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71.
Carlos Guerra Marc J. Metzger João Honrado Joaquim Alonso 《International journal of geographical information science》2013,27(10):2077-2098
When establishing environmental monitoring programmes, it crucial to make reliable cost estimates, especially where a field survey is involved. This paper presents a methodology for creating a spatial measure of a field survey effort (SE). A set of relevant variables affecting a SE (e.g. areas with rough terrain, or distant from the main road network) was classified using fuzzy sets and then combined to produce spatially explicit effort indicators, which were integrated to a single measure using an analytic hierarchy process (AHP). To evaluate this approach and identify the limits for its application, three spatially nested case studies were used to test the spatial expression of SE and the scalable capacity of the method itself. The presented methodology could cope with variations in the scale and data resolution, retrieving a coherent estimate of SE across the different case studies. The presented methodology is therefore useful for (i) testing the network designs for sampling bias related to SE, (ii) comparing alternative sampling designs, (iii) assessing the sampling costs and (iv) supporting the human and logistical resource management. 相似文献
72.
Carlos J. Chernicoff Eduardo O. Zappettini João O.S. Santos Marta C. Godeas E. Belousova Neal J. McNaughton 《Gondwana Research》2012,21(2-3):378-393
We have identified late Early Cambrian metaigneous rocks very poorly exposed at the Estancia El Carancho, in central La Pampa province, Argentina. They comprise calc–alkaline metadiorite and metagranite, and tholeiitic metapyroxenite and metagabbro. They are jointly referred to as the El Carancho Igneous Complex, and regarded to pertain to the Pampean magmatic arc and backarc, respectively. Titanite U–Pb SHRIMP dating of the metapyroxenite yielded 528 ± 5 Ma, and zircon U–Pb SHRIMP dating of the metadiorite yielded 520 ± 1.4 Ma. Hafnium isotope determinations on the dated zircons show 176Hf/177Hf ratios corresponding to positive εHf values from + 7.18 to + 9.37; Hf model ages of the Cambrian zircons yielded 884 Ma. It is interpreted that the metadiorites of the Complex crystallized from an Early Neoproterozoic (Tonian) juvenile source. We argue that the inferred occurrence of juvenile Tonian magmatic rocks in the (otherwise, mostly Paleo-Mesoproterozoic) substratum of the southern Pampia terrane could indicate a zone of thinned basement possibly associated with the early stage of Rodinia's breakup. In addition, the studied segment of the Pampean magmatic arc is contaminated by also juvenile, Late Mesoproterozoic crust, as evidenced by the presence of xenocrystic cores of 1140–1194 Ma – TDM-Hf 1720 Ma and εHf values of + 3.24 to + 4.85 – in the Cambrian zircons, hence suggesting that the studied segment of the Pampean magmatic arc was intruded into juvenile Late Mesoproterozoic magmatic arc rocks. The El Carancho Igneous Complex would be located at the tectonic boundary between the Pampia terrane and the Río de la Plata craton. This boundary stands out in the aeromagnetic data as a change in the structural orientation about a roughly N-S line located approximately at 65° W and representing the suture zone between the Pampia terrane and the Río de la Plata craton. Our geotectonic model envisages westward dipping subduction of oceanic crust beneath the Pampia terrane; the El Carancho Igneous Complex would, therefore, have been originated on the Pampia side (upper plate) of the suture. Slivers of the arc- and backarc-type rocks would have been tectonically imbricated in the suture zone during the Pampean orogeny. 相似文献
73.
Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments 总被引:1,自引:0,他引:1
Pyeong-Koo Lee Min-Ju Kang Ho Young Jo Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923
The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area. 相似文献
74.
75.
Borja A Barbone E Basset A Borgersen G Brkljacic M Elliott M Garmendia JM Marques JC Mazik K Muxika I Magalhães Neto J Norling K Rodríguez JG Rosati I Rygg B Teixeira H Trayanova A 《Marine pollution bulletin》2011,62(3):499-513
In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices. 相似文献
76.
Sabino R Veríssimo C Cunha MA Wergikoski B Ferreira FC Rodrigues R Parada H Falcão L Rosado L Pinheiro C Paixão E Brandão J 《Marine pollution bulletin》2011,62(7):1506-1511
Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci. 相似文献
77.
Catarina Vinagre João Salgado Henrique N. Cabral Maria J. Costa 《Estuaries and Coasts》2011,34(4):663-674
River flow variability is known to influence estuarine production, yet knowledge on its effect upon estuarine food webs dynamics
is still scarce. Stable carbon and nitrogen isotopes were used to assess the effect of river flow in the connectivity and
food web interactions between the two main fish nursery areas of the Tagus estuary. The aims of the present work were to investigate
the seasonal variation in food web structure and the exchange rate of individuals of marine juvenile fish among estuarine
nurseries, to compare the spring of a rainy year (2001) with that of an average year (2000), and to investigate the impact
of the winter floods of 2001. A low level of connectivity was observed for the fish species that use these areas as nurseries.
In low river flow conditions, two isotopically distinct food webs were established in each nursery area. These food webs were
very sensitive to small variations in the freshwater input. Winter floods seem to disrupt the localized food webs that are
established in low river flow periods, leading to the re-establishment of a wider food web. While in rainy years this wide
food web is maintained until spring, in average years the food web undergoes fragmentation into two localized and isotopically
distinctive food webs. The increase in frequency of droughts due to climate change should lower the connectivity of the estuarine
fish nurseries food webs, causing habitat fragmentation and consequent loss in complexity and resilience. 相似文献
78.
This paper describes the implementation of process-based models reflecting relative groundwater nitrate vulnerability of the
shallow alluvial Lower Savinja Valley (LSV) aquifer in Slovenia. A spatially explicit identification of the potentially vulnerable
priority areas within groundwater bodies at risk from a chemical point of view is being required for cost-effective measures
and monitoring planning. The shallow LSV unconfined aquifer system consists of high-permeable Holocene and middle- to low-permeable
Pleistocene gravel and sand, with a maximum thickness of about 30 m, mainly covered by shallow eutric fluvisoils or variously
deep eutric cambisoil. The hydrogeological parameters, e.g. the depth to the groundwater, hydrological role of the topographic
slope, etc. usually used in different point count schemes are, in the case of the lowland aquifer and shallow groundwater,
spatially very uniform with low variability. Furthermore, the parametric point count methods are generally not able to illustrate
and analyze important physical processes, and validation of the results is difficult and expensive. Instead of a parametric
point count scheme, we experimentally used the Arc-WofE extension for weights-of-evidence (WofE) modelling. All measurement
locations with a concentration higher than the value of 20 mg NO3
− per litre of groundwater have been considered as training points (173), and the three process-based models generalized output
layers of groundwater recharge (GROWA), nitrate leached from the soil profile (SWAT) and groundwater flow velocity (FEFLOW),
served as evidential themes. The technique is based on the Bayesian idea of phenomena occurrences probability before (prior
probability) and after consideration of any evidential themes (posterior probability), which were measured by positive and
negative weights as an indication of the association between a phenomena and a prediction pattern. The response theme values
describe the relative probability that a 100 × 100 m spatial unit will have a groundwater nitrate concentration higher than
the training points’ limit values with regard to prior probability value. The lowest probability of groundwater nitrate occurrence
is in the parts of the LSV aquifer, which are known as anoxic condition areas with very likely denitrification processes.
The cross-validation of the dissolved oxygen and dissolved nitrate response theme confirmed the accuracy of the groundwater
nitrate prediction. The WofE model results very clearly indicate regional groundwater nitrate distribution and enable spatial
prediction of the probability for increased groundwater nitrate concentration in order to plan the groundwater nitrate reduction
measures and optimize the programme for monitoring the effects of these measures. 相似文献
79.
Chemistry of the Ferraria thermal water, S. Miguel Island, Azores: mixing and precipitation processes 总被引:1,自引:1,他引:0
Maria do Rosário Carvalho António Mateus Jo?o C. Nunes José M. Carvalho 《Environmental Earth Sciences》2011,64(2):539-547
The Ferraria thermal water emerges at the sea level in the Ferraria lava delta (western edge of S. Miguel Island, Azores)
with temperature of ca. 60°C and pH varying between 5.4 and 6.2. It is of sodium chloride type, resulting from ca. 50% seawater
mixing with an acid brackish, at ≈100°C, denoting the presence of significant CO2(g) and the progress of water–rock interactions in open system conditions. The thermal Na–Cl water is strongly enriched with
Sr and Mn and, comparatively, has low concentrations in Al, Fe and As. These elements are removed from the solution as critical
conditions for the formation of several neo-formed mineral phases are gradually attained. Thermodynamic equilibrium calculations
are consistent with this interpretation, showing that the thermal fluid can precipitate Fe3+-(hydr-)oxides, kaolinite and non-crystalline silica. Wells logging show fracture planes and pores fully/partly filled up
with polyphase botryoidal aggregates mostly composed of goethite + ferrihydrite and displaying variable adsorbed contents
of Si, P and As. These neo-formed phases result from the pristine fluid oxidation due to seawater mixing; its precipitation
is easily affected by pH and redox variations of the brackish, due to volcanic gases pressure alterations, and fluid pressure
or flow-velocity oscillation in the fractured aquifer. 相似文献
80.
Abdelfettah Sifeddine Renato Campello Cordeiro Ana Luiza S. Albuquerque Marcelo Bernardes Bruno Turcq Jorge João Abrão 《Journal of Paleolimnology》2011,45(3):385-396
Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ13C values decreased between 0 and 4 m, whereas δ15N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems. 相似文献