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51.
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An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry
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Bouchaïb Tibari Arnaud Vacherat Martin Stab Raphaël Pik Delphine Yeghicheyan Pascal Hild 《Geostandards and Geoanalytical Research》2016,40(3):365-375
Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure. 相似文献
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Jo Beth Mullens 《The Journal of geography》2016,115(6):244-255
Charging undergraduate geography students with the task of designing a recreational trail in their local community offers an engaging experiential opportunity with potential to advance geographic learning in a real-world setting. This article presents an assignment in which students were asked to develop a recreational trail proposal for an undeveloped local conservation area and the results of a survey that asked the students to reflect and report upon the educational value of this experience one year later. Results of the survey validated the assignment's lasting value to the students across the cognitive, psychomotor, and affective learning domains. 相似文献
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A single specimen of the pelagic shrimps, Pasiphaea japonica Omori, 1976 (Pasiphaeidae) collected in the southeastern waters of Korea is described and illustrated. Although this species occurs widely in the Indo-West Pacific including the Japanese coast of the East/Japan Sea and the middle and southern parts of the East China Sea, this is the first record of the species and the genus in Korean waters. The species is distinguished from other congeners by the following combination of characteristics: non-carinate dorsal sixth abdominal somite with a terminal tooth, rudimentary pleurobranch on the eighth thoracic somite, merus of the first pereopod with more than eight spines, and almost entirely transparent white color. 相似文献
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Hydrocarbon reservoir modelling and characterisation is a challenging subject within the oil and gas industry due to the lack of well data and the natural heterogeneities of the Earth’s subsurface. Integrating historical production data into the geo-modelling workflow, commonly designated by history matching, allows better reservoir characterisation and the possibility of predicting the reservoir behaviour. We present herein a geostatistical-based multi-objective history matching methodology. It starts with the generation of an initial ensemble of the subsurface petrophysical property of interest through stochastic sequential simulation. Each model is then ranked according the match between its dynamic response, after fluid flow simulation, and the observed available historical production data. This enables building regionalised Pareto fronts and the definition of a large ensemble of optimal subsurface Earth models that fit all the observed production data without compromising the exploration of the uncertainty space. The proposed geostatistical multi-objective history matching technique is successfully implemented in a benchmark synthetic reservoir dataset, the PUNQ-S3, where 12 objectives are targeted. 相似文献
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Numerical representations of a target reservoir can help to assess the potential of different development plans. To be as predictive as possible, these representations or models must reproduce the data (static, dynamic) collected on the field. However, constraining reservoir models to dynamic data – the history-matching process – can be very time consuming. Many uncertain parameters need to be taken into account, such as the spatial distribution of petrophysical properties. This distribution is mostly unknown and usually represented by millions of values populating the reservoir grid. Dedicated parameterization techniques make it possible to investigate many spatial distributions from a small number of parameters. The efficiency of the matching process can be improved from the perturbation of specific regions of the reservoir. Distinct approaches can be considered to define such regions. For instance, one can refer to streamlines. The leading idea is to identify areas that influence the production behavior where the data are poorly reproduced. Here, we propose alternative methods based on connectivity analysis to easily provide approximate influence areas for any fluid-flow simulation. The reservoir is viewed as a set of nodes connected by weighted links that characterize the distance between two nodes. The path between nodes (or grid blocks) with the lowest cumulative weight yields an approximate flow path used to define influence areas. The potential of the approach is demonstrated on the basis of 2D synthetic cases for the joint integration of production and 4D saturation data, considering several formulations for the weights attributed to the links. 相似文献
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Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L?1, respectively), and nitrification rates in this region were up to 7 μmol L?1 day?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate. 相似文献