Influence of dissolved organic carbon on photochemically mediated cycling of hydrogen peroxide in rainwater     

Robert J. Kieber  Jeremy Smith  Katherine M. Mullaugh  Melissa W. Southwell  G. Brooks Avery Jr.  Joan D. Willey 《Journal of Atmospheric Chemistry》2009,64(2-3):149-158

The influence of sunlight and dissolved organic carbon (DOC) on the photochemically mediated cycling of hydrogen peroxide (H₂O₂) was investigated in rainwater samples collected in Wilmington, North Carolina USA. Upon exposure to simulated sunlight 14 of 19 authentic rainwater samples exhibited significant decreases in H₂O₂. The concentration of hydrogen peroxide did not change significantly in organic-free synthetic rainwater spiked with H₂O₂ in the light or in dark controls suggesting that the loss was not due to direct photolysis or dark mediated reactions. There was a significant correlation between pseudo-first order rate constants of H₂O₂ decay and initial H₂O₂ concentrations. There was also a significant correlation between the rate constant and the abundance of DOC suggesting that rainwater organic carbon plays an important role during photolytic decay either via direct reaction or indirectly through production of peroxide reactive species or scavenging of peroxide generating radicals. Several rain samples exhibited an initial increase in H₂O₂ during the first 2 h of irradiation. These increases were generally small and most likely do not represent a significant input of peroxide in precipitation. The photo-induced destruction of H₂O₂ is important because it may partly explain the late afternoon decrease of peroxide concentrations observed in earlier field studies and the substantial under saturation (<10%) of this oxidant in rainwater compared with gas phase concentrations.  相似文献   

Study of the total lightning activity in a hailstorm   总被引：1，自引：0，他引：1  

Joan Montany  Serge Soula  Nicolau Pineda  Oscar van der Velde  Pere Clapers  Glria Sol  Joan Bech  D. Romero 《Atmospheric Research》2009,91(2-4):430-437

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.  相似文献   

Use of stream response functions to determine impacts of replacing surface-water use with groundwater withdrawals   总被引：1，自引：0，他引：1  

Erik B. Pruneda  Michael E. Barber  Diana M. Allen  Joan Q. Wu 《Hydrogeology Journal》2010,18(5):1077-1092

A regional-scale numerical groundwater model is used to study the impacts of replacing surface-water use with groundwater wells to improve low-flow stream conditions for endangered species within the Bertrand and Fishtrap watersheds, southern British Columbia, Canada and Washington, USA. Stream response functions ranging from 0 to 1.0 were calculated for individual wells placed within a steady-state groundwater flow model at varying distances from the streams to determine the impact that these replacement wells, operating under sustained pumping rates, would have on summer instream flows. Lower response ratios indicate groundwater pumping will have less of an impact on streamflow than taking an equivalent amount of water directly from a surface-water source. Results show that replacing surface-water use with groundwater withdrawals may be a viable alternative for increasing summer streamflows. Assuming combined response factors should be ≤0.5 for irrigators to undergo the expense of installing new wells, ~57% of the land area within 0.8 km of Bertrand Creek would be suitable for replacement wells. Similarly, 70% of the land area within 0.8 km of Fishtrap Creek was found to be appropriate. A visual analysis tool was developed using STELLA to allow stakeholders to quickly evaluate the impact associated with moving their water right.  相似文献   

Future changes in Central Europe heat waves expected to mostly follow summer mean warming     

Joan Ballester  Xavier Rodó  Filippo Giorgi 《Climate Dynamics》2010,35(7-8):1191-1205

Daily output from the PRUDENCE ensemble of regional climate simulations for the end of the twentieth and twenty-first centuries over Europe is used to show that the increasing intensity of the most damaging summer heat waves over Central Europe is mostly due to higher base summer temperatures. In this context, base temperature is defined as the mean of the seasonal cycle component for those calendar days when regional heat waves occur and is close, albeit not identical, to the mean temperature for July–August. Although 36–47% of future Central Europe July and August days at the end of the twenty-first century are projected to be extreme according to the present day climatology, specific changes in deseasonalized heat wave anomalies are projected to be relatively small. Instead, changes in summer base temperatures appear much larger, clearly identifiable and of the same order of magnitude as changes in the whole magnitude of heat waves. Our results bear important consequences for the predictability of central European heat wave intensity under global warming conditions.  相似文献   

Transmission electron microscopy applied to fluid inclusion investigations   总被引：8，自引：0，他引：8  

Cecilia Viti  Maria-Luce Frezzotti 《Lithos》2001,55(1-4):125-138

The transmission electron microscope (TEM) allows a detailed characterization of textural and chemical features of fluid inclusions (shape, inner compositions and inner textures), at a resolution higher than that attainable with an optical microscope (OM). TEM investigation indicates that most fluid inclusions appear as perfectly euhedral negative crystals, with variable shape (from prismatic to equant) and size (typically from <0.02 to 0.15 μm). Inner texture (fluid phase/melt distribution) and composition are variable as well. Different kinds of negative crystals may coexist in the same trail of inclusions, possibly indicating locally variable trapping conditions.

A critical feature, revealed by TEM, is that inclusions are often connected to structural defects (in particular, to dislocation arrays), which are undetected by optical microscopy. The identification of these hidden nanostructures should be taken into account for the correct petrological interpretation of microthermometric results, particularly when controversial data have been obtained. In fact, these nanostructures may represent a possible path for fluid phase leakage, thus modifying the original composition and/or density of the inclusions.  相似文献   

GEOEssential – mainstreaming workflows from data sources to environment policy indicators with essential variables     

Anthony Lehmann  Stefano Nativi  Paolo Mazzetti  Joan Maso  Ivette Serral  Daniel Spengler 《International Journal of Digital Earth》2020,13(2):322-338

ABSTRACT

When defining indicators on the environment, the use of existing initiatives should be a priority rather than redefining indicators each time. From an Information, Communication and Technology perspective, data interoperability and standardization are critical to improve data access and exchange as promoted by the Group on Earth Observations. GEOEssential is following an end-user driven approach by defining Essential Variables (EVs), as an intermediate value between environmental policy indicators and their appropriate data sources. From international to local scales, environmental policies and indicators are increasingly percolating down from the global to the local agendas. The scientific business processes for the generation of EVs and related indicators can be formalized in workflows specifying the necessary logical steps. To this aim, GEOEssential is developing a Virtual Laboratory the main objective of which is to instantiate conceptual workflows, which are stored in a dedicated knowledge base, generating executable workflows. To interpret and present the relevant outputs/results carried out by the different thematic workflows considered in GEOEssential (i.e. biodiversity, ecosystems, extractives, night light, and food-water-energy nexus), a Dashboard is built as a visual front-end. This is a valuable instrument to track progresses towards environmental policies.  相似文献   

Effects of aging on silica solubility: A laboratory study     

Joan D. Willey 《Geochimica et cosmochimica acta》1980,44(4):573-578

In three separate experiments, one using a bicarbonate buffered aqueous NaCl solution and two using natural seawater. the solubility of chemically pure X-ray amorphous precipitated silica decreased by approximately 20‰ after aging in contact with solution for several months. The specific surface area of the silica decreased by approximately half during the same experimental time periods. The solubility decrease in buffered NaCl solution occurred at both 2 and 22°C and over the pressure range from 1.01 × 10⁵ to 7.45 × 10⁷ Pa (1–740 atm). The aging process which causes the solubility and surface area decreases may be caused by the formation of a smooth surface silica layer that is more dense than the original surface. No change in the bulk chemistry of the silica could be defined after aging. This short term aging process contributes to the scatter in published solubilities for amorphous silica in seawater.  相似文献   

High-resolution grain-size characterisation of gravel bars using imagery analysis and geo-statistics   总被引：2，自引：0，他引：2  

Joan M. Verdú  Ramon J. Batalla  Jos A. Martínez-Casasnovas 《Geomorphology》2005,72(1-4):73-93

The scarcity of grain-size data from gravel-bed rivers has traditionally hindered hydraulic, sediment transport and river habitat studies. A new remote sensing methodology to estimate grain-size distribution is presented. It combines textural digital images of the riverbed at 1 : 1000 and 1 : 40 scales with grain-size sampling. It was applied to a 12-km reach of the Isábena River (Central Pyrenees NE Spain). First, textural patterns for each grain-size range were obtained, selecting the most closely related texture variables, including the use of semivariograms. Second, multiple linear regression equations were derived from the textural variables to estimate each value of the grain-size distribution. The highest correlation values (r²) were obtained from the central part of the distribution (D₅₀ with a RMS error of 12.7%). Finally, new multiple linear regression equations to estimate the D₅₀ and D₈₄ were obtained from 1 : 1000 images and four textural variables. These were used to derive D₅₀ and D₈₄ maps of the riverbed, re-sampled at a resolution of 1.5 m pixels, with RMS estimation errors of 26% and 32%, respectively. Downstream change in grain-size is also well reproduced by the method. The mean D₅₀ of 72 and 32 mm were estimated in the upper and the lower reaches of the river, respectively. The methodology shows great potential for application, the relation between the spatial resolution of the images and the mean grain-size of the riverbed sediment being the main issue for future development.  相似文献   

Persistent organic pollutants in remote freshwater ecosystems   总被引：3，自引：0，他引：3  

Pilar Fernández  Guillem Carrera  Joan O. Grimalt 《Aquatic Sciences - Research Across Boundaries》2005,67(3):263-273

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History of sedimentary infilling and faulting in Subic Bay, Philippines revealed in high-resolution seismic reflection profiles     

Ma. Edweena Joan A. Cabato  Kelvin S. Rodolfo  Fernando P. Siringan 《Journal of Asian Earth Sciences》2005,25(6):849

Subic Bay sediments and faults identified in seismic-reflection profiles were dated using sea-level curves. The oldest sedimentary packages are marine sediments subaerially exposed and eroded 20 ka. Fluvio-marine to wholly marine sediments were deposited during the ensuing transgression, and prograding units were deposited during stillstands or minor sea-level falls. Faults within the bay have three age ranges. The oldest set cuts through the pre-δ¹⁸O Stage 2 rock units, >18 ka; a second disrupts 10.2–11.3 ka sediments; and the youngest, which cut the uppermost sedimentary package, show that movements occurred about every 2 ky, most recently about 3 ka. Northwest–southeast faults that parallel onshore structures associated with Paleogene emplacement of the Zambales Ophiolite Complex to the west and north likely represent rejuvenated tectonism. The northern coastline and north–south-trending axial bay islands appear related to a lineament that dissects Mt Pinatubo farther northeast. A breach in the caldera of Mt Natib is the most likely source of a presumed pyroclastic deposit in the eastern bay that is associated with sediments about 11.3–18 ka, indicating that a Natib eruption occurred much more recently than previously documented for this volcano.  相似文献