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101.
The beginning of dehydration melting in the tonalite system (biotite-plagioclase-quartz) is investigated in the pressure
range of 2–12 kbar. A special method consisting of surrounding a crystal of natural plagioclase (An45) with a biotite-quartz mixture, and observing reactions at the plagioclase margin was employed for precise determination
of the solidus for dehydration melting. The beginning of dehydration melting was worked out at 5 kbar for a range of compositions
of biotite varying from iron-free phlogopite to iron-rich Ann70, with and without titanium, fluorine and extra aluminium in the biotite. The dehydration melting of phlogopite + plagioclase
(An45) + quartz begins between 750 and 770°C at pressures of 2 and 5 kbar, at approximately 740°C at 8 kbar and between 700 and
730°C at 10 kbar. At 12 kbar, the first melts are observed at temperatures as low as 700°C. The data indicate an almost vertical
dehydration melting solidus curve at low pressures which bends backward to lower temperatures at higher pressures (> 5 kbar).
The new phases observed at pressures ≤ 10 kbar are melt + enstatite + clinopyroxene + potassium feldspar ± amphibole. In addition
to these, zoisite was also observed at 12 kbar. With increasing temperature, phlogopite becomes enriched in aluminium and
deficient in potassium. Substitution of octahedral magnesium by aluminium and titanium in the phlogopite, as well as substitution
of hydroxyl by fluorine, have little effect on the beginning of dehydration melting temperatures in this system. The dehydration
melting of biotite (Ann50) + plagioclase (An45) + quartz begins 50°C below that of phlogopite bearing starting composition. Solid reaction products are orthopyroxene +
clinopyroxene + potassium feldspar ± amphibole. Epidote was also observed above 8 kbar, and garnet at 12 kbar (750°C). The
experiments on the iron-bearing system performed at ≤ 5 kbar were buffered with NiNiO. The f
O
2 in high pressure runs lies close to CoCoO. With the substitution of octahedral magnesium and iron by aluminium and titanium,
and replacement of hydroxyl by fluorine in biotite, the beginning of dehydration melting temperatures in this system increase
up to 780°C at 5 kbar, which is 70°C above the beginning of dehydration melting of the assemblage containing biotite (Ann50) of ideal composition. The dehydration melting at 5 kbar in the more iron-rich Ann70-bearing starting composition begins at 730°C, and in the Ann25-bearing assemblage at 710°C. This indicates that quartz-biotite-plagioclase assemblages with intermediate compositions of
biotite (Ann25 and Ann50) melt at lower temperatures as compared to those containing Fe-richer or Mg-richer biotites. This study shows that the dehydration
melting of tonalites may begin at considerably lower temperatures than previously thought, especially at high pressures (>5
kbar).
Received: 27 December 1995 / Accepted: 7 May 1996 相似文献
102.
Dehydration melting of tonalitic compositions (phlogopite or biotite-plagioclase-quartz assemblages) is investigated within
a temperature range of 700–1000°C and pressure range of 2–15 kbar. The solid reaction products in the case of the phlogopite-plagioclase(An45)-quartz starting material are enstatite, clinopyroxene and potassium feldspar, with amphiboles occurring occasionally. At
12 kbar, zoisite is observed below 800°C, and garnet at 900°C. The reaction products of dehydration melting of the biotite
(Ann50)-plagioclase (An45)-quartz assemblage are melt, orthopyroxene, clinopyroxene, amphibole and potassium feldspar. At pressures > 8 kbar and temperatures
below 800°C, epidote is also formed. Almandine-rich garnet appears above 10 kbar at temperatures ≥ 750°C. The composition
of melts is granitic to granodioritic, hence showing the importance of dehydration melting of tonalites for the formation
of granitic melts and granulitic restites at pressure-temperature conditions within the continental crust. The melt compositions
plot close to the cotectic line dividing the liquidus surfaces between quartz and potassium feldspar in the haplogranite system
at 5 kbar and a
H
2O = 1. The composition of the melts changes with the composition of the starting material, temperature and pressure. With increasing
temperature, the melt becomes enriched in Al2O3 and FeO+MgO. Potash in the melt is highest just when biotite disappears. The amount of CaO decreases up to 900°C at 5 kbar
whereas at higher temperatures it increases as amphibole, clinopyroxene and more An-component dissolve in the melt. The Na2O content of the melt increases slightly with increase in temperature. The composition of the melt at temperatures > 900°C
approaches that of the starting assemblage. The melt fraction varies with composition and proportion of hydrous phases in
the starting composition as well as temperature and pressure. With increasing modal biotite from 20 to 30 wt%, the melt proportion
increases from 19.8 to 22.3 vol.% (850°C and 5 kbar). With increasing temperature from 800 to 950°C (at 5 kbar), the increase
in melt fraction is from 11 to 25.8 vol.%. The effect of pressure on the melt fraction is observed to be relatively small
and the melt proportion in the same assemblage decreases at 850°C from 19.8 vol.% at 5 kbar to 15.3 vol.% at 15 kbar. Selected
experiments were reversed at 2 and 5 kbar to demonstrate that near equilibrium compositions were obtained in runs of longer
duration.
Received: 27 December 1995 / Accepted: 7 May 1996 相似文献
103.
Johannes Bruining Diederik van Batenburg Larry W. Lake An Ping Yang 《Mathematical Geology》1997,29(6):823-848
Random field generators serve as a tool to model heterogeneous media for applications in hydrocarbon recovery and groundwater
flow. Random fields with a power-law variogram structure, also termed fractional Brownian motion (fBm) fields, are of interest
to study scale dependent heterogeneity effects on one-phase and two-phase flow. We show that such fields generated by the
spectral method and the Inverse Fast Fourier Transform (IFFT) have an incorrect variogram structure and variance. To illustrate
this we derive the prefactor of the fBm spectral density function, which is required to generate the fBm fields. We propose
a new method to generate fBm fields that introduces weighting functions into the spectral method. It leads to a flexible and
efficient algorithm. The flexibility permits an optimal choice of summation points (that is points in frequency space at which
the weighting function is calculated) specific for the autocovariance structure of the field. As an illustration of the method,
comparisons between estimated and expected statistics of fields with an exponential variogram and of fBm fields are presented.
For power-law semivariograms, the proposed spectral method with a cylindrical distribution of the summation points gives optimal
results. 相似文献
104.
105.
The identifiability of parameters in a water quality model of the Biebrza River, Poland 总被引:1,自引:0,他引:1
The identifiability of model parameters of a steady state water quality model of the Biebrza River and the resulting variation in model results was examined by applying the Monte Carlo method which combines calibration, identifiability analysis, uncertainty analysis, and sensitivity analysis. The water quality model simulates the steady state concentration profiles of chloride, phosphate, ammonium, and nitrate as a function of distance along a river. The water quality model with the best combination of parameter values simulates the observed concentrations very well. However, the range of possible modelled concentrations obtained for other more or less equally eligible combinations of parameter values is rather wide. This range in model outcomes reflects possible errors in the model parameters. Discrepancies between the range in model outcomes and the validation data set are only caused by errors in model structure, or (measurement) errors in boundary conditions or input variables. In this sense the validation procedure is a test of model capability, where the effects of calibration errors are filtered out. It is concluded that, despite some slight deviations between model outcome and observations, the model is successful in simulating the spatial pattern of nutrient concentrations in the Biebrza River. 相似文献
106.
Assuming a radially stratified Newtonian mantle in a steady-state approximation, we demonstrate that the permeability of a viscosity interface at 660-km depth strongly depends on the wavelength of buoyancy forces driving the flow. The flow induced by long-wavelength loads penetrates through the boundary freely even if the viscosity increases by two orders. In contrast, the boundary is practically impermeable for short-wavelength loads located in the upper mantle. Thus, a stepwise increase of viscosity is a significant obstacle for small descending features in the upper mantle, but huge upper mantle downwellings, or upwellings formed in the-lower mantle can overcome it easily. This indicates that certain care is necessary in interpreting the seismic structure of the mantle by means of flow models. The global tomographic image includes only the first few degrees of the harmonic series and, consequently, its interpretation in terms of a present-day flow field results in a predominantly whole-mantle circulation even for extreme viscosity contrasts. 相似文献
107.
A. Douaik M. van Meirvenne T. Tóth M. Serre 《Stochastic Environmental Research and Risk Assessment (SERRA)》2004,18(4):219-227
The mapping of saline soils is the first task before any reclamation effort. Reclamation is based on the knowledge of soil salinity in space and how it evolves with time. Soil salinity is traditionally determined by soil sampling and laboratory analysis. Recently, it became possible to complement these hard data with soft secondary data made available using field sensors like electrode probes. In this study, we had two data sets. The first includes measurements of field salinity (ECa) at 413 locations and 19 time instants. The second, which is a subset of the first (13 to 20 locations), contains, in addition to ECa, salinity determined in the laboratory (EC2.5). Based on a procedure of cross-validation, we compared the prediction performance in the space-time domain of 3 methods: kriging using either only hard data (HK) or hard and mid interval soft data (HMIK), and Bayesian maximum entropy (BME) using probabilistic soft data. We found that BME was less biased, more accurate and giving estimates, which were better correlated with the observed values than the two kriging techniques. In addition, BME allowed one to delineate with better detail saline from non-saline areas. 相似文献
108.
Water-level fluctuations may be used to promote the expansion of emergent vegetation along lakeshores. We present the case of the lake Volkerak-Zoommeer in the Netherlands, a fresh-water lake created in 1987 after the enclosure of an estuary. Using an experimental area in which the water level could be manipulated, it was shown that partial summer drawdown of the shoreline created suitable conditions for germination and growth of tall emergent species (in particular Phragmites australis). Plant survival and growth depended on subsequent water-level fluctuations and grazing by waterbirds. Based on the experiment and empirical data, a model was developed to predict the effects of the water-level regime on potential reed bed development. The model was applied for four hydrological scenarios that have been considered for the water-level management of the lake. 相似文献
109.
110.
Jens Fiebig Giovanni Chiodini Andrea Rizzo Johannes C. Hunziker 《Geochimica et cosmochimica acta》2004,68(10):2321-2334
The chemical and isotopic composition of fumarolic gases emitted from Nisyros Volcano, Greece, and of a single gas sample from Vesuvio, Italy, was investigated in order to determine the origin of methane (CH4) within two subduction-related magmatic-hydrothermal environments.Apparent temperatures derived from carbon isotope partitioning between CH4 and CO2 of around 340°C for Nisyros and 470°C for Vesuvio correlate well with aquifer temperatures as measured directly and/or inferred from compositional data using the H2O-H2-CO2-CO-CH4 geothermometer. Thermodynamic modeling reveals chemical equilibrium between CH4, CO2 and H2O implying that carbon isotope partitioning between CO2 and CH4 in both systems is controlled by aquifer temperature.N2/3He and CH4/3He ratios of Nisyros fumarolic gases are unusually low for subduction zone gases and correspond to those of midoceanic ridge environments. Accordingly, CH4 may have been primarily generated through the reduction of CO2 by H2 in the absence of any organic matter following a Fischer-Tropsch-type reaction. However, primary occurrence of minor amounts of thermogenic CH4 and subsequent re-equilibration with co-existing CO2 cannot be ruled out entirely. CO2/3He ratios and δ13CCO2 values imply that the evolved CO2 either derives from a metasomatized mantle or is a mixture between two components, one outgassing from an unaltered mantle and the other released by thermal breakdown of marine carbonates. The latter may contain traces of organic matter possibly decomposing to CH4 during thermometamorphism. 相似文献