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Haoran Ma Yihe Xu Kangjun Huang Yuanlin Sun Shan Ke Yang Peng Xianguo Lang Zhen Yan Bing Shen 《中国地球化学学报》2018,37(1):1-18
Carbonate precipitation and hydrothermal reaction are the two major processes that remove Mg from seawater. Mg isotopes are significantly (up to 5‰) fractionated during carbonate precipitation by preferential incorporation of 24Mg, while hydrothermal reactions are associated with negligible Mg isotope fractionation by preferential sequestration of 26Mg. Thus, the marine Mg cycle could be reflected by seawater Mg isotopic composition (δ26Mgsw), which might be recorded in marine carbonate. However, carbonates are both texturally and compositionally heterogeneous, and it is unclear which carbonate component is the most reliable for reconstructing δ26Mgsw. In this study, we measured Mg isotopic compositions of limestone samples collected from the early Carboniferous Huangjin Formation in South China. Based on petrographic studies, four carbonate components were recognized: micrite, marine cement, brachiopod shell, and mixture. The four components had distinct δ26Mg: (1) micrite samples ranged from ?2.86‰ to ?2.97‰; (2) pure marine cements varied from ?3.40‰ to ?3.54‰, while impure cement samples containing small amount of Rugosa coral skeletons showed a wider range (?3.27‰ to ?3.75‰); (3) values for the mixture component were ?3.17‰ and ?3.49‰; and (4) brachiopod shells ranged from ?2.20‰ to ?3.07‰, with the thickened hinge area enriched in 24Mg. Due to having multiple carbonate sources, neither the micrite nor the mixture component could be used to reconstruct δ26Mgsw. In addition, the marine cement was homogenous in Mg isotopes, but lacking the fractionation by inorganic carbonate precipitation that is prerequisite for the accurate determination of δ26Mgsw. Furthermore, brachiopod shells had heterogeneous C and Mg isotopes, suggesting a significant vital effect during growth. Overall, the heterogeneous δ26Mg of the Huangjin limestone makes it difficult to reconstruct δ26Mgsw using bulk carbonate/calcareous sediments. Finally, δ26Mgsw was only slightly affected by the faunal composition of carbonate-secreting organisms, even though biogenic carbonate accounts for more than 90% of marine carbonate production in Phanerozoic oceans and there is a wide range (0.2‰–4.8‰) of fractionation during biogenic carbonate formation. 相似文献
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Lin Zou Lin Dong Meng Ning Kangjun Huang Yongbo Peng Shujian Qin Honglin Yuan Bing Shen 《Acta Geochimica》2019,(4):481-496
The continent is the second largest carbon sink on Earth’s surface.With the diversification of vascular land plants in the late Paleozoic,terrestrial organic carbon burial is represented by massive coal formation,while the development of soil profiles would account for both organic and inorganic carbon burial.As compared with soil organic carbon,inorganic carbon burial,collectively known as the soil carbonate,would have a greater impact on the long-term carbon cycle.Soil carbonate would have multiple carbon sources,including dissolution of host calcareous rocks,dissolved inorganic carbon from freshwater,and oxidation of organic matter,but the host calcareous rock dissolution would not cause atmospheric CO2drawdown.Thus,to evaluate the potential effect of soil carbonate formation on the atmospheric p CO2level,different carbon sources of soil carbonate should be quantitatively differentiated.In this study,we analyzed the carbon and magnesium isotopes of pedogenic calcite veins developed in a heavily weathered outcrop,consisting of limestone of the early Paleogene Guanzhuang Group in North China.Based on the C and Mg isotope data,we developed a numerical model to quantify the carbon source of calcite veins.The modeling results indicate that4–37 wt%of carbon in these calcite veins was derived from atmospheric CO2.The low contribution from atmospheric CO2might be attributed to the host limestone that might have diluted the atmospheric CO2sink.Nevertheless,taking this value into consideration,it is estimated that soil carbonate formation would lower 1 ppm atmospheric CO2within 2000 years,i.e.,soil carbonate alone would sequester all atmospheric CO2within 1 million years.Finally,our study suggests the C–Mg isotope system might be a better tool in quantifying the carbon source of soil carbonate. 相似文献
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CAS-ESM2.0 Model Datasets for the CMIP6 Ocean Model Intercomparison Project Phase 1(OMIP1) 总被引：2，自引：2，他引：0
Xiao DONG Jiangbo JIN Hailong LIU He ZHANG Minghua ZHANG Pengfei LIN Qingcun ZENG Guangqing ZHOU Yongqiang YU Mirong SONG Zhaohui LIN Ruxu LIAN Xin GAO Juanxiong HE Dongling ZHANG Kangjun CHEN 《大气科学进展》2021,38(2):307-316
As a member of the Chinese modeling groups,the coupled ocean-ice component of the Chinese Academy of Sciences’Earth System Model,version 2.0(CAS-ESM2.0),is taking part in the Ocean Model Intercomparison Project Phase 1(OMIP1)experiment of phase 6 of the Coupled Model Intercomparison Project(CMIP6).The simulation was conducted,and monthly outputs have been published on the ESGF(Earth System Grid Federation)data server.In this paper,the experimental dataset is introduced,and the preliminary performances of the ocean model in simulating the global ocean temperature,salinity,sea surface temperature,sea surface salinity,sea surface height,sea ice,and Atlantic Meridional Overturning Circulation(AMOC)are evaluated.The results show that the model is at quasi-equilibrium during the integration of 372 years,and performances of the model are reasonable compared with observations.This dataset is ready to be downloaded and used by the community in related research,e.g.,multi-ocean-sea-ice model performance evaluation and interannual variation in oceans driven by prescribed atmospheric forcing. 相似文献
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为探究层状地基环形沟隔振中几何参数对其隔振效果的影响规律,文章采用振幅衰减比Ar值进行评价分析,并定义沟后Ar≤0.4区域为有效隔振区域,通过改变环形沟的几何参数,得到其对有效隔振区域影响变化规律,从而确定环形沟不同几何参数对其隔振效果的影响。结果表明：层状地基土中环形沟深度位于土层分界面附近时,环形沟隔振效果相对较弱;当宽度参数在0.01~0.35之间不断增大时,有效隔振区域占比变化幅度仅为4.8%,即环形沟宽度变化对环形沟隔振效果影响较小;随着环形沟弧长的增加,有效隔振区域面积的扩大速率减缓,弧长参数达到2.20以后,隔振效果趋于稳定;振源与环形沟之间及环形沟末端位置区域存在振动放大区。 相似文献
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利用设置在中国气象局寿县国家气候观象台2017年全年的太阳-天空辐射计CE318数据,对当地一年四季气溶胶光学和微物理特征进行分析。结果表明:春季气溶胶光学厚度最高,夏季和秋季最为接近,也最低,冬季介于夏、秋季之间;AE数据集中在0.9～1.5,以细模态粒子为主;四季的气溶胶体积谱分布基本相似,且既有细模态粒子,也有粗模态粒子;夏季气溶胶折射率实部最小,说明当地夏季水汽含量最大,实部与光谱波长没有明显关系,而虚部则有;单次散射反照率均在80%以上,气溶胶散射效应明显;非球形粒子占主要支配地位且在春季数量最多。研究结果对于掌握淮河流域中部区域气溶胶特征,及其对大气辐射、气候变化的影响,监测空气质量,以及提高我国该特定区域大气辐射传输模型计算精度有重要意义。 相似文献
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初步探讨了利用高盐抑制受精卵第2极体(PB2)的释放的方法诱导太平洋牡蛎(Crassostrea gigas)三倍体。水温25℃条件下,分别进行不同高盐处理(盐度梯度为40、45、50、55、60、65、70、75、80)、不同处理时机(受精卵出现第一个PB1,30%和50%PB1,出现第一个PB2,50%PB2)和不同持续处理时间(10~25min)的实验,通过胚胎孵化率、三倍体诱导率及综合评价指数的分析表明,高盐诱导太平洋牡蛎三倍体的最适方案为:当50%受精卵出第一极体时,以盐度为65的高盐海水处理受精卵20min,三倍体诱导率最高达65.53%。 相似文献
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基于压汞实验研究低渗储层孔隙结构及其对渗透率的影响——以鄂尔多斯盆地西南部三叠系延长组长7储层为例 总被引：6，自引：0，他引：6
压汞是研究孔隙结构的有效岩石物理学方法,毛管压力曲线能为我们提供多孔介质孔隙结构的大量信息。本文对鄂尔多斯盆地西南部三叠系延长组长7低渗储层的20个样品进行了压汞测试。主要从毛管压力曲线形态特征、孔喉分布特征、孔隙结构分形特征三个方面对储层的微观孔隙结构进行了深入研究。在此基础上,运用逐步回归法分析了孔喉参数对储层渗透率的影响。结果表明最大渗透率贡献半径对储层渗透率的影响最为显著,分选系数、孔喉均值和歪度也是影响储层渗透率的重要因素。并且发现,对于同一岩样,由双曲线顶点确定的半径值总是接近于但略小于对渗透率贡献最大的半径值。最后,讨论了运用逐步回归法优选出的四个孔喉参数对储层渗透率的影响,并对其它可能影响渗透率的因素作了有益探讨。 相似文献