Mercury speciation in surface and deep waters of the Mediterranean Sea     

Jože Kotnik  Milena Horvat  Emmanuel Tessier  Nives Ogrinc  Mathilde Monperrus  David Amouroux  Vesna Fajon  Darija Gibičar  Suzana Žižek  Francesca Sprovieri  Nicola Pirrone 《Marine Chemistry》2007

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California     

Jeffrey N. Cross  John T. Hardy  Jo Ellen Hose  G.Patrick Hershelman  Liam D. Antrim  Richard W. Gossett  Eric A. Crecelius 《Marine environmental research》1987,23(4)

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.  相似文献   

Evaluation of bending moments and shear forces at unit connections of very large floating structures using hydroelastic and rigid body analyses   总被引：1，自引：0，他引：1  

Byoung Wan Kim  Sa Young Hong  Jo Hyun Kyoung  Seok Kyu Cho 《Ocean Engineering》2007,34(11-12):1668-1679

This paper investigates the characteristics of bending moments, shear forces and stresses at unit connections of very large floating structures (VLFS) under wave loads. The responses of VLFS are calculated by solving multi-body motion equation considering hydroelasticity and connection stiffness. Hydroelastic responses are calculated by the direct method. Higher-order boundary element method (HOBEM) is used for fluid analysis and finite element method (FEM) is introduced for structural analysis. The equation of motion is modified to describe the unit connections by employing spring elements. Bending moments and shear forces at the connections are obtained from the dynamic equilibrium condition for pressures and inertia forces. Two types of VLFS units such as tandem arranged units and side-by-side arranged units are considered in the numerical examples. The influences of connection stiffness, wave frequency and heading angle on responses of VLFS are investigated through the numerical examples. Rigid body analysis along with hydroelastic analysis is also carried out in the numerical analysis and comparison of those two approaches is discussed.  相似文献   

Remote sensing and surface POC concentration in the South Atlantic   总被引：1，自引：0，他引：1  

Alexey V. Mishonov  Wilford D. Gardner  Mary Jo Richardson 《Deep Sea Research Part II: Topical Studies in Oceanography》2003,50(22-26):2997

Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.  相似文献   

Guest Editors’ Foreword     

Miran Veselič  Heinz Hoetzl  Božidar Biondič  Jože Pezdič 《Environmental Geology》2006,49(6):795-795

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Water temperature behaviour in the River Loire since 1976 and 1881     

Florentina Moatar  Joël Gailhard 《Comptes Rendus Geoscience》2006,338(5):319-328

Analysis of monthly mean river temperatures, recorded on an hourly basis in the middle reaches of the Loire since 1976, allows reconstruction by multiple linear regression of the annual, spring and summer water temperatures from equivalent information on air temperatures and river discharge. Since 1881, the average annual and summer temperatures of the Loire have risen by approximately 0.8?°C, this increase accelerating since the late 1980s due to the rise in air temperature and also to lower discharge rates. In addition, the thermal regime in the Orleans to Blois reach is considerably affected by the inflow of groundwater from the Calcaires de Beauce aquifer, as shown by the summer energy balance. To cite this article: F. Moatar, J. Gailhard, C. R. Geoscience 338 (2006).  相似文献   

T-distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo Røislien  Henning Omre 《Mathematical Geosciences》2006,38(7):821-849

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T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Deformability characteristics of brazilian laterites     

Jacques De Medina  Laura M. G. Motta  João D. G. Dos Santos 《Geotechnical and Geological Engineering》2006,24(4):949-971

This paper summarizes the resilient and permanent deformation characteristics of laterite gravels, determined by cyclic loading in triaxial tests of compacted specimens. A study of laterite pavements was carried out on eight paved road sections in the state of Mato Grosso. Also reported is the influence of fine sand admixture, specimen size and soaking in two laterite samples from Roraima and Rondônia in the North of Brazil. The experimental relationships of resilient moduli against applied stresses are interpreted empirically for models what may be incorporated in a structural analysis of full depth of laterite pavement.  相似文献   

Site Investigation for the Effects of Vegetation on Ground Stability     

John R. Greenwood  Joanne E. Norris  Jo Wint 《Geotechnical and Geological Engineering》2006,24(3):467-481

The procedure for geotechnical site investigation is well established but little attention is currently given to investigating the potential of vegetation to assist with ground stability. This paper describes how routine investigation procedures may be adapted to consider the effects of the vegetation. It is recommended that the major part of the vegetation investigation is carried out, at relatively low cost, during the preliminary (desk) study phase of the investigation when there is maximum flexibility to take account of findings in the proposed design and construction. The techniques available for investigation of the effects of vegetation are reviewed and references provided for further consideration. As for general geotechnical investigation work, it is important that a balance of effort is maintained in the vegetation investigation between (a) site characterisation (defining and identifying the existing and proposed vegetation to suit the site and ground conditions), (b) testing (in-situ and laboratory testing of the vegetation and root systems to provide design parameters) and (c) modelling (to analyse the vegetation effects).  相似文献