Petrographic and geochemical evidence for the formation of primary, bacterially induced lacustrine dolomite: La Roda 'white earth' (Pliocene, central Spain)   总被引：1，自引：0，他引：1  

M. Angeles García Del Cura  Jose P. Calvo  Salvador Ordóñez  Blair F. Jones  & Juan C. Cañaveras 《Sedimentology》2001,48(4):897-915

Upper Pliocene dolomites (‘white earth’) from La Roda, Spain, offer a good opportunity to evaluate the process of dolomite formation in lakes. The relatively young nature of the deposits could allow a link between dolomites precipitated in modern lake systems and those present in older lacustrine formations. The La Roda Mg‐carbonates (dolomite unit) occur as a 3·5‐ to 4‐m‐thick package of poorly indurated, white, massive dolomite beds with interbedded thin deposits of porous carbonate displaying root and desiccation traces as well as local lenticular gypsum moulds. The massive dolomite beds consist mainly of loosely packed 1‐ to 2‐μm‐sized aggregates of dolomite crystals exhibiting poorly developed faces, which usually results in a subrounded morphology of the crystals. Minute rhombs of dolomite are sparse within the aggregates. Both knobbly textures and clumps of spherical bodies covering the crystal surfaces indicate that bacteria were involved in the formation of the dolomites. In addition, aggregates of euhedral dolomite crystals are usually present in some more clayey (sepiolite) interbeds. The thin porous carbonate (mostly dolomite) beds exhibit both euhedral and subrounded, bacterially induced dolomite crystals. The carbonate is mainly Ca‐dolomite (51–54 mol% CaCO₃), showing a low degree of ordering (degree of ordering ranges from 0·27 to 0·48). Calcite is present as a subordinate mineral in some samples. Sr, Mn and Fe contents show very low correlation coefficients with Mg/Ca ratios, whereas SiO₂ and K contents are highly correlated. δ¹⁸O‐ and δ¹³C‐values in dolomites range from ?3·07‰ to 5·40‰ PDB (mean=0·06, σ=1·75) and from ?6·34‰ to ?0·39‰ PDB (mean=?3·55, σ=1·33) respectively. Samples containing significant amounts of both dolomite and calcite do not in general show significant enrichment or depletion in ¹⁸O and ¹³C between the two minerals. The correlation coefficient between δ¹⁸O and δ¹³C for dolomite is extremely low and negative (r=?0·05), whereas it is higher and positive (r=0·47) for calcite. The lacustrine dolomite deposit from La Roda is interpreted mainly as a result of primary precipitation of dolomite in a shallow, hydrologically closed perennial lake. The lake was supplied by highly saturated HCO₃^?/CO₃^2? groundwater that leached dolomitic Mesozoic formations. Precipitation of dolomite from alkaline lake waters took place under a semi‐arid to arid climate. However, according to our isotopic data, strong evaporative conditions were not required for the formation of the La Roda dolomite. A significant contribution by bacteria to the formation of the dolomites is assumed in view of both petrographic and geochemical evidence.  相似文献   

Skarns and Genesis of the Huanggang Fe-Sn Deposit, Inner Mongolia, China   总被引：2，自引：0，他引：2  

Li Juan WANG  Hidehiko SHIMAZAKI  Yoshihide SHIGA 《Resource Geology》2001,51(4):359-376

Abstract: The skarns and genesis were studied of the Huanggang Fe‐Sn deposit and the nearby Sumugou Zn‐Pb deposit in Inner Mongolia, China. In the Huanggang mine, Nos. 1 to 4 Fe ore bodies are arranged along a calcareous horizon from proximal to distal in this order to a granite intrusion named Luotuochangliang, while Sn ore body is situated near another granite intrusion named 204. According to the distance from the granitic intrusions, mineral assemblages in skarns are systematically changed. Garnet is the most predominant skarn mineral throughout the deposit. Hastingsitic amphiboles, however, predominate in the proximal skarns. Fluorite is common in the proximal skarns, while instead calcite is common in the distal skarns. Chlorite is characteristically present only in No. 3 ore body, and chlorite geothermometry gives near 300C for the mineralization of later stage. When garnet crystal shows zonal structure, isotropic andraditic garnet occupies the core, and is surrounded with anisotropic less‐andraditic garnet. The presence of white skarn along the boundary between main skarns and host sedimentary rocks confirms relatively reducing environment prevailing as a whole in the studied area. However, the compositional relation between coexisting garnet and clinopyroxene demonstrates that relatively oxidizing condition was achieved for garnet skarn and magnetite ore in the distal, Nos. 2 to 4 Fe ore bodies and Sumugou deposit, compared to that for garnet skarn in the proximal, No. 1 and Sn ore bodies. Preliminary study on the tin content of garnets in the studied area revealed a certain degree of contribution brought from granitic intrusives since the early stage of skarn formation, irrespective of proximal or distal. Oxygen isotope study on garnet, magnetite, quartz and skarn calcite, as well as hydrogen isotope study on hastingsitic amphibole, demonstrates mainly meteoric water origin for the skarn– and ore‐forming solutions. The occurrence of Sn, W, Mo and F minerals indicates that those elements were mainly supplied to the deposit later than the formation of skarns and iron ores, overlapping to them. These constraints allow to delineate the formation model of the deposit as follows (Fig. 10): At the time of late Jurassic to early Cretaceous, felsic activity occurred in this region as a part of Yanshanian magmatism, and formed granitic intrusions as well as thick volcanic piles on the surface. The circulation of meteoric water was provoked by the heat brought by the intrusions. By this circulation, much amount of iron was extracted from andesites of the Dashizhai Formation, and precipitated as skarns and magnetite ores along calcareous horizons near the bottom of the Huanggangliang Formation. Subsequently, volatile‐rich fluids with Sn, W and Mo were expelled from the solidifying granitic magmas, and precipitated these metals in the pre‐existing skarns and ores.  相似文献   

Ponderomotive effects in magnetospheric hydromagnetic waves     

W. Allan  J. R. Manuel 《Annales Geophysicae》1996,14(9):893-905

The ponderomotive force (PMF) is a ubiquitous nonlinear wave effect arising in plasma physics when applied wave fields or plasma parameters have significant spatial gradients. Some basic properties of the PMF are described as they relate to ULF hydromagnetic waves in the magnetosphere. Examples are given of recent results obtained using both analytical and numerical techniques for waves from the lowest frequencies (determined by the dimensions of the magnetosphere) up to the vicinity of the ion cyclotron frequency. These results include the possibilities that the PMF may transport plasma over large distances in the magnetosphere, and that the PMF may energize magnetospheric ions significantly. In particular the PMF may play a role in transporting and energizing O⁺ ions from the ionosphere into the body of the magnetosphere. The PMF can also generate nonlinear coupling between the slow magnetosonic mode and the other hydromagnetic modes. This should lead to limitation of density enhancements and, notably in the case of standing Alfvén waves, to spatial harmonic generation, secularly growing frequency shifts, and saturation of driven wave fields. Some implications of these results for the magnetosphere are discussed.Based on an invited review given in IAGA Symposium 3.07, Nonlinear and Kinetic Effects in ULF Waves, at the IUGG XXI General Assembly, Boulder, Colorado, July 2-14, 1995.  相似文献   

NO2 total column evolution during the 1989 spring at Antarctica Peninsula     

Manuel Gil  Javier Cacho 《Journal of Atmospheric Chemistry》1992,15(2):187-200

Ground-based visible differential absorption spectrometry during twilight has been used for NO₂ total column observations at the Antarctica Peninsula, Marambio Base (64S, 56W), during the austral spring of 1989 (9 September to 25 November).Results show moderate NO₂ vertical column levels of 1.5 to 2.5×10¹⁵ molec cm^-2 in the morning and 2 to 3×10¹⁵ molec cm^-2 in the evening until middle October, highly modulated by planetary wave activity. From that date until the end of the period, a steady increase occurs which is associated with the rising of lower stratosphere temperature as the vortex weakens, reaching values of 5×10¹⁵ molec cm^-2 in late November, with small a.m.-p.m. differences. NO₂ is found to be positively correlated to both total ozone and 50 hPa temperature during the entire spring. However, when analyzing the departures from linear trends, a highly negative correlation has been observed from day 301 onwards.  相似文献   

广西丹池成矿带芒场矿田岩浆岩源区特征及锆石U-Pb年龄分析   总被引：1，自引：0，他引：1  

伍静  苑宏伟  甘能俭  韦绍成  廖娟  张健  梁华英 《岩石学报》2020,36(5):1586-1596

丹池成矿带是我国重要锡多金属成矿带,过去对丹池成矿带成岩成矿研究主要集中在大厂矿田及五圩矿田,而对丹池成矿带北部的芒场矿田岩浆作用时代、源区特征及其成矿性缺少分析。芒场矿田岩浆活动强烈,发育隐伏斑状花岗岩及有关的花岗斑岩脉和隐伏细粒花岗斑岩及有关的白云母花岗斑岩脉。本文分析花岗斑岩脉U-Pb年龄及花岗斑岩脉和白云母花岗斑岩脉主、微量元素组成,以探讨岩浆活动时代、岩浆源区特征及其成矿潜力。芒场矿田花岗斑岩脉锆石U-Pb年龄为89.1±0.9Ma (MSWD=0.9),和丹池成矿带内大厂矿田岩浆活动时代相近,表明丹池成矿带岩浆活动时代都发生于90Ma左右。白云母花岗斑岩脉具高A/CNK比值(2.69～2.88),含高铝硅酸盐矿物白云母及在Th-Rb图上沿S型花岗岩趋势线分布,和大厂矿田S型黑云母花岗岩的特征基本一致,表明其主要为S型花岗岩。花岗斑岩脉形成时代晚于白云母花岗斑岩脉,但其具有更低的SiO_2含量和更高的MgO、Fe_2O_3~T、CaO和TiO_2含量,且在SiO_2与TiO_2、Fe_2O_3~T、Al_2O_3和P_2O_5关系图中分布于不同区域,没有线性变化关系,显示两者不是同一岩浆结晶分异演化形成的,而为不同沉积变质岩部分熔融形成的。白云母花岗斑岩脉富Al_2O_3、K_2O、Rb、Cs、Sn、W、Nb和Ta,在Rb/Ba-Rb/Sr图上位于富粘土源区,为强风化作用形成的富粘土质富稀有金属源区部分熔融形成的产物。华南西部基底发育经强风化作用形成的富粘土质富稀有金属元素沉积变质源区,为华南西南缘大规模锡矿床的形成提供了物质基础。  相似文献   

Palaeomagnetism of the Lower Cretaceous Sierra De Los Condores Group Cordoba Province Argentina     

Juan F. A.  Vilas 《Geophysical Journal International》1976,46(2):295-305

Measurements are described of the directions of remanent magnetization of 89 samples from nine lava flows and red beds. Stable remanent magnetization was isolated after AC demagnetizing. All the units have normal remanent magnetization, except one lava flow which yields a direction toward the north with positive inclination. From the mean direction of stable remanence, referred to the bedding, of each unit a virtual geomagnetic pole is computed; the mean of eight of these poles is 90·6 °E, 84·2° South, α₉₅= 4·7° and represents the position of the palaeomagnetic pole for the exposures of the Sierra de Los Condores group from El Estrecho-Cerro Libertad. The position of this pole is reasonably close to the positions of the South American Lower Cretaceous palaeomagnetic poles for the Serra Geral and Vulcanitas Cerro Colorado formations and the trachybasaltic dykes from Rio Los Molinos. This supports the interpretations that the South Atlantic Ocean was formed in Lower Cretaceous times and that the Earth's magnetic field was on average similar to that of a geocentric dipole in South America in the Lower Cretaceous, and suggests that there has not been substantial relative movements between Central Argentina and Southern Brazil.  相似文献   

A paleoenvironmental reconstruction of Laguna Babícora, Chihuahua, Mexico based on ostracode paleoecology and trace element shell chemistry     

Manuel R. Palacios-Fest  Ana Luisa Carreño  José R. Ortega-Ramírez  Guillermo Alvarado-Valdéz 《Journal of Paleolimnology》2002,27(2):185-206

Paleoecology of Laguna Babícora, Chihuahua, Mexico was reconstructed using ostracode faunal assemblages and shell chemistry. The paleolimnological record is used to show the magnitude of paleoclimatic changes in the area from 25,000 years to the present.Faunal assemblages consist of four species of the genus Limnocythere: L. sappaensis, L. ceriotuberosa, L. bradburyi and L. platyforma, all associated with Candona caudata, Candona patzcuaro and Cypridopsis vidua. A paleosalinity index developed from these assemblages indicates that the lake's salinity fluctuated frequently from oligo- to meso-haline conditions during the last 25,000 years. This pattern and low salinity range are in good agreement with modern TDS (here used as an indicator of salinity) values recorded from 26 wells and one spring from the area (258–975 mg l^–1). To estimate paleotemperature we examined the trace element content (Mg/Ca ratios) from individual valves of L. ceriotuberosa and L. platyforma, the two species most commonly recorded in Laguna Babícora.Shell Mg/Ca ratios of 204 specimens of these two species were used to estimate water temperature (Mg/Ca) by means of experimental standard coefficients. Our data show that paleowater temperature ranged from 5.6–21.3 °C (with 2 values ranging from 0.2–4.8 °C), which suggest a close correlation with atmospheric temperatures around the lake. These results are in good agreement with a modern mean winter temperature (3.5 °C) and mean summer temperature (20 °C) recorded in the area between 1970 and 1980.  相似文献   

Conceptual problems with remote element synthesis     

O. K. Manuel 《Journal of Earth System Science》2000,109(1):195-203

The notion of remote element synthesis has recently been modified to explain the presence of nucleogenetic isotopic anomalies and decay products of short-lived nuclides by injection of a small amount ofexotic nucleogenetic material. Even with this modification, remote element synthesis seems inconsistent with the following observations:

–	Evidence of coupled variations in the chemical and isotopic compositions of the source material for meteorites.
–	Residual coupling of chemical and isotopic heterogeneities across planetary distances in the solar system today.
–	The mass-fractionation relationship seen across isotopes of elements in the planetary system, in the solar wind, and in solar flares.
–	Linkage of short-lived radioactivities with isotopic anomalies and with physical properties of their host grains, as expected for early condensate of fresh stellar debris.
–	Temporal and spatial distributions of short-live nuclides and their decay products.
–	Mirror-image (+ and −) isotopic anomalies in meteorite grains that sum to “normal” isotopic ratios, as expected of unmixed products of the same nuclear reactions that produced our bulk elements.
–	The lac supporting evidence for “presolar” grains or nearby stars that injectedexotic material into the early solar nebula.

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Going quantitative with 4D seismic analysis   总被引：1，自引：0，他引：1  

Colin MacBeth  Mariano Floricich  Juan Soldo 《Geophysical Prospecting》2006,54(3):303-317

It is demonstrated that time‐lapse seismic signatures can be directly calibrated with historical data from producing and injecting wells via a reservoir simulator, material balance calculation or simply using the hard data. When this procedure is applied to a field over which two or more repeat surveys have been shot at different calendar times, the correlation coefficients that link the seismic difference signatures to the reservoir's pressure and saturation variations are determined. By utilizing several seismic attributes that respond differently to reservoir perturbations, pressure and saturation changes are then independently estimated. The approach is tested on synthetic data and then on data from the Schiehallion Field on the UK continental shelf, with favourable results.  相似文献   

Reliability of rayleigh wave dispersion curve obtained from f–k spectral analysis of microtremor array measurement     

Juan C. Tokeshi  Madan B. Karkee  Yoshihiro Sugimura 《Soil Dynamics and Earthquake Engineering》2006,26(2-4):163-174

The paper utilizes previously developed microtremor simulation technique to evaluate the reliability of Rayleigh wave dispersion curve estimated by f–k spectral analysis of microtremor array measurement. The simulated microtremors are obtained for a fictitious (TEST) site. Attempt is also made to obtain the dispersion curve for two real sites (OHDATE and SKC) by inverse analysis of the microtremor array measurement using f–k spectra method. The estimated dispersion curve from simulated microtremors (TEST site) compares well with the theoretical dispersion curve, demonstrating the reliability of f–k spectra method and indicating that the estimated dispersion curve from microtremor measurements could be adequately used as the target for inverse analysis purposes. It is also demonstrated that the dispersion curve from microtremor measurements can be utilized to estimate the soil profile at OHDATE and SKC sites by inverse analysis. Results show that the theoretical dispersion curve of the fundamental mode of Rayleigh wave after the end of inverse analysis are in good agreement with the dispersion curve obtained by f–k spectral analysis of microtremor array measurement.  相似文献