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1.
Toxicity Identification Evaluations (TIEs) can be used to determine the specific toxicant(s), including ammonia, causing toxicity observed in marine sediments. Two primary TIE manipulations are available for characterizing and identifying ammonia in marine sediments: Ulva lactuca addition and zeolite addition. In this study, we compared the efficacy of these methods to (1) remove NH(x) and NH(3) from overlying and interstitial waters and (2) reduce toxicity to the amphipod Ampelisca abdita and mysid Americamysis bahia using both spiked and environmentally contaminated sediments. The utility of aeration for removing NH(x) and NH(3) during a marine sediment TIE was also evaluated preliminarily. In general, the U. lactuca and zeolite addition methods performed similarly well at removing spiked NH(x) and NH(3) from overlying and interstitial waters compared to an unmanipulated sediment. Toxicity to the amphipod was reduced approximately the same by both methods. However, toxicity to the mysid was most effectively reduced by the U. lactuca addition indicating this method functions best with epibenthic species exposed to ammonia in the water column. Aeration removed NH(x) and NH(3) from seawater when the pH was adjusted to 10; however, very little ammonia was removed at ambient pHs ( approximately 8.0). This comparison demonstrates both U. lactuca and zeolite addition methods are effective TIE tools for reducing the concentrations and toxicity of ammonia in whole sediment toxicity tests.  相似文献   

2.
The toxicity of sediments in the Gulf of Gdansk is analyzed in relation to the chemical composition of interstitial and near‐bottom waters, and sediment properties. The toxicity of sediments, pore waters and saline elutriates is determined by using the Microtox® test based on changes in light production of the luminescent bacteria Vibrio fischeri. The results indicate considerable toxicity in the majority of examined sediments. Since the sediment elutriates and pore waters are toxic in some cases, the total toxicity of the sediments is likely to be due to both sediment‐bound and water soluble substances. The sediment toxicity is related to the percentage contribution of the fine fraction of sediments. A significant correlation between the toxicity of the sediments and the black carbon content implies anthropogenic contamination. The toxicity of the sediments is seen to increase with the increase of hydrogen sulfide concentration in pore waters. The ammonia in pore waters was found not to be responsible for the toxicity of the sediments.  相似文献   

3.
Marine sediment can function both as a source and as a sink of marine chemical contaminants. The toxicity of contaminated marine sediment can be assessed by toxic evaluation of its pore water, the inter-particle water of sediment, because toxicants in the pore water may be bioavailable to marine organisms. In this study, the toxicity identification evaluation (TIE) was performed to identify the major toxicants in the pore water of marine sediment collected in Hong Kong waters. In Phase 1 TIE, the suspected toxicants were characterized as anions or organic compounds that are either oxidizable or filterable in alkaline medium. In Phase 2 TIE, the suspected toxicants were identified as sulfide (S2−) based on the reduction of toxicity due to lowering of sulfide concentrations by experimental manipulations. The mass balance and spiking analyses in Phase 3 confirmed that S2− was one of the major toxicants and that some non-toxic unknown compounds measured by LC–MS, which was removed by C18 solid phase extraction, enhanced the toxicity of S2− in the pore water samples.  相似文献   

4.
During the Soviet era, Ukraine was an important industrial and agricultural region of the Soviet Union. This industrial and agricultural activity resulted in contamination of Ukraine’s estuaries with legacy anthropogenic pollutants. Investigations on the toxicological effects of this estuarine contamination have been limited. For this research, we measured the toxicity of contaminated sediments from four Ukrainian estuaries to several aquatic organisms over 3 years. Sediment chemical analyses and whole sediment toxicity identification evaluations (TIEs) were also performed to determine the classes of contaminants contributing to toxicity. Toxic sediments were observed in several of the Ukrainian estuaries and chemical analyses of the sediments demonstrated anthropogenic contaminants were widely distributed. Contaminants were also detected in macrobenthic organisms collected from the sediments. Several lines of evidence, including TIEs, indicated hydrophobic organic chemicals (HOCs) were contributing substantially to observed toxicity. This information can guide environmental managers to prioritize portions of the estuaries requiring remediation.  相似文献   

5.
Sediment toxicity in silty marine harbor sediments is frequently dominated by ammonia or sulfide, leaving the adverse effects of persistent toxic substances unnoticed. To investigate the latter, we subjected interstitial water from three contaminated silty sediments to toxicity identification evaluation (TIE) phase I manipulations and tested for toxicity with four bioassays: the amphipod Corophium volutator (survival as an endpoint), the sea urchin Psammechinus miliaris (fertilization, embryo development) and the bacterium Vibrio fischeri (bioluminescence inhibition).The graduated pH manipulations identified the prominent toxicity of ammonia in the amphipod and sea urchin embryo tests, and also sulfide toxicity in the bacterium test. In two of the three samples tested with the amphipods, sea urchin embryos and bacteria, a small but significant reduction in interstitial water toxicity was achieved by removing persistent compounds through C(18) solid phase extraction. EDTA chelation resulted in a slight detoxification of the interstitial water for the amphipods and sea urchin embryos, but this was not related to any measured trace metals. Despite the presence of toxic levels of ammonia and sulfide in the harbor sediments, we established the adverse biological effects of persistent constituents by means of the TIE manipulations and in vivo interstitial water bioassays.  相似文献   

6.
Feminization of fish has been reported throughout the world in freshwater and marine systems. While the population impacts are conflictive, enough negative effects warrant additional research into causation. In order to ascertain the identities of specific feminizing agents, variants of toxicity identification evaluations (TIEs) have been employed. The majority of these evaluations have utilized in vitro estrogen receptor-based cell-lines to identify chromatographic fractions that possess biological activity from predominately wastewater derived from municipal treatment facilities and have concluded that synthetic and natural estrogens are the primary cause for feminization of fish. This paper will focus on three aquatic systems impacted by wastewater originating from purely domestic, and industrial/domestic secondary treatment systems. Wastewater and sediment extracts were evaluated by in vitro and in vivo biological responses in a TIE fractionation design. While in vitro responses tended to mirror in vivo responses in purely domestic wastewater systems, in vitro responses tended to severely underestimate in vivo estrogenic activity when normalized to estradiol equivalents in more complex systems. TIE fractionation schemes using in vivo biological responses failed to indicate any relationship to steroids in either wastewater or sediment extractions. These data consistently support the view that mechanisms other than direct ER binding and activation by toxicants may be important in the feminization of fish particularly residing in habitats that receive complex wastewater or agricultural effluents.  相似文献   

7.
《Marine pollution bulletin》2009,58(6-12):250-254
Feminization of fish has been reported throughout the world in freshwater and marine systems. While the population impacts are conflictive, enough negative effects warrant additional research into causation. In order to ascertain the identities of specific feminizing agents, variants of toxicity identification evaluations (TIEs) have been employed. The majority of these evaluations have utilized in vitro estrogen receptor-based cell-lines to identify chromatographic fractions that possess biological activity from predominately wastewater derived from municipal treatment facilities and have concluded that synthetic and natural estrogens are the primary cause for feminization of fish. This paper will focus on three aquatic systems impacted by wastewater originating from purely domestic, and industrial/domestic secondary treatment systems. Wastewater and sediment extracts were evaluated by in vitro and in vivo biological responses in a TIE fractionation design. While in vitro responses tended to mirror in vivo responses in purely domestic wastewater systems, in vitro responses tended to severely underestimate in vivo estrogenic activity when normalized to estradiol equivalents in more complex systems. TIE fractionation schemes using in vivo biological responses failed to indicate any relationship to steroids in either wastewater or sediment extractions. These data consistently support the view that mechanisms other than direct ER binding and activation by toxicants may be important in the feminization of fish particularly residing in habitats that receive complex wastewater or agricultural effluents.  相似文献   

8.
Toxicity of 1,4-dichlorobenzene in sediments to juvenile polychaete worms   总被引：1，自引：0，他引：1  
Investigation of sediment contamination associated with a marine sewage outfall in Victoria (BC, Canada) found elevated concentrations of 1,4-dichlorobenzene (1,4-DCB). Juvenile polychaete worm (Neanthes) growth was significantly reduced at or near the outfall, roughly corresponding to elevated 1,4-DCB concentrations. There are few data on 1,4-DCB toxicity to marine organisms and no published literature on its toxicity to benthic marine organisms. To determine whether reduced polychaete growth (measured as dry weight) was due to 1,4-DCB exposure, a laboratory investigation was conducted. Uncontaminated marine sediment was spiked with 1,4-DCB and juvenile Neanthes were exposed in 20-d sublethal toxicity tests. There were no adverse effects on survival at any test concentration; mean survival was 80–100%. Statistically significant decreases in average dry weight only occurred at the highest 1,4-DCB concentration (19,900 μg/kg, dry weight); this represented a 1,4-DCB concentration more than 10 times higher than previously measured at the outfall (1710 μg/kg, dry weight). There were no adverse effects on survival or dry weight at the range of concentrations previously measured in sediments from the vicinity of the outfall.  相似文献   

9.
Kim E  Jun YR  Jo HJ  Shim SB  Jung J 《Marine pollution bulletin》2008,57(6-12):637-644
Because of complexity and diversity of toxicants in effluent, chemical analysis alone gives very limited information on identifying toxic chemicals to test organisms. Toxicity identification evaluation (TIE) techniques have been widely used to identify toxicants in various samples including industrial wastewater as well as natural waters. In response to new regulation for effluent discharge in Korea, which will be effective from 2011, a necessity of studies emerges that investigates toxicity levels in industrial effluents. This work was a preliminary study examining toxicity levels in effluent from one metal plating factory using Daphnia magna (48 h immobility) and identifying toxicity-causing substances. Toxicity tests showed variability on different sampling occasions and the results of TIE methods indicated that both organic compounds and metals contributed to the observed toxicity in metal plating effluent. Further studies are necessary to help reduce effluent toxicity especially from direct dischargers, who will have to comply with the new regulation.  相似文献   

10.
Heavy metal contamination levels are generally higher in estuaries than in the open sea. Some estuaries, the Seine estuary for example, have particularly high pollution levels of metals, yet continue to support a very high benthic biomass and remain quite productive. Measurements of sediment contamination are highly variable due to diverse chemical analysis methods, sediments origin and sources of contaminants found in the estuaries. Salinity appears to be the principal factor controlling contaminant distribution in the sediment and the overlying and/or interstitial waters; it also affects the bioavailability of contaminants in estuarine sediments. Of course, the response to contaminants varies greatly among species and assemblages. Trace metals explain only a small part of the variation in benthic community structure. Some species, such as the shrimp Crangon crangon, appears vulnerable to metal pollution, while other species, such as Scrobicularia plana, are able to tolerate quite high levels of cadmium in their tissue. This paper demonstrates the wide variability of benthic responses to contamination, which is probably due to the high spatio-temporal heterogeneity of the estuary. To reduce the problems due the heterogeneity and variability observed to date in the available results, it will be necessary to encourage integrated estuarine studies, in which sedimentologists, chemists, and biologists work together on the same campaigns at the same sites.  相似文献   

11.
《国际泥沙研究》2019,34(4):368-378
Sediment quality has been evaluated in a variety of ways since the early 1990 s in studies from Europe. In South Korea, most studies have used an indicator value for benthic macroinvertebrates based on water quality, not sediment quality. To date, few studies have examined the biological integrity of benthic macroinvertebrate communities in South Korea. In the current study, the tolerance valency and value in samples and the indicator weight values were measured for 43 benthic macroinvertebrate taxa from 73 sampling units in South Korea from 2014 to 2016. Total organic carbon, the amount of heavy metals, and total ammonia nitrogen were analyzed. The average grade for each pollutant was used as the sediment quality index. A benthic macroinvertebrates sediment index was developed for bioassessment of freshwater sediment. The benthic macroinvertebrates sediment index, which is based on the relative frequency of occurrence of macroinvertebrates, was highly correlated with pollution levels in the sediment. This index can be used in the field to assess the contamination of freshwater sediment. As the sample size was small in the current study and there were taxonomic limitations of Chironomidae larvae,further research is needed to improve the reliability of the benthic macroinvertebrates sediment index.  相似文献   

12.
Multiple Discriminant Analysis of Marine Sediment Data   总被引：2，自引：0，他引：2  
A multivariate statistical approach was used in the analysis of inter-relationships among marine benthic infaunal structure, physical and chemical characteristics of sediment samples and toxicity data derived from laboratory tests at 16 locations in shallow, inshore waters of Hong Kong. The method involved classification (cluster analysis using the Bray–Curtis similarity index) and ordination (multi-dimensional scaling) of infaunal patterns and the use of multiple discriminant analysis to relate groupings of the locations to the selected environmental and toxicity data. Analysis of the combined sediment physical, biological, chemical and toxicity dataset by stepwise multiple discriminant analysis allowed identification of those variables most sensitive for discriminating location groups. The use of multiple discriminant analysis in sediment quality characterization was evaluated against the Sediment Quality Triad approach and other statistical techniques.  相似文献   

13.
Programs for evaluating proposed discharges of dredged material into waters of the United States specify a tiered testing and evaluation protocol that includes performance of acute and chronic bioassays to assess toxicity of the dredged sediments. Although these evaluations reflect the toxicological risks associated with disposal activities to some degree, analysis activities are limited to the sediments of each dredging project separately. Cumulative risks to water column and benthic organisms at and near the designated disposal site are therefore difficult to assess. An alternate approach is to focus attention on the disposal site, with the goal of understanding more directly the risks of multiple disposal events to receiving ecosystems. Here we review current US toxicity testing and evaluation protocols, and describe an application of ecological risk assessment that allows consideration of the temporal and spatial components of risk to receiving aquatic ecosystems. When expanded to include other disposal options, this approach can provide the basis for holistic management of dredged material disposal.  相似文献   

14.
The Mid-Atlantic Integrated Assessment (MAIA-Estuaries) evaluated ecological conditions in US Mid-Atlantic estuaries during the summers of 1997 and 1998. Over 800 probability-based stations were monitored in four main estuarine systems--Chesapeake Bay, the Delaware Estuary, Maryland and Virginian coastal bays, and the Albemarle-Pamlico Estuarine System. Twelve smaller estuaries within the four main systems were also assessed to establish variance at the local scale. A subset of the MAIA-Estuaries data is used here to estimate the extent of eutrophication, sediment contamination, and benthic degradation in mid-Atlantic estuaries. An Environmental Report Card and Index of Environmental Integrity summarize conditions in individual estuaries, the four estuarine systems, and the entire MAIA region. Roughly 20-50% of the region showed signs of eutrophication (high nutrients, excessive production of organic matter, poor water clarity, or depleted dissolved oxygen), 30% had contaminated sediments, and 37% had degraded benthic communities. Compared with the Environmental Monitoring and Assessment Program (EMAP)-Virginian Province study in 1990-1993, larger fractions of Chesapeake Bay (17%) and Delaware River (32%) had increased metals or organics in sediments.  相似文献   

15.
Dissolved Zn, Cu and Cd concentrations in interstitial waters collected from a lacustrine mine tailings deposit indicate that the tailings are not releasing heavy metals to the overlying lake water at present, and there is no evidence to suggest that significant oxidation is occurring in the deposit. The lake waters are enriched in metals from surface drainage, however, while pore waters in natural sediments are heavy-metal-depleted. Diffusion into the natural sediments therefore tends to buffer the lacustrine metal load, but only to a very limited extent.  相似文献   

16.
The sedimentology of the floor of the Amvrakikos Gulf, a river influenced, semi-enclosed relatively shallow-silled embayment, lying along the northeastern Hellenic coast of the Ionian Sea (eastern Mediterranean Sea), is investigated with respect to its origin (terrigenous and/or biogenic), the prevailing oceanographic conditions and human interference. Nearshore (water depths approximately <10 m) sediments, especially along the northern margin of the Gulf, consist mostly of biogenic sands, as the result of water exchange between the freshwater lagoonal waters and the surface waters of the Gulf. An exception to this is the mouth area of the Arachthos River, which is dominated by the terrigenous riverine sediment influx. The offshore (water depths >10 m) bottom surficial sediments are fine-grained (silty and clayey) of terrigenous origin (>70%); this is attributed to the inter-seasonal, strong two-layer stratification of the water column in the Gulf which restricts benthic productivity by inhibiting the downward flux of surface eutrophic waters and the development of nearbed disoxic conditions in water depths >40 m. River damming has reduced also the riverine terrigenous sediment supply; this is more profound in the case of the Arachthos River where not only the deltaic evolution has been affected, but also the textural character of the seabed sediments of the mouth area has been altered; this is expected to influence the benthic communities of prodeltaic surficial sediment.  相似文献   

17.
《Marine pollution bulletin》2009,58(6-12):681-688
A laboratory study was carried out to investigate the influence of the biomass content in the sediment on the rate of diagenesis of particulate organic materials (POM) and the consequent sediment oxygen demand (SOD) and nutrient fluxes. Fish food pellets were loaded into the sediment to simulate a sudden POM input. Three types of sediments with different biomass contents were tested, including a raw marine sediment, the marine sediment after one month of cultivation and an artificial sediment of sand and clay without any biomass. There was little difference in organic flux from the three different sediments. However, compared to the artificial sediment, the marine sediments had much higher SOD and ammonia flux. A mathematical model also has been developed for the SOD dynamics and nutrient fluxes. Both the experimental and simulation results indicate the important role of the biomass in the sediment in POM diagenesis, SOD and nutrient fluxes.  相似文献   

18.
The Axios River (Axios R.) receives substantial loads of nutrients, heavy metals and other compounds, resulting from anthropogenic activities within its catchment. Long-term trends in nutrients were assessed. Dissolved and particulate fluxes of nutrients and selected metals to the Thermaikos Gulf were calculated and finally, data evaluation with water and sediment quality criteria was performed. Dissolved nutrient concentrations exhibited intra-annual variations related to the agricultural practices of the drainage area with elevated autumn–winter NO3 concentrations (related to fertilizers applied early spring) and high levels of total phosphorous in the summer attributed to point source pollution. Long-term inter-annual variability showed a 2.5-fold increase in nitrate concentration, coupled with a 3-fold decrease in water discharge. Elevated concentrations of dissolved Pb and As have been observed in the Axios R., and freshwater quality criteria for Pb were exceeded. Stream sediments exhibited high contents for Zn, Cr, Pb, and As, mainly originating in tailings and industrial effluents. On the other hand, a considerable portion of the heavy metals is derived from the weathering of ultra-mafic ophiolite complexes. Similar patterns were observed in the Thermaikos Gulf sediment chemistry; the geochemical signatures of the Axios and Aliakmon Rivers (Aliakmon R.), in respect to their contribution in heavy metals, were identified, as well as the impact of the Thessaloniki city. Quality criteria for both river and marine sediments were violated for As and Cr. Overall, the water and sediment quality of the Axios R. and the Thermaikos Gulf have been impacted by anthropogenic activities in the hinterland. The coastal waters and sediments do not appear to pose any threat to human health and aquatic life, however, the need for regular monitoring is highly recommended.  相似文献   

19.
The submarine sewage outfall of Santos (SSOS) is situated in the Santos Bay (São Paulo, Brazil) and is potentially a significant source of contaminants to the adjacent marine ecosystem. The present study aimed to assess the influence of SSOS on the sediment toxicity and contamination at Santos Bay. At the disposal site, sediments tended to be finer, organically richer and exhibited higher levels of surfactants and metals, sometimes exceeding the “Threshold Effect Level” values. The SSOS influence was more evident toward the East, where the sediments exhibited higher levels of TOC, total S and metals during the summer 2000 sampling campaign. Sediment toxicity to amphipods was consistently detected in four of the five stations studied. Amphipod survival tended to correlate negatively to Hg, total N and % mud. This work provides evidence that the SSOS discharge affects the quality of sediments from Santos Bay, and that control procedures are warranted.  相似文献   

20.
A laboratory study was carried out to investigate the influence of the biomass content in the sediment on the rate of diagenesis of particulate organic materials (POM) and the consequent sediment oxygen demand (SOD) and nutrient fluxes. Fish food pellets were loaded into the sediment to simulate a sudden POM input. Three types of sediments with different biomass contents were tested, including a raw marine sediment, the marine sediment after one month of cultivation and an artificial sediment of sand and clay without any biomass. There was little difference in organic flux from the three different sediments. However, compared to the artificial sediment, the marine sediments had much higher SOD and ammonia flux. A mathematical model also has been developed for the SOD dynamics and nutrient fluxes. Both the experimental and simulation results indicate the important role of the biomass in the sediment in POM diagenesis, SOD and nutrient fluxes.  相似文献   

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