The effect of H₂O on crystal-melt partitioning of trace elements     

Bernard J Wood  Jonathan D Blundy 《Geochimica et cosmochimica acta》2002,66(20):3647-3656

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An overview of toxicant identification in sediments and dredged materials   总被引：1，自引：0，他引：1  

Ho KT  Burgess RM  Pelletier MC  Serbst JR  Ryba SA  Cantwell MG  Kuhn A  Raczelowski P 《Marine pollution bulletin》2002,44(4):286-293

The identification of toxicants affecting aquatic benthic systems is critical to sound assessment and management of our nation's waterways. Identification of toxicants can be useful in designing effective sediment remediation plans and reasonable options for sediment disposal. Knowledge of which contaminants affect benthic systems allows managers to link pollution to specific dischargers and prevent further release of toxicant(s). In addition, identification of major causes of toxicity in sediments may guide programs such as those developing environmental sediment guidelines and registering pesticides, while knowledge of the causes of toxicity which drive ecological changes such as shifts in benthic community structure would be useful in performing ecological risk assessments. To this end, the US Environmental Protection Agency has developed tools (toxicity identification and evaluation (TIE) methods) that allow investigators to characterize and identify chemicals causing acute toxicity in sediments and dredged materials. To date, most sediment TIEs have been performed on interstitial waters. Preliminary evidence from the use of interstitial water TIEs reveals certain patterns in causes of sediment toxicity. First, among all sediments tested, there is no one predominant cause of toxicity; metals, organics, and ammonia play approximately equal roles in causing toxicity. Second, within a single sediment there are multiple causes of toxicity detected; not just one chemical class is active. Third, the role of ammonia is very prominent in these interstitial waters. Finally, if sediments are divided into marine or freshwater, TIEs perforMed on interstitial waters from freshwater sediments indicate a variety of toxicants in fairly equal proportions, while TIEs performed on interstitial waters from marine sediments have identified only ammonia and organics as toxicants, with metals playing a minor role. Preliminary evidence from whole sediment TIEs indicates that organic compounds play a major role in the toxicity of marine sediments, with almost no evidence for either metal or ammonia toxicity. However, interpretation of these results may be skewed because only a small number of interstitial water (n = 13) and whole sediment (n = 5) TIEs have been completed. These trends may change as more data are collected.  相似文献   

Reliability of dipole-dipole electrical resistivity tomography for defining depth to bedrock in covered karst terranes     

W. Zhou  B. F. Beck  J. B. Stephenson 《Environmental Geology》2000,39(7):760-766

 Sinkhole collapse is one of the main limitations on the development of karst areas, especially where bedrock is covered by unconsolidated material. Studies of sinkhole formation have shown that sinkholes are likely to develop in cutter (enlarged joint) zones as a result of subterranean erosion by flowing groundwater. Because of the irregular distribution of pinnacles and cutters on the bedrock surface, uncertainties arise when "hit-or-miss" borehole drilling is used to locate potential collapse sites. A high-resolution geophysical technique capable of depicting the details of the bedrock surface is essential for guiding the drilling program. Dipole-dipole electrical resistivity tomography (ERT) was used to map the bedrock surface at a site in southern Indiana where limestone is covered by about 9 m of clayey soils. Forty-nine transects were conducted over an area of approximately 42,037 m². The electrode spacing was 3 m. The length of the transects varied from 81 to 249 m. The tomographs were interpreted with the aid of soil borings. The repeatability of ERT was evaluated by comparing the rock surface elevations interpreted from pairs of transects where they crossed each other. The average difference was 2.4 m, with a maximum of 10 m. The discrepancy between interpreted bedrock-surface elevations for a transect intersection may be caused by variations in the subsurface geology normal to the transect. Averaging the elevation data interpreted from different transects improved the ERT results. A bedrock surface map was generated using only the averaged elevation data at the transect junctions. The accuracy of the map was further evaluated using data from four exploratory boreholes. The average difference between interpreted and actual bedrock surface-elevations was less than 0.4 m. The map shows two large troughs in the limestone surface: one coinciding with an existing sinkhole basin, while the other is in alignment with a small topographic valley. Because sinkholes were observed at the same elevation interval in similar valleys in the vicinity, the delineated trough may have implications for future land use at the site. Received: 4 January 1999 · Accepted: 8 March 1999  相似文献   

Thinking About Global Warming     

Jonathan Baron 《Climatic change》2006,77(1-2):137-150

Attitudes toward global warming are influenced by various heuristics, which may distort policy away from what is optimal for the well-being of people. These possible distortions, or biases, include: a focus on harms that we cause, as opposed to those that we can remedy more easily; a feeling that those who cause a problem should fix it; a desire to undo a problem rather than compensate for its presence; parochial concern with one’s own group (nation); and neglect of risks that are not available. Although most of these biases tend to make us attend relatively too much to global warming, other biases, such as wishful thinking, cause us to attend too little. I discuss these possible effects and illustrate some of them with an experiment conducted on the World Wide Web.  相似文献   

The influence of human activity in the Arctic on climate and climate impacts   总被引：1，自引：0，他引：1  

Henry P. Huntington  Michelle Boyle  Gwenn E. Flowers  John W. Weatherly  Lawrence C. Hamilton  Larry Hinzman  Craig Gerlach  Rommel Zulueta  Craig Nicolson  Jonathan Overpeck 《Climatic change》2007,82(1-2):77-92

Human activities in the Arctic are often mentioned as recipients of climate-change impacts. In this paper we consider the more complicated but more likely possibility that human activities themselves can interact with climate or environmental change in ways that either mitigate or exacerbate the human impacts. Although human activities in the Arctic are generally assumed to be modest, our analysis suggests that those activities may have larger influences on the arctic system than previously thought. Moreover, human influences could increase substantially in the near future. First, we illustrate how past human activities in the Arctic have combined with climatic variations to alter biophysical systems upon which fisheries and livestock depend. Second, we describe how current and future human activities could precipitate or affect the timing of major transitions in the arctic system. Past and future analyses both point to ways in which human activities in the Arctic can substantially influence the trajectory of arctic system change.  相似文献   

Methodological problems of intercultural comparisons of retail environments     

Jonathan Reynolds 《GeoJournal》1998,45(4):245-254

The internationalising activities of retailers have tended to precede the theoretical contributions of academics. This is particularly the case for the cultural context within which retail internationalisation takes place. Following an examination of the growth of international retailing activity, the article reviews generic difficulties in studying inter-cultural differences before considering the specific steps which retail practitioners have taken to understand the comparative characteristics of retail and consumer markets through the growth of geodemographic and lifestyle analysis. Finally, we relate one of the most significant integrative intercultural theoretical instruments to the case of retail internationalisation within Western Europe. We find that significant insights into retailer behaviour and strategy can be gained from an understanding of the culturally-specific characteristics of the activity. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The behaviour of ulvöspinel samples containing magnetized inclusions     

R.J. Veitch  A. Stephenson 《Physics of the Earth and Planetary Interiors》1978,16(3):209-214

Composite samples containing either magnetized iron or a ferrite magnet embedded in ulvöspinel have been cooled through the ulvöspinel Curie point. The observed changes in magnetic moment which occur are shown to be a result of TRM acquisition in the ulvöspinel rather than an effect of high permeability. Nevertheless by defining an effective permeability of about (1 + TRM/H), magnetostatic theory relevant to magnetized inclusions in a permeable medium can be applied to explain the main features observed in this system.  相似文献   

A major lava tube system from Undara Volcano,North Queensland     

A. Atkinson  T. J. Griffin  P. J. Stephenson 《Bulletin of Volcanology》1975,39(2):266-293

The Undara Volcano erupted 0.19 m.y. ago and formed lava fields covering 1,500 km² with a volume of approximately 23 km³. One of the flows extended 160 km on a gradient that averaged only 0.3°. This great length was a result of very high effusion rates, favourable topography and lava tube efficiency. The Undara lavas are rather uniform hawaiites. Lava temperatures are estimated to have been somewhat less than 1175–1220°C and viscosities greater than 10 to 30 Pa s. Long, apparently single lava tubes are well preserved in many places. They are marked by depressions, caves and long level ridges. A system of lava tubes extends for perhaps more than 100 km. The features of the lava tubes are comparable with those described elsewhere. Aligned depressions associated with caves appear to have formed contemporaneously. Most are much wider than the caves and probably represent collapsed lava ponds. The lava tubes appear to have formed by roofing over of lava channels. Close to lava tubes, the rocks developed strongly oxidised characteristics, such as oxidised olivine phenocrysts, ferric clinopyroxene and extensively developed hematite. Differentiated lava forms drips in some caves and is also oxidised.  相似文献   

Toward spatial understanding of environmentally-based voluntary groups     

Larry K. Stephenson 《Geoforum》1979,10(2):195-201

An attempt is made in this paper to complement existing analyses of voluntary groups by outlining some additional explicitly spatial dimensions which, it is argued, can be useful in examining those organizations with a land use or environmental focus. The distinction is drawn between groups which have direct spatial links and those with indirect spatial links; the hierarchical subdivision of space is considered; the role of scale and its relation to perception and desired use of areas is addressed; and the importance of considering the resolution scale of land use and environmental conflicts noted.  相似文献   

Coexisting garnets and biotites from Precambrian gneisses of the south coast of Western Australia     

N.C.N. Stephenson 《Lithos》1979,12(2):73-87

Garnet-biotite (-cordierite) phase relations in high-grade gneisses of the south coast of Western Australia reflect at least two metamorphic episodes. Chemical uniformity of the interiors of garnet and cordierite grains suggest thorough equilibration during a major phase of metamorphism. Narrow Mg-depleted rims on garnet grain boundaries in contact with biotite or cordierite, and complementary Mg-enriched rims on contiguous cordierites are the result of subsequent retrograde re-equilibration. The absence of reaction zoning in biotites suggests more complete retrograde modification of this mineral.Comparison between granulite and amphibolite facies garnet-biotite pairs shows that Mn contents of both minerals are higher, and Ti contents of the biotites are lower, in the lower-grade rocks. These differences, although not entirely unrelated to grade, are more directly controlled by variations in host rock chemistry and modal amounts of garnet and biotite.Partitioning of Mg, Fe²⁺ and Mn between garnet and biotite is fairly uniform, with no clear differences between granulite and amphibolite facies pairs. Application of the Mg-Fe²⁺ distributions to the geothermometers devised by Perchuk, Thompson, and Goldman & Albee yields variable T estimates of 600–680°C, 580–780°C, and 475–715°C respectively, for the main metamorphism. These estimates are low compared with the T indicated for the granulite facies rocks by other evidence (i.e. > 750°C at 5 kb P_T). The Mg-Fe²⁺ distributions between contiguous garnet-biotite rims suggest that retrograde re-equilibration occurred at least 20–140°C below the T of the main metamorphism.  相似文献