed on the micrometric level as a striped Fe-enriched ( [`(X)]<sub>\textFe</sub> \bar{X}_{\text{Fe}}  = 0.24 ± 0.02 (zones); 0.12 ± 0.02 (bulk)) or Fe-depleted ( [`(X)]_\textFe \bar{X}_{\text{Fe}}  = 0.10 ± 0.01 (zones); 0.13 ± 0.01 (bulk)) zoning in partly serpentinized olivine grains from two upper mantle sections in Norway. Focused ion beam sample preparation combined with transmission electron microscopy (TEM) and aberration-corrected scanning TEM, enabling atomic-level resolved electron energy-loss spectroscopic line profiling, reveals that every zone is immediately associated with a subgrain boundary. We infer that the zonings are a result of the environmental Fe²⁺Mg₋₁ exchange potential during antigorite serpentinization of olivine and the drive toward element exchange equilibrium. This is facilitated by enhanced solid-state diffusion along subgrain boundaries in a system, which otherwise re-equilibrates via dissolution-reprecipitation. Fe enrichment or depletion is controlled by the silica activity imposed on the system by the local olivine/orthopyroxene mass ratio, temperature and the effect of magnetite stability. The Fe-Mg exchange coefficients K_\textD^{\textAtg/\textOl} K_{\text{D}}^{{{\text{Atg}}/{\text{Ol}}}} between both types of zoning and antigorite display coalescence toward exchange equilibrium. With both types of zoning, Mn is enriched and Ni depleted compared with the unaffected bulk composition. Nanometer-sized, heterogeneously distributed antigorite precipitates along olivine subgrain boundaries suggest that water was able to ingress along them. Crystallographic orientation relationships gained via electron backscatter diffraction between olivine grain domains and different serpentine vein generations support the hypothesis that serpentinization was initiated along olivine subgrain boundaries.  相似文献   

Screening of extraction methods for Cd and As bioavailability prediction in rhizospheric soil using multivariate analyses     

Sung-Chul Kim  Jae E. Yang  Dong-Kuk Kim  Young-Wook Cheong  Jeffrey Skousen  Yeong-Sang Jung 《Environmental Earth Sciences》2012,66(1):327-335

Heavy metals in tailings and mining wastes from abandoned mines can be released into adjacent agricultural field and bioaccumulated in crops or vegetables. Therefore, prediction of metal bioavailability has become an important issue to prevent adverse effect of bioaccumulated metals on human health. In this study, single and sequential extraction methods were compared using multivariate analysis to predict the bioavailability of Cd and As in contaminated rhizosphere soils. Single extraction using 0.1 M HCl for Cd and 1.0 M HCl for As had an extraction efficiency of 8–12% for soil Cd and 14–17% for soil As compared to total concentration extracted with aqua regia. Using sequential extraction, Fe–Mn-bound Cd (FR3) and residual Cd (FR5) were the dominant fractions representing 43 and 41% of total Cd concentration. For As, the strongly absorbed form (FR2) was the most abundant chemical fraction showing 45–54% of the total As concentration in soil. Multivariate analyses showed that single extraction with HCl and total concentration of Cd and As in soil were significantly correlated to potato and green onion plant tissue metal concentration. Although little information was obtained with multiple regression analysis because of multicollinearity of variables, the result of principle component analysis (PCA) revealed that the highest positive loading was obtained using total concentration of Cd and As in soil in the first principle component (PC1). In addition, total concentration of Cd and As in soil was independently grouped with other chemical fractions by cluster analysis. Therefore, the overall result of this research indicated that total concentrations of Cd and As in rhizosphere soils were the best predictors of bioavailability of heavy metals in these contaminated soils.  相似文献   

The logistics of household hurricane evacuation   总被引：1，自引：1，他引：0  

Michael K. Lindell  Jung Eun Kang  Carla S. Prater 《Natural Hazards》2011,58(3):1093-1109

Although there is a substantial amount of research on households’ hurricane evacuation decision making, there is much less research on the logistical issues involved in implementing those evacuations. The limited research on household evacuation logistics has consistently shown that most evacuees stay in the homes of friends and relatives or in commercial facilities rather than in public shelters. However, evacuation logistics—which can be defined as the activities and associated resources needed to reach a safe location and remain there until it is safe to return—encompasses a much broader range of behaviors than this. The present study extends previous research by reporting data on other aspects of evacuation logistics such as departure timing, vehicle use, evacuation routes, travel distance, shelter type, evacuation duration, and evacuation cost. Hurricane Lili evacuation data at the county level are generally consistent with the data from previous hurricanes, but there is notable variation across counties studied here. There were only modest correlations of demographic and geographic variables with the evacuation logistics variables, a result that indicates further research is needed to better understand what happens between the time an evacuation decision is made and the time re-entry is begun. Moreover, research is needed to understand the logistics of evacuation by special populations such as transients and households with disabled members.  相似文献   

A biogeochemical orientation survey in the Moisan gold-mineralized area, Haenam district in Korea     

Ji-Eun Jung  Jong-Nam Kim  Hyo-Taek Chon 《Journal of Geochemical Exploration》2011,111(3):152-159

A biogeochemical orientation survey was carried out in the vicinity of an epithermal Au deposit in the Moisan Au–Ag mineralized area, Haenam district in Korea. The Au–Ag bearing quartz veins of the mine occur as narrow open-space fillings within Cretaceous silicic pyroclastics. The vein minerals consist mainly of quartz, sericite, pyrite, chalcopyrite, and galena, with some electrum and argentite. The main objectives of this study were to study the geochemical characteristics of rocks, soils and plants in this area, to investigate the spatial relationship between Au and associated elements in rock–soil–plant system, and to evaluate the applicability of biogeochemical prospecting for Au vein occurrences in Korea. Samples of rocks and soils, and leaves of three plant species (Japanese red pine — P. densiflora, oriental white oak — Q. aliena, Japanese mallotus — M. japonicus) were collected from the target mineralized area and control barren locations, and analyzed for trace elements by instrumental neutron activation analysis. Sampling lines were composed of one slope line which is almost parallel to the mineralized quartz-veins, and four transect lines spaced 100 m apart across the veins at 20 m sampling intervals. From the multi-element data of rock samples (n = 9), high values of Au (maximum 2030 ppb) are spatially related to Au–quartz veins. Soil samples (n = 61) collected from five sampling lines show higher values of Au (24–825 ppb) whereas soil samples from the control locations have lower values of Au (below 25 ppb). Many plant species collected from the vicinity of the veins have high Au contents compared with those at the control locations, but the ranges of Au values are variable among plant species. In a total of 128 samples of plant leaves, Q. aliena yielded Au values of 0.4 to 6.9 ppb, and M. japonicus 0.9 to 4.1 ppb. Gold contents in P. densiflora ranged from 0.1 to 5.6 ppb. Plant leaves from control areas show less than 1.6 ppb Au. The biological absorption coefficient (BAC) of Au in plants decreases in the order of Q. aliena > M. japonicus > P. densiflora. Based on the results of the study, Q. aliena appeared to be the best sampling media for biogeochemical prospecting of Au in the study area.  相似文献   

Modeling and control of a 75 kW class variable liquid-column oscillator for highly efficient wave energy converter     

Byung-Hak Cho  Dong-Soon Yang  Shin-Yeol Park  Kyung-Shik Choi  Do-Hwan Lee  Seung-Hyun Byun  Hoon Jung 《Ocean Engineering》2011,38(2-3):436-443

The modeling and control of a variable liquid-column oscillator having a liquid filled U-tube with air chambers at its vertical columns are presented. As an ocean wave energy extracting device, the structure of the variable liquid-column oscillator (VLCO) is analogous to that of the tuned liquid-column damper used to suppress oscillatory motion in large structures like tall buildings and cargo ships. However, owing to an air spring effect caused by the dynamic pressure of air chambers, the amplitude of response of the VLCO becomes significantly amplified for a desired wave period. The governing equations for the motion of VLCO structure under wave excitation and the motion of liquid with an air spring effect caused by an air–liquid interaction are described by a series of nonlinear differential equations. A set of control parameters for extracting maximum power from various wave conditions is determined for the efficient operation of the VLCO. It is found that the effect of the air spring has an important role to play in making the oscillation of the VLCO match with the ocean wave. In this way, the VLCO provides the most effective mode for extracting energy from the ocean wave.  相似文献   

Herbaceous layer development during spring does not deplete soil nitrogen in the Portuguese montado     

D.O. Otieno  H. MirzaeiM.Z. Hussain  Y.L. LiM.W.T. Schmidt  M. Wartinger  E. Jung  N. RibeiroJ.S. Pereira  J. Tenhunen 《Journal of Arid Environments》2011,75(3):231-238

Nitrogen (N) content in the soil and in the herbaceous biomass were monitored during spring of 2004-2006 to determine how the herbaceous layer development influences soil N availability in the montado ecosystem of southern Portugal. Highest (246.6 ± 52.7 g m⁻²) and lowest (123.2 ± 89.5 g m⁻²) peak biomass occurred in 2006 and 2005 respectively. Total soil N within the top 20 cm soil profile ranged between 0.2 ± 0.1% in February and 0.41 ± 0.2% in May, while available soil N was lowest (5 ± 2 μg g⁻¹soil) in February but increased three-to-five fold in March and was >17.5 μg g⁻¹soil at senescence in May. Significant (p < 0.001) increase in total N in the aboveground pool occurred between February and May. There was however, no decay in soil N content. Instead, the herbaceous vegetation enhanced soil N input and N retention in the ecosystem. Most of the herbaceous plants were annuals with large reserves of organic N at senescence, which returned to the soil as detritus. The herbaceous vegetation is a critical component of the montado that contributes to N recharge and cycling within the ecosystem.  相似文献